Multilayered packaging

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5 Layer co-extrusion of cosmetic "squeeze" tube 5 Layer Extrusion Technology.jpg
5 Layer co-extrusion of cosmetic "squeeze" tube
Typical liquid packaging board TBA packaging components.svg
Typical liquid packaging board

Multi-layered packaging are multilayer or composite materials using innovative technologies aimed to give barrier properties, strength and storage stability to food items, new materials as well as hazardous materials. [1]

Contents

Multiple layers are formed by coextrusion, lamination , or various coating technologies. The material of construction of multilayered packaging ranges from paper to plastics to metals. Most multilayered packages are not readily recyclable. [2] Basf company and Uflex recently developed multilayered food packaging from 100% recyclable materials. [3] [4]

History of multilayered packaging dates back to the late 1950s when Procter & Gamble first designed multilayered collapsible tubes for toothpastes. Amine group containing products deforms HDPE on storage, and are incapable of arresting amine odours. Multilayered CO-EX bottles are the best packaging solution for such products. [5]

Types

Multiwall paper sacks

These are made of multiple layers of extensible kraft paper of differing grammages. These are gaining popularity in the cement industry, drug and fertilizer industry where the inner or outer layer of the sacks are made of polyethylene to protect the product from moisture.

Laminated-cartons and plastic bottles

These find use in paint industry, tetra packs containing milk, fruit juice, syrups and pharmaceutical industry. [6] The typical combinations are as follows:

Apart from these nylon, EVOH, EAA, PA, EVA, SiO2 plasma coatings are also used in laminates to give various functional properties. The layer combinations are selected by the engineer depending on the product characteristic, shelf life and extent of vapour transmission rate. Precooked food are packed in PS/EVOH/PE bags with PVE/PDVC/PE closures. [7]

Coextrusion

Coextrusion is the plastic extrusion of multiple layers of material simultaneously. Such products are popularly known as CO-EX.

Related Research Articles

<span class="mw-page-title-main">Polyethylene</span> Most common thermoplastic polymer

Polyethylene or polythene (abbreviated PE; IUPAC name polyethene or poly(methylene)) is the most commonly produced plastic. It is a polymer, primarily used for packaging (plastic bags, plastic films, geomembranes and containers including bottles, cups, jars, etc.). As of 2017, over 100 million tonnes of polyethylene resins are being produced annually, accounting for 34% of the total plastics market.

<span class="mw-page-title-main">BoPET</span> Polyester film

BoPET is a polyester film made from stretched polyethylene terephthalate (PET) and is used for its high tensile strength, chemical stability, dimensional stability, transparency, reflectivity when metallized, gas and moisture barrier properties, and electrical insulation. The film is "biaxially oriented", which means that the polymer chains are oriented parallel to the plane of the film, and therefore oriented in two axes. A variety of companies manufacture boPET and other polyester films under different brand names. In the UK and US, the best-known trade names are Mylar, Melinex, Lumirror and Hostaphan. It was the first biaxially oriented polymer to be manufactured on a mass commercial scale.

<span class="mw-page-title-main">Thermoplastic</span> Plastic that softens with heat and hardens on cooling

A thermoplastic, or thermosoftening plastic, is any plastic polymer material that becomes pliable or moldable at a certain elevated temperature and solidifies upon cooling.

<span class="mw-page-title-main">Aluminium foil</span> A thin, flexible sheet of aluminium, used for wrapping food and other purposes

Aluminium foil is aluminium prepared in thin metal leaves. The foil is pliable and can be readily bent or wrapped around objects. Thin foils are fragile and are sometimes laminated with other materials such as plastics or paper to make them stronger and more useful.

<span class="mw-page-title-main">Lamination</span> Technique of fusing layers of material

Lamination is the technique/process of manufacturing a material in multiple layers, so that the composite material achieves improved strength, stability, sound insulation, appearance, or other properties from the use of the differing materials, such as plastic. A laminate is a layered object or material assembled using heat, pressure, welding, or adhesives. Various coating machines, machine presses and calendering equipment are used.

<span class="mw-page-title-main">Shrink wrap</span> Polymer used to bundle boxes on a pallet for transport

Shrink wrap, also shrink film, is a material made up of polymer plastic film. When heat is applied, it shrinks tightly over whatever it is covering. Heat can be applied with a handheld heat gun, or the product and film can pass through a heat tunnel on a conveyor.

<span class="mw-page-title-main">Plastic wrap</span> Thin plastic film used for sealing food

Plastic wrap, cling film, Saran wrap, cling wrap, Glad wrap or food wrap is a thin plastic film typically used for sealing food items in containers to keep them fresh over a longer period of time. Plastic wrap, typically sold on rolls in boxes with a cutting edge, clings to many smooth surfaces and can thus remain tight over the opening of a container without adhesive. Common plastic wrap is roughly 0.0005 inches thick. The trend has been to produce thinner plastic wrap, particularly for household use, so now the majority of brands on shelves around the world are 8, 9 or 10 μm thick.

<span class="mw-page-title-main">Low-density polyethylene</span> Chemical compound

Low-density polyethylene (LDPE) is a thermoplastic made from the monomer ethylene. It was the first grade of polyethylene, produced in 1933 by Dr John C. Swallow and M.W Perrin who were working for Imperial Chemical Industries (ICI) using a high pressure process via free radical polymerization. Its manufacture employs the same method today. The EPA estimates 5.7% of LDPE is recycled in the United States. Despite competition from more modern polymers, LDPE continues to be an important plastic grade. In 2013 the worldwide LDPE market reached a volume of about US$33 billion.

<span class="mw-page-title-main">Blister pack</span> Type of packaging

A blister pack is any of several types of pre-formed plastic packaging used for small consumer goods, foods, and for pharmaceuticals.

Coated paper is paper that has been coated by a mixture of materials or a polymer to impart certain qualities to the paper, including weight, surface gloss, smoothness, or reduced ink absorbency. Various materials, including kaolinite, calcium carbonate, bentonite, and talc, can be used to coat paper for high-quality printing used in the packaging industry and in magazines.

<span class="mw-page-title-main">Plasticulture</span> Use of plastic materials in agriculture

Plasticulture is the practice of using plastic materials in agricultural applications. The plastic materials themselves are often and broadly referred to as "ag plastics". Plasticulture ag plastics include soil fumigation film, irrigation drip tape/tubing, plastic plant packaging cord, nursery pots and bales, but the term is most often used to describe all kinds of plastic plant/soil coverings. Such coverings range from plastic mulch film, row coverings, high and low tunnels (polytunnels), to plastic greenhouses.

<span class="mw-page-title-main">Plastic bottle</span> Narrow-necked container

A plastic bottle is a bottle constructed from high-density or low density plastic. Plastic bottles are typically used to store liquids such as water, soft drinks, motor oil, cooking oil, medicine, shampoo, milk, ink, etc. They come in a range of sizes, from very small bottles to large carboys. Consumer blow molded containers often have integral handles or are shaped to facilitate grasping.

Borealis AG is an Austrian plastics manufacturer. As the second largest producer of polyolefins in Europe, it is one of the market leaders in the petrochemicals industry.

<span class="mw-page-title-main">Ethylene vinyl alcohol</span> Chemical compound

Ethylene vinyl alcohol (EVOH) is a formal copolymer of ethylene and vinyl alcohol. Because the latter monomer mainly exists as its tautomer acetaldehyde, the copolymer is prepared by polymerization of ethylene and vinyl acetate to give the ethylene vinyl acetate (EVA) copolymer followed by hydrolysis. EVOH copolymer is defined by the mole % ethylene content: lower ethylene content grades have higher barrier properties; higher ethylene content grades have lower temperatures for extrusion.

PBAT is a biodegradable random copolymer, specifically a copolyester of adipic acid, 1,4-butanediol and terephthalic acid. PBAT is produced by many different manufacturers and may be known by the brand names ecoflex, Wango,Ecoworld, Eastar Bio, and Origo-Bi. It is also called poly(butylene adipate-co-terephthalate) and sometimes polybutyrate-adipate-terephthalate or even just "polybutyrate". It is generally marketed as a fully biodegradable alternative to low-density polyethylene, having many similar properties including flexibility and resilience, allowing it to be used for many similar uses such as plastic bags and wraps. The structure is a random-block polymer consisting of butanediol–adipic acid and butanediol-terephthalic acid blocks.

Metallised films are polymer films coated with a thin layer of metal, usually aluminium. They offer the glossy metallic appearance of an aluminium foil at a reduced weight and cost. Metallised films are widely used for decorative purposes and food packaging, and also for specialty applications including insulation and electronics.

Extrusion coating is the coating of a molten web of synthetic resin onto a substrate material. It is a versatile coating technique used for the economic application of various plastics, notably polyethylene, onto paperboard, corrugated fiberboard, paper, aluminium foils, cellulose, Non-wovens, or plastic films. It was. first developed in the 1940s for polyethylene coated paper for bags and packaging.

<span class="mw-page-title-main">Release liner</span>

A release liner or release paper is a paper or plastic-based film sheet used to prevent a sticky surface from prematurely adhering. It is coated on one or both sides with a release agent, which provides a release effect against any type of a sticky material such as an adhesive or a mastic. Release liners are available in different colors, with or without printing under the low surface energy coating or on the backside of the liner. Release is separation of the liner from a sticky material; liner is the carrier for the release agent.

<span class="mw-page-title-main">Plastic film</span> Thin continuous polymeric material

Plastic film is a thin continuous polymeric material. Thicker plastic material is often called a "sheet". These thin plastic membranes are used to separate areas or volumes, to hold items, to act as barriers, or as printable surfaces.

<span class="mw-page-title-main">Plastic</span> Material of a wide range of synthetic or semi-synthetic organic solids

Plastics are a wide range of synthetic or semi-synthetic materials that use polymers as a main ingredient. Their plasticity makes it possible for plastics to be molded, extruded or pressed into solid objects of various shapes. This adaptability, plus a wide range of other properties, such as being lightweight, durable, flexible, and inexpensive to produce, has led to their widespread use. Plastics typically are made through human industrial systems. Most modern plastics are derived from fossil fuel-based chemicals like natural gas or petroleum; however, recent industrial methods use variants made from renewable materials, such as corn or cotton derivatives.

References

  1. Delva, Laurens; Deceur, Cédric; Van Damme, Nicolas; Ragaert, Kim (2019). "Compatibilization of PET-PE blends for the recycling of multilayer packaging foils" (PDF). Proceedings of the Europe/Africa Conference Dresden 2017 - Polymer Processing Society PPS. AIP Conference Proceedings. 2055 (1): 030005. Bibcode:2019AIPC.2055c0005D. doi: 10.1063/1.5084815 .
  2. "Plastic curbs to spare multi-layered packaging". www.telegraphindia.com. Retrieved 2020-04-16.
  3. "Multilayer packaging: innovative and sustainable". www.basf.com. Retrieved 2020-04-16.
  4. Pinto, Viveat Susan (2019-10-02). "ITC launches first multilayered plastic collection, recycling drive in Pune". Business Standard India. Retrieved 2020-04-16.
  5. Brody, Aaron L.; Strupinsky, E. P.; Kline, Lauri R. (2001-06-08). Active Packaging for Food Applications. CRC Press. ISBN   978-1-4200-3181-2.
  6. "Multilayer Films". polymerdatabase.com. Retrieved 2020-04-16.
  7. "University of Pittsburgh". New Plastics Economy (en-GB). Retrieved 2020-04-16.