| Year of induction | Name | Born | Died | Notes |
|---|
| 1801 | Peter of Portugal, Prince of Beira | 1798 | 1834 | later Emperor Peter I of Brazil and King Peter IV of Portugal |
| 1802 | Prince Leopoldo Giovanni of the Two Siciles | 1790 | 1851 | son of King Ferdinand I of the Two Sicilies |
| Sir John Acton, Bt. | 1736 | 1811 | |
| Carlo Maria Caracciolo, Duke of San Teodoro | 1764 | 1823 | |
| 1804 | Infant Miguel of Portugal | 1802 | 1866 | later King Miguel of Portugal |
| 1805 | Napoleon I, Emperor of the French | 1769 | 1821 | |
| Joseph Bonaparte [3] | 1768 | 1844 | later King of Naples and Spain |
| Louis Bonaparte | 1778 | 1846 | later King of Holland |
| Felice Baciocchi, Prince of Lucca and Piombino | 1762 | 1841 | |
| Camillo Borghese, Prince of Sulmona and Rossano | 1775 | 1832 | |
| Joseph, Cardinal Fesch | 1763 | 1839 | |
| Joachim Murat | 1767 | 1815 | later King of Naples |
| Eugène de Beauharnais | 1781 | 1824 | Viceroy of Italy |
| 1812 | Arthur Wellesley, 1st Duke of Wellington, Prince of Waterloo, Duke of Ciudad Rodrigo and Marquis of Vimeiro | 1769 | 1852 | |
| 1814 | José Miguel de Carvajal, 2nd Duke of San Carlos | 1771 | 1828 | |
| Alexander I, Emperor of Russia | 1777 | 1825 | |
| Frederick William III, King of Prussia | 1770 | 1840 | |
| George, Prince of Wales | 1762 | 1830 | Prince Regent of United Kingdom, later King George IV of the United Kingdom and Hanover |
| Charles Maurice de Talleyrand-Périgord, Prince of Talleyrand and Benevente | 1754 | 1838 | |
| William, Hereditary Prince of Orange | 1792 | 1849 | later King William II of the Netherlands |
| Louis-Antoine, Duke of Angoulême | 1775 | 1844 | |
| Charles-Ferdinand, Duke of Berry | 1778 | 1820 | |
| Charles XIII, King of Sweden | 1748 | 1818 | |
| Carlos Gutiérrez de los Ríos Fernández de Córdoba, Count (later Duke) of Fernan-Nuñez and Montellano | 1779 | 1827 | |
| 1816 | Pedro Cevallos | 1764 | 1840 | |
| Dmitriy Tatistcheff | 1767 | 1845 | Russian diplomat |
| William I, King of the Netherlands | 1772 | 1843 | |
| Juan de la Cruz Belvis de Moncada, Marquis of Belgida | 1756 | 1835 | |
| Pedro de Alcántara Álvarez de Toledo, Count of Miranda and Duke Peneranda | 1765 | 1824 | |
| Ignacio de Arteaga e Idiáquez, Marquis of Valmediano | 1748 | 1817 | |
| Francisco de Meneses Silveira y Castro, Marquis of Valada | 1754 | 1834 | |
| Francisco de Paula Fernández de Córdoba, 18th Count of la Puebla del Maestre | 1763 | 1824 | |
| Nicola Caetano Jose Centurioni e Vera, Marquis of la Lapilla | 1761 | 1834 | |
| Francisco de Borja Idiaquez de Palafox, Duke of Granada and Ega [ es ] | 1755 | 1817 | |
| Pedro de Alcántara de Toledo, 13th Duke of Infantado | 1773 | 1841 | |
| Joaquín Antonio Samaniego, Count of Torrejón and Marquis of Valverde | 1769 | 1844 | |
| 1817 | Constantine, Tsesarevich and Grand Duke of Russia | 1779 | 1831 | |
| Grand Duke Nicholas Pavlovich of Russia | 1796 | 1855 | later Emperor Nicholas I of Russia |
| Grand Duke Michael Pavlovich of Russia | 1798 | 1849 | son of Emperor Paul I of Russia |
| Antonio María Ponce de León, Duke of Montemar | 1757 | 1826 | |
| Augustin Pedro González Telmo Fernández de Híjar, Duke of Híjar | 1773 | 1817 | |
| Antonio Rocaberti de Dameto, Count of Peralada and Viscount of Rocaberti | 1782 | 1825 | |
| 1818 | Infante Carlos Luis of Spain | 1818 | 1861 | Second Carlist Claimant to the throne of Spain, Count of Montemolin |
| Frederick William, Prince of Prussia | 1795 | 1861 | later King Frederick William IV of Prussia |
| Frederick VI, King of Denmark | 1786 | 1839 | |
| Ramón San Martín, Marquis of San Martin | 1764 | 1826 | |
| 1819 | Antoine Claude de Noailles, Duke of Mouchy | 1777 | 1846 | |
| Fulco Ruffo di Calabria, 8th Prince of Scilla | 1773 | 1852 | |
| Tommaso Maria di Somma, 9th Marquis of Circello | 1737 | 1826 | |
| Frederick Augustus I, King of Saxony | 1750 | 1827 | |
| Francisco Ramón de Spes Fernández de Córdoba, Duke of Alagón | 1758 | 1841 | |
| Valentín Carlos, Marquis de Villanueva del Duero, Count of Villariezo | 1762 | 1823 | |
| 1820 | Infante Francis of Spain | 1820 | 1821 | son of Infante Francisco de Paula of Spain |
| Luis María de Borbón y Vallabriga, 14th Count of Chinchón | 1777 | 1823 | Archbishop of Seville and Toledo, Cardinal. |
| 1821 | José Gabriel Bazán de Silva, 10th Marquis of Santa Cruz | 1782 | 1839 | |
| Ferdinand, Duke of Noto | 1810 | 1859 | later Ferdinand II of the Two-Siciles |
| Anne Pierre, Prince of Montmorency-Laval | 1768 | 1837 | |
| 1822 | Infante Francis of Spain | 1822 | 1902 | Duke of Cádiz, later King Consort of Spain |
| Infante Juan Carlos of Spain | 1822 | 1887 | son of Infante Carlos of Spain, the first Carlist Claimant |
| Charles XIV John, King of Sweden | 1764 | 1844 | |
| 1823 | Ferdinand Charles, Prince of Lucca | 1823 | 1854 | later Duke Charles III of Parma |
| Infante Enrique of Spain | 1823 | 1870 | son of the Infante Francisco de Paula, youngest son of King Charles IV of Spain. Later Duke of Seville |
| Joaquín José Melgarejo de Ruiz Dávalos, Duke of San Fernando | 1780 | 1835 | |
| Charles Albert, Prince of Savoy-Carignan | 1798 | 1849 | later King of Sardinia |
| Louis Justin, marquis de Talaru [ fr ] | 1773 | 1850 | French Ambassador to Spain |
| Infante Sebastian of Spain | 1813 | 1875 | son of Teresa, Princess of Beira and Infante Pedro Carlos of Spain |
| Carlo Andrea Pozzo di Borgo | 1764 | 1842 | Russian diplomat |
| Henri, Duke of Bordeaux | 1820 | 1883 | later the French legitimist pretender, count of Chambord |
| Jean Baptiste Guillaume, Count of Villèle | 1773 | 1854 | |
| François, Viscount of Chateaubriand | 1768 | 1848 | |
| 1824 | Pedro de Sousa Holstein, Duke of Palmella | 1781 | 1850 | |
| Charles Robert, Count of Nesselrode | 1780 | 1862 | the Russian foreign minister |
| Christian Gunther, Count of Bernstorff | 1769 | 1835 | |
| Infante Ferdinand of Spain | 1824 | 1861 | son of the Infante Carlos of Spain, the first Carlist Claimant |
| Paul, Duke of Noailles and Ayen | 1802 | 1885 | |
| 1825 | Prince John of Saxony | 1801 | 1873 | later King John I of Saxony |
| 1826 | Infante Edward Philip of Spain | 1826 | 1830 | |
| Charles, Prince of Capua | 1811 | 1862 | son of King Francis I of the Two-Sicilies |
| Leopold, Count of Syracuse | 1813 | 1860 | son of King Francis I of the Two-Sicilies |
| Grand Duke Alexander Nikolayevich of Russia | 1818 | 1881 | later Emperor Alexander II of Russia |
| Antonio, Count of Lecce | 1814 | 1843 | son of King Francis I of the Two-Sicilies |
| 1827 | José Antonio Aragon y Azlor, 12th Duke of Villahermosa, Duke of Palata and Count of Real | 1785 | 1852 | |
| 1829 | Vicenze Maria Grifeo, Duke of Floridia, Prince of Partanna | ? | ? | |
| Luigi de' Medici dei Principi de Ottajano | 1760 | 1830 | |
| Donato, Marquis Tommasi and Casaliecho | ? | ? | |
| Pedro Gómez Labrador, Marquis of Labrador | 1755 | 1852 | |
| José Rafael Fadrique Fernández de Híjar, 13th Duke of Híjar | ? | 1863 | |
| Francisco Castaños, 1st Duke of Bailén | 1758 | 1852 | |
| Francisco Tadeo Calomarde, Duke of Santa Isabel | 1773 | 1842 | |
| 1830 | Auguste Pierre, Count of La Ferronays | 1777 | 1842 | |
| Louis, Duke of Aquila | 1824 | 1897 | |
| Francis, Count of Trapani | 1827 | 1892 | |
| 1832 | Girolamo, Marquis Ruffo | ? | ? | |
| Prudencio de Guadalfajara, Duke of Castroterrano | ? | ? | |
| 1834 | William IV, King of the United Kingdom and Hanover | 1765 | 1837 | |
| Louis-Philippe I, King of the French | 1775 | 1850 | |
| 1835 | Leopold I, King of the Belgians | 1790 | 1865 | |
| Augustus, Prince of Leuchtenberg | 1810 | 1835 | 1st husband of Queen Maria II of Portugal |
| Pedro II, Emperor of Brazil | 1825 | 1891 | |
| Otto, King of the Hellenes | 1815 | 1867 | |
| Bernardino José López Pacheco, 14th Duke of Frías | 1783 | 1851 | |
| Ferdinand Philippe, Duke of Orléans and Prince Royal of France | 1810 | 1842 | |
| 1837 | Ferdinand II, King-consort of Portugal | 1816 | 1885 | 2nd husband of Queen Maria II of Portugal |
| 1838 | Miguel Tacón, Duke of la Unión and Cuba | 1775 | 1855 | |
| Fernando de Aguillara, Marquis of Cerralbo | ? | ? | |
| Napoléon Louis de Talleyrand-Périgord, Duke of Valençay | 1811 | 1898 | |
| Juan Baptista de Queralt y Silva, Count of Santa Coloma | ? | ? | |
| Nicolas Jean de Dieu Soult | 1769 | 1851 | |
| Manuel Pando Fernandez de Pinedo, 2nd Marquis of Miraflores | 1792 | 1872 | |
| 1840 | Christian VIII, King of Denmark | 1786 | 1848 | |
| Baldomero Espartero, Regent of Spain and Prince of Vergara | 1793 | 1879 | |
| 1841 | Albert of Saxe-Coburg and Gotha, Prince Consort of the United Kingdom | 1819 | 1861 | |
| 1842 | William Alexander, Prince of Orange | 1817 | 1890 | later King William III of the Netherlands |
| 1843 | Salustiano de Olózaga | 1803 | 1873 | |
| Louis, Duke of Nemours | 1814 | 1896 | second son of the King Louis Philippe of the French |
| Diego Isidro Guzmán de la Cerda, 8th Marquis of Montealegre, Duke of Nájera | ? | 1849 | |
| 1844 | François Guizot | 1787 | 1874 | Prime Minister of France |
| Oscar I, King of Sweden | 1799 | 1859 | |
| Francis, Duke of Calabria | 1836 | 1894 | later King Francis II of the Two Sicilies |
| 1845 [4] | Henri, Duke of Aumale | 1822 | 1897 | |
| 1846 | Eugène Lamoral, Prince of Ligne | 1804 | 1880 | |
| Agustín Fernando Muñoz, Duke of Riánsares | 1808 | 1873 | |
| Antoine, Duke of Montpensier | 1824 | 1890 | youngest son of the King Louis Philippe of the French; husband of the Infanta Luisa, sister of Queen Isabella II of Spain |
| François, Prince of Joinville | 1818 | 1900 | |
| Pedro, Crown Prince of Portugal | 1837 | 1861 | later King Pedro V of Portugal |
| 1847 | Ramón María Narváez y Campos, 1st Duke of Valencia | 1800 | 1868 | |
| José María Osorio de Mosco de Carvajal, 17th Duke of Sessa, 19th Duke of Trastamara and 14th Count of Altamira | 1828 | 1881 | |
| 1848 | Frederick VII, King of Denmark | 1808 | 1863 | |
| 1849 | Juan Roca de Togores, 3rd Count of Pinohermoso | 1801 | 1883 | |
| 1850 | Louis Napoleon Bonaparte, President of the French Republic | 1808 | 1873 | later Napoleon III, Emperor of the French. Co-Prince of Andorra. |
| 1851 | Francisco Martinez de la Rosa | 1787 | 1862 | |
| Joaquín Fernández de Córdoba, 6th Duke of Arion | 1787 | 1871 | |
| 1852 | Francisco Javier de Istúriz | 1790 | 1871 | |
| Nicolás de Osorio y Zayas, 16th Marquis of Alcañices, 15th Duke of Albuquerque and 15th Duke of Ledesma | 1793 | 1866 | |
| Juan Bravo Murillo | 1803 | 1873 | |
| Albert Edward, Prince of Wales | 1841 | 1910 | later King Edward VII of the United Kingdom, Emperor of India |
| Louis, Count of Trani | 1838 | 1886 | |
| Charles Louis, Count of Ficquelmont and of the Holy Roman Empire | 1777 | 1857 | heir from a prominent noble family from Lorraine, former imperial ambassador and former Minister-President of the Austrian Empire |
| 1853 | William, Prince of Prussia | 1797 | 1888 | later King William I of Prussia and German Emperor |
| 1854 | Robert, Duke of Parma | 1848 | 1907 | |
| 1855 | Charles, Crown Prince of Sweden | 1826 | 1872 | later King Charles XV of Sweden |
| 1856 | Juan Carlos Francisco, Duke of Saldaña | 1791 | 1876 | |
| Napoleon, Prince Imperial | 1856 | 1879 | son of Emperor Napoleon III of France |
| Prince Adalbert of Bavaria | 1828 | 1875 | son of King Louis I of Bavaria |
| 1857 | Nicholas, Tsarevich and Grand Duke of Russia | 1843 | 1865 | |
| Alexander, Prince Gorchakov | 1798 | 1883 | Foreign Minister of Russia |
| Alfonso, Prince of the Asturias | 1857 | 1885 | later King Alfonso XII of Spain. Head of the Order from 1870/1874 |
| 1859 | Infante Ferdinand of Spain | 1859 | 1872 | nephew of Queen Isabella II of Spain |
| Prince Ludwig Ferdinand of Bavaria | 1859 | 1949 | |
| 1860 | Antonio Remón Zarco del Valle y Huet | 1785 | 1866 | |
| Mariano Téllez Girón, 12th Duke of Osuna and Infantado | 1814 | 1882 | |
| 1861 | Luís I, King of Portugal | 1838 | 1889 | |
| 1862 | Frederick, Crown Prince of Prussia | 1831 | 1888 | later German Emperor Frederick III |
| Francisco, Duke of Marchena | 1861 | 1923 | |
| 1863 | Louis III, Grand Duke of Hesse | 1806 | 1877 | |
| William Nicholas, Prince of Orange and Crown Prince of the Netherlands | 1840 | 1879 | |
| 1864 | Christian IX, King of Denmark | 1818 | 1906 | |
| 1865 | Pedro José Pidal, 1st Marquis of Pidal | 1800 | 1865 | |
| Ángel Ramírez de Bapredano, 3rd Duke of Rivas | 1791 | 1865 | |
| Luis Tomas Fernández de Córdoba, 15th Duke of Medinaceli [ ca ] | 1813 | 1873 | |
| 1866 | George V, King of Hanover | 1819 | 1878 | |
| Prince Friedrich Karl of Prussia | 1801 | 1883 | |
| Alexander, Tsarevich and Grand Duke of Russia | 1845 | 1894 | later Emperor Alexander III of Russia |
| Leopold Ferdinand, Count of Hainaut | 1859 | 1869 | son of King Leopold II of the Belgians |
| Francisco Serrano y Domínguez, Duke de la Torre | 1810 | 1885 | |
| Pedro Colón, Duke of Veragua | ? | ? | |
| Fernando Díaz de Mendoza y Valcárcel, Count of Lalaing de Balazote | 1810 | 1884 | |
| Carlos, Crown Prince of Portugal | 1863 | 1908 | later King Carlos of Portugal |
| 1867 | Luis González Bravo | 1811 | 1871 | |
| 1868 | Gaetano, Count of Girgenti | 1846 | 1871 | Son-in-law of Queen Isabella II of Spain |
| Manuel Seijas Lozano | 1800 | 1868 | |
| Lorenzo Arrazola | 1797 | 1873 | |
| Francisco Javier Arias Dávila Matheu, Count of Punonrostro | 1812 | 1890 | |
| 1870 | Pedro Gómez de la Serna | 1806 | 1871 | |
| Casimiro Vigodet y Guernica | 1787 | 1872 | |
| Abdulaziz (عبد العزيز), Sultan of the Ottoman Empire | 1830 | 1876 | |
| Muhammad III as-Sadiq (محمد الصادق بن حسين), Bey of Tunis | 1813 | 1882 | |
| Amadeo I, King of Spain | 1845 | 1890 | |
| 1871 | Eugenio Emanuele Prince of Savoy-Carignan | 1816 | 1888 | |
| Adolphe Thiers, President of the French Republic | 1797 | 1877 | Co-Prince of Andorra |
| George I, King of the Hellenes | 1845 | 1913 | |
| Frederick Charles, Prince of Prussia | 1828 | 1885 | |
| 1872 | Prince Philippe, Count of Flanders | 1837 | 1905 | son of King Leopold I of the Belgians |
| Manuel Falcó de Adda, 3rd Duke of Fernan-Nuñez and Arco [ es ] | 1856 | 1927 | |
| Cirilo Álvarez Martínez de Velasco [ es ] | 1807 | 1878 | President of the Supreme Court of Spain |
| Antonio de los Ríos y Rosas | 1812 | 1873 | |
| Oscar II, King of Sweden | 1829 | 1907 | |
| 1875 | Juan Manuel González de la Pezuela, Count of Cheste | 1809 | 1906 | |
| José Osorio y Silva, Marquis of Alcañices, Sexto and Alburquerque | 1825 | 1910 | |
| Alejandro Mon y Martínez | 1801 | 1882 | |
| Mariano Roca de Togores, Marquis de Molins, Viscount of Rocamora | 1812 | 1889 | |
| Manuel Pavia y Lacy, 1st Marquis de Novaliches | 1814 | 1896 | |
| Patrice MacMahon, President of the French Republic | 1808 | 1893 | Duke of Magenta and Marshal of France. Co-Prince of Andorra |
| Otto von Bismarck, Prince of Bismarck | 1815 | 1898 | Minister-President of Prussia and Chancellor of German Empire |
| Charles Alexander, Grand Duke of Saxe-Weimar-Eisenach | 1818 | 1901 | |
| Cardinal James Santiago Antonelli | 1806 | 1876 | |
| Alexander, Count of Adlerberg | 1818 | 1884 | |
| Wilhelm, Prince of Prussia | 1859 | 1941 | later German Emperor Wilhelm II |
| Antonio Cánovas del Castillo | 1828 | 1897 | |
| 1877 | Francisco de Borja Bazán de Silva, 11th Marquis of Santa Cruz | 1815 | 1889 | |
| 1878 | Francisco Santa Cruz y Pacheco | 1797 | 1883 | |
| Juan Zavala y de la Puente, Marquis of Sierra Bullones | 1804 | 1879 | |
| Manuel García, Marquis of Barzanallana | 1817 | 1892 | |
| Frederick I, Grand Duke of Baden | 1826 | 1907 | |
| Arsenio Martínez Campos | 1831 | 1900 | |
| Victor Emmanuel, Prince of Italy | 1869 | 1947 | later King Victor Emmanuel III of Italy |
| 1879 | Antonio Maria Fontes Pereria de Mello | 1819 | 1887 | |
| 1880 | Abdul Hamid II (عبد الحميد ثانی), Sultan of the Ottoman Empire | 1842 | 1918 | |
| Antonio d'Orléans, Infant of Spain, Duke of Galliera | 1866 | 1930 | brother-in-law of King Alfonso XII of Spain |
| 1881 | Gaston d'Orléans, Count of Eu | 1842 | 1922 | |
| Manuel Lorenzo Antonio de Acuna y Dewite, Marquis of Bedmar [ es ] | 1821 | 1883 | |
| Gustaf, Crown Prince of Sweden | 1858 | 1950 | later King Gustaf V of Sweden |
| 1882 | Jules Grévy, President of the French Republic | 1807 | 1891 | Co-Prince of Andorra |
| 1883 | Nicholas, Tsarevitch and Grand Duke of Russia | 1868 | 1918 | later Emperor Nicholas II of Russia |
| Frederik, Crown Prince of Denmark | 1843 | 1912 | later King Frederik VIII of Denmark |
| Prince Heinrich of Prussia | 1862 | 1929 | |
| Emperor Meiji of Japan (明治天皇) | 1852 | 1912 | Mutsuhito (personal name) |
| Infante Alfonso of Portugal, Duke of Porto | 1865 | 1920 | |
| 1884 | José Posada Herrera | 1815 | 1885 | |
| Fernando Calderón de la Barca y Collantes, Marquis of Reinosa | 1811 | 1890 | |
| Rafael de Bustos et Castillo, Marquis of Corvera | 1807 | 1894 | |
| 1886 | Alfonso XIII, King of Spain | 1886 | 1941 | posthumous son of Alfonso XII of Spain, King and Grand Master of the Order at his birth (nominal until 1902) |
| Infante Augusto of Portugal, Duke of Coimbra | 1847 | 1889 | |
| Cardinal Louis Jacobini | 1832 | 1887 | |
| José Gutierrez de la Concha, 1st Marquis of La Habana | 1809 | 1895 | |
| 1888 | Thomas, 2nd Duke of Genoa | 1854 | 1931 | |
| Charles I, King of Württemberg | 1823 | 1891 | |
| Alfred, Duke of Edinburgh | 1844 | 1900 | |
| 1889 | Constantine, Crown Prince of Greece | 1868 | 1923 | later King Constantine I of the Hellenes |
| 1890 | José Joaquín Álvarez de Toledo, 18th Duke of Medina Sidonia | 1826 | 1900 | |
| 1891 | Práxedes Mateo Sagasta | 1827 | 1903 | |
| Vladimir Alexandrovitch, Grand Duke of Russia | 1847 | 1909 | |
| Albert, Prince of Prussia, Regent of the Duchy of Brunswick | 1837 | 1906 | |
| 1892 | William II, King of Württemberg | 1848 | 1921 | |
| Cristóbal Colón de la Cerday Gante, Duke of Veragua and Marquis of Jamaica | 1837 | 1910 | |
| Prince Luís Filipe of Portugal, Duke of Braganza | 1887 | 1908 | |
| 1893 | George, Prince of the United Kingdom and Duke of York | 1865 | 1936 | later King George V of the United Kingdom and British dominions beyond the seas, Emperor of India |
| 1895 | Guillermo Chacón y Maldonado | 1813 | 1899 | |
| José Elduayen y Gorriti, Marquis of Pazo de la Merced | 1823 | 1898 | |
| Eugenio Montero Ríos | 1832 | 1914 | |
| 1896 | George Alexandrovitch, Grand Duke of Russia | 1871 | 1899 | |
| Yoshihito, Crown Prince of Japan (嘉仁) | 1879 | 1926 | later Emperor Taishō (大正天皇) of Japan |
| 1897 | Ferdinand, Duke of Calabria | 1869 | 1960 | |
| 1898 | Félix Faure, President of the French Republic | 1841 | 1899 | Co-Prince of Andorra |
| 1900 | Wilhelm, Crown Prince of Germany | 1882 | 1951 | |
| Enrique Ramírez de Saaveda y Cueto, 4th Duke of Rivas and Marquis de Andia | 1828 | 1914 | |
| Carlos María Stuart Fitz James y Portocarrero, 9th Duke of Berwick and 16th Duke of Alba | 1849 | 1901 | |
| Alejandro Llorente y Lamas | 1814 | 1901 | |