O-Cymene

Last updated
o-Cymene
O-Cymol.svg
Names
Preferred IUPAC name
1-Methyl-2-(propan-2-yl)benzene
Other names
  • o-Cymene
  • 2-isopropyltoluene
  • 2-methylcumene
  • 1-isopropyl-2-methylbenzene
Identifiers
3D model (JSmol)
ChEBI
ChemSpider
EC Number
  • 208-426-0
PubChem CID
UNII
  • InChI=1S/C10H14/c1-8(2)10-7-5-4-6-9(10)3/h4-8H,1-3H3
    Key: WWRCMNKATXZARA-UHFFFAOYSA-N
  • CC1=CC=CC=C1C(C)C
Properties
C10H14
Molar mass 134.22
Appearancecolorless liquid
Density 0.88 g/cm3
Melting point −71.5 °C (−96.7 °F; 201.7 K)
Boiling point 178 °C (352 °F; 451 K)
23.3 mg/L
Hazards
Occupational safety and health (OHS/OSH):
Main hazards
Flammable
GHS labelling:
GHS-pictogram-flamme.svg
Warning
H226
P210, P233, P240, P241, P242, P243, P280, P303+P361+P353, P370+P378, P403+P235, P501
Flash point 50.6 °C (123.1 °F; 323.8 K)
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

o-Cymene is an organic compound classified as an aromatic hydrocarbon. Its structure consists of a benzene ring ortho-substituted with a methyl group and an isopropyl group. It is a flammable colorless liquid which is nearly insoluble in water but soluble in organic solvents.

Isomers and production

In addition to o-cymene, there are two other geometric isomers called m-cymene, in which the alkyl groups are meta-substituted, and p-cymene, in which they are para-substituted. p-Cymene is the only isomer found in nature. The three isomers form the group of cymenes.

Cymenes can be produced by alkylation of toluene with propylene. [1] [2]

Related Research Articles

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Alkylation Transfer of an alkyl group from one molecule to another

Alkylation is the transfer of an alkyl group from one molecule to another. The alkyl group may be transferred as an alkyl carbocation, a free radical, a carbanion, or a carbene. Alkylating agents are reagents for effecting alkylation. Alkyl groups can also be removed in a process known as dealkylation. Alkylating agents are often classified according to their nucleophilic or electrophilic character.

2,2,4-Trimethylpentane Chemical compound

2,2,4-Trimethylpentane, also known as isooctane or iso-octane, is an organic compound with the formula (CH3)3CCH2CH(CH3)2. It is one of several isomers of octane (C8H18). This particular isomer is the standard 100 point on the octane rating scale (the zero point is n-heptane). It is an important component of gasoline, frequently used in relatively large proportions to increase the knock resistance of fuel.

Pentene Chemical compound

Pentenes are alkenes with the chemical formula C
5
H
10
. Each contains one double bond within its molecular structure. Six different compounds are in this class, differing from each other by whether the carbon atoms are attached linearly or in a branched structure, and whether the double bond has a cis or trans form.

Norbornene Chemical compound

Norbornene or norbornylene or norcamphene is a highly strained bridged cyclic hydrocarbon. It is a white solid with a pungent sour odor. The molecule consists of a cyclohexene ring with a methylene bridge between carbons 1 and 4. The molecule carries a double bond which induces significant ring strain and significant reactivity.

Cumene Chemical compound

Cumene (isopropylbenzene) is an organic compound that is based on an aromatic hydrocarbon with an aliphatic substitution. It is a constituent of crude oil and refined fuels. It is a flammable colorless liquid that has a boiling point of 152 °C. Nearly all the cumene that is produced as a pure compound on an industrial scale is converted to cumene hydroperoxide, which is an intermediate in the synthesis of other industrially important chemicals, primarily phenol and acetone.

p-Cymene is a naturally occurring aromatic organic compound. It is classified as an alkylbenzene related to a monoterpene. Its structure consists of a benzene ring para-substituted with a methyl group and an isopropyl group. p-Cymene is insoluble in water, but miscible with organic solvents.

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Dodecylbenzene is an organic compound with the formula C12H25C6H5.Dodecylbenzene is a colorless liquid with a weak oily odor. Floats on water.

Perfluoroethers are a class of organofluorine compound containing one or more ether functional group. In general these compounds are structurally analogous to the related hydrocarbon ethers, except for the distinctive properties of fluorocarbons.

Hexachlorobutadiene Chemical compound

Hexachlorobutadiene, Cl2C=C(Cl)C(Cl)=CCl2, is a colorless liquid at room temperature that has an odor similar to that of turpentine. It is a chlorinated aliphatic diene with niche applications but is most commonly used as a solvent for other chlorine-containing compounds.

3-Methylpyridine Chemical compound

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<i>N</i>-Formylpiperidine Chemical compound

N-Formylpiperidine is an organic compound with the formula C6H11NO. It is the amide of formic acid and piperidine. It can be used as a polar aprotic solvent, with better hydrocarbon solubility than other amide solvents such as dimethylformamide (DMF). It has also been used to transfer the formyl group to a Grignard reagent:

Benzopyrene

A benzopyrene is an organic compound with the formula C20H12. Structurally speaking, the colorless isomers of benzopyrene are pentacyclic hydrocarbons and are fusion products of pyrene and a phenylene group. Two isomeric species of benzopyrene are benzo[a]pyrene and the less common benzo[e]pyrene. They belong to the chemical class of polycyclic aromatic hydrocarbons.

Tripropylene Chemical compound

Tripropylene, also known as propylene trimer, is usually sold as a mixture of structural isomers of nonene. This mixture is obtained by oligomerization of propene:

Propylbarbital

Propylbarbital, also known as 5,5-dipropylbarbituric acid, is a barbiturate derivative used as a hypnotic drug.

2,4-Dimethylpentane Chemical compound

2,4-Dimethylpentane is an alkane with the chemical formula [(H3C)2CH]2CH2. This colorless hydrocarbon is produced in large quantities in oil refineries. It results from the alkylation of isobutane by propylene. Often referred to as "alkylate", it is blended with other gasoline components to give a high octane fuel. Unlike n-heptane, 2,4-dimethylpentane is a desirable fuel because its branched structure allows combustion without knocking.

Neohexene Chemical compound

Neohexene is the organic compound with the formula (CH3)3CCH=CH2. It is a colorless liquid, with properties similar to other hexenes. It is a precursor to commercial synthetic musk perfumes.

<i>m</i>-Cymene Organic compound

m-Cymene is an organic compound classified as an aromatic hydrocarbon. Its structure consists of a benzene ring meta-substituted with a methyl group and an isopropyl group. It is a flammable colorless liquid which is nearly insoluble in water but soluble in organic solvents.

Hemimellitic acid Chemical compound

Hemimellitic acid (benzene-1,2,3-tricarboxylic acid) is an organic compound with the molecular formula C6H3(СО2Н)3. Like the other isomers of benzenetricarboxylic acid, hemimellitic acid is a colorless solid. It is prepared by oxidation of 1,2,3-trimethylbenzene.

References

  1. Vora, Bipin V.; Kocal, Joseph A.; Barger, Paul T.; Schmidt, Robert J.; Johnson, James A. (2003). "Alkylation". Kirk-Othmer Encyclopedia of Chemical Technology. Kirk‐Othmer Encyclopedia of Chemical Technology. doi:10.1002/0471238961.0112112508011313.a01.pub2. ISBN   0471238961.
  2. Griesbaum, Karl; Behr, Arno; Biedenkapp, Dieter; Voges, Heinz-Werner; Garbe, Dorothea; Paetz, Christian; Collin, Gerd; Mayer, Dieter; Höke (2002). "Hydrocarbons". Ullmann's Encyclopedia of Industrial Chemistry . Weinheim: Wiley-VCH. doi:10.1002/14356007.a13_227.