Nuclear reactor coolant

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Nuclear reactor coolants
Coolant Melting point Boiling point
Heavy water at 154 bar345 °C
NaK eutectic-11 °C785 °C
Sodium 97.72 °C883 °C
FLiNaK 454 °C1570 °C
FLiBe 459 °C1430 °C
Lead 327.46 °C1749 °C
Lead-bismuth eutectic 123.5 °C1670 °C

A nuclear reactor coolant is a coolant in a nuclear reactor used to remove heat from the nuclear reactor core and transfer it to electrical generators and the environment. Frequently, a chain of two coolant loops are used because the primary coolant loop takes on short-term radioactivity from the reactor.

Contents

Water

Almost all currently operating nuclear power plants are light water reactors using ordinary water under high pressure as coolant and neutron moderator. About 1/3 are boiling water reactors where the primary coolant undergoes phase transition to steam inside the reactor. About 2/3 are pressurized water reactors at even higher pressure. Current reactors stay under the critical point at around 374 °C and 218 bar where the distinction between liquid and gas disappears, which limits thermal efficiency, but the proposed supercritical water reactor would operate above this point.

Heavy water reactors use deuterium oxide which has identical properties to ordinary water but much lower neutron capture, allowing more thorough moderation.

Disadvantages

Tritium leak

As the hydrogen atoms in water coolants are bombarded with neutrons, some absorb a neutron to become deuterium, and then some become radioactive tritium. Water contaminated with tritium sometimes leaks to groundwater by accident or by official approval. [1]

Hydrogen explosion

Fuel rods create high temperatures which boil water into steam. During a power outage, diesel power generators which provide emergency power to water pumps may be damaged by a tsunami, earthquake or both; if no fresh water is being pumped to cool the fuel rods then the fuel rods continue to heat up. Once the fuel rods reach more than 1200°C, the zirconium tubes that contain the nuclear fuel will interact with the steam and split hydrogen from water molecules. This hydrogen may leak from breaches in the reactor core and containment vessel. If hydrogen accumulates in sufficient quantities - concentrations of 4% or more in the air - then it can explode, as has apparently occurred at Fukushima Daiichi reactors No. 1, 3, and 4.

Such an explosion was avoided at Reactor No. 2, which opened its vent to let out hydrogen, decreasing pressure by releasing radioactive hydrogen gas. [2]

Borated water

Borated water is used as a coolant during normal operation of pressurized water reactors (PWRs) as well as in Emergency Core Cooling Systems (ECCS) of both PWRs and boiling water reactors (BWRs). [3] [4] [5]

Advantages

Boron, often in the form of boric acid or sodium borate, is combined with water — a cheap and plentiful resource — where it acts as a coolant to remove heat from the reactor core and transfers the heat to a secondary circuit. [6] Part of the secondary circuit is the steam generator that is used to turn turbines and generate electricity. Borated water also provides the additional benefits of acting as a neutron poison due to its large neutron absorption cross-section, where it absorbs excess neutrons to help control the fission rate of the reactor. Thus, the reactivity of the nuclear reactor can be easily adjusted by changing the boron concentration in the coolant. That is, when the boron concentration is increased (boration) by dissolving more boric acid into the coolant, the reactivity of the reactor is decreased. Conversely, when the boron concentration is decreased (dilution) by adding more water, the reactivity of the reactor is increased. [7]

Disadvantages

Approximately 90% of the tritium in PWR coolants is produced by reactions of boron-10 with neutrons. Since tritium itself is a radioactive isotope of hydrogen, the coolant becomes contaminated with radioactive isotopes and must be kept from leaking into the environment. Additionally, this effect must be taken into account for longer cycles of nuclear reactor operation and thus requires higher initial concentration of boron in the coolant. [7]

Molten metal

Fast reactors have a high power density and do not need, and must avoid, neutron moderation. Most have been liquid metal cooled reactors using molten sodium. Lead, lead-bismuth eutectic, and other metals have also been proposed and occasionally used. Mercury was used in the first fast reactor.

Molten salt

Molten salts share with metals the advantage of low vapor pressure even at high temperatures, and are less chemically reactive than sodium. Salts containing light elements like FLiBe can also provide moderation. In the Molten-Salt Reactor Experiment it even served as a solvent carrying the nuclear fuel.

Gas

Gases have also been used as coolant. Helium is extremely inert both chemically and with respect to nuclear reactions but has a low heat capacity,

Hydrocarbons

Organically moderated and cooled reactors were an early concept studied, using hydrocarbons as coolant. They were not successful.

Related Research Articles

<span class="mw-page-title-main">Nuclear reactor</span> Device used to initiate and control a nuclear chain reaction

A nuclear reactor is a device used to initiate and control a fission nuclear chain reaction or nuclear fusion reactions. Nuclear reactors are used at nuclear power plants for electricity generation and in nuclear marine propulsion. Heat from nuclear fission is passed to a working fluid, which in turn runs through steam turbines. These either drive a ship's propellers or turn electrical generators' shafts. Nuclear generated steam in principle can be used for industrial process heat or for district heating. Some reactors are used to produce isotopes for medical and industrial use, or for production of weapons-grade plutonium. As of 2022, the International Atomic Energy Agency reports there are 422 nuclear power reactors and 223 nuclear research reactors in operation around the world.

<span class="mw-page-title-main">Pressurized water reactor</span> Type of nuclear reactor

A pressurized water reactor (PWR) is a type of light-water nuclear reactor. PWRs constitute the large majority of the world's nuclear power plants. In a PWR, the primary coolant (water) is pumped under high pressure to the reactor core where it is heated by the energy released by the fission of atoms. The heated, high pressure water then flows to a steam generator, where it transfers its thermal energy to lower pressure water of a secondary system where steam is generated. The steam then drives turbines, which spin an electric generator. In contrast to a boiling water reactor (BWR), pressure in the primary coolant loop prevents the water from boiling within the reactor. All light-water reactors use ordinary water as both coolant and neutron moderator. Most use anywhere from two to four vertically mounted steam generators; VVER reactors use horizontal steam generators.

<span class="mw-page-title-main">Boiling water reactor</span> Type of nuclear reactor that directly boils water

A boiling water reactor (BWR) is a type of light water nuclear reactor used for the generation of electrical power. It is the second most common type of electricity-generating nuclear reactor after the pressurized water reactor (PWR), which is also a type of light water nuclear reactor.

<span class="mw-page-title-main">Nuclear meltdown</span> Reactor accident due to core overheating

A nuclear meltdown is a severe nuclear reactor accident that results in core damage from overheating. The term nuclear meltdown is not officially defined by the International Atomic Energy Agency or by the United States Nuclear Regulatory Commission. It has been defined to mean the accidental melting of the core of a nuclear reactor, however, and is in common usage a reference to the core's either complete or partial collapse.

<span class="mw-page-title-main">Scram</span> Emergency shutdown of a nuclear reactor

A scram or SCRAM is an emergency shutdown of a nuclear reactor effected by immediately terminating the fission reaction. It is also the name that is given to the manually operated kill switch that initiates the shutdown. In commercial reactor operations, this type of shutdown is often referred to as a "scram" at boiling water reactors (BWR), a "reactor trip" at pressurized water reactors and at a CANDU reactor. In many cases, a scram is part of the routine shutdown procedure, which serves to test the emergency shutdown system.

<span class="mw-page-title-main">Control rod</span> Device used to regulate the power of a nuclear reactor

Control rods are used in nuclear reactors to control the rate of fission of the nuclear fuel – uranium or plutonium. Their compositions include chemical elements such as boron, cadmium, silver, hafnium, or indium, that are capable of absorbing many neutrons without themselves decaying. These elements have different neutron capture cross sections for neutrons of various energies. Boiling water reactors (BWR), pressurized water reactors (PWR), and heavy-water reactors (HWR) operate with thermal neutrons, while breeder reactors operate with fast neutrons. Each reactor design can use different control rod materials based on the energy spectrum of its neutrons. Control rods have been used in nuclear aircraft engines like Project Pluto as a method of control.

<span class="mw-page-title-main">Light-water reactor</span> Type of nuclear reactor that uses normal water

The light-water reactor (LWR) is a type of thermal-neutron reactor that uses normal water, as opposed to heavy water, as both its coolant and neutron moderator; furthermore a solid form of fissile elements is used as fuel. Thermal-neutron reactors are the most common type of nuclear reactor, and light-water reactors are the most common type of thermal-neutron reactor.

Passive nuclear safety is a design approach for safety features, implemented in a nuclear reactor, that does not require any active intervention on the part of the operator or electrical/electronic feedback in order to bring the reactor to a safe shutdown state, in the event of a particular type of emergency. Such design features tend to rely on the engineering of components such that their predicted behaviour would slow down, rather than accelerate the deterioration of the reactor state; they typically take advantage of natural forces or phenomena such as gravity, buoyancy, pressure differences, conduction or natural heat convection to accomplish safety functions without requiring an active power source. Many older common reactor designs use passive safety systems to a limited extent, rather, relying on active safety systems such as diesel powered motors. Some newer reactor designs feature more passive systems; the motivation being that they are highly reliable and reduce the cost associated with the installation and maintenance of systems that would otherwise require multiple trains of equipment and redundant safety class power supplies in order to achieve the same level of reliability. However, weak driving forces that power many passive safety features can pose significant challenges to effectiveness of a passive system, particularly in the short term following an accident.

<span class="mw-page-title-main">Nuclear fuel</span> Material fuelling nuclear reactors

Nuclear fuel is material used in nuclear power stations to produce heat to power turbines. Heat is created when nuclear fuel undergoes nuclear fission.

<span class="mw-page-title-main">Containment building</span> Structure surrounding a nuclear reactor to prevent radioactive releases

A containment building is a reinforced steel, concrete or lead structure enclosing a nuclear reactor. It is designed, in any emergency, to contain the escape of radioactive steam or gas to a maximum pressure in the range of 275 to 550 kPa. The containment is the fourth and final barrier to radioactive release, the first being the fuel ceramic itself, the second being the metal fuel cladding tubes, the third being the reactor vessel and coolant system.

<span class="mw-page-title-main">Supercritical water reactor</span> Concept nuclear reactor whose water operates at supercritical pressure

The supercritical water reactor (SCWR) is a concept Generation IV reactor, designed as a light water reactor (LWR) that operates at supercritical pressure. The term critical in this context refers to the critical point of water, and must not be confused with the concept of criticality of the nuclear reactor.

Generation IVreactors are nuclear reactor design technologies that are envisioned as successors of generation III reactors. The Generation IV International Forum (GIF) – an international organization that coordinates the development of generation IV reactors – specifically selected six reactor technologies as candidates for generation IV reactors. The designs target improved safety, sustainability, efficiency, and cost. The first commercial Gen IV plants are not expected before 2040–2050, although the World Nuclear Association in 2015 suggested that some might enter commercial operation before 2030.

<span class="mw-page-title-main">Lead-cooled fast reactor</span> Type of nuclear reactor cooled by molten lead

The lead-cooled fast reactor is a nuclear reactor design that features a fast neutron spectrum and molten lead or lead-bismuth eutectic coolant. Molten lead or lead-bismuth eutectic can be used as the primary coolant because especially lead, and to a lesser degree bismuth have low neutron absorption and relatively low melting points. Neutrons are slowed less by interaction with these heavy nuclei and therefore, help make this type of reactor a fast-neutron reactor. In simple terms, if a neutron hits a particle with a similar mass, it tends to lose kinetic energy. In contrast, if it hits a much heavier atom such as lead, the neutron will "bounce off" without losing this energy. The coolant does, however, serve as a neutron reflector, returning some escaping neutrons to the core. Fuel designs being explored for this reactor scheme include fertile uranium as a metal, metal oxide or metal nitride. Smaller capacity lead-cooled fast reactors can be cooled by natural convection, while larger designs use forced circulation in normal power operation, but will employ natural circulation emergency cooling. No operator interference is required, nor pumping of any kind to cool the residual heat of the reactor after shutdown. The reactor outlet coolant temperature is typically in the range of 500 to 600 °C, possibly ranging over 800 °C with advanced materials for later designs. Temperatures higher than 800 °C are theoretically high enough to support thermochemical production of hydrogen through the sulfur-iodine cycle, although this has not been demonstrated.

<span class="mw-page-title-main">Sodium-cooled fast reactor</span> Type of nuclear reactor cooled by molten sodium

A sodium-cooled fast reactor is a fast neutron reactor cooled by liquid sodium.

In applications such as nuclear reactors, a neutron poison is a substance with a large neutron absorption cross-section. In such applications, absorbing neutrons is normally an undesirable effect. However, neutron-absorbing materials, also called poisons, are intentionally inserted into some types of reactors in order to lower the high reactivity of their initial fresh fuel load. Some of these poisons deplete as they absorb neutrons during reactor operation, while others remain relatively constant.

<span class="mw-page-title-main">Steam generator (nuclear power)</span>

A steam generator is a heat exchanger used to convert water into steam from heat produced in a nuclear reactor core. They are used in pressurized water reactor between the primary and secondary coolant loops.

The three primary objectives of nuclear reactor safety systems as defined by the U.S. Nuclear Regulatory Commission are to shut down the reactor, maintain it in a shutdown condition and prevent the release of radioactive material.

Boiling water reactor safety systems are nuclear safety systems constructed within boiling water reactors in order to prevent or mitigate environmental and health hazards in the event of accident or natural disaster.

<span class="mw-page-title-main">GE BWR</span> Type of commercial fission reactor

General Electric's BWR product line of boiling water reactors represents the designs of a relatively large (~18%) percentage of the commercial fission reactors around the world.

<span class="mw-page-title-main">Integral Molten Salt Reactor</span>

The Integral Molten Salt Reactor (IMSR) is a nuclear power plant design targeted at developing a commercial product for the small modular reactor (SMR) market. It employs molten salt reactor technology which is being developed by the Canadian company Terrestrial Energy. It is based closely on the denatured molten salt reactor (DMSR), a reactor design from Oak Ridge National Laboratory. It also incorporates elements found in the SmAHTR, a later design from the same laboratory. The IMSR belongs to the DMSR class of molten salt reactors (MSR) and hence is a "burner" reactor that employs a liquid fuel rather than a conventional solid fuel; this liquid contains the nuclear fuel and also serves as primary coolant.

References

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  2. "Partial Meltdowns Led to Hydrogen Explosions at Fukushima Nuclear Power Plant;from google (fukushima hydrogen explosion) result 1". Scientific American .
  3. "Pressurized Water Reactor Systems" (PDF). USNRC Technical Training Center. Retrieved March 12, 2019.
  4. Aaltonen1, Hanninen2, P.1, H.2. "Water Chemistry and Behavior of Materials in PWRs and BWRs" (PDF). VTT Manufacturing Technology. Retrieved March 12, 2019.{{cite web}}: CS1 maint: multiple names: authors list (link) CS1 maint: numeric names: authors list (link)
  5. Buongiorno, Jacopo. "Nuclear Safety" (PDF). MIT OpenCourseWare. Retrieved March 12, 2019.
  6. "Borated Water" (PDF). Columbus Chemical Industries. Retrieved March 12, 2019.
  7. 1 2 Monterrosa, Anthony (May 5, 2012). "Boron Use and Control in PWRs and FHRs" (PDF). Department of Nuclear Engineering, University of California, Berkeley. Retrieved March 12, 2019.