Nickel azide

Last updated
Nickel azide
Names
IUPAC name
Nickel(II) diazide
Other names
Nickel diazide
Identifiers
3D model (JSmol)
ChemSpider
PubChem CID
  • InChI=1S/2N3.Ni/c2*1-3-2;/q2*-1;+2
    Key: JRUBGUVYQMKOMK-UHFFFAOYSA-N
  • [N-]=[N+]=[N-].[N-]=[N+]=[N-].[Ni+2]
Properties
Ni(N3)2
Molar mass 142.73 g/mol
Hazards
GHS labelling:
GHS-pictogram-explos.svg
Danger
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

Nickel azide is an inorganic chemical compound with the formula Ni(N3)2. It can be formed through the reaction between nickel tetracarbonyl and iodine azide. [1]

2Ni(CO)4 + 2IN3 → Ni(N3)2 + NiI2 + 8CO

Properties

Nickel azide water solution has high absorbance in the ultraviolet with a peak at 292 nm. The solution also contains hexaaquanickel cations with visible light absorption peaks at 394, 656, and 720 nm. [2] A related mixed anion compound with nicotinic acid and nicotinate exhibits EO bridging coordination (μ-1,1) on the azide, and possesses an unusual angle between the nickel and nitrogen present within the complex. [3] Like most azides, it is explosive.

References

  1. ↑ Dehnicke, K.; Dübgen, R. (1 September 1978). "Die Reaktionen des Jodazids mit Metallcarbonylen". Zeitschrift für anorganische und allgemeine Chemie (in German). 444 (1): 61–70. doi:10.1002/zaac.19784440106. ISSN   0044-2313. Archived from the original on 2022-10-24. Retrieved 2023-10-30.
  2. ↑ Egghart, H. C. (26 August 1968). "A study of nickel-azido complex formation in aqueous solution" . J. Inorg. Nucl. Chem. 31 (5): 1538–1541. doi:10.1016/0022-1902(69)80278-2 . Retrieved 30 October 2023.
  3. ↑ Liu, Fu-Chen; Zeng, Yong-Fei; Li, Jian-Rong; Bu, Xian-He; Zhang, Hong-Jie; Ribas, Joan (15 September 2005). "Novel 3-D Framework Nickel(II) Complex with Azide, Nicotinic Acid, and Nicotinate(1−) as Coligands: Hydrothermal Synthesis, Structure, and Magnetic Properties" . Inorganic Chemistry. 44 (21): 7298–7300. doi:10.1021/ic051030b. PMID   16212349 . Retrieved 30 October 2023.
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