Fuller's earth is a term for various clays used as an absorbent, filter, or bleaching agent. Products labeled fuller's earth typically consist of palygorskite (also known as attapulgite) or bentonite. [1] Primary modern uses include as absorbents for oil, grease, and animal waste (cat litter), and as a carrier for pesticides and fertilizers. Minor uses include filtering, clarifying, and decolorizing; [1] [2] as an active and inactive ingredient in beauty products; and as a filler in paint, plaster, adhesives, and pharmaceuticals. [1] It also has a number of uses in the film industry and on stage.
The English name reflects the historical use of the material for fulling (cleaning and shrinking) wool, by textile workers known as fullers. [1] [2] [3] In past centuries, fullers kneaded fuller's earth and water into woollen cloth to absorb lanolin, oils, and other greasy impurities as part of the cloth finishing process.
The original spelling was without an apostrophe, but the apostrophe became more common in the 19th century, both before or after the s. Fuller's earth is the most common spelling today, but both fullers earth and fullers' earth remain in wide use. [4]
Fuller's earth is also known by the following other names:
Fuller's earth consists primarily of hydrous aluminum silicates (clay minerals) of varying composition. [1] Common components are montmorillonite, kaolinite, and attapulgite. Small amounts of other minerals may be present in fuller's earth deposits, including calcite, dolomite, and quartz. In some localities fuller's earth refers to calcium bentonite, which is altered volcanic ash composed mostly of montmorillonite. [2] [7]
In 2005, the United States was the largest producer of fuller's earth with an almost 70% world share followed at a distance by Japan and Mexico. In the United States fuller's earth is typically derived from deposits of volcanic ash of Cretaceous age and younger (glacial clays do not form fuller's earth). [1] [5] Fuller's earth deposits have been mined in 24 states. [1] The first discovery of fuller's earth in the United States was near Quincy, Florida, in 1893; previously it was imported from England. In 1939 mines near Quincy produced half the U.S. production. [8]
In the United Kingdom, fuller's earth occurs mainly in England. It has been mined in the Lower Greensand Group and the Vale of White Horse, Oxfordshire. The Combe Hay Mine was a fuller's earth mine operating to the south of Bath, Somerset, until 1979. [9] Other sites south of Bath included Frome, Lonsdale, Englishcombe, Tucking Mill, and Duncorn Hill. [10] Although these sites had been used since Roman times, William Smith developed new methods for the identification of deposits of fuller's earth to the south of Bath. [11] Other English sources include a mine near Redhill, Surrey (worked until 2000), and Woburn, Bedfordshire, where production ceased in 2004. [12]
Hills, cliffs, and slopes that contain fuller's earth can be unstable, since this material can be thixotropic when saturated by heavy rainfall.
Fulling is an important step in the production of woolen garments, and can be traced back to ancient times. Cuneiform texts from Mesopotamia mention a raw material, im-bab-bár (Akkadian : 𒅎𒌓, gaṣṣu: 'gypsum, plaster'), literally "white earth", which was delivered to fullers for the finishing of cloth. [13] There are several Biblical references to fulling (2 Kings 18:17; Isaiah 7:3 and 36:2; Malachi 3:2; Mark 9:3), but the materials used to whiten the fabric are not specified. Pliny the Elder mentions several types of fuller's earth (creta fullonia in Latin) from a variety of locations, each with different properties and therefore different uses.
The first references to fulling mills are from Persia, and by the time of the Crusades in the late eleventh century, fulling mills were active throughout the medieval world. [14]
The use of fuller's earth across the Indian subcontinent dates back to at least 1879. [15] While its household use and transportation by local carts in the Sindh region of Pakistan predates the 1800s, export by rail was first recorded in 1929 in British India.
The value of fuller's earth is a plot point in the Sherlock Holmes story "The Adventure of the Engineer's Thumb" (1892). In the story, an engineer is paid an outlandish sum to repair a hydraulic press, accepting his client's explanation that the potential profit from fuller's earth warrants both the expense and total secrecy. The adventure is set in 1889, implying that fuller's earth was then well-known as a lucrative commodity, "only found in one or two places in England". [16]
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Fuller's earth is utilized in a number of industries. [1] [5] Most important modern applications make use of the minerals' natural absorbent properties in products sold as absorbents or filters.
Clay is a type of fine-grained natural soil material containing clay minerals (hydrous aluminium phyllosilicates, e.g. kaolinite, Al2Si2O5(OH)4). Most pure clay minerals are white or light-coloured, but natural clays show a variety of colours from impurities, such as a reddish or brownish colour from small amounts of iron oxide.
Fulling, also known as tucking or walking, is a step in woollen clothmaking which involves the cleansing of woven cloth to eliminate (lanolin) oils, dirt, and other impurities, and to make it shrink by friction and pressure. The work delivers a smooth, tightly finished fabric that is insulating and water-repellent. Well-known examples are duffel cloth, first produced in Flanders in the 14th century, and loden, produced in Austria from the 16th century on.
Bentonite is an absorbent swelling clay consisting mostly of montmorillonite which can either be Na-montmorillonite or Ca-montmorillonite. Na-montmorillonite has a considerably greater swelling capacity than Ca-montmorillonite.
A litter box, also known as a sandbox, cat box, litter tray, cat pan, potty, pot or litter pan, is an indoor feces and urine collection box for cats, as well as rabbits, ferrets, miniature pigs, small dogs, and other pets that instinctively or through training will make use of such a repository. They are provided for pets that are permitted free roam of a home but who cannot or do not always go outside to excrete their metabolic waste.
Diatomaceous earth, also known as diatomite, celite, or kieselguhr, is a naturally occurring, soft, siliceous sedimentary rock that can be crumbled into a fine white to off-white powder. It has a particle size ranging from more than 3 mm to less than 1 μm, but typically 10 to 200 μm. Depending on the granularity, this powder can have an abrasive feel, similar to pumice powder, and has a low density as a result of its high porosity. The typical chemical composition of oven-dried diatomaceous earth is 80–90% silica, with 2–4% alumina, and 0.5–2% iron oxide.
Clay minerals are hydrous aluminium phyllosilicates (e.g. kaolin, Al2Si2O5(OH)4), sometimes with variable amounts of iron, magnesium, alkali metals, alkaline earths, and other cations found on or near some planetary surfaces.
Geophagia, also known as geophagy, is the intentional practice of eating earth or soil-like substances such as clay, chalk, or termite mounds. It is a behavioural adaptation that occurs in many non-human animals and has been documented in more than 100 primate species. Geophagy in non-human primates is primarily used for protection from parasites, to provide mineral supplements and to help metabolize toxic compounds from leaves. Geophagy also occurs in humans and is most commonly reported among children and pregnant women.
Montmorillonite is a very soft phyllosilicate group of minerals that form when they precipitate from water solution as microscopic crystals, known as clay. It is named after Montmorillon in France. Montmorillonite, a member of the smectite group, is a 2:1 clay, meaning that it has two tetrahedral sheets of silica sandwiching a central octahedral sheet of alumina. The particles are plate-shaped with an average diameter around 1 μm and a thickness of 0.96 nm; magnification of about 25,000 times, using an electron microscope, is required to resolve individual clay particles. Members of this group include saponite, nontronite, beidellite, and hectorite.
Palygorskite or attapulgite is a magnesium aluminium phyllosilicate with the chemical formula (Mg,Al)2Si4O10(OH)·4(H2O) that occurs in a type of clay soil common to the Southeastern United States. It is one of the types of fuller's earth. Some smaller deposits of this mineral can be found in Mexico, where its use is tied to the manufacture of Maya blue in pre-Columbian times.
An anticaking agent is an additive placed in powdered or granulated materials, such as table salt or confectioneries, to prevent the formation of lumps (caking) and for easing packaging, transport, flowability, and consumption. Caking mechanisms depend on the nature of the material. Crystalline solids often cake by formation of liquid bridge and subsequent fusion of microcrystals. Amorphous materials can cake by glass transitions and changes in viscosity. Polymorphic phase transitions can also induce caking.
A smectite is a mineral mixture of various swelling sheet silicates (phyllosilicates), which have a three-layer 2:1 (TOT) structure and belong to the clay minerals. Smectites mainly consist of montmorillonite, but can often contain secondary minerals such as quartz and calcite.
Sepiolite, also known in English by the German name meerschaum ( MEER-shawm, -shəm; German:[ˈmeːɐ̯ʃaʊm] ; meaning "sea foam"), is a soft white clay mineral, often used to make tobacco pipes (known as meerschaum pipes). A complex magnesium silicate, a typical chemical formula for which is Mg4Si6O15(OH)2·6H2O, it can be present in fibrous, fine-particulate, and solid forms.
Industrial resources (minerals) are geological materials that are mined for their commercial value, which are not fuel and are not sources of metals but are used in the industries based on their physical and/or chemical properties. They are used in their natural state or after beneficiation either as raw materials or as additives in a wide range of applications.
A fullo was a Roman fuller or laundry worker, known from many inscriptions from Italy and the western half of the Roman Empire and references in Latin literature, e.g. by Plautus, Martialis and Pliny the Elder. A fullo worked in a fullery or fullonica. There is also evidence that fullones dealt with cloth straight from the loom, though this has been doubted by some modern scholars. In some large farms, fulleries were built where slaves were used to clean the cloth. In several Roman cities, the workshops of fullones, have been found. The most important examples are in Ostia and Pompeii, but fullonicae also have been found in Delos, Florence, Fréjus and near Forlì: in the Archaeological Museum of Forlì, there is an ancient relief with a fullery view. While the small workshops at Delos go back to the 1st century BC, those in Pompeii date from the 1st century AD and the establishments in Ostia and Florence were built during the reign of the Emperors Trajan and Hadrian.
The shrink–swell capacity of soils refers to the extent certain clay minerals will expand when wet and retract when dry. Soil with a high shrink–swell capacity is problematic and is known as shrink–swell soil, or expansive soil. The amount of certain clay minerals that are present, such as montmorillonite and smectite, directly affects the shrink-swell capacity of soil. This ability to drastically change volume can cause damage to existing structures, such as cracks in foundations or the walls of swimming pools.
Mining in the United Kingdom produces a wide variety of fossil fuels, metals, and industrial minerals due to its complex geology. In 2013, there were over 2,000 active mines, quarries, and offshore drilling sites on the continental land mass of the United Kingdom producing £34bn of minerals and employing 36,000 people.
The use of medicinal clay in folk medicine goes back to prehistoric times. Indigenous peoples around the world still use clay widely, which is related to geophagy. The first recorded use of medicinal clay goes back to ancient Mesopotamia.
Chaoqi is a traditional Chinese snack. It is made with dough pieces covered with Guanyin clay, a kind of soil. The primary raw materials for making Chaoqi are flour, edible oil, egg, sugar, salt, and sesame. It has various flavors like milk flavor, sesame flavor, and five spices flavor.
Scouring is a preparatory treatment of certain textile materials. Scouring removes soluble and insoluble impurities found in textiles as natural, added and adventitious impurities: for example, oils, waxes, fats, vegetable matter, as well as dirt. Removing these contaminants through scouring prepares the textiles for subsequent processes such as bleaching and dyeing. Though a general term, "scouring" is most often used for wool. In cotton, it is synonymously called "boiling out", and in silk, and "boiling off.
Mountain soap, rock-soap or bolus — a partially outdated trivial name for a large group of clay minerals similar in properties from the group of hydrous layered aluminum silicates with variable composition. Minerals from the mountain soap group contain primarily silicates (44-46%), alumina (17-26%), iron oxides (6-10%) and water (13-25%). The mountain soap group included at different times up to two dozen mineral species and varieties. In different cases, this name could mean different minerals, most often halloysite, saponite (soapstone), bentonite or montmorillonite. The last mineral is a large group, each of which could be called mountain soap. All these minerals received their common colloquial name, which gradually penetrated into mineralogy, for their ability to lather and serve as a detergent for various purposes.