Names | |
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Preferred IUPAC name N-(5-tert-Butyl-1,3,4-thiadiazol-2-yl)-N,N′-dimethylurea | |
Other names Spike; Brulan; Brush Bullet; EL-103; Graslan; Perflan; Herbec; Herbic; Reclaim | |
Identifiers | |
3D model (JSmol) | |
ChEBI | |
ChEMBL | |
ChemSpider | |
ECHA InfoCard | 100.047.070 |
EC Number |
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KEGG | |
PubChem CID | |
UNII | |
UN number | 3077 |
CompTox Dashboard (EPA) | |
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Properties | |
C9H16N4OS | |
Molar mass | 228.31 g·mol−1 |
Appearance | Off-white to buff-colored crystalline solid |
Density | 1.186 g/cm3 |
Melting point | 163.19 °C (325.74 °F; 436.34 K) (mean or weighted MP) |
Boiling point | 394.23 °C (741.61 °F; 667.38 K) (Adapted Stein & Brown method)[ who? ] |
2500 mg/L | |
Hazards | |
Occupational safety and health (OHS/OSH): | |
Main hazards | dangerous for the environment |
GHS labelling: | |
Warning | |
H302, H410 | |
P264, P270, P273, P301+P312, P330, P391, P501 | |
Safety data sheet (SDS) | ChemAdvisor MSDS |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). |
Tebuthiuron is a nonselective broad spectrum herbicide of the urea class. It is used to control weeds, woody and herbaceous plants, and sugar cane. [1] It is absorbed by the roots and transported to the leaves, where it inhibits photosynthesis. [4] [6] The ingredient was discovered by Air Products and Chemicals, but was registered by Elanco in the United States in 1974, and later sold to Dow AgroSciences. [7]
The Environmental Protection Agency considers tebuthiuron to have a great potential for groundwater contamination, due to its high water solubility, low adsorption to soil particles, and high persistence in soil (its soil half-life is 360 days).
In Europe, tebuthiuron has been banned since November 2002. [8]
In 2010, tebuthiuron in the form of Dow AgroSciences Spike 80DF was deliberately used in an act of vandalism to poison the live oak trees at Toomer's Corner on the Auburn University campus following the 2010 Iron Bowl. [6] [9] The lone perpetrator, a University of Alabama fan, was charged with first-degree criminal mischief and was placed in jail on a $50,000 bond. Remediation of the incident required removal of about 1,780 tons of contaminated material.
In 2021, Arthur and Amelia Bond, wealthy summer residents of Camden, Maine poisoned their neighbor's oak trees with tebuthiuron in order to obtain a better view of Camden Harbor. They paid over $200 thousand in fines to address illegal pesticide use and environmental contamination, and $1.5 million to settle with their neighbor. [10]
Pesticides are substances that are used to control pests. They include herbicides, insecticides, nematicides, fungicides, and many others. The most common of these are herbicides, which account for approximately 50% of all pesticide use globally. Most pesticides are used as plant protection products, which in general protect plants from weeds, fungi, or insects. In general, a pesticide is a chemical or biological agent that deters, incapacitates, kills, or otherwise discourages pests. Target pests can include insects, plant pathogens, weeds, molluscs, birds, mammals, fish, nematodes (roundworms), and microbes that destroy property, cause nuisance, or spread disease, or are disease vectors. Along with these benefits, pesticides also have drawbacks, such as potential toxicity to humans and other species.
Herbicides, also commonly known as weed killers, are substances used to control undesired plants, also known as weeds. Selective herbicides control specific weed species while leaving the desired crop relatively unharmed, while non-selective herbicides kill plants indiscriminately. The combined effects of herbicides, nitrogen fertilizer, and improved cultivars has increased yields of major crops by 3x to 6x from 1900 to 2000.
Glyphosate is a broad-spectrum systemic herbicide and crop desiccant. It is an organophosphorus compound, specifically a phosphonate, which acts by inhibiting the plant enzyme 5-enolpyruvylshikimate-3-phosphate synthase (EPSP). It is used to kill weeds, especially annual broadleaf weeds and grasses that compete with crops. Its herbicidal effectiveness was discovered by Monsanto chemist John E. Franz in 1970. Monsanto brought it to market for agricultural use in 1974 under the trade name Roundup. Monsanto's last commercially relevant United States patent expired in 2000.
Triclopyr is an organic compound in the pyridine group that is used as a systemic foliar herbicide and fungicide.
Chlorpyrifos (CPS), also known as chlorpyrifos ethyl, is an organophosphate pesticide that has been used on crops, animals, and buildings, and in other settings, to kill several pests, including insects and worms. It acts on the nervous systems of insects by inhibiting the acetylcholinesterase enzyme. Chlorpyrifos was patented in 1966 by Dow Chemical Company.
The Auburn Tigers are the athletic teams representing Auburn University, a public four-year university located in Auburn, Alabama, United States. The Auburn Tigers compete in Division I of the National Collegiate Athletic Association (NCAA) as a member of the Southeastern Conference (SEC).
An agrochemical or agrichemical, a contraction of agricultural chemical, is a chemical product used in industrial agriculture. Agrichemical refers to biocides and synthetic fertilizers. It may also include hormones and other chemical growth agents.
Alachlor is an herbicide from the chloroacetanilide family. It is an odorless, white solid. The greatest use of alachlor is for control of annual grasses and broadleaf weeds in crops. Use of alachlor is illegal in the European Union and no products containing alachlor are currently registered in the United States.
Picloram is a systemic herbicide used for general woody plant control. It also controls a wide range of broad-leaved weeds, but most grasses are resistant. A chlorinated derivative of picolinic acid, picloram is in the pyridine family of herbicides.
Soil contamination, soil pollution, or land pollution as a part of land degradation is caused by the presence of xenobiotic (human-made) chemicals or other alteration in the natural soil environment. It is typically caused by industrial activity, agricultural chemicals or improper disposal of waste. The most common chemicals involved are petroleum hydrocarbons, polynuclear aromatic hydrocarbons, solvents, pesticides, lead, and other heavy metals. Contamination is correlated with the degree of industrialization and intensity of chemical substance. The concern over soil contamination stems primarily from health risks, from direct contact with the contaminated soil, vapour from the contaminants, or from secondary contamination of water supplies within and underlying the soil. Mapping of contaminated soil sites and the resulting clean ups are time-consuming and expensive tasks, and require expertise in geology, hydrology, chemistry, computer modelling, and GIS in Environmental Contamination, as well as an appreciation of the history of industrial chemistry.
Acetochlor is an herbicide developed by Monsanto Company and Zeneca. It is a member of the class of herbicides known as chloroacetanilides. Its mode of action is elongase inhibition, and inhibition of geranylgeranyl pyrophosphate (GGPP) cyclization enzymes, part of the gibberellin pathway. It carries high risks of environmental contamination.
Pesticide drift, also known as spray drift refers to the unintentional diffusion of pesticides toward nontarget species. It is one of the most negative effects of pesticide application. Drift can damage human health, environment, and crops. Together with runoff and leaching, drift is a mechanism for agricultural pollution. Some drift results from contamination of sprayer tanks.
The environmental effects of pesticides describe the broad series of consequences of using pesticides. The unintended consequences of pesticides is one of the main drivers of the negative impact of modern industrial agriculture on the environment. Pesticides, because they are toxic chemicals meant to kill pest species, can affect non-target species, such as plants, animals and humans. Over 98% of sprayed insecticides and 95% of herbicides reach a destination other than their target species, because they are sprayed or spread across entire agricultural fields. Other agrochemicals, such as fertilizers, can also have negative effects on the environment.
Auburn University has several notable traditions, many related to its varsity teams, the Auburn Tigers.
Aminopyralid is a selective herbicide used for control of broadleaf weeds, especially thistles and clovers. It is in the picolinic acid family of herbicides, which also includes clopyralid, picloram, triclopyr, and several less common herbicides. It was first registered for use in 2005, in the USA under the brand name "Milestone" and later under various names starting with "Grazon". In the UK it is sold under the brand names Banish, Forefront, Halcyon, Pharaoh, Pro-Banish, Runway, Synero, and Upfront.
Pesticides in the United States are used predominantly by the agricultural sector, but approximately a quarter of them are used in houses, yards, parks, golf courses, and swimming pools.
2,4-Dichlorophenoxyacetic acid is an organic compound with the chemical formula Cl2C6H3OCH2CO2H. It is usually referred to by its ISO common name 2,4-D. It is a systemic herbicide that kills most broadleaf weeds by causing uncontrolled growth, but most grasses such as cereals, lawn turf, and grassland are relatively unaffected.
The Enlist Weed Control System is an agricultural system that includes seeds for genetically modified crops that are resistant to Enlist and the Enlist herbicide; spraying the herbicide will kill weeds but not the resulting crop. The system was developed by Dow AgroSciences, part of Dow Chemical Company. In October 2014 the system was registered for restricted use in Illinois, Indiana, Iowa, Ohio, South Dakota and Wisconsin by the US Environmental Protection Agency. In 2013, the system was approved by Canada for the same uses.
Toomer's Corner is a street corner located at the intersection of Magnolia Avenue and College Street, and marks the northeastern-most reach of the campus of Auburn University, and the beginning of downtown Auburn, Alabama. Two landmarks are located on Toomer's Corner, the Bank of Auburn and Toomer's Drugs Pharmacy, which was the first establishment in the city with a telegraph, and the intersection is patterned in bricks forming the paw print logo of the Auburn Tigers athletic teams.
Oxyfluorfen is a chemical compound used as an herbicide. It is manufactured by Dow AgroSciences and Adama Agricultural Solutions under the trade names Goal and Galigan. Oxyfluorfen is used to control broadleaf and grassy weeds in a variety of nut, tree fruit, vine, and field crops, especially wine grapes and almonds. It is also used for residential weed control.