Heat death of the universe

Last updated

The heat death of the universe (also known as the Big Chill or Big Freeze) [1] [2] is a scientific hypothesis regarding the ultimate fate of the universe which posits the universe will evolve to a state of no thermodynamic free energy and, having reached maximum entropy, will therefore be unable to sustain any further thermodynamic processes. The hypothesized heat death does not imply any particular absolute temperature; it only requires that temperature differences or other processes may no longer be exploited to perform work. In the language of physics, this is when the universe reaches thermodynamic equilibrium.

Contents

If the curvature of the universe is hyperbolic or flat, or if dark energy is a positive cosmological constant, the universe will continue expanding forever, and a heat death is expected to occur, [3] with the universe cooling to approach equilibrium at a very low temperature after a long time period.

The theory of heat death stems from the ideas of Lord Kelvin who, in the 1850s, took the theory of heat as mechanical energy loss in nature (as embodied in the first two laws of thermodynamics) and extrapolated it to larger processes on a universal scale. This also allowed Kelvin to formulate the heat death paradox, which disproves an infinitely old universe. [4]

Concept

The heat death of the universe is the exhaustion of the universe's potential energy:

Although mechanical energy is indestructible, there is a universal tendency to its dissipation, which produces throughout the system a gradual augmentation and diffusion of heat, cessation of motion and exhaustion of the potential energy of the material Universe.

—Thomson, William. On the Age of the Sun's Heat Macmillan's Magazine, 5 March 1862, pp. 388–93

The universe's potential energy is the universe's rest mass, which exists in the form of baryons and becomes radiated away in the course of time:

The quantity factor of potential energy is space or volume which however is equivalent to mass.

Mathews, Albert P. The Nature of Matter, Gravitation, and Light W. Wood and Company, 1927, p. 106

As we go forwards in time, material weight continually changes into radiation. Conversely, as we go backwards in time, the total material weight of the universe must continually increase.

Jeans, James Hopwood. The Universe Around Us CUP, 1930, pp. 330–32

The more negative a baryon's potential energy (rest mass [5] ), the smaller the baryon's radius and the more positive the baryon's internal temperature. [6] Initially, every baryon's potential energy (rest mass) was maximal, i.e. zero, so that every baryon had an infinitely big radius and a zero internal temperature, which is why the baryon could not radiate its rest mass away:

The baryons or leptons that formed the original collapsing body cannot reappear because all their rest mass energy has been carried away by the thermal radiation. It is tempting to speculate that this might be the reason why the universe now contains so few baryons compared to photons: the universe might have started out with baryons only, and no radiation.

—Hawking, Stephen W. The Big Bang and Black Holes World Scientific, 1993, p. 105

To begin radiating its rest mass away, a baryon must raise its internal temperature above zero by collapsing to a lesser-than-infinite radius.

As the radius of a baryon shrinks by a factor of ten, the baryon's internal temperature increases by a factor of ten:

Lane's law
(astrophysics)
For the contraction of a star that is assumed to be a sphere of perfect gas, the law that the temperature of the perfect-gas sphere is inversely proportional to its radius.

—McGraw-Hill Dictionary of Scientific & Technical Terms. 2003

The Stefan–Boltzmann law (1879) dictates that the radiant exitance from a unit surface area of a self-gravitationally collapsing baryon is proportional to the fourth power of the baryon's temperature.

When the radius of a self-gravitationally collapsing baryon decreases by a factor of 10, the baryon's surface area decreases by a factor of 102, while the radiant exitance from the baryon's unit surface area increases by a factor of 104, so that the total amount of rest mass, radiated away by the baryon per unit of time, increases by a factor of 102.

Consequently, the duration of the next tenfold decrease in the self-gravitationally collapsing baryon's radius will be only 1 percent of the duration of the current tenfold decrease in the self-gravitationally collapsing baryon's radius.

Thus, every baryon collapses and radiatively loses its rest mass with a catastrophic self-acceleration.

But a baryon cannot collapse for ever:

But a star cannot go on contracting for ever, because its molecules are of a certain size, and we cannot squeeze them together beyond a definite limit. What will happen is that the temperature on contraction reaches a maximum; the body later behaves practically like a solid, and begins to lose its heat.

—Russell, Henry Norris. Stellar Evolution Popular Astronomy, vol. 29, 1921, pp. 542–43

The collapse eventually comes to a halt because any self-gravitationally collapsing baryon converts its rest mass into radiant energy but radiates away only a half of that radiant energy while retaining the other half:

As the protostar contracts, half of the gravitational potential energy released will be stored as internal heat, and the remaining half will be radiated away from the surface.

—Cameron, A. G. W. Technical Note D-1682: The Collapse Phase of Early Solar Evolution NASA, January 1963, p. 4

After each infinitesimal step of collapse the star has to wait until it has radiated away half of the released gravitational energy before it can continue to contract.

—Böhm-Vitense, Erika. Introduction to Stellar Astrophysics CUP, 1992, p. 29

Therefore, upon converting all of its rest mass into radiant energy, every baryon will retain a half of that radiant energy circulating within itself and serving as a quasi rest mass. Such an end-time baryon will formally have a rest mass but essentially will be a massless "radiant spirit".

So, every baryon self-gravitationally collapses and thus acquires an ever more negative potential energy, manifesting itself as an ever stronger suction exerted by the baryon's gravitational centre:

Force in such a potential field is a flux in the sense of a mechanical driving agent.

—Ziegler, Franz. Mechanics of Solids and Fluids Springer, 1995, p. 167

The negative energy force that moves water is called suction.

—Sachs, Paul D. Dynamics of a Natural Soil System Edaphic Press, 1999, p. 56

But the gravitational suctions of homogeneously distributed baryons would cancel each other out to zero. That is why concomitantly with every baryon's self-gravitational collapse, the totality of the universe's baryons must become ever more hierarchized, i.e. become ever more subjugated by the gravitational suction exerted by the universe's central baryon, at the centre of which the universal gravitational flux reaches the highest speed and sends a beam of suction into the universe's past:

A beam of negative energy that travels into the past can be generated by the acceleration of the source to high speeds.

—Skinner, Ray. Relativity for Scientists and Engineers Courier Corporation, 2014, pp. 188–89

Due to this beam of negative potential energy or suction sent into the universe's past, the universe's potential energy is never equal to zero. Even during the first moment of the universe's existence, the universe's potential energy is slightly negative.

Thus, the universe's ever more negative-energied gravitational field is an ever more hierarchic mycelium of suction tubes, growing from the universe's central baryon towards the universe's periphery:

The universe's ever more negative-energied gravitational field is a wormhole mycelium, growing from the universe's gravitational centre towards the universe's periphery. Mycelium growth simulation.gif
The universe's ever more negative-energied gravitational field is a wormhole mycelium, growing from the universe's gravitational centre towards the universe's periphery.

More fundamentally, the results suggest that gravity may, in fact, emerge from entanglement. What's more, the geometry, or bending, of the universe as described by classical gravity, may be a consequence of entanglement, such as that between pairs of particles strung together by tunneling wormholes.

You can't get entangled without a wormhole: Physicist finds entanglement instantly gives rise to a wormhole ScienceDaily, 2013 12 05

In any case, the peculiarities of the quantum mechanics of highly entangled particle pairs seem much less mysterious in this picture, once one swallows the very large pill of the odd metric, essentially a one-dimensional universal wormhole.

—Coyne, D. G. A Scenario for Strong Gravity without Extra Dimensions 2006, p. 31

The universe's gravitational field has a negative mass and a negative temperature:

So the gravitational energy binding the Earth to the sun is negative (it requires work to sever the bond). If the gravitational field has negative energy, it must also have negative mass and must be subtracted from the positive mass-energy of the sun and planets.

Davies, Paul. The Goldilocks Enigma: Why Our Universe Is Just Right for Life Mariner Books, 2008, p. 43

The conclusion is, then, that negative mass can only exist at negative temperature, and must be adiabatically separate from positive mass.

—Pollard, D.; Dunning-Davies, J. A consideration of the possibility of negative mass Il Nuovo Cimento B (1971–96), July 1995, vol. 110, no. 7, pp. 857–64

By radiatively losing its heat into the wormhole mycelium of the universe's gravitational field, every baryon shrinks to ever more positive temperatures, while the wormhole mycelium expands to ever more negative temperatures, so that the radiative evaporation of the universe's baryons catastrophically self-accelerates:

Self-gravitating systems have negative specific heats, thus if heat is allowed to flow between two of them, the hotter one loses heat and gets yet hotter while the colder gains heat and gets yet colder. Evolution is thus away from equilibrium.

—Lynden-Bell, D.; Wood, Roger. The Gravo-thermal Catastrophe in Isothermal Spheres and the Onset of Red-giant Structure for Stellar Systems Received 1967 August 1, published in Monthly Notices of the Royal Astronomical Society (1968) 138, 495–525

Eventually, the enormously expanded and negative-temperatured wormhole mycelium of the universe's gravitational field will swallow the universe's enormously shrunken and positive-temperatured baryons:

The latest theory on how the universe will end involves everything being swallowed by a giant wormhole—a scenario dubbed the ‘Big Trip’.

—Swarup, Amarendra. Phantom energy may fuel universe-eating wormhole New Scientist, 2005 11 11

Origins of the idea

The idea of heat death stems from the second law of thermodynamics, of which one version states that entropy tends to increase in an isolated system. From this, the hypothesis implies that if the universe lasts for a sufficient time, it will asymptotically approach a state where all energy is evenly distributed. In other words, according to this hypothesis, there is a tendency in nature towards the dissipation (energy transformation) of mechanical energy (motion) into thermal energy; hence, by extrapolation, there exists the view that, in time, the mechanical movement of the universe will run down as work is converted to heat because of the second law.

The conjecture that all bodies in the universe cool off, eventually becoming too cold to support life, seems to have been first put forward by the French astronomer Jean Sylvain Bailly in 1777 in his writings on the history of astronomy and in the ensuing correspondence with Voltaire. In Bailly's view, all planets have an internal heat and are now at some particular stage of cooling. Venus, for instance, is still too hot for life to arise there for thousands of years, while Mars is already too cold. The final state, in this view, is described as one of "equilibrium" in which all motion ceases. [7]

The idea of heat death as a consequence of the laws of thermodynamics, however, was first proposed in loose terms beginning in 1851 by Lord Kelvin (William Thomson), who theorized further on the mechanical energy loss views of Sadi Carnot (1824), James Joule (1843) and Rudolf Clausius (1850). Thomson's views were then elaborated over the next decade by Hermann von Helmholtz and William Rankine. [8]

History

The idea of the heat death of the universe derives from discussion of the application of the first two laws of thermodynamics to universal processes. Specifically, in 1851, Lord Kelvin outlined the view, as based on recent experiments on the dynamical theory of heat: "heat is not a substance, but a dynamical form of mechanical effect, we perceive that there must be an equivalence between mechanical work and heat, as between cause and effect." [9]

Lord Kelvin originated the idea of universal heat death in 1852. Baron Kelvin 1906.jpg
Lord Kelvin originated the idea of universal heat death in 1852.

In 1852, Thomson published On a Universal Tendency in Nature to the Dissipation of Mechanical Energy, in which he outlined the rudiments of the second law of thermodynamics summarized by the view that mechanical motion and the energy used to create that motion will naturally tend to dissipate or run down. [10] The ideas in this paper, in relation to their application to the age of the Sun and the dynamics of the universal operation, attracted the likes of William Rankine and Hermann von Helmholtz. The three of them were said to have exchanged ideas on this subject. [8] In 1862, Thomson published "On the age of the Sun's heat", an article in which he reiterated his fundamental beliefs in the indestructibility of energy (the first law) and the universal dissipation of energy (the second law), leading to diffusion of heat, cessation of useful motion (work), and exhaustion of potential energy, "lost irrecoverably" through the material universe, while clarifying his view of the consequences for the universe as a whole. Thomson wrote:

The result would inevitably be a state of universal rest and death, if the universe were finite and left to obey existing laws. But it is impossible to conceive a limit to the extent of matter in the universe; and therefore science points rather to an endless progress, through an endless space, of action involving the transformation of potential energy into palpable motion and hence into heat, than to a single finite mechanism, running down like a clock, and stopping for ever. [4]

The clock's example shows how Kelvin was unsure whether the universe would eventually achieve thermodynamic equilibrium. Thomson later speculated that restoring the dissipated energy in " vis viva " and then usable work – and therefore revert the clock's direction, resulting in a "rejuvenating universe" – would require "a creative act or an act possessing similar power". [11] [12] Starting from this publication, Kelvin also introduced the heat death paradox (Kelvin's paradox), which challenged the classical concept of an infinitely old universe, since the universe has not achieved its thermodynamic equilibrium, thus further work and entropy production are still possible. The existence of stars and temperature differences can be considered an empirical proof that the universe is not infinitely old. [13] [4]

In the years to follow both Thomson's 1852 and the 1862 papers, Helmholtz and Rankine both credited Thomson with the idea, along with his paradox, but read further into his papers by publishing views stating that Thomson argued that the universe will end in a "heat death" (Helmholtz), which will be the "end of all physical phenomena" (Rankine). [8] [14] [ unreliable source? ]

Current status

Proposals about the final state of the universe depend on the assumptions made about its ultimate fate, and these assumptions have varied considerably over the late 20th century and early 21st century. In a theorized "open" or "flat" universe that continues expanding indefinitely, either a heat death or a Big Rip is expected to eventually occur. [3] [15] If the cosmological constant is zero, the universe will approach absolute zero temperature over a very long timescale. However, if the cosmological constant is positive, the temperature will asymptote to a non-zero positive value, and the universe will approach a state of maximum entropy in which no further work is possible. [16]

Time frame for heat death

The theory suggests that from the "Big Bang" through the present day, matter and dark matter in the universe are thought to have been concentrated in stars, galaxies, and galaxy clusters, and are presumed to continue to do so well into the future. Therefore, the universe is not in thermodynamic equilibrium, and objects can do physical work. [17] :§VID The decay time for a supermassive black hole of roughly 1 galaxy mass (1011  solar masses) because of Hawking radiation is in the order of 10100  years, [18] so entropy can be produced until at least that time. Some large black holes in the universe are predicted to continue to grow up to perhaps 1014M during the collapse of superclusters of galaxies. Even these would evaporate over a timescale of up to 10106 years. [19] After that time, the universe enters the so-called Dark Era and is expected to consist chiefly of a dilute gas of photons and leptons. [17] :§VIA With only very diffuse matter remaining, activity in the universe will have tailed off dramatically, with extremely low energy levels and extremely long timescales. Speculatively, it is possible that the universe may enter a second inflationary epoch, or assuming that the current vacuum state is a false vacuum, the vacuum may decay into a lower-energy state. [17] :§VE It is also possible that entropy production will cease and the universe will reach heat death. [17] :§VID

It has been hypothesized that, over vast periods of time, a spontaneous entropy decrease could eventually occur via the Poincaré recurrence theorem, [20] [ additional citation(s) needed ] thermal fluctuations, [21] [22] [23] and fluctuation theorem. [24] [25] Through this, another Big Bang could possibly create a new universe similar to the current one by quantum fluctuations and quantum tunnelling in roughly years. [26]

Opposing views

Max Planck wrote that the phrase "entropy of the universe" has no meaning because it admits of no accurate definition. [27] [28] In 2008, Walter Grandy wrote: "It is rather presumptuous to speak of the entropy of a universe about which we still understand so little, and we wonder how one might define thermodynamic entropy for a universe and its major constituents that have never been in equilibrium in their entire existence." [29] According to László Tisza, "If an isolated system is not in equilibrium, we cannot associate an entropy with it." [30] Hans Adolf Buchdahl writes of "the entirely unjustifiable assumption that the universe can be treated as a closed thermodynamic system". [31] According to Giovanni Gallavotti, "there is no universally accepted notion of entropy for systems out of equilibrium, even when in a stationary state". [32] Discussing the question of entropy for non-equilibrium states in general, Elliott H. Lieb and Jakob Yngvason express their opinion as follows: "Despite the fact that most physicists believe in such a nonequilibrium entropy, it has so far proved impossible to define it in a clearly satisfactory way." [33] In Peter Landsberg's opinion: "The third misconception is that thermodynamics, and in particular, the concept of entropy, can without further enquiry be applied to the whole universe. ... These questions have a certain fascination, but the answers are speculations." [34] Julian Barbour said: “It’s because entropy does not apply to the universe. It’s just naïve extrapolation from what is perfectly true in a box. … Heat death. This has been a horrendous sort of nightmare for the universe. But it could be just a complete, fundamental mistake in thinking that what happens in a box is true of what happens in the whole universe.” [35]

A 2010 analysis of entropy states, "The entropy of a general gravitational field is still not known", and "gravitational entropy is difficult to quantify". The analysis considers several possible assumptions that would be needed for estimates and suggests that the observable universe has more entropy than previously thought. This is because the analysis concludes that supermassive black holes are the largest contributor. [36] Lee Smolin goes further: "It has long been known that gravity is important for keeping the universe out of thermal equilibrium. Gravitationally bound systems have negative specific heat—that is, the velocities of their components increase when energy is removed. ... Such a system does not evolve toward a homogeneous equilibrium state. Instead it becomes increasingly structured and heterogeneous as it fragments into subsystems." [37] This point of view is also supported by the fact of a recent[ when? ] experimental discovery of a stable non-equilibrium steady state in a relatively simple closed system. It should be expected that an isolated system fragmented into subsystems does not necessarily come to thermodynamic equilibrium and remain in non-equilibrium steady state. Entropy will be transmitted from one subsystem to another, but its production will be zero, which does not contradict the second law of thermodynamics. [38] [39]

Philosophical views

The discovery of the principle of the heat death of the universe led to philosophical reevaluation of the place of man in the universe. In 1856, Hermann von Helmholtz suggest that it compelled to humans to complete a moral destiny. Philipp Mainländer, another philosopher whose 1875 work Die Philosophie der Erlösung has been associated with the philosophy of pandeism, saw the expected heat death of the Universe as "a different, redemptive destiny for humanity: an end of suffering". [40]

In Isaac Asimov's 1956 short story The Last Question , humans through the ages repeatedly wonder how the heat death of the universe can be avoided.

In the 1981 Doctor Who story "Logopolis", the Doctor realizes that the Logopolitans have created vents in the universe to expel heat build-up into other universes—"Charged Vacuum Emboitments" or "CVE"—to delay the demise of the universe. The Doctor unwittingly travelled through such a vent in "Full Circle".

In the 1995 computer game I Have No Mouth, and I Must Scream , based on Harlan Ellison's short story of the same name, it is stated that AM, the malevolent supercomputer, will survive the heat death of the universe and continue torturing its immortal victims to eternity.

In the 2011 anime series Puella Magi Madoka Magica , the antagonist Kyubey reveals he is a member of an alien race who has been creating magical girls for millennia in order to harvest their energy to combat entropy and stave off the heat death of the universe.

In the last act of Final Fantasy XIV: Endwalker , the player encounters an alien race known as the Ea who have lost all hope in the future and any desire to live further, all because they have learned of the eventual heat death of the universe and see everything else as pointless due to its probable inevitability.

The overarching plot of the Xeelee Sequence concerns the Photino Birds' efforts to accelerate the heat death of the universe by accelerating the rate at which stars become white dwarves.

The 2019 hit indie video game Outer Wilds has several themes grappling with the idea of the heat death of the universe, and the theory that the universe is a cycle of big bangs once the previous one has experienced a heat death.

In "Singularity Immemorial", [41] the seventh main story event of the mobile game Girls' Frontline: Neural Cloud , the plot is about a virtual sector made to simulate space exploration and the threat of the heat death of the universe. The simulation uses an imitation of Neural Cloud's virus entities known as the Entropics as a stand in for the effects of a heat death.

See also

References

  1. WMAP – Fate of the Universe, WMAP's Universe, NASA. Accessed online July 17, 2008.
  2. Dyer, Alan (2007-07-24). Insiders: Space. Simon & Schuster Books for Young Readers. pp. 40–41. ISBN   978-1-4169-3860-6.
  3. 1 2 Plait, Philip (2008). Death from the Skies!. Viking Adult (published 16 October 2008). p. 259. ISBN   978-0-670-01997-7.
  4. 1 2 3 Thomson, Sir William (5 March 1862). "On the Age of the Sun's Heat". Macmillan's Magazine . Vol. 5. pp. 388–93.
  5. Davies, Paul. The Goldilocks Enigma: Why Our Universe Is Just Right for Life Mariner Books, 2008, p. 43. "So the gravitational energy binding the Earth to the sun is negative (it requires work to sever the bond). If the gravitational field has negative energy, it must also have negative mass and must be subtracted from the positive mass-energy of the sun and planets."
  6. McGraw-Hill Dictionary of Scientific & Technical Terms. 2003. "Lane's law (astrophysics) : For the contraction of a star that is assumed to be a sphere of perfect gas, the law that the temperature of the perfect-gas sphere is inversely proportional to its radius."
  7. Brush, Stephen G. (1996). A History of Modern Planetary Physics: Nebulous Earth. Vol. 1. Cambridge University Press. p.  77. ISBN   978-0-521-44171-1.
  8. 1 2 3 Smith, Crosbie; Wise, M. Norton (1989). Energy and Empire: A Biographical Study of Lord Kelvin. Cambridge University Press. p. 500. ISBN   978-0-521-26173-9.
  9. Thomson, Sir William. (1851). "On the Dynamical Theory of Heat, with numerical results deduced from Mr Joule's equivalent of a Thermal Unit, and M. Regnault's Observations on Steam" Excerpts. [§§1–14 & §§99–100], Transactions of the Royal Society of Edinburgh , March 1851, and Philosophical Magazine IV , 1852. This version from Mathematical and Physical Papers, vol. i, art. XLVIII, pp. 174.
  10. Thomson, Sir William (1852). "On a Universal Tendency in Nature to the Dissipation of Mechanical Energy" Proceedings of the Royal Society of Edinburgh for 19 April 1852, also Philosophical Magazine , Oct. 1852. This version from Mathematical and Physical Papers, vol. i, art. 59, pp. 511.
  11. Harold I. Sharlin (13 December 2019). "William Thomson, Baron Kelvin". Encyclopædia Britannica. Retrieved 24 January 2020.
  12. Otis, Laura (2002). "Literature and Science in the Nineteenth Century: An Anthology". OUP Oxford. Vol. 1. pp. 60–67.
  13. Laws of Thermodynamics Thompson and Clausius, Oxford University Press, 2015.
  14. "Physics Chronology". Archived from the original on 22 May 2011.
  15. Consolmagno, Guy (2008-05-08). "Heaven or Heat Death?". Thinking Faith. Archived from the original on 2023-11-16. Retrieved 2008-10-06.
  16. Dyson, Lisa; Kleban, Matthew; Susskind, Leonard (12 November 2002). "Disturbing Implications of a Cosmological Constant". Journal of High Energy Physics . 2002 (10): 011. arXiv: hep-th/0208013 . Bibcode:2002JHEP...10..011D. doi:10.1088/1126-6708/2002/10/011. S2CID   2344440.
  17. 1 2 3 4 Adams, Fred C.; Laughlin, Gregory (1997). "A dying universe: the long-term fate and evolution of astrophysical objects". Reviews of Modern Physics . 69 (2): 337–72. arXiv: astro-ph/9701131 . Bibcode:1997RvMP...69..337A. doi:10.1103/RevModPhys.69.337. S2CID   12173790.
  18. See in particular equation (27) in Page, Don N. (15 January 1976). "Particle emission rates from a black hole: Massless particles from an uncharged, nonrotating hole". Physical Review D . 13 (2): 198–206. Bibcode:1976PhRvD..13..198P. doi:10.1103/PhysRevD.13.198.
  19. Frautschi, Steven (13 August 1982). "Entropy in an Expanding Universe" (PDF). Science . 217 (4560): 593–9. Bibcode:1982Sci...217..593F. doi:10.1126/science.217.4560.593. JSTOR   1688892. PMID   17817517. S2CID   27717447. Since we have assumed a maximum scale of gravitational binding—for instance, superclusters of galaxies—black hole formation eventually comes to an end in our model, with masses of for up to 1014M ... the timescale for black holes to radiate away all their energy ranges ... to 10106 years for black holes of up to 1014M
  20. Poincaré, Henri (1890). "Sur le problème des trois corps et les équations de la dynamique". Acta Mathematica. 13: A3 –A270.
  21. Tegmark, Max (2003). "Parallel Universes". Scientific American . 288 (2003): 40–51. arXiv: astro-ph/0302131 . Bibcode:2003SciAm.288e..40T. doi:10.1038/scientificamerican0503-40. PMID   12701329.
  22. Tegmark, Max (May 2003). "Parallel Universes". Scientific American . 288 (5): 40–51. arXiv: astro-ph/0302131 . Bibcode:2003SciAm.288e..40T. doi:10.1038/scientificamerican0503-40. PMID   12701329.
  23. Werlang, T.; Ribeiro, G. A. P.; Rigolin, Gustavo (2013). "Interplay between quantum phase transitions and the behavior of quantum correlations at finite temperatures". International Journal of Modern Physics B . 27 (1n03): 1345032. arXiv: 1205.1046 . Bibcode:2013IJMPB..2745032W. doi:10.1142/S021797921345032X. S2CID   119264198.
  24. Xiu-San Xing (1 November 2007). "Spontaneous entropy decrease and its statistical formula". arXiv: 0710.4624 [cond-mat.stat-mech].
  25. Linde, Andrei (2007). "Sinks in the landscape, Boltzmann brains and the cosmological constant problem". Journal of Cosmology and Astroparticle Physics . 2007 (1): 022. arXiv: hep-th/0611043 . Bibcode:2007JCAP...01..022L. CiteSeerX   10.1.1.266.8334 . doi:10.1088/1475-7516/2007/01/022. S2CID   16984680.
  26. Carroll, Sean M.; Chen, Jennifer (October 2004). "Spontaneous Inflation and Origin of the Arrow of Time". arXiv: hep-th/0410270 . Bibcode : 2004hep.th...10270C
  27. Uffink, Jos (2003). "Irreversibility and the Second Law of Thermodynamics". In Greven, Andreas; Warnecke, Gerald; Keller, Gerhard (eds.). Entropy (Princeton Series in Applied Mathematics). Princeton University Press. p. 129. ISBN   978-0-691-11338-8. The importance of Planck's Vorlesungen über Thermodynamik (Planck 1897) can hardly be [over]estimated. The book has gone through 11 editions, from 1897 until 1964, and still remains the most authoritative exposition of classical thermodynamics.
  28. Planck, Max (1903). Treatise on Thermodynamics. Translated by Ogg, Alexander. London: Longmans, Green. p. 101.
  29. Grandy, Walter T. Jr. (2008). Entropy and the Time Evolution of Macroscopic Systems. Oxford University Press. p. 151. ISBN   978-0-19-954617-6.
  30. Tisza, László (1966). Generalized Thermodynamics. MIT Press. p. 41. ISBN   978-0-262-20010-3.{{cite book}}: CS1 maint: ignored ISBN errors (link)
  31. Buchdahl, H. A. (1966). The Concepts of Classical Thermodynamics. Cambridge University Press. p. 97. ISBN   978-0-521-11519-3.{{cite book}}: CS1 maint: ignored ISBN errors (link)
  32. Gallavotti, Giovanni (1999). Statistical Mechanics: A Short Treatise. Springer. p. 290. ISBN   978-3-540-64883-3.
  33. Lieb, Elliott H.; Yngvason, Jakob (2003). "The Entropy of Classical Thermodynamic". In Greven, Andreas; Warnecke, Gerald; Keller, Gerhard (eds.). Entropy. Princeton Series in Applied Mathematics. Princeton University Press. p. 190. ISBN   978-0-691-11338-8.
  34. Landsberg, Peter Theodore (1961). Thermodynamics with Quantum Statistical Illustrations (First ed.). Interscience Publishers. p. 391. ISBN   978-0-470-51381-1.{{cite book}}: CS1 maint: ignored ISBN errors (link)
  35. Curt Jaimungal interviewing Julian Barbour, 2025, “We’ve been wrong about Entropy, Time, and Quantum Mechanics,” https://www.youtube.com/watch?v=q-bImnQ9cmw&t=46m01s”
  36. Egan, Chas A.; Lineweaver, Charles H. (2010). "A Larger Estimate of the Entropy of the Universe". The Astrophysical Journal . 710 (2) (published 3 February 2010): 1825–34 [1826]. arXiv: 0909.3983 . Bibcode:2010ApJ...710.1825E. doi:10.1088/0004-637X/710/2/1825. S2CID   1274173.
  37. Smolin, Lee (2014). "Time, laws, and future of cosmology". Physics Today . 67 (3): 38–43 [42]. Bibcode:2014PhT....67c..38S. doi:10.1063/pt.3.2310.
  38. Lemishko, Sergey S.; Lemishko, Alexander S. (2017). "Cu2+/Cu+ Redox Battery Utilizing Low-Potential External Heat for Recharge". The Journal of Physical Chemistry C . 121 (6) (published 30 January 2017): 3234–3240. doi:10.1021/acs.jpcc.6b12317.
  39. Lemishko, Sergey S.; Lemishko, Alexander S. (2020). "Non-equilibrium steady state in closed system with reversible reactions: Mechanism, kinetics and its possible application for energy conversion". Results in Chemistry . 2 100031 (published 8 February 2020). doi: 10.1016/j.rechem.2020.100031 .
  40. Kellis, Devin M. (August 2025). "Existential Health Care Ethics". AMA Journal of Ethics. 27 (8): E543-548. doi: 10.1001/amajethics.2025.543 . PMID   40748272.
  41. "PNC Story - IOP Wiki". iopwiki.com. Retrieved 2024-09-11.