Stibiotantalite

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Stibiotantalite
Stibiotantalite-ch10a.jpg
General
Category Oxide minerals
Formula
(repeating unit)
Sb(Ta,Nb)O4
IMA symbol Sttl [1]
Strunz classification 04.DE.30
Dana classification08.01.06.02
Crystal system orthorhombic
Space group mm2
Unit cell a = 4.9, b = 11.79, c = 5.57Å, Z = 4; V = 321.78
Identification
Formula mass 336.70
Colouryellow to dark brown, reddish
Fracture brittle-conchoidal
Mohs scale hardness5.5
Streak light yellow
Diaphaneity transparent to translucent
Density 6 to 7.57
Refractive index 1.55 - 1.69
Birefringence Biaxial (+), a=2.3742, b=2.4039
2V angle 75.083
Dispersion strong

Stibiotantalite is a mineral consisting of Sb(Ta,Nb)O4 (antimony, tantalum or niobium, and oxygen). It is found in complex granite pegmatites. [2]

Contents

If the quantity of niobium exceeds the tantalum content, the mineral is called stibiocolumbite. [3]

It is translucent to transparent, medium hard (5.5 mohs), appears yellow to dark brown, reddish or greenish brown, with an adamantine luster.

Stibiotantalite is found in veins and walls associated with tin mines. It is a fairly rare to rare mineral. Due to its relative softness, it is more likely to be found in mineral collections than in jewelry. [3]

Occurrence

Stibiotantalite has been found in several countries, but the most significant are Mozambique, Sri Lanka, and the USA. It occurs in complex granite pegmatites. [4]

Mozambique and the USA have the most localities where Stibiotantalite has been found. [5] Mozambique has 6, while the USA has 18. California alone has 15 of these localities.

Use

Stibiotantalite is primarily used as a gemstone. [4] These gems are vivid, shiny, and golden-brown. These gems come between 0.73 carats and 6.34 carats, with the average being 3.54. These gems are similar in appearance to sphalerite, but they are brown instead of orange. While stibiotantalite and tantalite are similar, stibiotantalite is softer, brighter, and heavier.

Etymology

The "stibio-" prefix is a reference to its antimony content. The tantalite suffix shows that the mineral is actually very similar to tantalite. [4]

Related Research Articles

<span class="mw-page-title-main">Niobium</span> Chemical element, symbol Nb and atomic number 41

Niobium is a chemical element with chemical symbol Nb and atomic number 41. It is a light grey, crystalline, and ductile transition metal. Pure niobium has a Mohs hardness rating similar to pure titanium, and it has similar ductility to iron. Niobium oxidizes in Earth's atmosphere very slowly, hence its application in jewelry as a hypoallergenic alternative to nickel. Niobium is often found in the minerals pyrochlore and columbite, hence the former name "columbium". Its name comes from Greek mythology: Niobe, daughter of Tantalus, the namesake of tantalum. The name reflects the great similarity between the two elements in their physical and chemical properties, which makes them difficult to distinguish.

<span class="mw-page-title-main">Pegmatite</span> Igneous rock with very large interlocked crystals

A pegmatite is an igneous rock showing a very coarse texture, with large interlocking crystals usually greater in size than 1 cm (0.4 in) and sometimes greater than 1 meter (3 ft). Most pegmatites are composed of quartz, feldspar, and mica, having a similar silicic composition to granite. However, rarer intermediate composition and mafic pegmatites are known.

<span class="mw-page-title-main">Columbite</span>

Columbite, also called niobite, niobite-tantalite and columbate [(Fe, Mn)Nb
2
O
6
], is a black mineral group that is an ore of niobium. It has a submetallic luster and a high density and is a niobate of iron and manganese. This mineral group was first found in Haddam, Connecticut, in the United States. It forms a series with the tantalum-dominant analogue ferrotantalite and one with the manganese-dominant analogue manganocolumbite. The iron-rich member of the columbite group is ferrocolumbite. Some tin and tungsten may be present in the mineral. Yttrocolumbite is the yttrium-rich columbite with the formula (Y,U,Fe)(Nb,Ta)O
4
. It is a radioactive mineral found in Mozambique.

<span class="mw-page-title-main">Euxenite</span> Oxide mineral

Euxenite, or euxenite-(Y), is a brownish black mineral with a metallic luster.

<span class="mw-page-title-main">Phenakite</span>

Phenakite or phenacite is a fairly rare nesosilicate mineral consisting of beryllium orthosilicate, Be2SiO4. Occasionally used as a gemstone, phenakite occurs as isolated crystals, which are rhombohedral with parallel-faced hemihedrism, and are either lenticular or prismatic in habit: the lenticular habit is determined by the development of faces of several obtuse rhombohedra and the absence of prism faces. There is no cleavage, and the fracture is conchoidal. The Mohs hardness is high, being 7.5 – 8; the specific gravity is 2.96. The crystals are sometimes perfectly colorless and transparent, but more often they are greyish or yellowish and only translucent; occasionally they are pale rose-red. In general appearance the mineral is not unlike quartz, for which indeed it has been mistaken. Its name comes from Ancient Greek: φέναξ, romanized: phénax, meaning "deceiver" due to its close visual similarity to quartz, named by Nils Gustaf Nordenskiöld in 1833.

<span class="mw-page-title-main">Tantalite</span> Tantalum ore

The mineral group tantalite [(Fe, Mn)Ta2O6] is the primary source of the chemical element tantalum, a corrosion (heat and acid) resistant metal. It is chemically similar to columbite, and the two are often grouped together as a semi-singular mineral called coltan or "columbite-tantalite" in many mineral guides. However, tantalite has a much greater specific gravity than columbite (8.0+ compared to columbite's 5.2). Iron-rich tantalite is the mineral tantalite-(Fe) or ferrotantalite and manganese-rich is tantalite-(Mn) or manganotantalite.

<span class="mw-page-title-main">Spessartine</span> Nesosilicate, manganese aluminium garnet species

Spessartine is a nesosilicate, manganese aluminium garnet species, Mn2+3Al2(SiO4)3. This mineral is sometimes mistakenly referred to as spessartite.

<span class="mw-page-title-main">Polycrase</span>

Polycrase or polycrase-(Y) is a black or brown metallic complex uranium yttrium oxide mineral with the chemical formula (Y,Ca,Ce,U,Th)(Ti,Nb,Ta)2O6. It is amorphous. It has a Mohs hardness of 5 to 6 and a specific gravity of 5. It is radioactive due to its uranium content. It occurs in granitic pegmatites.

Tantite is a rare tantalum oxide mineral with formula: Ta2O5. Tantite forms transparent microscopic colorless triclinic - pedial crystals with an adamantine luster. It has a Mohs hardness of 7 and a high specific gravity of 8.45. Chemical analyses show minor inclusion (1.3%) of niobium oxide.

<span class="mw-page-title-main">Microlite</span>

Microlite was once known as a pale-yellow, reddish-brown, or black isometric mineral composed of sodium calcium tantalum oxide with a small amount of fluorine. Its chemical formula is(Na,Ca)2Ta2O6(O,OH,F). Today it is a name of a group of oxide minerals of a similar stoichiometry having tantalum prevailing over titanium and niobium. The microlite group belongs to a large pyrochlore supergroup that occurs in pegmatites and constitutes an ore of tantalum. It has a Mohs hardness of 5.5 and a variable specific gravity of 4.2 to 6.4. It occurs as disseminated microscopic subtranslucent to opaque octahedral crystals with a refractive index of 2.0 to 2.2. Microlite is also called djalmaite, but both names are now obsolete.

<span class="mw-page-title-main">Jeremejevite</span>

Jeremejevite is an aluminium borate mineral with variable fluoride and hydroxide ions. Its chemical formula is Al6B5O15(F,OH)3. It is considered as one of the rarest, thus one of the most expensive stones. For nearly a century, it was considered as one of the rarest gemstones in the world.

<span class="mw-page-title-main">Tapiolite</span>

Tapiolite [(Fe, Mn)(Nb, Ta)2O6] is a black mineral series that is an ore of niobium and tantalum. The tapiolite group includes tapiolite-(Fe) or ferrotapiolite and tapiolite-(Mn) or manganotapiolite. Tapiolite-(Fe) is by far the more common of the two.

<span class="mw-page-title-main">Wodginite</span>

Wodginite is a manganese, tin, tantalum oxide mineral with the chemical formula Mn2+(Sn,Ta)Ta2O8. It may also include significant amounts of niobium.

<span class="mw-page-title-main">Ixiolite</span>

Ixiolite is an accessory oxide mineral found in granitic pegmatites. It is an oxide with the general chemical formula (Ta,Nb,Sn,Mn,Fe)4O8 or (Ta,Mn,Nb)O2.

Billwiseite is a very rare oxide mineral found at the pegmatite commonly referred to as "Stak Nala" located within a few hundred yards from the village of Toghla in the Stak Nala, Gilgit-Baltistan Pakistan. It has only been found as a coating on a single crystal of lepidolite. The sole rock containing Billwiseite is kept at the Royal Ontario Museum, catalogue number M5595.

<span class="mw-page-title-main">Béhierite</span>

Béhierite is a very rare mineral, a natural tantalum borate of the formula (Ta,Nb)BO4. Béhierite is also one of the most simple tantalum minerals. It contains simple tetrahedral borate anions, instead of more common among minerals, planar BO3 groups. It forms a solid solution with its niobium-analogue, schiavinatoite. Both have zircon-type structure (tetragonal, space group I41/amd) and are found in pegmatites. Béhierite and holtite are minerals with essential tantalum and boron.

Szklaryite is an extremely rare mineral with the formula []Al6BAs33+O15. It is essentially vacant ("[]"), arsenic-dominant member of dumortierite supergroup, giving a name of szklaryite group. It is one of three quite recently found minerals of this group, the other two being nioboholtite and titanoholtite, all coming from the Szklary village near Ząbkowice Śląskie in Poland. They occur in a unique pegmatite of probable anatectic origin.

Nioboholtite is an extremely rare mineral with the formula (Nb0.6[]0.4)Al6BSi3O18. It is the niobium-rich member of the dumortierite supergroup, and the niobium analogue of holtite of the holtite group. It is one of three quite recently found minerals of this group, the other two being titanoholtite and szklaryite, all coming from the Szklary village near Ząbkowice Śląskie in Poland. They occur in a unique pegmatite. Nioboholtite and schiavinatoite are both minerals with essential niobium and boron.

Titanoholtite is an extremely rare mineral with the formula (Ti0.75[]0.25)Al6BSi3O18. It is titanium-rich member of dumortierite supergroup, and titanium-analogue of holtite of the holtite group. It is one of three quite recently found minerals of this group, the other two being nioboholtite and szklaryite, all coming from the Szklary village near Ząbkowice Śląskie in Poland. They occur in a unique pegmatite of probable anatectic origin.

<span class="mw-page-title-main">Chiolite</span> Dipyramidal mineral

Chiolite is a tetragonal-ditetragonal dipyramidal mineral, composed of sodium, fluorine, and aluminium. The name originates from the combination of the Greek words for snow (χιώυ) and stone (λίθος). It is an allusion to its similarity and appearance to cryolite. Chiolite is an IMA approved mineral that has been grandfathered, meaning the name chiolite is believed to refer to a valid species to this day. Synonmys of chiolite are arksudite, arksutite, chodneffite, chodnewite and nipholith. It was first discovered in the Ilmen mountains, Russia, in 1846. Chiolite has been a valid species from the same year of its discovery.

References

  1. Warr, L.N. (2021). "IMA–CNMNC approved mineral symbols". Mineralogical Magazine. 85 (3): 291–320. Bibcode:2021MinM...85..291W. doi: 10.1180/mgm.2021.43 . S2CID   235729616.
  2. "Stibiotantalite Mineral Data". Web Mineral. Retrieved March 9, 2019.
  3. 1 2 "Stibiotantalite Value, Price, and Jewelry Information". International Gem Society. Retrieved March 9, 2019.
  4. 1 2 3 "Stibiotantalite". Gemdat. Gemdat. Retrieved 28 September 2022.
  5. "Stibiotantalite". Mindat. mindat. Retrieved 28 September 2022.