Green photocatalyst

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Green photocatalysts are photocatalysts derived from environmentally friendly sources. [1] [2] They are synthesized from natural, renewable, and biological resources, such as plant extracts, biomass, or microorganisms, minimizing the use of toxic chemicals and reducing the environmental impact associated with conventional photocatalyst production. [3] [4]

Contents

A photocatalyst is a material that absorbs light energy to initiate or accelerate a chemical reaction without being consumed in the process. [5] They are semiconducting materials which generate electron-hole pairs upon light irradiation. These photogenerated charge carriers [6] then migrate to the surface of the photocatalyst and interact with adsorbed species, triggering redox reactions. [7] They are promising candidates for a wide range of applications, including the degradation of organic pollutants in wastewater, the reduction of harmful gases, and the production of hydrogen or solar fuels. [8] Many methods exist to produce photocatalysts via both conventional and more green approaches including hydrothermal synthesis or sol-gel, the difference being in the material sources used.

Trend of Scopus-indexed publications on green photocatalysts, including bio-waste, macroalgae, and plant-based materials, from 2000 to 2024 The Rise of Green Photocatalysis A Visual Representation 01.png
Trend of Scopus-indexed publications on green photocatalysts, including bio-waste, macroalgae, and plant-based materials, from 2000 to 2024
VOSviewer analysis ((c) 2024 Centre for Science and Technology Studies, Leiden University) of 5,375 Scopus documents (1999-2026) retrieved using the search query "TITLE-ABS-KEY(green AND photocatalyst) AND PUBYEAR > 1999 AND PUBYEAR < 2026" reveals key trends in green photocatalyst research, including a focus on environmentally friendly synthesis methods and applications in environmental remediation and energy production Scopus vosviewer gp 31oct67.png
VOSviewer analysis (© 2024 Centre for Science and Technology Studies, Leiden University) of 5,375 Scopus documents (1999–2026) retrieved using the search query "TITLE-ABS-KEY(green AND photocatalyst) AND PUBYEAR > 1999 AND PUBYEAR < 2026" reveals key trends in green photocatalyst research, including a focus on environmentally friendly synthesis methods and applications in environmental remediation and energy production

Green precursor materials for photocatalysts

Green sources

A green source for photocatalyst synthesis refers to a material that is renewable, biodegradable, and has minimal environmental impact during its extraction and processing. [3] [4] This approach aligns with the principles of green chemistry, which aim to reduce or eliminate the use and generation of hazardous substances in chemical processes. [3] [4] Green sources are abundant, readily available, and often considered as waste materials, thus offering a sustainable and cost-effective alternative to conventional photocatalyst precursors. [9]

Different synthesis approaches available for the preparation of metal nanoparticles for various application including as Green Photocatalyst Diff synthesis for green nps.webp
Different synthesis approaches available for the preparation of metal nanoparticles for various application including as Green Photocatalyst

Plant-based precursors

Plant extracts and agricultural waste products have emerged as promising green sources for photocatalyst production, offering attractive alternatives to conventional precursors due to their abundance, biodegradability, and cost-effectiveness. [10] Extracts from various plant parts, such as leaves, roots, and fruits, contain phyto-chemicals that can act as reducing and stabilizing agents in nanoparticle synthesis, [10] [11] contributing to the formation of desired photocatalyst morphologies. Meanwhile, waste materials from agricultural processes, such as rice husks and sugarcane bagasse, are rich in cellulose and lignin. [12] These components can be used as precursors for carbon-based photocatalyst or as templates for the synthesis of porous nano-materials. [13] [14]

Phenolic compounds role in the M. oleifera NPs synthesis Incorporation of phenolic compounds in the M. oleifera NP synthesis.webp
Phenolic compounds role in the M. oleifera NPs synthesis
Plant-Based Nanoparticle/Nanocatalysts: Synthesis, Size, and Shape
PlantCommon/Popular NameNPs synthesized and producedSize of NPs (nm)Shape of NPsReference
Citrus limetta Sweet Lime/Mosambi CdO54Quasi-spherical [15]
Dillenia indica Elephant Apple CuO15Spherical [16]
Mikania micrantha Mile-a-minute Weed/American Rope CuO15Spherical [16]
Jackfruit Jackfruit La2O330Needle-shaped [17]
Sansevieria trifasciata Snake Plant/Mother-in-Law's Tongue ZnFe2O45–20Spherical [18]
Commelina benghalensis Benghal Dayflower/Tropical Spiderwort Ag–ZnO–CSs20-100Spherical [19]
Commelina benghalensis Benghal Dayflower/Tropical Spiderwort Au–ZnO–CSs50-400Spherical [19]
Senna siamea Siamese Cassia/Kassod Tree ZnO37.39Spherical [20]
Acacia nilotica Gum Arabic Tree Ag5.72 ± 0.16Spherical [21]
Epipremnum aureum Pothos/Devil's Ivy/Money Plant ZnO29Spherical [22]
Chinese Mahogany Chinese Mahogany LO22.56Long rod-like particles [23]
Citrullus colocynthis Colocynth/Bitter Apple Cu17 ± 4.2Spherical [24]
Aegle marmelos Bael/Bengal Quince FeO18.78Spherical [25]
Couroupita guianensis Cannonball Tree CaO25.2Clusters with irregular forms [26]

Notes:

High-resolution transmission electron microscopy (HRTEM) images of ZnO nanoparticles synthesized by chemical and green methods using beetroot, cedar, and pomegranate extracts at different resolutions 41598 2024 66975 Fig4 HTML.png
High-resolution transmission electron microscopy (HRTEM) images of ZnO nanoparticles synthesized by chemical and green methods using beetroot, cedar, and pomegranate extracts at different resolutions
SEM images of ZnO nanoparticles synthesized by chemical and green methods using beetroot, cedar, and pomegranate extracts at different resolutions 41598 2024 66975 Fig5 HTML.png
SEM images of ZnO nanoparticles synthesized by chemical and green methods using beetroot, cedar, and pomegranate extracts at different resolutions

Bio-waste precursors

Utilizing bio-waste, such as food waste and animal waste, for green photocatalyst synthesis offers a dual benefit of waste management and material production. [27] These waste streams are rich in organic matter, which can be converted into valuable carbon-based photocatalyst through various thermochemical processes. [28] [29]

Bio-Waste/Agro-Waste Derived Nanomaterials: A Summary of Synthesis, Size, and Shape
Bio-wasteNPs synthesized and producedSize of NPs (nm)Shape of NPsReference
Waste oyster shellsnHAp/ZnO/GO9–22Spherical [30]
Rice husk TiO26.2–7.6Irregular sharp cylinder-like particles [31]
Waste of chicken eggshellCaO@NiO15-20Rod-like shape [32]
Papaya (Carica papaya L.) peel biowasteCuO85–140Agglomerated spherical [33]
Dragon fruit (Hylocereus polyrhizus) peel biowasteZnO56Spherical [34]
Longan seeds biowasteZnO10–100Irregular and hexagonal [35]
Banana pseudo stemTiO29.98–24.56Polyhedral [36]
Agro-waste durva grassZrO215-35Spherical [37]
Agricultural waste Hibiscus cannabinus γ-Fe2O3/Si48.3Spherical [38]
Citrus reticulata Blanco (C. reticulata) wasteZnO9Hexagonal [39]
Rooibos tea wasteFe2O3–SnO2-Tone-like structures, tiny rod-like structures, and well-dispersed [40]
Sugarcane bagasseCu2O38.02Irregular [41]

Notes/Explanations:

Green synthesis of ZnO nanoparticles using extracts from three marine macroalgae: (A) Ulva lactuca, (B) Ulva intestinalis, and (C) Sargassum muticum Applsci-14-07069-g001.png
Green synthesis of ZnO nanoparticles using extracts from three marine macroalgae: (A) Ulva lactuca , (B) Ulva intestinalis , and (C) Sargassum muticum

Marine macroalgae/seaweed precursors

Seaweed is a highly promising green source for photocatalyst synthesis due to its rapid growth rates and minimal environmental requirements. [42] It does not require freshwater or fertilizers for cultivation, making it a sustainable and environmentally friendly option. [43] [44] Various seaweed species have been explored for their ability to produce nanoparticles and to act as templates for the synthesis of photocatalytic materials. [45] [46] [47]

Bio-Fabrication of Nanoparticles Using Marine Macroalgae Extracts
Species of MacroalgalBioactive SubstancesPhytochemical ActivitiesNPs synthesized and producedSize of NPs (nm)Shape of NPsReference
Sargassum vulgare Polyphenols, polysaccharides, phytohormones, carotenoids, vitamins, unsaturated fatty acids and free amino acids.Reducing and capping agentsZn50-150Spherical [48]
Sargassum myriocystum PhenolReducing and capping agentsAg20 ± 2.2Well dispersed hexagonal [49]
Sargassum coreanum Polysaccharides, polyphenols, lignansReducing and stabilizing agentAg19Distorted spherical shape [50]
Sargassum spp. Phenolics compoundsCapping agentAg2-35Spherical [51]
Padina tetrastromatica Favonoids, steroids, saponins, tannins, phenols and proteinsReducing and stabilizing agentAu11.4Nearly spherical [52]
Sargassum spp. Ase terpenoids, flavones, and polysaccharidesCapping and stabilization agentFe3O423.60 ± 0.62Agglomerated spherical [53]
Sargassum tenerrimum Polyphenol and proteinsReducing, capping, and stabilizing agentsAg22.5Spherical [54]
Sargassum duplicatum Proteins containing amide and carboxyl groups and carbohydratesReducing and stabilizing agentAg20-50Spherical [55]
Caulerpa sertularioides Alkaloids, phenols, flavonoids, tannins, terpenoids, carbohydrates, glycosides, amino acids, and proteinsReducing and capping agentAg24-57Spherical [56]
Galaxaura elongata , Turbinaria ornata , and Enteromorpha flexuosa Alkaloids, flavonoids, phenolic compounds, proteins, and sugarsReducing and capping agentAg20-25Spherical [57]
Lobophora variegata Polyphenol, bromophenols, lobophorones, and sulphated polysaccharideReduction, capping and stabilizing agentAg6.5-10Oval [58]
red marine algae (Bushehr province, Iran)Amino acids, polysaccharides, carbohydratesReducing and coating agentNiO32.64Spherical [59]

Notes/Explanations:

Dispersion and stability of green sources

Marine Macroalgae as Green Stabilizing Agents for Nanoparticle Synthesis: Dispersion and Stability
ReferenceMarine MacroalgaeBiogenic Capping AgentsNPs synthesized and producedZeta PotentialStabilityPDIDispersionPotential Applications
[51] Sargassum spp.PolyphenolsAg−22.6 mVHigh stability0.246MonodispersityPollutant detection in environmental
[60] Polycladia crinitaPrimary and tertiary amines, polysaccharides, amino acidsSe− 13.9 mVHigh stability-PolydispersedDrug delivery
[61] Cystoseira tamariscifoliaPolyphenols and polysaccharidesAu−24.6 ± 1.5 mVHigh stability--Biomedical
[62] Polysiphonia urceolataPhenols (bromophenols), terpenes, steroids, carbohydrates, and polypeptidesCeO2NPs, NiONPs and CeO2/NiO NCS-High stability-PolydispersedToxic ofloxacin remediation and antibacterial (green surfactant)
[63] Padina boergeseniiPhenolic compounds, aromatic amine groups, nitro compounds, and aliphatic aminesSe-ZnO−16.4 mVHigh stability0.262PolydispersedBiomedicine (anti-cancer)
[64] Ulva lactucaPolyphenols, flavonoids, terpenoids, polysaccharides, and proteinsAg−59.0 mVHigh stability1.092MonodispersedAzo-dyes Photodegradation and biomedical usage
[65] Enteromorpha proliferaAlcohol, thiol, carbon dioxide, and ketanine, alkene, carboxylic acid and amine and alkene compoundAg− 30.8 mVHigh stability0.277PolydispersedBiomedical field
[66] Sargassum wightiiPolyphenolsZnO− 49.39 mVHigh stability0.150PolydispersedBiomedical field
[67] Turbinaria ornataFlavonoid and phenolicAg–63.3 mVHigh stability0.313MonodispersedBiomedical field
[68] Sargassum angustifoliumPolyphenolsAg− 27 mVHigh stability0.15MonodispersedBiomedicine (anti-bactrerial)
[69] Gracilaria birdiaePolysaccharidesAg−28.7 ± 0.7 mV - −31.7 ± 0.4 mVHigh stability0.35 -0.68MonodispersedBiomedicine

Notes/Explanations:

Common green precursor materials for photocatalysts

Green Synthesis of Nano-materials Using Plant and Bio-Waste Extracts
MaterialGreen Source(s)Advantages of SourceReference
TiO2Plant extracts (e.g., Aloe vera)Abundant, biocompatible [70]
ZnOAgricultural waste (e.g., rice husks)Renewable, low cost, high surface area in derived materials [71]
CuOPlant extracts (e.g., Hibiscus sabdariffa L.)Biocompatible, non-toxic, can act as reducing and capping agents [72]
CeO2Plant extracts (e.g., Azadirachta indica)Abundant, eco-friendly [73]
Carbon quantum dots Bio-waste (e.g., food waste)Waste management, cost-effective, tunable properties [74]
Graphene quantum dots Bio-waste (e.g., Spent tea leaves)Waste management, cost-effective, tunable properties [75]

Photocatalyst synthesis methods

Schematic representation of the preparation of Lemon Peel, LP-ZnO NPs by hydrothermal method Catalysts-12-01347-g001-550.webp
Schematic representation of the preparation of Lemon Peel, LP-ZnO NPs by hydrothermal method

Hydrothermal synthesis

Hydrothermal synthesis is a green method that utilizes water under high pressure and temperature to facilitate chemical reactions. [76] It often avoids the need for organic solvents and offers control over crystal size and morphology, making it a versatile approach for producing various photocatalyst materials. [76]

Microwave-assisted synthesis

Microwave-assisted synthesis employs microwaves to provide rapid and uniform heating, leading to faster reaction rates and potential for significant energy savings compared to conventional heating methods. [77] This technique is increasingly favored in green synthesis due to its reduced energy consumption and potential for shorter reaction times. [77]

Sol-gel method

The sol-gel method involves the formation of a gel from a solution, followed by its conversion into a solid material through controlled drying and calcination. [78] It is a versatile technique widely used in the production of various photocatalyst materials, offering advantages in terms of controlling material composition and morphology. [78]

The schematic representation of the sol-gel synthesis of ZnO NPs using different types of chitosan sources and their application in antibacterial and photocatalytic degradation of MB dye 10971 2023 6172 Fig2 HTML.webp
The schematic representation of the sol-gel synthesis of ZnO NPs using different types of chitosan sources and their application in antibacterial and photocatalytic degradation of MB dye

Comparing photocatalyst synthesis methods

The table below provides a comparison of the advantages, potential limitations, and suitability of different green synthesis methods:

Comparison of Common Green Nanomaterials Synthesis Methods
MethodDescriptionAdvantagesPotential LimitationsSuitable for...Reference
Hydrothermal Synthesis Water under high pressure & temperature facilitate chemical reactionsAvoids organic solvents, controls crystal size & morphologyLonger reaction times, specialized equipment neededProducing various photocatalytic materials [79]
Microwave-Assisted SynthesisMicrowaves provide rapid & uniform heatingFaster reaction rates, energy efficientLimited scalability, potential for uneven heatingSynthesis of nanomaterials with controlled size & morphology [80]
Sol-Gel Method Gel from a solution is converted into a solid materialVersatile in producing various materials, controls composition & morphologyRequires careful control of parameters, can be time-consumingMetal oxide nanoparticles, thin films, and coatings [81]

Applications of photocatalysts

Wastewater treatment

Photocatalytic degradation mechanism of Safranin O dye pollutant using Centaurea behen leaf-AgNP composites under sunlight irradiation 41598 2024 64468 Fig7 HTML.webp
Photocatalytic degradation mechanism of Safranin O dye pollutant using Centaurea behen leaf-AgNP composites under sunlight irradiation

Degradation of organic pollutants

Green photocatalyst effectively break down organic contaminants in wastewater into less harmful products through a process known as photocatalytic oxidation. [82] Upon light irradiation, the photocatalyst generates reactive oxygen species (ROS), such as hydroxyl radicals (•OH) and superoxide radicals (O2•-), which attack and decompose organic pollutants. [83] Green photocatalyst synthesized from plant extracts or agricultural waste have shown promising results in degrading various dye molecules, including methylene blue, rhodamine B, and methyl orange. [84] Green photocatalyst have demonstrated the ability to remove pharmaceutical contaminants such as carbamazepine, [85] ibuprofen, [86] tetracycline [87] [88] from wastewater. Additionally, green photocatalyst have been successfully employed in the degradation of pesticides such as alachlor. [89]

Green synthesis of magnetic nanocomposites using Eucalyptus globulus leaf extract and sugarcane bagasse biochar for the photocatalytic degradation of ciprofloxacin and amoxicillin Images large ao3c08116 0002 01.jpg
Green synthesis of magnetic nanocomposites using Eucalyptus globulus leaf extract and sugarcane bagasse biochar for the photocatalytic degradation of ciprofloxacin and amoxicillin
Plant-Based Synthesis of Nanoparticles for Environmental Remediation (Organic Compounds Degradation)
PlantBioactive substancesNPs synthesized and producedSize of NPs (nm)Shape of NPsApplicationsRef
Froriepia subpinnataFlavonoids and phenolicAg18Hemispherical and hexagonalAntimicrobial and adsorption of the Azo dye Acid-Red 58 [90]
Rhododendron arboreumSteroids, terpenoids, alkaloids, saponins, phenols, flavonoids, tannins, glycosides and polyphenolicZnO29.424SphericalDye photodegradation [91]
Elettaria cardamomumPhenolicCoFe2O420–50SphericalPhenol red dye photodegradation [92]
Zingiber officinalePhenolicCoFe2O420–50SphericalPhenol red dye photodegradation [92]
Tillandsia recurvataTannins, reducing sugars, and carbohydratesZnO12–61SphericalMethylene blue (MB) photodegradation [93]
Ajuga ivaCarbohydrates, phenol groups, acidic fractionsAg100-300Polygonal poly–dispersedMethylene blue (MB) photodegradation [94]
Macleaya cordataPhenolicCuO80rectangular and square with irregular rodMethylene blue (MB) photodegradation and antibacterial [95]
Coleus scutellariodesPhenolicNiO23Rod shapeAntibiotic (rufloxacin) photodegradation [96]
Eupatorium adenophorumSesquiterpenoids, triterpenes, flavonoids, phenolics, coumarins, steroids, polyphenols, and phenylpropanolsAg30–400SphericalRhodamin B photodegradation [97]

Notes/Explanations:

  • NPs: Nanoparticles
  • CoFe2O4: Cobalt Ferrite
Magnetic separation of green synthesized of magnetic nanocomposites using Eucalyptus globulus leaf extract and sugarcane bagasse biochar for the photocatalytic degradation of antibiotics, ciprofloxacin and amoxicillin Images large ao3c08116 0002 02.jpg
Magnetic separation of green synthesized of magnetic nanocomposites using Eucalyptus globulus leaf extract and sugarcane bagasse biochar for the photocatalytic degradation of antibiotics, ciprofloxacin and amoxicillin

Removal of heavy metals

In addition to degrading organic pollutants, green photocatalyst can also contribute to the removal of toxic heavy metals from wastewater. The large surface area and functional groups present on green photocatalyst, particularly those derived from carbon-based sources like bio-waste, can effectively adsorb heavy metal ions from the water. [98] Furthermore, photogenerated electrons [99] from the green photocatalyst can reduce heavy metal ions to their less toxic elemental forms, which can then be more easily removed from the wastewater. [98]

Antibacterial mechanism of Cb-AgNPs: disruption of cell membrane, generation of reactive oxygen species (ROS), and damage to cellular components 41598 2024 64468 Fig9 HTML.png
Antibacterial mechanism of Cb-AgNPs: disruption of cell membrane, generation of reactive oxygen species (ROS), and damage to cellular components

Antibacterial activity

Mechanisms of action

Green photocatalyst exhibit potent antibacterial properties due to their ability to generate ROS upon light irradiation. [100] These ROS, including hydroxyl radicals and superoxide radicals, can damage bacterial cell walls and membranes, leading to cell death. [101]

Antibacterial activity of Ligustrum vulgare berry extracts derived silver nanoparticles (LV-AgNPs) against P. aeruginosa and E. coli at various concentrations 41598 2022 11811 Fig8 HTML.webp
Antibacterial activity of Ligustrum vulgare berry extracts derived silver nanoparticles (LV-AgNPs) against P. aeruginosa and E. coli at various concentrations

Examples and applications

Several green photocatalyst have shown promising antibacterial activity. ZnO nanoparticles synthesized using plant extracts have demonstrated strong antibacterial activity against a wide range of bacteria, including E. coli and Staphylococcus aureus . [102] TiO2-based photocatalyst, particularly those doped with silver or copper, exhibit enhanced antibacterial properties under visible light irradiation, making them suitable for disinfection applications. [103] Potential applications of these materials include water disinfection and the creation of antibacterial surfaces. Green photocatalyst can be used to disinfect water by killing harmful bacteria, offering a sustainable alternative to conventional disinfection methods. [103] Incorporating them into coatings or surfaces can create self-sterilizing materials, reducing the risk of bacterial contamination in healthcare settings and other environments. [103]

Plant-Based Synthesis of Nanoparticles for Biomedical Applications (Antimicrobial)
PlantBioactive substancesNPs synthesized and producedSize of NPs (nm)Shape of NPsApplicationsRef
Piper guineense (Uziza) Phenolics and flavonoids ZnO7.39Spherical and well-dispersedAntibacterial [104]
Olea Europaea Protein, carbonyl, carboxyl, amide, and phenols Ag/Ag2O45SphericalAntimicrobial [105]
Froriepia subpinnata Flavonoids and phenolic Ag18Hemispherical and hexagonalAntimicrobial and adsorption of the Azo dye Acid-Red 58 [90]
Vitex negundo Flavonoids ZnO40-50SphericalAntibacterial and Anticancer [106]

Notes/Explanations:

Toxicity assessments

Importance of toxicity evaluation

Cytotoxic effect of shilajit-derived ZnO nanoparticles on HeLa cancer cells compared to cisplatin and normal Vero cells 41598 2024 52217 Fig8 HTML.png
Cytotoxic effect of shilajit-derived ZnO nanoparticles on HeLa cancer cells compared to cisplatin and normal Vero cells

Despite their sustainable origins, a thorough evaluation of the potential toxicity of green photocatalyst is essential to ensure their safe and responsible application in various settings. Even though they are synthesized from environmentally benign materials, their unique properties and nanoscale dimensions can potentially pose risks to human health and the environment. [107] It is crucial to assess the potential for adverse effects before widespread implementation of these materials in water treatment, air purification, or biomedical applications.

Methods for toxicity assessment

Various methods are employed to assess the potential toxicity of green photocatalyst. Eco-toxicity tests expose organisms such as algae, daphnia, or fish to varying concentrations of the photocatalyst to evaluate their effects on growth, reproduction, or mortality. [108] These tests provide valuable insights into the potential impact of green photocatalyst on aquatic ecosystems. Cytotoxicity assays are conducted in laboratory settings using human cell lines to evaluate the potential toxicity of green photocatalysts to human cells. [109] [110] These assays help determine the potential for adverse effects on human health upon exposure to these materials.

Toxicity Assessment of Marine Macroalgae-Derived Nanoparticles
ReferenceMacroalgal–NPsAnimal/Organism ModelToxicity TestExposure DurationConcentration/DoseToxicity
[111] Ericaria amentacea–AgNPs Artemia salina Brine shrimp test24 h17.08 μg/mLLow
[112] Sargassum polycystum–AgNPs Artemia salina Brine shrimp test24 h and 48 h20 to 100 ppmLow
[113] Polycladia myrica–GZ Amphibalanus amphitrite Barnacle larvae cytotoxicity24 h0.031 mg mL−1Low
[114] Kappaphycus alvarezii–ZnONPs 3T3 MTT assay 24 h and 48 h5, 10, 20, 25, 50 and 100 μg/mLLow
[114] Kappaphycus alvarezii–ZnONPs MCF 7 MTT assay 48 h75 μg/mLHigh

Notes/Explanations:

See also

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<span class="mw-page-title-main">Zinc oxide nanoparticle</span>

Zinc oxide nanoparticles are nanoparticles of zinc oxide (ZnO) that have diameters less than 100 nanometers. They have a large surface area relative to their size and high catalytic activity. The exact physical and chemical properties of zinc oxide nanoparticles depend on the different ways they are synthesized. Some possible ways to produce ZnO nano-particles are laser ablation, hydrothermal methods, electrochemical depositions, sol–gel method, chemical vapor deposition, thermal decomposition, combustion methods, ultrasound, microwave-assisted combustion method, two-step mechanochemical–thermal synthesis, anodization, co-precipitation, electrophoretic deposition, and precipitation processes using solution concentration, pH, and washing medium. ZnO is a wide-bandgap semiconductor with an energy gap of 3.37 eV at room temperature.

<span class="mw-page-title-main">Chuanyi Wang</span> Environmental chemistry scientist

Chuanyi Wang is a Chinese American, environmental chemistry scientist, academic, and an author. He is a Distinguished Professor and Academic Dean at the School of Environmental Science and Engineering at the Shaanxi University of Science & Technology. He is recognized for his research in environmental photocatalysis, environmental materials, surface/interface chemistry, nanomaterials, and pollution controlling.

Solar reforming is the sunlight-driven conversion of diverse carbon waste resources into sustainable fuels and value-added chemicals. It encompasses a set of technologies operating under ambient and aqueous conditions, utilizing solar spectrum to generate maximum value. Solar reforming offers an attractive and unifying solution to address the contemporary challenges of climate change and environmental pollution by creating a sustainable circular network of waste upcycling, clean fuel generation and the consequent mitigation of greenhouse emissions.

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