Buckypaper

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Buckypaper made of carbon nanotubes Buckypaper.jpg
Buckypaper made of carbon nanotubes

Buckypaper is a thin sheet made from an aggregate of carbon nanotubes [1] or carbon nanotube grid paper. The nanotubes are approximately 50,000 times thinner than a human hair. Originally, it was fabricated as a way to handle carbon nanotubes, but it is also being studied and developed into applications by several research groups, showing promise as vehicle armor, personal armor, and next-generation electronics and displays.

Contents

Background

Buckypaper is a macroscopic aggregate of carbon nanotubes (CNT), or "buckytubes". It owes its name to the buckminsterfullerene, the 60 carbon fullerene (an allotrope of carbon with similar bonding that is sometimes referred to as a "Buckyball" in honor of R. Buckminster Fuller). [1]

Synthesis

The generally accepted methods of making CNT films involves the use of surfactants, such as Triton X-100 [2] and sodium lauryl sulfate, [3] which improves their dispersibility in aqueous solution. These suspensions can then be membrane filtered under positive or negative pressure to yield uniform films. [4] The van der Waals force's interaction between the nanotube surface and the surfactant can often be mechanically strong and quite stable and therefore there are no assurances that all the surfactant is removed from the CNT film after formation. Washing with methanol, an effective solvent in the removal of Triton X, was found to cause cracking and deformation of the film. It has also been found that Triton X can lead to cell lysis and in turn tissue inflammatory responses even at low concentrations. [5]

In order to avoid adverse side-effects from the possible presence of surfactants, an alternative casting process can be used involving a frit compression method that did not require the use of surfactants or surface modification. [6] The dimensions can be controlled through the size of the syringe housing and through the mass of carbon nanotubes added. Their thicknesses are typically much larger than surfactant-cast buckypaper and have been synthesized from 120 μm up to 650 μm; whilst no nomenclature system exists to govern thicknesses for samples to be classified as paper, samples with thicknesses greater than 500 μm are referred to as buckydiscs. The frit compression method allows rapid casting of buckypaper and buckydiscs with recovery of the casting solvent and control over the 2D and 3D geometry.

Aligned multi-walled carbon nanotube (MWNT) growth has been used in CNT film synthesis through the domino effect. [7] In this process, "forests" of MWNTs are pushed flat in a single direction, compressing their vertical orientation into the horizontal plane, which results in the formation of high-purity buckypaper with no further purification or treatment required. By comparison, when a buckypaper sample was formed from the 1 ton compression of chemical vapor deposition (CVD) generated MWNT powder, any application of a solvent led to the immediate swelling of the film till it reverted into particulate matter. It appears that for the CNT powder used, compression alone was insufficient to generate robust buckypaper and highlights that the aligned growth methodology generates in situ tube-tube interactions not found in CVD CNT powder and are preserved through to the domino pushing formation of buckypaper.

Recently, [8] a new scalable CNT film fabrication method has been developed: Surface-Engineered Tape Casting (SETC) technique. The SETC technique solves the main challenge of tape-casting which is the detachment of the dried and the typically sticky CNT film from the supporting-substrate. To achieve a perfect detached film, the supporting-substrate has to be engineered with micro-pyramid pore structure morphology. SETC produces large area films from any commercially available carbon nanotubes with tunable length, thickness, density and composition.

Properties

Comparative flame test of airplanes made of cellulose, carbon buckypaper and inorganic boron nitride nanotube buckypaper. Flame test of buckypapers.jpg
Comparative flame test of airplanes made of cellulose, carbon buckypaper and inorganic boron nitride nanotube buckypaper.

Buckypaper is one tenth the weight yet potentially 500 times stronger than steel when its sheets are stacked to form a composite. [1] It could disperse heat like brass or steel and it could conduct electricity like copper or silicon. [1]

Applications

Among the possible uses for buckypaper that are being researched:

See also

Related Research Articles

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References

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  2. ↑ in het Panhuis M, Salvador-Morales C, Franklin E, Chambers G, Fonseca A, Nagy JB (2003). "Characterization of an Interaction between Functionalized Carbon Nanotubes and an Enzyme". Journal of Nanoscience and Nanotechnology. 3 (3): 209–13. doi:10.1166/jnn.2003.187. PMID   14503402.
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  5. ↑ Cornett JB, Shockman GD (1978). "Cellular lysis of Streptococcus faecalis induced with triton X-100". Journal of Bacteriology. 135 (1): 153–60. doi:10.1128/jb.135.1.153-160.1978. PMC   224794 . PMID   97265.
  6. ↑ Whitby R, Fukuda T, Maekawa T, James SL, Mikhalovsky SV (2008). "Geometric control and tuneable pore size distribution of buckypaper and buckydiscs". Carbon. 46 (6): 949–956. Bibcode:2008Carbo..46..949W. doi:10.1016/j.carbon.2008.02.028.
  7. ↑ Wang D, Song PC, Liu CH, Wu W, Fan SS (2008). "Highly oriented carbon nanotube papers made of aligned carbon nanotubes". Nanotechnology. 19 (7): 075609. Bibcode:2008Nanot..19g5609W. doi:10.1088/0957-4484/19/7/075609. PMID   21817646. S2CID   2529608.
  8. ↑ Susantyoko, Rahmat Agung; Karam, Zainab; Alkhoori, Sara; Mustafa, Ibrahim; Wu, Chieh-Han; Almheiri, Saif (2017). "A surface-engineered tape-casting fabrication technique toward the commercialisation of freestanding carbon nanotube sheets". Journal of Materials Chemistry A. 5 (36): 19255–19266. doi:10.1039/c7ta04999d. ISSN   2050-7488.
  9. ↑ Kim, Keun Su; Jakubinek, Michael B.; Martinez-Rubi, Yadienka; Ashrafi, Behnam; Guan, Jingwen; O'Neill, K.; Plunkett, Mark; Hrdina, Amy; Lin, Shuqiong; Dénommée, Stéphane; Kingston, Christopher; Simard, Benoit (2015). "Polymer nanocomposites from free-standing, macroscopic boron nitride nanotube assemblies". RSC Adv. 5 (51): 41186–41192. Bibcode:2015RSCAd...541186K. doi:10.1039/C5RA02988K.
  10. ↑ Zhao, Zhongfu; Gou, Jan (2009). "Improved fire retardancy of thermoset composites modified with carbon nanofibers". Science and Technology of Advanced Materials. 10 (1): 015005. Bibcode:2009STAdM..10a5005Z. doi:10.1088/1468-6996/10/1/015005. PMC   5109595 . PMID   27877268.
  11. ↑ Susantyoko, Rahmat Agung; Parveen, Fathima; Mustafa, Ibrahim; Almheiri, Saif (2018-05-16). "MWCNT/activated-carbon freestanding sheets: a different approach to fabricate flexible electrodes for supercapacitors". Ionics. 25: 265–273. doi:10.1007/s11581-018-2585-4. ISSN   0947-7047. S2CID   104278214.
  12. ↑ Susantyoko, Rahmat Agung; Karam, Zainab; Alkhoori, Sara; Mustafa, Ibrahim; Wu, Chieh-Han; Almheiri, Saif (2017). "A surface-engineered tape-casting fabrication technique toward the commercialisation of freestanding carbon nanotube sheets". Journal of Materials Chemistry A. 5 (36): 19255–19266. doi:10.1039/c7ta04999d. ISSN   2050-7488.
  13. ↑ Karam, Zainab; Susantyoko, Rahmat Agung; Alhammadi, Ayoob; Mustafa, Ibrahim; Wu, Chieh-Han; Almheiri, Saif (2018-02-26). "Development of Surface-Engineered Tape-Casting Method for Fabricating Freestanding Carbon Nanotube Sheets Containing Fe2O3 Nanoparticles for Flexible Batteries". Advanced Engineering Materials. 20 (6): 1701019. doi:10.1002/adem.201701019. ISSN   1438-1656. S2CID   139283096.
  14. ↑ Susantyoko, Rahmat Agung; Alkindi, Tawaddod Saif; Kanagaraj, Amarsingh Bhabu; An, Boohyun; Alshibli, Hamda; Choi, Daniel; AlDahmani, Sultan; Fadaq, Hamed; Almheiri, Saif (2018). "Performance optimization of freestanding MWCNT-LiFePO4 sheets as cathodes for improved specific capacity of lithium-ion batteries". RSC Advances. 8 (30): 16566–16573. Bibcode:2018RSCAd...816566S. doi: 10.1039/c8ra01461b . ISSN   2046-2069. PMC   9081850 . PMID   35540508.
  15. ↑ Mustafa, Ibrahim; Lopez, Ivan; Younes, Hammad; Susantyoko, Rahmat Agung; Al-Rub, Rashid Abu; Almheiri, Saif (March 2017). "Fabrication of Freestanding Sheets of Multiwalled Carbon Nanotubes (Buckypapers) for Vanadium Redox Flow Batteries and Effects of Fabrication Variables on Electrochemical Performance". Electrochimica Acta. 230: 222–235. doi:10.1016/j.electacta.2017.01.186. ISSN   0013-4686.
  16. ↑ Mustafa, Ibrahim; Bamgbopa, Musbaudeen O.; Alraeesi, Eman; Shao-Horn, Yang; Sun, Hong; Almheiri, Saif (2017-01-01). "Insights on the Electrochemical Activity of Porous Carbonaceous Electrodes in Non-Aqueous Vanadium Redox Flow Batteries". Journal of the Electrochemical Society. 164 (14): A3673–A3683. doi:10.1149/2.0621714jes. hdl: 1721.1/134874 . ISSN   0013-4651.
  17. ↑ Mustafa, Ibrahim; Al Shehhi, Asma; Al Hammadi, Ayoob; Susantyoko, Rahmat; Palmisano, Giovanni; Almheiri, Saif (May 2018). "Effects of carbonaceous impurities on the electrochemical activity of multiwalled carbon nanotube electrodes for vanadium redox flow batteries". Carbon. 131: 47–59. Bibcode:2018Carbo.131...47M. doi:10.1016/j.carbon.2018.01.069. ISSN   0008-6223.
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