Gold(I) sulfide

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Gold(I) sulfide
Gold(I)-sulfide-xtal-1995-unit-cell-CM-3D-balls.png
Names
IUPAC name
Gold(I) sulfide
Other names
Aurous sulfide
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.013.749 OOjs UI icon edit-ltr-progressive.svg
EC Number
  • 215-123-7
PubChem CID
UNII
  • InChI=1S/2Au.S/q2*+1;-2
    Key: YVIYNOINIIHOCG-UHFFFAOYSA-N
  • [S-2].[Au+].[Au+]
Properties
Au2S
Molar mass 425.998 g/mol
Density 11 g/cm3 [1]
Melting point 240 °C (464 °F; 513 K)
Insoluble
Related compounds
Other anions
Copper(I) sulfide
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Gold(I) sulfide is the inorganic compound with the formula Au2S. It is the principal sulfide of gold. It decomposes to gold metal and elemental sulfur, illustrating the "nobility" of gold.

Structure and preparation

The compound crystallizes in the motif seen for cuprous oxide: gold is 2-coordinate, sulfur 4-coordinate, and the S-Au-S linkage is linear. [2] Linear coordination geometry is typical of gold(I) compounds, e.g. the coordination complex chloro(dimethyl sulfide)gold(I). The structure is similar to the α form of silver sulfide (argentite), which only exists at high temperatures. [3]

It can be prepared by treating gold chloride with hydrogen sulfide [4] It also arises by sulfiding dicyanoaurate:

H2S + 2 K[Au(CN)2] → Au2S + 2 KCN + 2 HCN

This product is described as "initially dark reddish-brown" solid that turns "steel-gray". [5] [3]

Related Research Articles

Inorganic chemistry Field of chemistry

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Calcium fluoride is the inorganic compound of the elements calcium and fluorine with the formula CaF2. It is a white insoluble solid. It occurs as the mineral fluorite (also called fluorspar), which is often deeply coloured owing to impurities.

Polysulfide

Polysulfides are a class of chemical compounds containing chains of sulfur atoms. There are two main classes of polysulfides: inorganic and organic. Among the inorganic polysulfides, there are ones which contain anions, which have the general formula S2−
n
. These anions are the conjugate bases of the hydrogen polysulfides H2Sn. Organic polysulfides generally have the formulae R1SnR2, where R = alkyl or aryl.

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Copper monosulfide Chemical compound

Copper monosulfide is a chemical compound of copper and sulfur. It was initially thought to occur in nature as the dark indigo blue mineral covellite. However, it was later shown to be rather a cuprous compound, formula Cu+3S(S2). CuS is a moderate conductor of electricity. A black colloidal precipitate of CuS is formed when hydrogen sulfide, H2S, is bubbled through solutions of Cu(II) salts. It is one of a number of binary compounds of copper and sulfur (see copper sulfide for an overview of this subject), and has attracted interest because of its potential uses in catalysis and photovoltaics.

Sodium hydrosulfide Chemical compound

Sodium hydrosulfide is the chemical compound with the formula NaSH. This compound is the product of the half-neutralization of hydrogen sulfide with sodium hydroxide (NaOH). NaSH and sodium sulfide are used industrially, often for similar purposes. Solid NaSH is colorless. The solid has an odor of H2S owing to hydrolysis by atmospheric moisture. In contrast with sodium sulfide, which is insoluble in organic solvents, NaSH, being a 1:1 electrolyte, is more soluble.

Mercury(II) thiocyanate Chemical compound

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Potassium sulfide Chemical compound

Potassium sulfide is an inorganic compound with the formula K2S. The colourless solid is rarely encountered, because it reacts readily with water, a reaction that affords potassium hydrosulfide (KSH) and potassium hydroxide (KOH). Most commonly, the term potassium sulfide refers loosely to this mixture, not the anhydrous solid.

Chloro(triphenylphosphine)gold(I) Chemical compound

Chloro(triphenylphosphine)gold(I) or triphenylphosphinegold(I) chloride is a coordination complex with the formula (Ph3P)AuCl. This colorless solid is a common reagent for research on gold compounds.

Copper(I) bromide Chemical compound

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Thiosulfuric acid is the inorganic compound with the formula H2S2O3. It has attracted academic interest as a simple, easily accessed compound that is labile. It has few practical uses.

Bismuth(III) sulfide Chemical compound

Bismuth(III) sulfide is a chemical compound of bismuth and sulfur. It occurs in nature as the mineral bismuthinite.

Copper(I) sulfide Chemical compound

Copper(I) sulfide is a copper sulfide, a chemical compound of copper and sulfur. It has the chemical compound Cu2S. It is found in nature as the mineral chalcocite. It has a narrow range of stoichiometry ranging from Cu1.997S to Cu2.000S.

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Europium(II) sulfide Chemical compound

Europium (II) sulfide is the inorganic compound with the chemical formula EuS. It is a black, air-stable powder. Europium possesses an oxidation state of +II in europium sulfide, whereas the lanthanides exhibit a typical oxidation state of +III. Its Curie temperature (Tc) is 16.6 K. Below this temperature EuS behaves like a ferromagnetic compound, and above it exhibits simple paramagnetic properties. EuS is stable up to 500 °C in air, when it begins to show signs of oxidation. In an inert environment it decomposes at 1470 °C.

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Gold(III) sulfide or auric sulfide is an inorganic compound with the formula Au2S3. Little evidence has been published supporting the existence of macroscopic quantities of this material.

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Gold(I) cyanide Chemical compound

Gold(I) cyanide is the inorganic compound with the chemical formula AuCN. It is the binary cyanide of gold(I). It is an odourless, tasteless yellow solid. Wet gold(I) cyanide is unstable to light and will become greenish. Gold(I) cyanide itself is of only of academic interest, but its derivative dicyanoaurate is an intermediate in gold cyanidation, the extraction of gold from its ores.

References

  1. Perry, Dale, ed. (1995). Handbook of Inorganic Compounds. p. 184. ISBN   9780849386718.
  2. Wells, A.F. (1984) Structural Inorganic Chemistry, Oxford: Clarendon Press. ISBN   0-19-855370-6.
  3. 1 2 Ishikawa, K. (1995). "Structure and Electrical Properties of Au2S". Solid State Ionics. 79: 60–66. doi:10.1016/0167-2738(95)00030-A.
  4. N. N. Greenwood, A. Earnshaw, Chemistry of the Elements, 2nd ed., Butterworth-Heinemann, Oxford, UK, 1997.
  5. Faltens, Marjorie O. (1970). "Mössbauer Spectroscopy of Gold Compounds". The Journal of Chemical Physics. 53 (11): 4249–4264. Bibcode:1970JChPh..53.4249F. doi:10.1063/1.1673931.