Reprocessed uranium

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Reprocessed uranium (RepU) is the uranium recovered from nuclear reprocessing, as done commercially in France, the UK and Japan and by nuclear weapons states' military plutonium production programs. This uranium makes up the bulk of the material separated during reprocessing.

Commercial LWR spent nuclear fuel contains on average (excluding cladding) only four percent plutonium, minor actinides and fission products by weight. Despite it often containing more fissile material than natural uranium, reuse of reprocessed uranium has not been common because of low prices in the uranium market of recent decades, and because it contains undesirable isotopes of uranium.

Isotopic composition of reprocessed uranium [1]
IsotopeProportionCharacteristics
uranium-238 98.5% Fertile material
uranium-237 0%Around 0.001% at discharge, but half-life only 1 week. Produces soluble, long-lived neptunium-237 which is hard to contain in a geological repository. 237
Np
is the feedstock for the production of 238
Pu
which is used in radioisotope thermoelectric generators
uranium-236 0.4–0.6%Neither fissile nor fertile. Affects reactivity.
uranium-235 0.5–1.0% Fissile material
uranium-234 >0.02%Fertile material but can affect reactivity differently [2]
uranium-233 traceFissile material
uranium-232 traceFertile material, decay product thallium-208 emits strong gamma radiation making handling difficult

Given sufficiently high uranium prices, it is feasible for reprocessed uranium to be re-enriched and reused. A higher enrichment level is required to compensate for the 236U which is lighter than 238U and therefore concentrates in the enriched product. [3] As enrichment concentrates lighter isotopes on the "enriched" side and heavier isotopes on the "depleted" side, 234
U
will inevitably be enriched slightly stronger than 235
U
, which is a negligible effect in a once through fuel cycle due to the low (55 ppm) share of 234
U
in natural uranium but can become relevant after successive passes through an enrichment-burnup-reprocessing-enrichment cycle, depending on enrichment and burnup characteristics. 234
U
readily absorbs thermal neutrons and converts to fissile 235
U
which needs to be taken into account if it reaches significant proportions of the fuel material. If 235
U
interacts with a fast neutron there is a chance of a (n,2n) "knockout" reaction. Depending on the characteristics of the reactor and burnup, this can be a larger source of 234
U
in spent fuel than enrichment. Also, if fast breeder reactors ever come into commercial use, reprocessed uranium, like depleted uranium, will be usable in their breeding blankets.

There have been some studies involving the use of reprocessed uranium in CANDU reactors. CANDU is designed to use natural uranium as fuel; the 235U content remaining in spent PWR/BWR fuel is typically greater than that found in natural uranium, which is about 0.72% 235U, allowing the re-enrichment step to be skipped. Fuel cycle tests also have included the DUPIC (Direct Use of spent PWR fuel In CANDU) fuel cycle, where used fuel from a Pressurized Water Reactor (PWR) is packaged into a CANDU fuel bundle with only physical reprocessing (cut into pieces) but no chemical reprocessing. [4] Opening the cladding inevitably releases volatile fission products like xenon, tritium or krypton-85. Some variations of the DUPIC fuel cycle make deliberate use of this by including a voloxidation step whereby the fuel is heated to drive off semi-volatile fission products and/or subjected to one or more reduction / oxidation cycles to transform nonvolatile oxides into volatile native elements and vice versa.

The direct use of recovered uranium to fuel a CANDU reactor was first demonstrated at Qinshan Nuclear Power Plant in China. [5] The first use of re-enriched uranium in a commercial LWR was in 1994 at the Cruas Nuclear Power Plant in France. [6] [7]

In 2020 France, one of the countries with the biggest reprocessing capacity, held a stock of 40,020 tonnes (39,390 long tons; 44,110 short tons) of reprocessed uranium, up from 24,100 tonnes (23,700 long tons; 26,600 short tons) in 2010. [8] Every year France processes 1,100 tonnes (1,100 long tons; 1,200 short tons) of spent fuel into 11 tonnes (11 long tons; 12 short tons) reactor grade plutonium (for immediate further processing into MOX fuel) and 1,045 tonnes (1,028 long tons; 1,152 short tons) of reprocessed uranium which is largely stockpiled. There are provisions in place for the storage of this reprocessed uranium for up to 250 years for potential future use. [9] Given France's domestic uranium enrichment capabilities, this stockpile constitutes a strategic reserve for the case of a major disruption of uranium supply as France does not have domestic uranium mining.

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<span class="mw-page-title-main">Pressurized water reactor</span> Type of nuclear reactor

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<span class="mw-page-title-main">Nuclear fuel cycle</span> Process of manufacturing and consuming nuclear fuel

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<span class="mw-page-title-main">Uranium-238</span> Isotope of uranium

Uranium-238 is the most common isotope of uranium found in nature, with a relative abundance of 99%. Unlike uranium-235, it is non-fissile, which means it cannot sustain a chain reaction in a thermal-neutron reactor. However, it is fissionable by fast neutrons, and is fertile, meaning it can be transmuted to fissile plutonium-239. 238U cannot support a chain reaction because inelastic scattering reduces neutron energy below the range where fast fission of one or more next-generation nuclei is probable. Doppler broadening of 238U's neutron absorption resonances, increasing absorption as fuel temperature increases, is also an essential negative feedback mechanism for reactor control.

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A fast-neutron reactor (FNR) or fast-spectrum reactor or simply a fast reactor is a category of nuclear reactor in which the fission chain reaction is sustained by fast neutrons, as opposed to slow thermal neutrons used in thermal-neutron reactors. Such a fast reactor needs no neutron moderator, but requires fuel that is relatively rich in fissile material when compared to that required for a thermal-neutron reactor. Around 20 land based fast reactors have been built, accumulating over 400 reactor years of operation globally. The largest of this was the Superphénix Sodium cooled fast reactor in France that was designed to deliver 1,242 MWe. Fast reactors have been intensely studied since the 1950s, as they provide certain decisive advantages over the existing fleet of water cooled and water moderated reactors. These are:

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<span class="mw-page-title-main">Plutonium-239</span> Isotope of plutonium

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Uranium (92U) is a naturally occurring radioactive element that has no stable isotope. It has two primordial isotopes, uranium-238 and uranium-235, that have long half-lives and are found in appreciable quantity in the Earth's crust. The decay product uranium-234 is also found. Other isotopes such as uranium-233 have been produced in breeder reactors. In addition to isotopes found in nature or nuclear reactors, many isotopes with far shorter half-lives have been produced, ranging from 214U to 242U. The standard atomic weight of natural uranium is 238.02891(3).

<span class="mw-page-title-main">Weapons-grade nuclear material</span> Nuclear material pure enough to be used for nuclear weapons

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Uranium-236 (236U) is an isotope of uranium that is neither fissile with thermal neutrons, nor very good fertile material, but is generally considered a nuisance and long-lived radioactive waste. It is found in spent nuclear fuel and in the reprocessed uranium made from spent nuclear fuel.

In nuclear power technology, burnup is a measure of how much energy is extracted from a primary nuclear fuel source. It is measured as the fraction of fuel atoms that underwent fission in %FIMA or %FIFA as well as, preferably, the actual energy released per mass of initial fuel in gigawatt-days/metric ton of heavy metal (GWd/tHM), or similar units.

Reactor-grade plutonium (RGPu) is the isotopic grade of plutonium that is found in spent nuclear fuel after the uranium-235 primary fuel that a nuclear power reactor uses has burnt up. The uranium-238 from which most of the plutonium isotopes derive by neutron capture is found along with the U-235 in the low enriched uranium fuel of civilian reactors.

Peak uranium is the point in time that the maximum global uranium production rate is reached. After that peak, according to Hubbert peak theory, the rate of production enters a terminal decline. While uranium is used in nuclear weapons, its primary use is for energy generation via nuclear fission of the uranium-235 isotope in a nuclear power reactor. Each kilogram of uranium-235 fissioned releases the energy equivalent of millions of times its mass in chemical reactants, as much energy as 2700 tons of coal, but uranium-235 accounts for only 0.7% of the mass of natural uranium. While Uranium-235 can be "bred" from 234
U
, a natural decay product of 238
U
present at 55 ppm in all natural uranium samples, Uranium-235 is ultimately a finite non-renewable resource. Due to the currently low price of uranium, the majority of commercial light water reactors operate on a "once through fuel cycle" which leaves virtually all the energy contained in the original 238
U
- which makes up over 99% of natural uranium - unused. Nuclear reprocessing is a technology currently used at industrial scale in France, Russia and Japan, which can recover part of that energy by producing MOX fuel or Remix Fuel for use in conventional power generating light water reactors. However, at current uranium prices, this is widely deemed uneconomical if only the "input" side is considered.

<span class="mw-page-title-main">Traveling wave reactor</span> Type of nuclear fission reactor

A traveling-wave reactor (TWR) is a proposed type of nuclear fission reactor that can convert fertile material into usable fuel through nuclear transmutation, in tandem with the burnup of fissile material. TWRs differ from other kinds of fast-neutron and breeder reactors in their ability to use fuel efficiently without uranium enrichment or reprocessing, instead directly using depleted uranium, natural uranium, thorium, spent fuel removed from light water reactors, or some combination of these materials. The concept is still in the development stage and no TWRs have ever been built.

A pressurized heavy-water reactor (PHWR) is a nuclear reactor that uses heavy water (deuterium oxide D2O) as its coolant and neutron moderator. PHWRs frequently use natural uranium as fuel, but sometimes also use very low enriched uranium. The heavy water coolant is kept under pressure to avoid boiling, allowing it to reach higher temperature (mostly) without forming steam bubbles, exactly as for pressurized water reactor. While heavy water is very expensive to isolate from ordinary water (often referred to as light water in contrast to heavy water), its low absorption of neutrons greatly increases the neutron economy of the reactor, avoiding the need for enriched fuel. The high cost of the heavy water is offset by the lowered cost of using natural uranium and/or alternative fuel cycles. As of the beginning of 2001, 31 PHWRs were in operation, having a total capacity of 16.5 GW(e), representing roughly 7.76% by number and 4.7% by generating capacity of all current operating reactors.

Remix Fuel was developed in Russia to make use of Mixed Recycled Uranium and Plutonium from spent nuclear fuel to manufacture fresh fuel suitable for widespread use in Russian reactor designs.

References

  1. "Processing of Used Nuclear Fuel". World Nuclear Association. 2013. Retrieved 2014-02-16.
  2. "Uranium from reprocessing". Archived from the original on 2007-10-19.
  3. "Advanced Fuel Cycle Cost Basis" (PDF). Idaho National Laboratory. Archived from the original (PDF) on 2009-01-24.
  4. "The Evolution of CANDU Fuel Cycles and Their Potential Contribution to World Peace". DUPIC.
  5. Use of CANDU fuel from spent light water reactor fuel at Qinshan nuclear power plant
  6. Framatome to supply EDF with reprocessed uranium fuel
  7. EDF plans to restart use of reprocessed uranium in some of its reactors [ permanent dead link ]
  8. "Recovered & depleted uranium stocks in France 2010-2030".
  9. "Processing of Used Nuclear Fuel - World Nuclear Association".

Further reading

Advanced Fuel Cycle Cost Basis - Idaho National Laboratory