Tin(II) oxalate

Last updated
Tin(II) oxalate
Tin oxalate.svg
Names
Other names
Tin(II) oxalate, Stannous oxalate
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.011.285 OOjs UI icon edit-ltr-progressive.svg
EC Number
  • 212-414-0
PubChem CID
UNII
  • InChI=1S/C2H2O4.Sn/c3-1(4)2(5)6;/h(H,3,4)(H,5,6);/q;+2/p-2
    Key: OQBLGYCUQGDOOR-UHFFFAOYSA-L
  • C(=O)(C(=O)O)O.[Sn]
Properties
C2O4Sn
Molar mass 206.728 g·mol−1
Appearancecolorless crystals
Density 3.56
Melting point 280 °C (536 °F; 553 K) [1]
0.5 g/l
Hazards
GHS labelling:
GHS-pictogram-acid.svg GHS-pictogram-exclam.svg
Warning
H302, H312, H318
P264, P270, P280, P301+P312, P302+P352, P305+P351+P338, P310, P312, P322, P330, P363, P501
Related compounds
Related compounds
 Magnesium oxalate
Strontium oxalate
Barium oxalate
Iron(II) oxalate
Iron(III) oxalate
Praseodymium oxalate
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

Tin(II) oxalate is an inorganic compound, a salt of tin and oxalic acid with the chemical formula SnC
2O
4. [2] The compound looks like colorless crystals, does not dissolve in water, and forms crystalline hydrates.

Contents

Synthesis

Effect of oxalic acid solution on tin(II) oxide  :

Tin(II) oxalate can also be obtained by using tin(II) chloride and oxalic acid. [3]

Properties

Tin (II) oxalate forms colorless crystals.

Insoluble in water and acetone. Soluble in dilute HCl, [4] methanol, and petroleum ether. [5]

Forms crystal hydrates of the composition SnC2O4•n H2O, where n = 1 and 2.

Decomposes on heating:

Applications

Related Research Articles

<span class="mw-page-title-main">Oxalic acid</span> Simplest dicarboxylic acid

Oxalic acid is an organic acid with the systematic name ethanedioic acid and formula HO2C−CO2H. It is the simplest dicarboxylic acid. It is a white crystalline solid that forms a colorless solution in water. Its name comes from the fact that early investigators isolated oxalic acid from flowering plants of the genus Oxalis, commonly known as wood-sorrels. It occurs naturally in many foods. Excessive ingestion of oxalic acid or prolonged skin contact can be dangerous.

<span class="mw-page-title-main">Tin(II) chloride</span> Chemical compound

Tin(II) chloride, also known as stannous chloride, is a white crystalline solid with the formula SnCl2. It forms a stable dihydrate, but aqueous solutions tend to undergo hydrolysis, particularly if hot. SnCl2 is widely used as a reducing agent (in acid solution), and in electrolytic baths for tin-plating. Tin(II) chloride should not be confused with the other chloride of tin; tin(IV) chloride or stannic chloride (SnCl4).

<span class="mw-page-title-main">Tin(II) oxide</span> Chemical compound, stannous oxide (SnO)

Tin(II) oxide is a compound with the formula SnO. It is composed of tin and oxygen where tin has the oxidation state of +2. There are two forms, a stable blue-black form and a metastable red form.

A solubility chart is a chart with a list of ions and how, when mixed with other ions, they can become precipitates or remain aqueous.

<span class="mw-page-title-main">Dimethyl oxalate</span> Chemical compound

Dimethyl oxalate is the organic compound with the formula (CO2CH3)2. It is the dimethyl ester of oxalic acid. Dimethyl oxalate is a colorless or white solid that is soluble in water.

<span class="mw-page-title-main">Sodium hydrogenoxalate</span> Partly deprotonated oxalic acid

Sodium hydrogenoxalate is salt of formula NaHC
2O
4, consisting of sodium cations Na+
 and hydrogenoxalate anions HC
2O−
4 or HO(O=)C-C(=O)O−
. The anion can be described as the result of removing one hydrogen ion H+
 from oxalic acid H
2C
2O
4, or adding one to the oxalate anion C
2O2−
4.

<span class="mw-page-title-main">Beryllium oxalate</span> Chemical compound

Beryllium oxalate is an inorganic compound, a salt of beryllium metal and oxalic acid with the chemical formula C
2BeO
4. It forms colorless crystals, dissolves in water, and also forms crystalline hydrates. The compound is used to prepare ultra-pure beryllium oxide by thermal decomposition.

<span class="mw-page-title-main">Lithium oxalate</span> Chemical compound

Lithium oxalate is an inorganic compound, a salt of lithium metal and oxalic acid with the chemical formula C
2Li
2O
4. Lithium oxalate is soluble in water and converts to the oxide when heated.

Praseodymium(III) oxalate is an inorganic compound, a salt of praseodymium metal and oxalic acid with the chemical formula C6O12Pr2. The compound forms light green crystals, insoluble in water, also forms crystalline hydrates.

<span class="mw-page-title-main">Copper oxalate</span> Chemical compound

Copper oxalate is an inorganic compound, a salt of copper metal and oxalic acid with the chemical formula CuC
2O
4. The compound is practically insoluble in water, alcohol, ether, and acetic acid but soluble in ammonium hydroxide. Copper oxalate forms a hydrate, which forms acid-blue crystals.

<span class="mw-page-title-main">Yttrium oxalate</span> Chemical compound

Yttrium oxalate is an inorganic compound, a salt of yttrium and oxalic acid with the chemical formula Y2(C2O4)3. The compound does not dissolve in water and forms crystalline hydrates—colorless crystals.

Manganese oxalate is a chemical compound, a salt of manganese and oxalic acid with the chemical formula MnC
2O
4. The compound creates light pink crystals, does not dissolve in water, and forms crystalline hydrates. It occurs naturally as the mineral Lindbergite.

Neptunium (IV) oxalate is an inorganic compound, a salt of neptunium and oxalic acid with the chemical formula Np(C2O4)2. The compound is slightly soluble in water, forms crystalline hydrates—green crystals.

Samarium(III) oxalate is an inorganic compound, a salt of samarium and oxalic acid with the formula Sm2(C2O4)3. The compound does not dissolve in water, forms a crystalline hydrate with yellow crystals.

<span class="mw-page-title-main">Dysprosium(III) nitrate</span> Chemical compound

Dysprosium(III) nitrate is an inorganic compound, a salt of dysprosium and nitric acid with the chemical formula Dy(NO3)3. The compound forms yellowish crystals, dissolves in water, forms a crystalline hydrate.

<span class="mw-page-title-main">Holmium(III) nitrate</span> Chemical compound

Holmium (III) nitrate is an inorganic compound, a salt of holmium and nitric acid with the chemical formula Ho(NO3)3. The compound forms yellowish crystals, dissolves in water, also forms crystalline hydrates.

<span class="mw-page-title-main">Ytterbium(III) nitrate</span> Chemical compound

Ytterbium(III) nitrate is an inorganic compound, a salt of ytterbium and nitric acid with the chemical formula Yb(NO3)3. The compound forms colorless crystals, dissolves in water, and also forms crystalline hydrates.

Lutetium(III) nitrate is an inorganic compound, a salt of lutetium and nitric acid with the chemical formula Lu(NO3)3. The compound forms colorless crystals, dissolves in water, and also forms crystalline hydrates. The compound is poisonous.

Erbium(III) nitrate is an inorganic compound, a salt of erbium and nitric acid with the chemical formula Er(NO3)3. The compound forms pink crystals, readily soluble in water, also forms crystalline hydrates.

<span class="mw-page-title-main">Europium compounds</span> Chemical compounds with at least one europium atom

Europium compounds are compounds formed by the lanthanide metal europium (Eu). In these compounds, europium generally exhibits the +3 oxidation state, such as EuCl3, Eu(NO3)3 and Eu(CH3COO)3. Compounds with europium in the +2 oxidation state are also known. The +2 ion of europium is the most stable divalent ion of lanthanide metals in aqueous solution. Lipophilic europium complexes often feature acetylacetonate-like ligands, e.g., Eufod.

References

  1. ↑ "Tin Oxalate". American Elements . Retrieved 5 August 2021.
  2. ↑ "Tin(II) oxalate 98% | Sigma-Aldrich". sigmaaldrich.com . Retrieved 5 August 2021.
  3. ↑ Nagirnyak, Svitlana V.; Lutz, Victoriya A.; Dontsova, Tatiana A.; Astrelin, Igor M. (26 July 2016). "Synthesis and Characterization of Tin(IV) Oxide Obtained by Chemical Vapor Deposition Method". Nanoscale Research Letters . 11 (1): 343. Bibcode:2016NRL....11..343N. doi:10.1186/s11671-016-1547-x. ISSN   1556-276X. PMC   4960077 . PMID   27456501 . Retrieved 5 August 2021.
  4. 1 2 "814-94-8 - Tin(II) oxalate - Stannous oxalate - 14113 - Alfa Aesar". Alfa Aesar . Retrieved 5 August 2021.
  5. ↑ "Registration Dossier - ECHA". European Chemical Agency . Retrieved 5 August 2021.
  6. ↑ Park, Jae-Sang; Jo, Jae-Hyeon; Yashiro, Hitoshi; Kim, Sung-Soo; Kim, Sun-Jae; Sun, Yang-Kook; Myung, Seung-Taek (9 August 2017). "Synthesis and Electrochemical Reaction of Tin Oxalate-Reduced Graphene Oxide Composite Anode for Rechargeable Lithium Batteries". ACS Applied Materials & Interfaces . 9 (31): 25941–25951. doi:10.1021/acsami.7b03325. ISSN   1944-8252. PMID   28718628 . Retrieved 5 August 2021.
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