Power-to-X (also P2X and P2Y) are electricity conversion, energy storage, and reconversion pathways from surplus renewable energy. [1] [2] Power-to-X conversion technologies allow for the decoupling of power from the electricity sector for use in other sectors (such as transport or chemicals), possibly using power that has been provided by additional investments in generation. [1] The term is widely used in Germany and may have originated there.
The X in the terminology can refer to one of the following: power-to-ammonia, power-to-chemicals, power-to-fuel, [3] power-to-gas (power-to-hydrogen, power-to-methane) power-to-liquid (synthetic fuel), power to food, [4] power-to-heat. Electric vehicle charging, space heating and cooling, and water heating can be shifted in time to match generation, forms of demand response that can be called power-to-mobility and power-to-heat.
Collectively power-to-X schemes which use surplus power fall under the heading of flexibility measures and are particularly useful in energy systems with high shares of renewable generation and/or with strong decarbonization targets. [1] [2] A large number of pathways and technologies are encompassed by the term. In 2016 the German government funded a €30 million first-phase research project into power-to-X options. [5]
Surplus electric power can be converted to gas fuel energy for storage and reconversion. [6] [7] [8] [9] Direct current electrolysis of water (efficiency 80–85% at best) can be used to produce hydrogen which can, in turn, be converted to methane (CH4) via methanation. [6] [10] Another possibility is converting the hydrogen, along with CO2 to methanol. [11] Both these fuels can be stored and used to produce electricity again, hours to months later.
Hydrogen and methane can be used as downstream fuels, fed into the natural gas grid, or used to make synthetic fuel. [12] [13] Alternatively they can be used as a chemical feedstock, as can ammonia (NH3).
Reconversion technologies include gas turbines, combined cycle plants, reciprocating engines and fuel cells. Power-to-power refers to the round-trip reconversion efficiency. [6] For hydrogen storage, the round-trip efficiency remains limited at 35–50%. [2] Electrolysis is expensive and power-to-gas processes need substantial full-load hours to be economic. [1] However, while round-trip conversion efficiency of power-to-power is lower than with batteries and electrolysis can be expensive, storage of the fuels themselves is quite inexpensive.[ citation needed ] This means that large amounts of energy can be stored for long periods of time with power-to-power, which is ideal for seasonal storage. This could be particularly useful for systems with high variable renewable energy penetration, since many areas have significant seasonal variability of solar, wind, and run-of-the-river-hydroelectric generation.
Despite it also being based fundamentally on electrolytic chemical reactions, battery storage is not normally considered a power-to-fuel concept.
The purpose of power-to-heat systems is to utilize excess electricity generated by renewable energy sources which would otherwise be wasted. Depending on the context, the power-to-heat can either be stored as heat, or delivered as heat to meet a need. [14]
In contrast to simple electric heating systems such as night storage heating which covers the complete heating requirements, power-to-heat systems are hybrid systems, which additionally have traditional heating systems using chemical fuels like wood or natural gas. [15] : 124 When there are excess energy the heat production can result from electric energy otherwise the traditional heating system will be used. In order to increase flexibility power-to-heat systems are often coupled with heat accumulators. The power supply occurs for the most part in the local and district heating networks. Power-to-heat systems are also able to supply buildings or industrial systems with heat. [16]
Power-to-heat involves contributing to the heat sector, either by resistance heating or via a heat pump. Resistance heaters have unity efficiency, and the corresponding coefficient of performance (COP) of heat pumps is 2–5. [6] Back-up immersion heating of both domestic hot water and district heating offers a cheap way of using surplus renewable energy and will often displace carbon-intensive fossil fuels for the task. [1] Large-scale heat pumps in district heating systems with thermal energy storage are an especially attractive option for power-to-heat: they offer exceptionally high efficiency for balancing excess wind and solar power, and they can be profitable investments. [17] [18]
Power-to-mobility refers to the charging of battery electric vehicles (BEV). Given the expected uptake of EVs, dedicated dispatch will be required. As vehicles are idle for most of the time, shifting the charging time can offer considerable flexibility: the charging window is a relatively long 8–12 hours, whereas the charging duration is around 90 minutes. [2] The EV batteries can also be discharged to the grid to make them work as electricity storage devices, but this causes additional wear to the battery. [2]
According to the German concept of sector coupling interconnecting all the energy-using sectors will require the digitalisation and automation of numerous processes to synchronise supply and demand. [19]
A 2023 study examined to role that power‑to‑X could play in a highly‑renewable future energy system for Japan. The P2X technologies considered include water electrolysis, methanation, Fischer–Tropsch synthesis, and Haber–Bosch synthesis and the study used linear programming to determine least‑cost system structure and operation. Results indicate that these various P2X technologies can effectively shift electricity loads and reduce curtailment by 80% or more. [20]
A fuel cell is an electrochemical cell that converts the chemical energy of a fuel and an oxidizing agent into electricity through a pair of redox reactions. Fuel cells are different from most batteries in requiring a continuous source of fuel and oxygen to sustain the chemical reaction, whereas in a battery the chemical energy usually comes from substances that are already present in the battery. Fuel cells can produce electricity continuously for as long as fuel and oxygen are supplied.
Energy storage is the capture of energy produced at one time for use at a later time to reduce imbalances between energy demand and energy production. A device that stores energy is generally called an accumulator or battery. Energy comes in multiple forms including radiation, chemical, gravitational potential, electrical potential, electricity, elevated temperature, latent heat and kinetic. Energy storage involves converting energy from forms that are difficult to store to more conveniently or economically storable forms.
Solar energy is radiant light and heat from the Sun that is harnessed using a range of technologies such as solar power to generate electricity, solar thermal energy, and solar architecture. It is an essential source of renewable energy, and its technologies are broadly characterized as either passive solar or active solar depending on how they capture and distribute solar energy or convert it into solar power. Active solar techniques include the use of photovoltaic systems, concentrated solar power, and solar water heating to harness the energy. Passive solar techniques include orienting a building to the Sun, selecting materials with favorable thermal mass or light-dispersing properties, and designing spaces that naturally circulate air.
Syngas, or synthesis gas, is a mixture of hydrogen and carbon monoxide, in various ratios. The gas often contains some carbon dioxide and methane. It is principally used for producing ammonia or methanol. Syngas is combustible and can be used as a fuel. Historically, it has been used as a replacement for gasoline, when gasoline supply has been limited; for example, wood gas was used to power cars in Europe during WWII.
Alternative fuels, also known as non-conventional and advanced fuels, are fuels derived from sources other than petroleum. Alternative fuels include gaseous fossil fuels like propane, natural gas, methane, and ammonia; biofuels like biodiesel, bioalcohol, and refuse-derived fuel; and other renewable fuels like hydrogen and electricity.
The hydrogen economy is an umbrella term that draws together the roles hydrogen can play alongside renewable electricity to decarbonize those sectors and activities which may be technically difficult to decarbonize through other means, or where cheaper and more energy-efficient clean solutions are not available. In this context, hydrogen economy encompasses hydrogen's production through to end-uses in ways that substantively contribute to avoiding the use of fossil fuels and mitigating greenhouse gas emissions.
Energy is sustainable if it "meets the needs of the present without compromising the ability of future generations to meet their own needs." Most definitions of sustainable energy include considerations of environmental aspects such as greenhouse gas emissions and social and economic aspects such as energy poverty. Renewable energy sources such as wind, hydroelectric power, solar, and geothermal energy are generally far more sustainable than fossil fuel sources. However, some renewable energy projects, such as the clearing of forests to produce biofuels, can cause severe environmental damage.
The Sabatier reaction or Sabatier process produces methane and water from a reaction of hydrogen with carbon dioxide at elevated temperatures and pressures in the presence of a nickel catalyst. It was discovered by the French chemists Paul Sabatier and Jean-Baptiste Senderens in 1897. Optionally, ruthenium on alumina makes a more efficient catalyst. It is described by the following exothermic reaction:
Grid energy storage is a collection of methods used for energy storage on a large scale within an electrical power grid. Electrical energy is stored during times when electricity is plentiful and inexpensive or when demand is low, and later returned to the grid when demand is high, and electricity prices tend to be higher.
The methanol economy is a suggested future economy in which methanol and dimethyl ether replace fossil fuels as a means of energy storage, ground transportation fuel, and raw material for synthetic hydrocarbons and their products. It offers an alternative to the proposed hydrogen economy or ethanol economy, although these concepts are not exclusive. Methanol can be produced from a variety of sources including fossil fuels as well as agricultural products and municipal waste, wood and varied biomass. It can also be made from chemical recycling of carbon dioxide.
Hydrogen gas is produced by several industrial methods. Fossil fuels are the dominant source of hydrogen. As of 2020, the majority of hydrogen (~95%) is produced by steam reforming of natural gas and other light hydrocarbons, and partial oxidation of heavier hydrocarbons. Other methods of hydrogen production include biomass gasification and methane pyrolysis. Methane pyrolysis and water electrolysis can use any source of electricity including renewable energy.
Energy conversion efficiency (η) is the ratio between the useful output of an energy conversion machine and the input, in energy terms. The input, as well as the useful output may be chemical, electric power, mechanical work, light (radiation), or heat. The resulting value, η (eta), ranges between 0 and 1.
The energy policy of India is to increase the locally produced energy in India and reduce energy poverty, with more focus on developing alternative sources of energy, particularly nuclear, solar and wind energy. Net energy import dependency was 40.9% in 2021-22.
Electromethanogenesis is a form of electrofuel production where methane is produced by direct biological conversion of electrical current and carbon dioxide.
A microbial electrolysis cell (MEC) is a technology related to Microbial fuel cells (MFC). Whilst MFCs produce an electric current from the microbial decomposition of organic compounds, MECs partially reverse the process to generate hydrogen or methane from organic material by applying an electric current. The electric current would ideally be produced by a renewable source of power. The hydrogen or methane produced can be used to produce electricity by means of an additional PEM fuel cell or internal combustion engine.
A solar fuel is a synthetic chemical fuel produced from solar energy. Solar fuels can be produced through photochemical, photobiological, and electrochemical reactions.
Carbon-neutral fuel is fuel which produces no net-greenhouse gas emissions or carbon footprint. In practice, this usually means fuels that are made using carbon dioxide (CO2) as a feedstock. Proposed carbon-neutral fuels can broadly be grouped into synthetic fuels, which are made by chemically hydrogenating carbon dioxide, and biofuels, which are produced using natural CO2-consuming processes like photosynthesis.
Power-to-gas is a technology that uses electric power to produce a gaseous fuel. When using surplus power from wind generation, the concept is sometimes called windgas.
Proton exchange membrane(PEM) electrolysis is the electrolysis of water in a cell equipped with a solid polymer electrolyte (SPE) that is responsible for the conduction of protons, separation of product gases, and electrical insulation of the electrodes. The PEM electrolyzer was introduced to overcome the issues of partial load, low current density, and low pressure operation currently plaguing the alkaline electrolyzer. It involves a proton-exchange membrane.
A reversible solid oxide cell (rSOC) is a solid-state electrochemical device that is operated alternatively as a solid oxide fuel cell (SOFC) and a solid oxide electrolysis cell (SOEC). Similarly to SOFCs, rSOCs are made of a dense electrolyte sandwiched between two porous electrodes. Their operating temperature ranges from 600°C to 900°C, hence they benefit from enhanced kinetics of the reactions and increased efficiency with respect to low-temperature electrochemical technologies.
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