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The year 1877 in science and technology involved some significant events, listed below.
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Ludwig Eduard Boltzmann was an Austrian physicist and philosopher. His greatest achievements were the development of statistical mechanics, and the statistical explanation of the second law of thermodynamics. In 1877 he provided the current definition of entropy, , where Ω is the number of microstates whose energy equals the system's energy, interpreted as a measure of the statistical disorder of a system. Max Planck named the constant kB the Boltzmann constant.
The Peirce quincuncial projection is the conformal map projection from the sphere to an unfolded square dihedron, developed by Charles Sanders Peirce in 1879. Each octant projects onto an isosceles right triangle, and these are arranged into a square. The name quincuncial refers to this arrangement: the north pole at the center and quarters of the south pole in the corners form a quincunx pattern like the pips on the five face of a traditional die. The projection has the distinctive property that it forms a seamless square tiling of the plane, conformal except at four singular points along the equator.
In statistical mechanics, Boltzmann's equation is a probability equation relating the entropy , also written as , of an ideal gas to the multiplicity, the number of real microstates corresponding to the gas's macrostate: