Prosulfocarb

Last updated
Prosulfocarb [1] [2]
Prosulfocarb v2.svg
Names
IUPAC name
S-Benzyl N,N-dipropylcarbamothioate
Other names
Prosulfocarb
Identifiers
ECHA InfoCard 100.100.363 OOjs UI icon edit-ltr-progressive.svg
PubChem CID
Properties
C14H21NOS
Molar mass 251.39 g·mol−1
AppearanceColourless - pale yellow
Odor Aromatic
Density 1049 kg/m3 [1]
Melting point -20 °C [3]
Boiling point 341 °C [3]
Insoluble [3]
Solubility in xylene Soluble [3]
Solubility in acetone Soluble [3]
Solubility in heptane Soluble [3]
Solubility in ethyl acetate Soluble [3]
Vapor pressure 0.79 mPa [3]
Hazards
GHS labelling:
GHS-pictogram-silhouette.svg GHS-pictogram-pollu.svg
Warning
H227, H302, H317, H335, H371, H373, H401
Flash point 167.1 °C [1]
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

Prosulfocarb is a pre-emergent herbicide used agriculturally in Australia, the EU, Morocco [3] and Iran, for control of annual ryegrass and toad rush in wheat and barley crops. [4] It was introduced to the EU in 1988 and is rapidly growing in use, with sales increasing by over 500% in France since 2008. [5]

Contents

Prosulfocarb is a thiocarbamate, and is absorbed by the roots of germinating seedlings to inhibit growth in the meristem by inhibiting fat synthesis. [6]

Usage

To target annual ryegrass, 2.5L/ha (of 800 g/L emulsifiable concentrate) is prepared and sprayed before sowing. It can be applied to barley post-emergence, but if applied wrongly may cause crop damage. [7]

Prosulfocarb is often applied alongside s-Metolachlor and pyroxasulfone, or in Australia with trifluralin, with which it more efficiently circumvents weed resistance. [8]

Safety and Environmental Effect

Prosulfocarb's LD50 toxicity is 1820 mg/kg orally for rats, [2] which is comparable to paracetamol. The human toxicological effect is low. [5] Prosulfocarb itself is not a combustible, but formulations can be due to other components. (e.g. solvent naphtha) [9] Prosulfocarb is an irritant. [3]

Prosulfocarb is toxic to aquatic organisms; it is mandatory in Australia not to spray it within 20 metres upwind of aquatic or wetland areas or to apply by air. Nor if heavy rain is expected, to prevent runoff. [6] It is not persistent in soil, with a halflife of 35 days. Prosulfocarb bioaccumulates, and has slight mobility in soil. [9]

Trade Names

Related Research Articles

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Herbicides, also commonly known as weed killers, are substances used to control undesired plants, also known as weeds. Selective herbicides control specific weed species while leaving the desired crop relatively unharmed, while non-selective herbicides kill plants indiscriminately. The combined effects of herbicides, nitrogen fertilizer, and improved cultivars has increased yields of major crops by 3x to 6x from 1900 to 2000.

<span class="mw-page-title-main">Roundup (herbicide)</span> Glyphosate-based herbicide made by Monsanto

Roundup is a brand name of herbicide originally produced by Monsanto, which Bayer acquired in 2018. Prior to the late-2010s formulations, it used broad-spectrum glyphosate-based herbicides. As of 2009, sales of Roundup herbicides still represented about 10 percent of Monsanto's revenue despite competition from Chinese producers of other glyphosate-based herbicides. The overall Roundup line of products represented about half of Monsanto's yearly revenue in 2009. The product is marketed to consumers by Scotts Miracle-Gro Company. In the late-2010s other non-glyphosate containing herbicides were also sold under the Roundup brand.

<span class="mw-page-title-main">Weed control</span> Botanical component of pest control for plants

Weed control is a type of pest control, which attempts to stop or reduce growth of weeds, especially noxious weeds, with the aim of reducing their competition with desired flora and fauna including domesticated plants and livestock, and in natural settings preventing non native species competing with native species.

<span class="mw-page-title-main">Glyphosate</span> Systemic herbicide and crop desiccant

Glyphosate is a broad-spectrum systemic herbicide and crop desiccant. It is an organophosphorus compound, specifically a phosphonate, which acts by inhibiting the plant enzyme 5-enolpyruvylshikimate-3-phosphate synthase (EPSP). It is used to kill weeds, especially annual broadleaf weeds and grasses that compete with crops. Its herbicidal effectiveness was discovered by Monsanto chemist John E. Franz in 1970. Monsanto brought it to market for agricultural use in 1974 under the trade name Roundup. Monsanto's last commercially relevant United States patent expired in 2000.

<span class="mw-page-title-main">Paraquat</span> Chemical compound used as an herbicide

Paraquat (trivial name; ), or N,N′-dimethyl-4,4′-bipyridinium dichloride (systematic name), also known as methyl viologen, is an organic compound with the chemical formula [(C6H7N)2]Cl2. It is classified as a viologen, a family of redox-active heterocycles of similar structure. This salt is one of the most widely used herbicides. It is quick-acting and non-selective, killing green plant tissue on contact. It is also toxic (lethal) to human beings and animals due to its redox activity, which produces superoxide anions. It has been linked to the development of Parkinson's disease and is banned in 58 countries.

<span class="mw-page-title-main">MCPA</span> Organic compound used as an herbicide

MCPA is a widely used phenoxy herbicide introduced in 1945. It selectively controls broad-leaf weeds in pasture and cereal crops. The mode of action of MCPA is as an auxin, which are growth hormones that naturally exist in plants.

<span class="mw-page-title-main">Alachlor</span> Chemical compound; herbicide

Alachlor is an herbicide from the chloroacetanilide family. It is an odorless, white solid. The greatest use of alachlor is for control of annual grasses and broadleaf weeds in crops. Use of alachlor is illegal in the European Union and no products containing alachlor are currently registered in the United States.

<span class="mw-page-title-main">Diquat</span> Chemical compound

Diquat is the ISO common name for an organic dication that, as a salt with counterions such as bromide or chloride is used as a contact herbicide that produces desiccation and defoliation. Diquat is no longer approved for use in the European Union, although its registration in many other countries including the USA is still valid.

<span class="mw-page-title-main">Glufosinate</span> Broad-spectrum herbicide

Glufosinate is a naturally occurring broad-spectrum herbicide produced by several species of Streptomyces soil bacteria. Glufosinate is a non-selective, contact herbicide, with some systemic action. Plants may also metabolize bialaphos and phosalacine, other naturally occurring herbicides, directly into glufosinate. The compound irreversibly inhibits glutamine synthetase, an enzyme necessary for the production of glutamine and for ammonia detoxification, giving it antibacterial, antifungal and herbicidal properties. Application of glufosinate to plants leads to reduced glutamine and elevated ammonia levels in tissues, halting photosynthesis and resulting in plant death.

<span class="mw-page-title-main">Algaecide</span>

Algaecide or algicide is a biocide used for killing and preventing the growth of algae, often defined in a loose sense that, beyond the biological definition, also includes cyanobacteria. An algaecide may be used for controlled bodies of water, but may also be used on land for locations such as turfgrass.

<span class="mw-page-title-main">Pendimethalin</span> Chemical compound

Pendimethalin is a herbicide of the dinitroaniline class used in premergence and postemergence applications to control annual grasses and certain broadleaf weeds. It inhibits cell division and cell elongation. Pendimethalin is listed in the K1-group according to the Herbicide Resistance Action Committee (HRAC) classification and is approved in Europe, North America, South America, Africa, Asia and Oceania for different crops including cereals, corn, soybeans, rice, potato, legumes, fruits, vegetables, nuts as well as lawns and ornamental plants.

<span class="mw-page-title-main">Trifluralin</span> Weed control herbicide

Trifluralin is a commonly used pre-emergence selective herbicide. With about 14 million pounds (6,400 t) used in the United States in 2001, and 3–7 million pounds (1,400–3,200 t) in 2012, it is one of the most widely used herbicides. Trifluralin is also used in Australia. Introduced in 1964, Trifluralin was the first organofluorine compound used as an agrochemical.

<span class="mw-page-title-main">Lactofen</span> Chemical compound

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<span class="mw-page-title-main">Mesotrione</span> Chemical compound used as an herbicide

Mesotrione is a selective herbicide used mainly in maize crops. It is a synthetic compound inspired by the natural substance leptospermone found in the bottlebrush tree Callistemon citrinus. It inhibits the enzyme 4-hydroxyphenylpyruvate dioxygenase (HPPD) and is sold under brand names including Callisto and Tenacity. It was first marketed by Syngenta in 2001.

<span class="mw-page-title-main">2,4-Dichlorophenoxyacetic acid</span> Herbicide

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<span class="mw-page-title-main">Imazaquin</span> Chemical compound

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Diflufenican is a herbicide used to control weeds including wild radish and wild turnip weeds or suppress capeweed, crassula, marshmallow or shepherd's purse, in clover pasture, lupins, lentils or field peas. It has seen use in Australia, Europe, and in Feb 2024 registered in North America by the PMRA, EPA registration pending, for use on soybean and corn.

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References

  1. 1 2 3 "Prosulfocarb SDS" (PDF). ChemicalBook. Retrieved 5 August 2024.
  2. 1 2 "Prosulfocarb Standard SDS" (PDF). FujiFilm. Retrieved 5 August 2024.
  3. 1 2 3 4 5 6 7 8 9 10 "Prosulfocarb (Ref: SC 0574)". Pesticide Properties DataBase. Retrieved 8 August 2024.
  4. "Prosulfocarb 800 Label" (PDF). GenFarm. Retrieved 5 August 2024.
  5. 1 2 Devault, Damnien; Guillemin, Jean-Philippe; Maurice, Millet; Eymery, Frank (January 2022). "Prosulfocarb at center stage!". Environmental Science and Pollution Research. doi:10.1007/s11356-019-06928-8 . Retrieved 5 August 2024.
  6. 1 2 "Prosulfocarb Leaflet" (PDF). 4Farmers Australia. Retrieved 5 August 2024.
  7. "4Farmers Prosulfocarb 800 EC Infosheet" (PDF). 4Farmers Australia. Retrieved 5 August 2024.
  8. Kleemann, Samuel G. L.; Preston, Christopher; Gill, Gurjeet S. (2014). "Influence of Seeding System Disturbance on Preplant Incorporated Herbicide Control of Rigid Ryegrass (Lolium rigidum) in Wheat in Southern Australia" (PDF). Weed Technology (28): 323–331. Retrieved 5 August 2024.
  9. 1 2 "4Farmers Prosulfocarb Herbicide Safety Data Sheet" (PDF). 4farmers.com.au. 4Farmers Australia. Retrieved 5 August 2024.