Hollow-cathode lamp

Last updated
Basic diagram of a hollow-cathode lamp Hollow Cathode Lamp.svg
Basic diagram of a hollow-cathode lamp
Hollow-cathode lamps from an atomic absorption spectrometer Hollow cathode lamp.JPG
Hollow-cathode lamps from an atomic absorption spectrometer

A hollow-cathode lamp (HCL) is type of cold cathode lamp used in physics and chemistry as a spectral line source (e.g. for atomic absorption spectrometers) and as a frequency tuner for light sources such as lasers. An HCL takes advantage of the hollow cathode effect, which causes conduction at a lower voltage and with more current than a cold cathode lamp that does not have a hollow cathode. [1]

An HCL usually consists of a glass tube containing a cathode, an anode, and a buffer gas (usually a noble gas). A large voltage across the anode and cathode will cause the buffer gas to ionize, creating a plasma. The buffer gas ions will then be accelerated into the cathode, sputtering off atoms from the cathode. Both the buffer gas and the sputtered cathode atoms will in turn be excited by collisions with other atoms/particles in the plasma. As these excited atoms decay to lower states, they will emit photons. These photons will then excite the atoms in the sample, which will release their own photons and be used to generate data. [2]

An HCL can also be used to tune light sources to a specific atomic transition by making use of the optogalvanic effect, which is a result of direct or indirect photoionization. By shining the light source into the HCL, one can excite or even eject electrons (directly photoionize) from the atoms inside the lamp, so long as the light source includes frequencies corresponding to the right atomic transitions. Indirect photoionization can then occur when electron collisions with the excited atom eject an atomic electron.

= atom, = photon, = atom in excited state, and = electron

The newly created ions cause an increase in the current across the cathode/anode and a resulting change in the voltage, which can then be measured.

To tune the light source to a specific transition frequency, a tuning parameter (often the driving current) of the light source is varied. By looking for a resonance on a data plot of the voltage signal versus source tuning parameter, the light source can be tuned to the desired frequency. This is often aided by use of a lock-in circuit.

The power supply current range is 0 to 25mA and a 600V ignition followed with 300V sustained power.

See also

Related Research Articles

<span class="mw-page-title-main">Atomic absorption spectroscopy</span> Type of spectroanalytical ciao

Atomic absorption spectroscopy (AAS) and atomic emission spectroscopy (AES) is a spectroanalytical procedure for the quantitative determination of chemical elements by free atoms in the gaseous state. Atomic absorption spectroscopy is based on absorption of light by free metallic ions.

<span class="mw-page-title-main">Photoelectric effect</span> Emission of electrons when light hits a material

The photoelectric effect is the emission of electrons from a material caused by electromagnetic radiation such as ultraviolet light. Electrons emitted in this manner are called photoelectrons. The phenomenon is studied in condensed matter physics, solid state, and quantum chemistry to draw inferences about the properties of atoms, molecules and solids. The effect has found use in electronic devices specialized for light detection and precisely timed electron emission.

In physics, specifically statistical mechanics, a population inversion occurs while a system exists in a state in which more members of the system are in higher, excited states than in lower, unexcited energy states. It is called an "inversion" because in many familiar and commonly encountered physical systems, this is not possible. This concept is of fundamental importance in laser science because the production of a population inversion is a necessary step in the workings of a standard laser.

Spontaneous emission is the process in which a quantum mechanical system transits from an excited energy state to a lower energy state and emits a quantized amount of energy in the form of a photon. Spontaneous emission is ultimately responsible for most of the light we see all around us; it is so ubiquitous that there are many names given to what is essentially the same process. If atoms are excited by some means other than heating, the spontaneous emission is called luminescence. For example, fireflies are luminescent. And there are different forms of luminescence depending on how excited atoms are produced. If the excitation is effected by the absorption of radiation the spontaneous emission is called fluorescence. Sometimes molecules have a metastable level and continue to fluoresce long after the exciting radiation is turned off; this is called phosphorescence. Figurines that glow in the dark are phosphorescent. Lasers start via spontaneous emission, then during continuous operation work by stimulated emission.

<span class="mw-page-title-main">Stimulated emission</span> Release of a photon triggered by another

Stimulated emission is the process by which an incoming photon of a specific frequency can interact with an excited atomic electron, causing it to drop to a lower energy level. The liberated energy transfers to the electromagnetic field, creating a new photon with a frequency, polarization, and direction of travel that are all identical to the photons of the incident wave. This is in contrast to spontaneous emission, which occurs at a characteristic rate for each of the atoms/oscillators in the upper energy state regardless of the external electromagnetic field.

<span class="mw-page-title-main">Ionization</span> Process by which atoms or molecules acquire charge by gaining or losing electrons

Ionization is the process by which an atom or a molecule acquires a negative or positive charge by gaining or losing electrons, often in conjunction with other chemical changes. The resulting electrically charged atom or molecule is called an ion. Ionization can result from the loss of an electron after collisions with subatomic particles, collisions with other atoms, molecules, electrons, positrons, protons, antiprotons and ions, or through the interaction with electromagnetic radiation. Heterolytic bond cleavage and heterolytic substitution reactions can result in the formation of ion pairs. Ionization can occur through radioactive decay by the internal conversion process, in which an excited nucleus transfers its energy to one of the inner-shell electrons causing it to be ejected.

<span class="mw-page-title-main">Emission spectrum</span> Frequencies of light emitted by atoms or chemical compounds

The emission spectrum of a chemical element or chemical compound is the spectrum of frequencies of electromagnetic radiation emitted due to electrons making a transition from a high energy state to a lower energy state. The photon energy of the emitted photons is equal to the energy difference between the two states. There are many possible electron transitions for each atom, and each transition has a specific energy difference. This collection of different transitions, leading to different radiated wavelengths, make up an emission spectrum. Each element's emission spectrum is unique. Therefore, spectroscopy can be used to identify elements in matter of unknown composition. Similarly, the emission spectra of molecules can be used in chemical analysis of substances.

<span class="mw-page-title-main">Ion source</span> Device that creates charged atoms and molecules (ions)

An ion source is a device that creates atomic and molecular ions. Ion sources are used to form ions for mass spectrometers, optical emission spectrometers, particle accelerators, ion implanters and ion engines.

<span class="mw-page-title-main">Franck–Hertz experiment</span> 1914 confirmation of the quantum nature of atoms

The Franck–Hertz experiment was the first electrical measurement to clearly show the quantum nature of atoms, and thus "transformed our understanding of the world". It was presented on April 24, 1914, to the German Physical Society in a paper by James Franck and Gustav Hertz. Franck and Hertz had designed a vacuum tube for studying energetic electrons that flew through a thin vapor of mercury atoms. They discovered that, when an electron collided with a mercury atom, it could lose only a specific quantity of its kinetic energy before flying away. This energy loss corresponds to decelerating the electron from a speed of about 1.3 million metres per second to zero. A faster electron does not decelerate completely after a collision, but loses precisely the same amount of its kinetic energy. Slower electrons merely bounce off mercury atoms without losing any significant speed or kinetic energy.

<span class="mw-page-title-main">Flashtube</span> Incoherent light source

A flashtube (flashlamp) is an gas-discharge lamp designed to produce extremely intense, incoherent, full-spectrum white light for a very short time. A flashtube is a glass tube with an electrode at each end and is filled with a gas that, when triggered, ionizes and conducts a high-voltage pulse to make light. Flashtubes are used most in photography; they also are used in science, medicine, industry, and entertainment.

<span class="mw-page-title-main">Gas-filled tube</span> Assembly of electrodes at either end of an insulated tube filled with gas

A gas-filled tube, also commonly known as a discharge tube or formerly as a Plücker tube, is an arrangement of electrodes in a gas within an insulating, temperature-resistant envelope. Gas-filled tubes exploit phenomena related to electric discharge in gases, and operate by ionizing the gas with an applied voltage sufficient to cause electrical conduction by the underlying phenomena of the Townsend discharge. A gas-discharge lamp is an electric light using a gas-filled tube; these include fluorescent lamps, metal-halide lamps, sodium-vapor lamps, and neon lights. Specialized gas-filled tubes such as krytrons, thyratrons, and ignitrons are used as switching devices in electric devices.

<span class="mw-page-title-main">Photoemission spectroscopy</span> Examining a substance by measuring electrons emitted in the photoelectric effect

Photoemission spectroscopy (PES), also known as photoelectron spectroscopy, refers to energy measurement of electrons emitted from solids, gases or liquids by the photoelectric effect, in order to determine the binding energies of electrons in the substance. The term refers to various techniques, depending on whether the ionization energy is provided by X-ray, XUV or UV photons. Regardless of the incident photon beam, however, all photoelectron spectroscopy revolves around the general theme of surface analysis by measuring the ejected electrons.

<span class="mw-page-title-main">Glow discharge</span> Plasma formed by passage of current through gas

A glow discharge is a plasma formed by the passage of electric current through a gas. It is often created by applying a voltage between two electrodes in a glass tube containing a low-pressure gas. When the voltage exceeds a value called the striking voltage, the gas ionization becomes self-sustaining, and the tube glows with a colored light. The color depends on the gas used.

<span class="mw-page-title-main">Induction lamp</span> Gas-discharge lamp using electric and magnetic fields to transfer energy to the gas inside

The induction lamp, electrodeless lamp, or electrodeless induction lamp is a gas-discharge lamp in which an electric or magnetic field transfers the power required to generate light from outside the lamp envelope to the gas inside. This is in contrast to a typical gas discharge lamp that uses internal electrodes connected to the power supply by conductors that pass through the lamp envelope. Eliminating the internal electrodes provides two advantages:

<span class="mw-page-title-main">Einstein coefficients</span> Quantities describing probability of absorption or emission of light

In atomic, molecular, and optical physics, the Einstein coefficients are quantities describing the probability of absorption or emission of a photon by an atom or molecule. The Einstein A coefficients are related to the rate of spontaneous emission of light, and the Einstein B coefficients are related to the absorption and stimulated emission of light. Throughout this article, "light" refers to any electromagnetic radiation, not necessarily in the visible spectrum.

<span class="mw-page-title-main">Magneto-optical trap</span> Apparatus for trapping and cooling neutral atoms

In atomic, molecular, and optical physics, a magneto-optical trap (MOT) is an apparatus which uses laser cooling and a spatially-varying magnetic field to create a trap which can produce samples of cold, neutral atoms. Temperatures achieved in a MOT can be as low as several microkelvin, depending on the atomic species, which is two or three times below the photon recoil limit. However, for atoms with an unresolved hyperfine structure, such as 7Li, the temperature achieved in a MOT will be higher than the Doppler cooling limit.

Resonance fluorescence is the process in which a two-level atom system interacts with the quantum electromagnetic field if the field is driven at a frequency near to the natural frequency of the atom.

Photoelectrochemical processes are processes in photoelectrochemistry; they usually involve transforming light into other forms of energy. These processes apply to photochemistry, optically pumped lasers, sensitized solar cells, luminescence, and photochromism.

An excimer lamp is a source of ultraviolet light based on spontaneous emission of excimer (exciplex) molecules.

The hollow cathode effect allows electrical conduction at a lower voltage or with more current in a cold-cathode gas-discharge lamp when the cathode is a conductive tube open at one end than a similar lamp with a flat cathode. The hollow cathode effect was recognized by Friedrich Paschen in 1916.

References

  1. Eichhorn, H.; Schoenbach, K. H.; Tessnow, T. (1993). "Paschen's law for a hollow cathode discharge" (PDF). Applied Physics Letters. 63 (18): 2481–2483. Bibcode:1993ApPhL..63.2481E. doi:10.1063/1.110455. ISSN   0003-6951. Archived from the original (PDF) on August 8, 2017. Retrieved June 5, 2017.
  2. Analytical Methods for Atomic Absorption Spectrometry (Release E (2000) ed.). Perkin Elmer, Inc. 1964–2000. pp. 6–9.