Volcanic gases are gases given off by active (or, at times, by dormant) volcanoes. These include gases trapped in cavities (vesicles) in volcanic rocks, dissolved or dissociated gases in magma and lava, or gases emanating from lava, from volcanic craters or vents. Volcanic gases can also be emitted through groundwater heated by volcanic action.
Substances that may become gaseous or give off gases when heated are termed volatile substances.
Composition
Sketch showing typical carbon dioxide emission patterns from volcanic and magmatic systemsAverage carbon dioxide (CO2) emissions of subaerial volcanoes globally from the time period of 2005 to 2017Degassing at the summit crater of Villarrica, Chile
The abundance of gases varies considerably from volcano to volcano, with volcanic activity and with tectonic setting. Water vapour is consistently the most abundant volcanic gas, normally comprising more than 60% of total emissions. Carbon dioxide typically accounts for 10 to 40% of emissions.[4]
Volcanoes located at convergent plate boundaries emit more water vapor and chlorine than volcanoes at hot spots or divergent plate boundaries. This is caused by the addition of seawater into magmas formed at subduction zones. Convergent plate boundary volcanoes also have higher H2O/H2, H2O/CO2, CO2/He and N2/He ratios than hot spot or divergent plate boundary volcanoes.[4]
Magmatic gases and high-temperature volcanic gases
Magma contains dissolved volatile components, as described above. The solubilities of the different volatile constituents are dependent on pressure, temperature and the composition of the magma. As magma ascends towards the surface, the ambient pressure decreases, which decreases the solubility of the dissolved volatiles. Once the solubility decreases below the volatile concentration, the volatiles will tend to come out of solution within the magma (exsolve) and form a separate gas phase (the magma is super-saturated in volatiles).
The gas will initially be distributed throughout the magma as small bubbles, that cannot rise quickly through the magma. As the magma ascends the bubbles grow through a combination of expansion through decompression and growth as the solubility of volatiles in the magma decreases further causing more gas to exsolve. Depending on the viscosity of the magma, the bubbles may start to rise through the magma and coalesce, or they remain relatively fixed in place until they begin to connect and form a continuously connected network. In the former case, the bubbles may rise through the magma and accumulate at a vertical surface, e.g. the 'roof' of a magma chamber. In volcanoes with an open path to the surface, e.g. Stromboli in Italy, the bubbles may reach the surface and as they pop small explosions occur. In the latter case, the gas can flow rapidly through the continuous permeable network towards the surface. This mechanism has been used to explain activity at Santiaguito, Santa Maria volcano, Guatemala[5] and Soufrière Hills Volcano, Montserrat.[6] If the gas cannot escape fast enough from the magma, it will fragment the magma into small particles of ash. The fluidised ash has a much lower resistance to motion than the viscous magma, so accelerates, causing further expansion of the gases and acceleration of the mixture. This sequence of events drives explosive volcanism. Whether gas can escape gently (passive eruptions) or not (explosive eruptions) is determined by the total volatile contents of the initial magma and the viscosity of the magma, which is controlled by its composition.
The term 'closed system' degassing refers to the case where gas and its parent magma ascend together and in equilibrium with each other. The composition of the emitted gas is in equilibrium with the composition of the magma at the pressure, temperature where the gas leaves the system. In 'open system' degassing, the gas leaves its parent magma and rises up through the overlying magma without remaining in equilibrium with that magma. The gas released at the surface has a composition that is a mass-flow average of the magma exsolved at various depths and is not representative of the magma conditions at any one depth.
Molten rock (either magma or lava) near the atmosphere releases high-temperature volcanic gas (>400°C). In explosive volcanic eruptions, the sudden release of gases from magma may cause rapid movements of the molten rock. When the magma encounters water, seawater, lake water or groundwater, it can be rapidly fragmented. The rapid expansion of gases is the driving mechanism of most explosive volcanic eruptions. However, a significant portion of volcanic gas release occurs during quasi-continuous quiescent phases of active volcanism.
Low-temperature volcanic gases and hydrothermal systems
As magmatic gas travelling upward encounters meteoric water in an aquifer, steam is produced. Latent magmatic heat can also cause meteoric waters to ascend as a vapour phase. Extended fluid-rock interaction of this hot mixture can leach constituents out of the cooling magmatic rock and also the country rock, causing volume changes and phase transitions, reactions and thus an increase in ionic strength of the upward percolating fluid. This process also decreases the fluid's pH. Cooling can cause phase separation and mineral deposition, accompanied by a shift toward more reducing conditions. At the surface expression of such hydrothermal systems, low-temperature volcanic gases (<400°C) are either emanating as steam-gas mixtures or in dissolved form in hot springs. At the ocean floor, such hot supersaturated hydrothermal fluids form gigantic chimney structures called black smokers, at the point of emission into the cold seawater.
Over geological time, this process of hydrothermal leaching, alteration, and/or redeposition of minerals in the country rock is an effective process of concentration that generates certain types of economically valuable ore deposits.
Non-explosive volcanic gas release
The gas release can occur by advection through fractures, or via diffuse degassing through large areas of permeable ground as diffuse degassing structures (DDS). At sites of advective gas loss, precipitation of sulfur and rare minerals forms sulfur deposits and small sulfur chimneys, called fumaroles.[7] Very low-temperature (below 100°C) fumarolic structures are also known as solfataras. Sites of cold degassing of predominantly carbon dioxide are called mofettes. Hot springs on volcanoes often show a measurable amount of magmatic gas in dissolved form.
Current emissions of volcanic gases to the atmosphere
Present day global emissions of volcanic gases to the atmosphere can be classified as eruptive or non-eruptive. Although all volcanic gas species are emitted to the atmosphere, the emissions of CO2 (a greenhouse gas) and SO2 have received the most study.
It has long been recognized that eruptions contribute much lower total SO2 emissions than passive degassing does.[8][9] Fischer et al (2019) estimated that, from 2005 to 2015, SO2 emissions during eruptions were 2.6 teragrams (Tg or 1012g or 0.907 gigatons Gt) per year[10] and during non-eruptive periods of passive degassing were 23.2 ± 2Tg per year.[10] During the same time interval, CO2 emissions from volcanoes during eruptions were estimated to be 1.8 ± 0.9 Tg per year[10] and during non-eruptive activity were 51.3 ± 5.7 Tg per year.[10] Therefore, CO2 emissions during volcanic eruptions are less than 10% of CO2 emissions released during non-eruptive volcanic activity.
The 15 June 1991 eruption of Mount Pinatubo (VEI 6) in the Philippines released a total of 18 ± 4 Tg of SO2.[11] Such large VEI 6 eruptions are rare and only occur once every 50 – 100 years. The 2010 eruptions of Eyjafjallajökull (VEI 4) in Iceland emitted a total of 5.1 Tg CO2.[12] VEI 4 eruptions occur about once per year.
For comparison, Le Quéré, C. et al estimates that human burning of fossil fuels and production of cement processed 9.3 Gt carbon per year from 2006 through 2015,[13] creating up to 34.1 Gt CO2 annually.
Some recent volcanic CO2 emission estimates are higher than Fischer et al (2019).[10] The estimates of Burton et al. (2013) of 540 Tg CO2/year[14] and of Werner et al. (2019) of 220 - 300 Tg CO2/year[12] take into account diffuse CO2 emissions from volcanic regions.
Sensing, collection and measurement
Volcanic gases were collected and analysed as long ago as 1790 by Scipione Breislak in Italy.[15] The composition of volcanic gases is dependent on the movement of magma within the volcano. Therefore, sudden changes in gas composition often presage a change in volcanic activity. Accordingly, a large part of hazard monitoring of volcanoes involves regular measurement of gaseous emissions. For example, an increase in the CO2 content of gases at Stromboli has been ascribed to injection of fresh volatile-rich magma at depth within the system. [16]
Volcanic gases can be sensed (measured in-situ) or sampled for further analysis. Volcanic gas sensing can be:
within the gas by means of electrochemical sensors and flow-through infrared-spectroscopic gas cells
Sulphur dioxide (SO2) absorbs strongly in the ultraviolet wavelengths and has low background concentrations in the atmosphere. These characteristics make sulphur dioxide a good target for volcanic gas monitoring. It can be detected by satellite-based instruments, which allow for global monitoring, and by ground-based instruments such as DOAS. DOAS arrays are placed near some well-monitored volcanoes and used to estimate the flux of SO2 emitted. The Multi-Component Gas Analyzer System (Multi-GAS) is also used to remotely measure CO2, SO2 and H2S.[17] The fluxes of other gases are usually estimated by measuring the ratios of different gases within the volcanic plume, e.g. by FTIR, electrochemical sensors at the volcano crater rim, or direct sampling, and multiplying the ratio of the gas of interest to SO2 by the SO2 flux.
Direct sampling of volcanic gas sampling is often done by a method involving an evacuated flask with caustic solution, first used by Robert W. Bunsen (1811-1899) and later refined by the German chemist Werner F. Giggenbach (1937-1997), dubbed Giggenbach-bottle. Other methods include collection in evacuated empty containers, in flow-through glass tubes, in gas wash bottles (cryogenic scrubbers), on impregnated filter packs and on solid adsorbent tubes.
Certain constituents of volcanic gases may show very early signs of changing conditions at depth, making them a powerful tool to predict imminent unrest. Used in conjunction with monitoring data on seismicity and deformation, correlative monitoring gains great efficiency. Volcanic gas monitoring is a standard tool of any volcano observatory. Unfortunately, the most precise compositional data still require dangerous field sampling campaigns. However, remote sensing techniques have advanced tremendously through the 1990s. The Deep Earth Carbon Degassing Project is employing Multi-GAS remote sensing to monitor 9 volcanoes on a continuous basis.
Hazards
Volcanic gases were directly responsible for approximately 3% of all volcano-related deaths of humans between 1900 and 1986.[4] Some volcanic gases kill by acidic corrosion; others kill by asphyxiation. Some volcanic gases including sulfur dioxide, hydrogen chloride, hydrogen sulfide and hydrogen fluoride react with other atmospheric particles to form aerosols.[4]
A volcano is a rupture in the crust of a planetary-mass object, such as Earth, that allows hot lava, volcanic ash, and gases to escape from a magma chamber below the surface.
Magma is the molten or semi-molten natural material from which all igneous rocks are formed. Magma is found beneath the surface of the Earth, and evidence of magmatism has also been discovered on other terrestrial planets and some natural satellites. Besides molten rock, magma may also contain suspended crystals and gas bubbles.
A fumarole is a vent in the surface of the Earth or another rocky planet from which hot volcanic gases and vapors are emitted, without any accompanying liquids or solids. Fumaroles are characteristic of the late stages of volcanic activity, but fumarole activity can also precede a volcanic eruption and has been used for eruption prediction. Most fumaroles die down within a few days or weeks of the end of an eruption, but a few are persistent, lasting for decades or longer. An area containing fumaroles is known as a fumarole field.
A stratovolcano, also known as a composite volcano, is a conical volcano built up by many layers (strata) of hardened lava and tephra. Unlike shield volcanoes, stratovolcanoes are characterized by a steep profile with a summit crater and periodic intervals of explosive eruptions and effusive eruptions, although some have collapsed summit craters called calderas. The lava flowing from stratovolcanoes typically cools and hardens before spreading far, due to high viscosity. The magma forming this lava is often felsic, having high to intermediate levels of silica, with lesser amounts of less viscous mafic magma. Extensive felsic lava flows are uncommon, but have traveled as far as 15 km (9 mi).
Mammoth Mountain is a lava dome complex partially located within the town of Mammoth Lakes, California, in the Inyo National Forest of Madera and Mono Counties. It is home to a large ski area primarily on the Mono County side.
An effusive eruption is a type of volcanic eruption in which lava steadily flows out of a volcano onto the ground.
Lascar is a stratovolcano in Chile within the Central Volcanic Zone of the Andes, a volcanic arc that spans Peru, Bolivia, Argentina and Chile. It is the most active volcano in the region, with records of eruptions going back to 1848. It is composed of two separate cones with several summit craters. The westernmost crater of the eastern cone is presently active. Volcanic activity is characterized by constant release of volcanic gas and occasional vulcanian eruptions.
Prediction of volcanic activity, or volcanic eruption forecasting, is an interdisciplinary monitoring and research effort to predict the time and severity of a volcano's eruption. Of particular importance is the prediction of hazardous eruptions that could lead to catastrophic loss of life, property, and disruption of human activities.
Volatiles are the group of chemical elements and chemical compounds that can be readily vaporized. In contrast with volatiles, elements and compounds that are not readily vaporized are known as refractory substances.
Pele is an active volcano on the surface of Jupiter's moon Io. It is located on Io's trailing hemisphere at 18.7°S 255.3°W. A large, 300-kilometer (190 mi) tall volcanic plume has been observed at Pele by various spacecraft starting with Voyager 1 in 1979, though it has not been persistent. The discovery of the Pele plume on March 8, 1979 confirmed the existence of active volcanism on Io. The plume is associated with a lava lake at the northern end of the mountain Danube Planum. Pele is also notable for a persistent, large red ring circling the volcano resulting from sulfurous fallout from the volcanic plume.
Volcanism on Io, a moon of Jupiter, is represented by the presence of volcanoes, volcanic pits and lava flows on the moon's surface. Its volcanic activity was discovered in 1979 by Voyager 1 imaging scientist Linda Morabito. Observations of Io by passing spacecraft and Earth-based astronomers have revealed more than 150 active volcanoes. Up to 400 such volcanoes are predicted to exist based on these observations. Io's volcanism makes the satellite one of only five known currently volcanically or cryovolcanically active worlds in the Solar System
Alaska's Mount Redoubt volcano began erupting on March 22, 2009, and activity continued for several months.
Magmatic water, also known as juvenile water, is an aqueous phase in equilibrium with minerals that have been dissolved by magma deep within the Earth's crust and is released to the atmosphere during a volcanic eruption. It plays a key role in assessing the crystallization of igneous rocks, particularly silicates, as well as the rheology and evolution of magma chambers. Magma is composed of minerals, crystals and volatiles in varying relative natural abundance. Magmatic differentiation varies significantly based on various factors, most notably the presence of water. An abundance of volatiles within magma chambers decreases viscosity and leads to the formation of minerals bearing halogens, including chloride and hydroxide groups. In addition, the relative abundance of volatiles varies within basaltic, andesitic, and rhyolitic magma chambers, leading to some volcanoes being exceedingly more explosive than others. Magmatic water is practically insoluble in silicate melts but has demonstrated the highest solubility within rhyolitic melts. An abundance of magmatic water has been shown to lead to high-grade deformation, altering the amount of δ18O and δ2H within host rocks.
A volcanic hazard is the probability a volcanic eruption or related geophysical event will occur in a given geographic area and within a specified window of time. The risk that can be associated with a volcanic hazard depends on the proximity and vulnerability of an asset or a population of people near to where a volcanic event might occur.
A gas slug is a conglomerate of high pressure gas bubbles that forms within certain volcanoes, the agitation of which is a driving factor in Strombolian eruptions. They start out as small bubbles of gas inside of volcanic magma. These accumulate into one large bubble, which starts to rise through the lava plume. Gas slugs also consist of many chemical properties that assist scientists in monitoring volcanic eruptions.
Tectonic–climatic interaction is the interrelationship between tectonic processes and the climate system. The tectonic processes in question include orogenesis, volcanism, and erosion, while relevant climatic processes include atmospheric circulation, orographic lift, monsoon circulation and the rain shadow effect. As the geological record of past climate changes over millions of years is sparse and poorly resolved, many questions remain unresolved regarding the nature of tectonic-climate interaction, although it is an area of active research by geologists and palaeoclimatologists.
Irruputuncu is a volcano in the commune of Pica, Tamarugal Province, Tarapacá Region, Chile, as well as San Pedro de Quemes Municipality, Nor Lípez Province, Potosí Department, Bolivia. The mountain's summit is 5,163 m (16,939 ft) high and has two summit craters—the southernmost 200 m (660 ft)-wide one has active fumaroles. The volcano also features lava flows, block and ash flows and several lava domes. The volcano is part of the Andean Central Volcanic Zone (CVZ).
A multi-component gas analyzer system (Multi-GAS) is an instrument package used to take real-time high-resolution measurements of volcanic gases. A Multi-GAS package includes an infrared spectrometer for CO2, two electrochemical sensors for SO2 and H2S, and pressure–temperature–humidity sensors, all in a weatherproof box. The system can be used for individual surveys or set up as permanent stations connected to radio transmitters for transmission of data from remote locations. The instrument package is portable, and its operation and data analysis are simple enough to be conducted by non-specialists.
The Deep Earth Carbon Degassing (DECADE) project is an initiative to unite scientists around the world to make tangible advances towards quantifying the amount of carbon outgassed from the Earth's deep interior into the surface environment through naturally occurring processes. DECADE is an initiative within the Deep Carbon Observatory (DCO).
NW Rota-1 is a seamount in the Mariana Islands, northwest of Rota, which was discovered through its hydrothermal activity in 2003. The volcano has been observed to be erupting underwater, the first time that submarine explosive eruptions have been directly witnessed.
References
↑ Grasby, Stephen E; Them, Theodore R II; Chen, Zhuoheng; Yin, Runsheng; Ardakani, Omid H (September 2019). "Mercury as a proxy for volcanic emissions in the geologic record". Earth-Science Reviews. 196: 102880. doi:10.1016/j.earscirev.2019.102880. S2CID197575240.
1 2 3 4 H. Sigurdsson et al. (2000) Encyclopedia of Volcanoes, San Diego, Academic Press
↑ Holland et al. (2011), Degassing processes during lava dome growth: Insights from Santiaguito lava dome, Guatemala, Journal of Volcanology and Geothermal Research vol. 202 p153-166
↑ Hautmann et al. (2014), Strain field analysis on Montserrat (W.I.) as a tool for assessing permeable flow paths in the magmatic system of Soufrière Hills Volcano, Geochemistry, Geophysics, Geosystems vol. 15 p676-690
↑ Capuano, F.; Cavalchi, B.; Davoli, V.; Manzini, P. (1998). "Eudiometric measures at the end of 18th century. Air quality of the Dog Cave from Iazzaro Spallanzani's travel in the Two Sicilies". In Morello, N. (ed.). Volcanoes and History. Genoa: Brigati. pp.53–63.
↑ Burton et al. (2007) Magmatic Gas Composition Reveals the Source Depth of Slug-Driven Strombolian Explosive Activity Science vol 317 p.227-230.
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