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The heat death of the universe (also known as the Big Chill or Big Freeze) [1] [2] is a hypothesis on the ultimate fate of the universe, which suggests the universe will evolve to a state of no thermodynamic free energy, and will therefore be unable to sustain processes that increase entropy. Heat death does not imply any particular absolute temperature; it only requires that temperature differences or other processes may no longer be exploited to perform work. In the language of physics, this is when the universe reaches thermodynamic equilibrium.
If the curvature of the universe is hyperbolic or flat, or if dark energy is a positive cosmological constant, the universe will continue expanding forever, and a heat death is expected to occur, [3] with the universe cooling to approach equilibrium at a very low temperature after a long time period.
The hypothesis of heat death stems from the ideas of Lord Kelvin who, in the 1850s, took the theory of heat as mechanical energy loss in nature (as embodied in the first two laws of thermodynamics) and extrapolated it to larger processes on a universal scale. This also allowed Kelvin to formulate the heat death paradox, which disproves an infinitely old universe. [4]
The idea of heat death stems from the second law of thermodynamics, of which one version states that entropy tends to increase in an isolated system. From this, the hypothesis implies that if the universe lasts for a sufficient time, it will asymptotically approach a state where all energy is evenly distributed. In other words, according to this hypothesis, there is a tendency in nature towards the dissipation (energy transformation) of mechanical energy (motion) into thermal energy; hence, by extrapolation, there exists the view that, in time, the mechanical movement of the universe will run down as work is converted to heat because of the second law.
The conjecture that all bodies in the universe cool off, eventually becoming too cold to support life, seems to have been first put forward by the French astronomer Jean Sylvain Bailly in 1777 in his writings on the history of astronomy and in the ensuing correspondence with Voltaire. In Bailly's view, all planets have an internal heat and are now at some particular stage of cooling. Jupiter, for instance, is still too hot for life to arise there for thousands of years, while the Moon is already too cold. The final state, in this view, is described as one of "equilibrium" in which all motion ceases. [5]
The idea of heat death as a consequence of the laws of thermodynamics, however, was first proposed in loose terms beginning in 1851 by Lord Kelvin (William Thomson), who theorized further on the mechanical energy loss views of Sadi Carnot (1824), James Joule (1843) and Rudolf Clausius (1850). Thomson's views were then elaborated over the next decade by Hermann von Helmholtz and William Rankine. [6]
The idea of the heat death of the universe derives from discussion of the application of the first two laws of thermodynamics to universal processes. Specifically, in 1851, Lord Kelvin outlined the view, as based on recent experiments on the dynamical theory of heat: "heat is not a substance, but a dynamical form of mechanical effect, we perceive that there must be an equivalence between mechanical work and heat, as between cause and effect." [7]
In 1852, Thomson published On a Universal Tendency in Nature to the Dissipation of Mechanical Energy, in which he outlined the rudiments of the second law of thermodynamics summarized by the view that mechanical motion and the energy used to create that motion will naturally tend to dissipate or run down. [8] The ideas in this paper, in relation to their application to the age of the Sun and the dynamics of the universal operation, attracted the likes of William Rankine and Hermann von Helmholtz. The three of them were said to have exchanged ideas on this subject. [6] In 1862, Thomson published "On the age of the Sun's heat", an article in which he reiterated his fundamental beliefs in the indestructibility of energy (the first law) and the universal dissipation of energy (the second law), leading to diffusion of heat, cessation of useful motion (work), and exhaustion of potential energy, "lost irrecoverably" through the material universe, while clarifying his view of the consequences for the universe as a whole. Thomson wrote:
The result would inevitably be a state of universal rest and death, if the universe were finite and left to obey existing laws. But it is impossible to conceive a limit to the extent of matter in the universe; and therefore science points rather to an endless progress, through an endless space, of action involving the transformation of potential energy into palpable motion and hence into heat, than to a single finite mechanism, running down like a clock, and stopping for ever. [4]
The clock's example shows how Kelvin was unsure whether the universe would eventually achieve thermodynamic equilibrium. Thompson later speculated that restoring the dissipated energy in " vis viva " and then usable work – and therefore revert the clock's direction, resulting in a "rejuvenating universe" – would require "a creative act or an act possessing similar power". [9] [10] Starting from this publication, Kelvin also introduced the heat death paradox (Kelvin's paradox), which challenged the classical concept of an infinitely old universe, since the universe has not achieved its thermodynamic equilibrium, thus further work and entropy production are still possible. The existence of stars and temperature differences can be considered an empirical proof that the universe is not infinitely old. [11] [4]
In the years to follow both Thomson's 1852 and the 1862 papers, Helmholtz and Rankine both credited Thomson with the idea, along with his paradox, but read further into his papers by publishing views stating that Thomson argued that the universe will end in a "heat death" (Helmholtz), which will be the "end of all physical phenomena" (Rankine). [6] [12] [ unreliable source? ]
Proposals about the final state of the universe depend on the assumptions made about its ultimate fate, and these assumptions have varied considerably over the late 20th century and early 21st century. In a hypothesized "open" or "flat" universe that continues expanding indefinitely, either a heat death or a Big Rip is expected to eventually occur. [3] [13] If the cosmological constant is zero, the universe will approach absolute zero temperature over a very long timescale. However, if the cosmological constant is positive, the temperature will asymptote to a non-zero positive value, and the universe will approach a state of maximum entropy in which no further work is possible. [14]
The theory suggests that from the "Big Bang" through the present day, matter and dark matter in the universe are thought to have been concentrated in stars, galaxies, and galaxy clusters, and are presumed to continue to do so well into the future. Therefore, the universe is not in thermodynamic equilibrium, and objects can do physical work. [15] :§VID The decay time for a supermassive black hole of roughly 1 galaxy mass (1011 solar masses) because of Hawking radiation is in the order of 10100 years, [16] so entropy can be produced until at least that time. Some large black holes in the universe are predicted to continue to grow up to perhaps 1014M☉ during the collapse of superclusters of galaxies. Even these would evaporate over a timescale of up to 10106 years. [17] After that time, the universe enters the so-called Dark Era and is expected to consist chiefly of a dilute gas of photons and leptons. [15] :§VIA With only very diffuse matter remaining, activity in the universe will have tailed off dramatically, with extremely low energy levels and extremely long timescales. Speculatively, it is possible that the universe may enter a second inflationary epoch, or assuming that the current vacuum state is a false vacuum, the vacuum may decay into a lower-energy state. [15] :§VE It is also possible that entropy production will cease and the universe will reach heat death. [15] :§VID
It is suggested that, over vast periods of time, a spontaneous entropy decrease would eventually occur via the Poincaré recurrence theorem, [18] thermal fluctuations, [19] [20] [21] and fluctuation theorem. [22] [23] Through this, another universe could possibly be created by random quantum fluctuations or quantum tunnelling in roughly years. [24]
Max Planck wrote that the phrase "entropy of the universe" has no meaning because it admits of no accurate definition. [25] [26] In 2008, Walter Grandy wrote: "It is rather presumptuous to speak of the entropy of a universe about which we still understand so little, and we wonder how one might define thermodynamic entropy for a universe and its major constituents that have never been in equilibrium in their entire existence." [27] According to László Tisza, "If an isolated system is not in equilibrium, we cannot associate an entropy with it." [28] Hans Adolf Buchdahl writes of "the entirely unjustifiable assumption that the universe can be treated as a closed thermodynamic system". [29] According to Giovanni Gallavotti, "there is no universally accepted notion of entropy for systems out of equilibrium, even when in a stationary state". [30] Discussing the question of entropy for non-equilibrium states in general, Elliott H. Lieb and Jakob Yngvason express their opinion as follows: "Despite the fact that most physicists believe in such a nonequilibrium entropy, it has so far proved impossible to define it in a clearly satisfactory way." [31] In Peter Landsberg's opinion: "The third misconception is that thermodynamics, and in particular, the concept of entropy, can without further enquiry be applied to the whole universe. ... These questions have a certain fascination, but the answers are speculations." [32]
A 2010 analysis of entropy states, "The entropy of a general gravitational field is still not known", and "gravitational entropy is difficult to quantify". The analysis considers several possible assumptions that would be needed for estimates and suggests that the observable universe has more entropy than previously thought. This is because the analysis concludes that supermassive black holes are the largest contributor. [33] Lee Smolin goes further: "It has long been known that gravity is important for keeping the universe out of thermal equilibrium. Gravitationally bound systems have negative specific heat—that is, the velocities of their components increase when energy is removed. ... Such a system does not evolve toward a homogeneous equilibrium state. Instead it becomes increasingly structured and heterogeneous as it fragments into subsystems." [34] This point of view is also supported by the fact of a recent[ when? ] experimental discovery of a stable non-equilibrium steady state in a relatively simple closed system. It should be expected that an isolated system fragmented into subsystems does not necessarily come to thermodynamic equilibrium and remain in non-equilibrium steady state. Entropy will be transmitted from one subsystem to another, but its production will be zero, which does not contradict the second law of thermodynamics. [35] [36]
This section includes a list of references, related reading, or external links, but its sources remain unclear because it lacks inline citations .(November 2023) |
In Isaac Asimov's 1956 short story The Last Question , humans repeatedly wonder how the heat death of the universe can be avoided.
In the 1981 Doctor Who story "Logopolis", the Doctor realizes that the Logopolitans have created vents in the universe to expel heat build-up into other universes—"Charged Vacuum Emboitments" or "CVE"—to delay the demise of the universe. The Doctor unwittingly travelled through such a vent in "Full Circle".
In the 1995 computer game I Have No Mouth, and I Must Scream , based on the Harlan Ellison short story of the same name, it is stated that AM, the malevolent supercomputer, will survive the heat death of the universe and continue torturing its immortal victims to eternity.
In the 2011 anime series Puella Magi Madoka Magica , the antagonist Kyubey reveals he is a member of an alien race who has been creating magical girls for millennia in order to harvest their energy to combat entropy and stave off the heat death of the universe.
In the last act of Final Fantasy XIV: Endwalker , the player encounters an alien race known as the Ea who have lost all hope in the future and any desire to live further, all because they have learned of the eventual heat death of the universe and see everything else as pointless due to its probable inevitability.
The overarching plot of the Xeelee Sequence concerns the Photino Birds' efforts to accelerate the heat death of the universe by accelerating the rate at which stars become white dwarves.
The 2019 hit indie video game Outer Wilds has several themes grappling with the idea of the heat death of the universe, and the theory that the universe is a cycle of big bangs once the previous one has experienced a heat death.
In Singularity Immemorial [37] — the 7th main story event of a mobile game Girls' Frontline: Neural Cloud — the plot is about a virtual sector made to simulate space exploration and the threat of the heat death of the universe. The simulation uses an imitation of Neural Cloud's virus entities known as the Entropics as a stand in for the effects of a heat death.
Absolute zero is the lowest limit of the thermodynamic temperature scale; a state at which the enthalpy and entropy of a cooled ideal gas reach their minimum value. The fundamental particles of nature have minimum vibrational motion, retaining only quantum mechanical, zero-point energy-induced particle motion. The theoretical temperature is determined by extrapolating the ideal gas law; by international agreement, absolute zero is taken as 0 kelvin, which is −273.15 degrees on the Celsius scale, and equals −459.67 degrees on the Fahrenheit scale. The Kelvin and Rankine temperature scales set their zero points at absolute zero by definition.
Entropy is a scientific concept that is most commonly associated with a state of disorder, randomness, or uncertainty. The term and the concept are used in diverse fields, from classical thermodynamics, where it was first recognized, to the microscopic description of nature in statistical physics, and to the principles of information theory. It has found far-ranging applications in chemistry and physics, in biological systems and their relation to life, in cosmology, economics, sociology, weather science, climate change and information systems including the transmission of information in telecommunication.
The holographic principle is a property of string theories and a supposed property of quantum gravity that states that the description of a volume of space can be thought of as encoded on a lower-dimensional boundary to the region – such as a light-like boundary like a gravitational horizon. First proposed by Gerard 't Hooft, it was given a precise string theoretic interpretation by Leonard Susskind, who combined his ideas with previous ones of 't Hooft and Charles Thorn. Susskind said, "The three-dimensional world of ordinary experience—the universe filled with galaxies, stars, planets, houses, boulders, and people—is a hologram, an image of reality coded on a distant two-dimensional surface." As pointed out by Raphael Bousso, Thorn observed in 1978, that string theory admits a lower-dimensional description in which gravity emerges from it in what would now be called a holographic way. The prime example of holography is the AdS/CFT correspondence.
In physics, statistical mechanics is a mathematical framework that applies statistical methods and probability theory to large assemblies of microscopic entities. Sometimes called statistical physics or statistical thermodynamics, its applications include many problems in the fields of physics, biology, chemistry, neuroscience, computer science, information theory and sociology. Its main purpose is to clarify the properties of matter in aggregate, in terms of physical laws governing atomic motion.
Thermodynamics is a branch of physics that deals with heat, work, and temperature, and their relation to energy, entropy, and the physical properties of matter and radiation. The behavior of these quantities is governed by the four laws of thermodynamics, which convey a quantitative description using measurable macroscopic physical quantities, but may be explained in terms of microscopic constituents by statistical mechanics. Thermodynamics applies to a wide variety of topics in science and engineering, especially physical chemistry, biochemistry, chemical engineering and mechanical engineering, but also in other complex fields such as meteorology.
A timeline of events in the history of thermodynamics.
Maxwell's demon is a thought experiment that appears to disprove the second law of thermodynamics. It was proposed by the physicist James Clerk Maxwell in 1867. In his first letter, Maxwell referred to the entity as a "finite being" or a "being who can play a game of skill with the molecules". Lord Kelvin would later call it a "demon".
The second law of thermodynamics is a physical law based on universal empirical observation concerning heat and energy interconversions. A simple statement of the law is that heat always flows spontaneously from hotter to colder regions of matter. Another statement is: "Not all heat can be converted into work in a cyclic process."
In physics, black hole thermodynamics is the area of study that seeks to reconcile the laws of thermodynamics with the existence of black hole event horizons. As the study of the statistical mechanics of black-body radiation led to the development of the theory of quantum mechanics, the effort to understand the statistical mechanics of black holes has had a deep impact upon the understanding of quantum gravity, leading to the formulation of the holographic principle.
In science, a process that is not reversible is called irreversible. This concept arises frequently in thermodynamics. All complex natural processes are irreversible, although a phase transition at the coexistence temperature is well approximated as reversible.
In physics, Loschmidt's paradox, also known as the reversibility paradox, irreversibility paradox, or Umkehreinwand, is the objection that it should not be possible to deduce an irreversible process from time-symmetric dynamics. This puts the time reversal symmetry of (almost) all known low-level fundamental physical processes at odds with any attempt to infer from them the second law of thermodynamics which describes the behaviour of macroscopic systems. Both of these are well-accepted principles in physics, with sound observational and theoretical support, yet they seem to be in conflict, hence the paradox.
The heat death paradox, also known as thermodynamic paradox, Clausius' paradox, and Kelvin's paradox, is a reductio ad absurdum argument that uses thermodynamics to show the impossibility of an infinitely old universe. It was formulated in February 1862 by Lord Kelvin and expanded upon by Hermann von Helmholtz and William John Macquorn Rankine.
The mathematical expressions for thermodynamic entropy in the statistical thermodynamics formulation established by Ludwig Boltzmann and J. Willard Gibbs in the 1870s are similar to the information entropy by Claude Shannon and Ralph Hartley, developed in the 1940s.
Entropy is one of the few quantities in the physical sciences that require a particular direction for time, sometimes called an arrow of time. As one goes "forward" in time, the second law of thermodynamics says, the entropy of an isolated system can increase, but not decrease. Thus, entropy measurement is a way of distinguishing the past from the future. In thermodynamic systems that are not isolated, local entropy can decrease over time, accompanied by a compensating entropy increase in the surroundings; examples include objects undergoing cooling, living systems, and the formation of typical crystals.
In thermodynamics, entropy is often associated with the amount of order or disorder in a thermodynamic system. This stems from Rudolf Clausius' 1862 assertion that any thermodynamic process always "admits to being reduced [reduction] to the alteration in some way or another of the arrangement of the constituent parts of the working body" and that internal work associated with these alterations is quantified energetically by a measure of "entropy" change, according to the following differential expression:
The Boltzmann brain thought experiment suggests that it might be more likely for a brain to spontaneously form in space, complete with a memory of having existed in our universe, rather than for the entire universe to come about in the manner cosmologists think it actually did. Physicists use the Boltzmann brain thought experiment as a reductio ad absurdum argument for evaluating competing scientific theories.
Temperature is a physical quantity that quantitatively expresses the attribute of hotness or coldness. Temperature is measured with a thermometer. It reflects the average kinetic energy of the vibrating and colliding atoms making up a substance.
Energy dissipation and entropy production extremal principles are ideas developed within non-equilibrium thermodynamics that attempt to predict the likely steady states and dynamical structures that a physical system might show. The search for extremum principles for non-equilibrium thermodynamics follows their successful use in other branches of physics. According to Kondepudi (2008), and to Grandy (2008), there is no general rule that provides an extremum principle that governs the evolution of a far-from-equilibrium system to a steady state. According to Glansdorff and Prigogine, irreversible processes usually are not governed by global extremal principles because description of their evolution requires differential equations which are not self-adjoint, but local extremal principles can be used for local solutions. Lebon Jou and Casas-Vásquez (2008) state that "In non-equilibrium ... it is generally not possible to construct thermodynamic potentials depending on the whole set of variables". Šilhavý (1997) offers the opinion that "... the extremum principles of thermodynamics ... do not have any counterpart for [non-equilibrium] steady states ." It follows that any general extremal principle for a non-equilibrium problem will need to refer in some detail to the constraints that are specific for the structure of the system considered in the problem.
Entropic gravity, also known as emergent gravity, is a theory in modern physics that describes gravity as an entropic force—a force with macro-scale homogeneity but which is subject to quantum-level disorder—and not a fundamental interaction. The theory, based on string theory, black hole physics, and quantum information theory, describes gravity as an emergent phenomenon that springs from the quantum entanglement of small bits of spacetime information. As such, entropic gravity is said to abide by the second law of thermodynamics under which the entropy of a physical system tends to increase over time.
Quantum thermodynamics is the study of the relations between two independent physical theories: thermodynamics and quantum mechanics. The two independent theories address the physical phenomena of light and matter. In 1905, Albert Einstein argued that the requirement of consistency between thermodynamics and electromagnetism leads to the conclusion that light is quantized, obtaining the relation . This paper is the dawn of quantum theory. In a few decades quantum theory became established with an independent set of rules. Currently quantum thermodynamics addresses the emergence of thermodynamic laws from quantum mechanics. It differs from quantum statistical mechanics in the emphasis on dynamical processes out of equilibrium. In addition, there is a quest for the theory to be relevant for a single individual quantum system.
Since we have assumed a maximum scale of gravitational binding—for instance, superclusters of galaxies—black hole formation eventually comes to an end in our model, with masses of up to 1014M☉ ... the timescale for black holes to radiate away all their energy ranges ... to 10106 years for black holes of up to 1014M☉
The importance of Planck's Vorlesungen über Thermodynamik (Planck 1897) can hardly be [over]estimated. The book has gone through 11 editions, from 1897 until 1964, and still remains the most authoritative exposition of classical thermodynamics.