Gas syringe

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A gas syringe showing its components separated and assembled Gas syringe.jpg
A gas syringe showing its components separated and assembled

A gas syringe is a piece of laboratory glassware used to insert or withdraw a volume of a gas from a closed system, or to measure the volume of gas evolved from a chemical reaction. [1] A gas syringe can also be used to measure and dispense liquids, especially where these liquids need to be kept free from air. [2]

Contents

A gas syringe has an inner syringe chamber which has a ground glass surface. The syringe barrel also has a ground glass surface. The ground surface of the barrel moves freely within the ground glass surface of the syringe chamber with very little friction. The close mating of these ground glass surfaces also gives a reasonably gas-tight seal. [3] Like a ground glass stopcock, the two parts of a gas syringe should preferably not be interchanged with another gas syringe of the same volume, unless told otherwise by the distributor. [3] Gas syringes come in various sizes from 500 ml to 0.25 ml and tend to be accurate to between 0.01 and 1 ml, depending on the size of the syringe. [4]

Gas syringe use

A gas syringe can be used to measure gaseous products from a reaction. [1]

When using a gas syringe to measure gases it is important to keep the syringe free from liquids. As gases can dissolve in liquids, especially under any resulting pressure, this may result in inaccurate measurements (Henry's law). [5]

The amount of gas in moles formed in a reaction can be measured by measuring the volume of gas evolved at standard (or known) pressure conditions (gas law, PV=nRT). [1]

Accordingly, it is important that the syringe barrel should move freely within the syringe chamber, if one assumes that the measured gas is at standard temperature and pressure. Any friction would result in a pressure build-up in the syringe and would lead to an inaccurate measurement, that is, a lower amount of gas would be determined, than really obtained. [6]

Liquid use

Glass syringes are also conveniently used to measure and dispense solvents and other liquids. They are often used in air-free techniques to take solvents after they have been purified in stills, or from containers sealed with septa, to prevent gas entering the solution. They can also be use for transportation of substances that react spontaneously with air (pyrophoric reagents). [7]

Liquids drawn up into a gas syringes can optionally be sparged with inert gas before dispensing into a reaction vessel such as a Schlenk flask. This is done by drawing the liquid into the syringe via a needle, inserting the needle into the septum sealing a flask under a positive pressure of an inert gas, removing the glass plunger, and allowing the gas to bubble through the liquid in the syringe for several minutes. The glass plunger is then re-inserted and the liquid is added to the reaction flask. [2] Other techniques such as cannulation can also be used to transfer liquids instead.

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<span class="mw-page-title-main">Pipette</span> Liquid-transferring laboratory tool

A pipette is a laboratory tool commonly used in chemistry, biology and medicine to transport a measured volume of liquid, often as a media dispenser. Pipettes come in several designs for various purposes with differing levels of accuracy and precision, from single piece glass pipettes to more complex adjustable or electronic pipettes. Many pipette types work by creating a partial vacuum above the liquid-holding chamber and selectively releasing this vacuum to draw up and dispense liquid. Measurement accuracy varies greatly depending on the instrument.

<span class="mw-page-title-main">Graduated cylinder</span> Common piece of laboratory equipment used to measure the volume of a liquid

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<span class="mw-page-title-main">Syringe</span> Medical injection device

A syringe is a simple reciprocating pump consisting of a plunger that fits tightly within a cylindrical tube called a barrel. The plunger can be linearly pulled and pushed along the inside of the tube, allowing the syringe to take in and expel liquid or gas through a discharge orifice at the front (open) end of the tube. The open end of the syringe may be fitted with a hypodermic needle, a nozzle or tubing to direct the flow into and out of the barrel. Syringes are frequently used in clinical medicine to administer injections, infuse intravenous therapy into the bloodstream, apply compounds such as glue or lubricant, and draw/measure liquids. There are also prefilled syringes.

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<span class="mw-page-title-main">Laboratory flask</span>

Laboratory flasks are vessels or containers that fall into the category of laboratory equipment known as glassware. In laboratory and other scientific settings, they are usually referred to simply as flasks. Flasks come in a number of shapes and a wide range of sizes, but a common distinguishing aspect in their shapes is a wider vessel "body" and one narrower tubular sections at the top called necks which have an opening at the top. Laboratory flask sizes are specified by the volume they can hold, typically in metric units such as milliliters or liters. Laboratory flasks have traditionally been made of glass, but can also be made of plastic.

The Dean–Stark apparatus, Dean–Stark receiver, distilling trap, or Dean–Stark Head is a piece of laboratory glassware used in synthetic chemistry to collect water from a reactor. It is used in combination with a reflux condenser and a distillation flask for the separation of water from liquids. This may be a continuous removal of the water that is produced during a chemical reaction performed at reflux temperature, such as in esterification reactions. It was invented by the American chemists Ernest Woodward Dean (1888–1959) and David Dewey Stark (1893–1979) in 1920 for determination of the water content in petroleum.

<span class="mw-page-title-main">Dropping funnel</span>

A dropping funnel is a type of laboratory glassware used to transfer fluids. They are fitted with a stopcock which allows the flow to be controlled. Dropping funnels are useful for adding reagents slowly, i.e. drop-wise. This may be desirable when the quick addition of the reagent may result in side reactions, or if the reaction is too vigorous.

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Round-bottom flasks are types of flasks having spherical bottoms used as laboratory glassware, mostly for chemical or biochemical work. They are typically made of glass for chemical inertness; and in modern days, they are usually made of heat-resistant borosilicate glass. There is at least one tubular section known as the neck with an opening at the tip. Two- or three-necked flasks are common as well. Round bottom flasks come in many sizes, from 5 mL to 20 L, with the sizes usually inscribed on the glass. In pilot plants even larger flasks are encountered.

<span class="mw-page-title-main">Schlenk line</span> Glass apparatus used in chemistry

The Schlenk line is a commonly used chemistry apparatus developed by Wilhelm Schlenk. It consists of a dual manifold with several ports. One manifold is connected to a source of purified inert gas, while the other is connected to a vacuum pump. The inert-gas line is vented through an oil bubbler, while solvent vapors and gaseous reaction products are prevented from contaminating the vacuum pump by a liquid-nitrogen or dry-ice/acetone cold trap. Special stopcocks or Teflon taps allow vacuum or inert gas to be selected without the need for placing the sample on a separate line.

<span class="mw-page-title-main">Schlenk flask</span>

A Schlenk flask, or Schlenk tube, is a reaction vessel typically used in air-sensitive chemistry, invented by Wilhelm Schlenk. It has a side arm fitted with a PTFE or ground glass stopcock, which allows the vessel to be evacuated or filled with gases. These flasks are often connected to Schlenk lines, which allow both operations to be done easily.

<span class="mw-page-title-main">Drying tube</span>

A drying tube or guard tube is a tube-like piece of apparatus used to house a disposable solid desiccant, wherein at one end the tube-like structure terminates in a ground glass joint for use in connecting the drying tube to a reaction vessel, for the purpose of keeping the vessel free of moisture.

<span class="mw-page-title-main">Ground glass joint</span> Used in laboratories to quickly and easily assemble apparatus from available parts

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<span class="mw-page-title-main">Eye dropper</span> Device used to transfer small quantities of liquids

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This glossary of chemistry terms is a list of terms and definitions relevant to chemistry, including chemical laws, diagrams and formulae, laboratory tools, glassware, and equipment. Chemistry is a physical science concerned with the composition, structure, and properties of matter, as well as the changes it undergoes during chemical reactions; it features an extensive vocabulary and a significant amount of jargon.

<span class="mw-page-title-main">Cannula transfer</span>

Cannula transfer or cannulation is a set of air-free techniques used with a Schlenk line, in transferring liquid or solution samples between reaction vessels via cannulae, avoiding atmospheric contamination. While the syringes are not the same as cannulae, the techniques remain relevant.

<span class="mw-page-title-main">Media dispenser</span>


A media dispenser or a culture media dispenser is a device for repeatedly delivering small fixed volumes of liquid such as a laboratory growth medium like molten agar or caustic or volatile solvents like toluene into a series of receptacles. It is often important that such dispensers operate without biological or chemical contamination, and so must be internally sealed from the environment and designed for easy cleaning and sterilization before use. At a minimum, a media dispenser consists of some kind of pump connected to a length of discharge tubing or a spout. Dispensers used in laboratories are also frequently connected to microcontrollers to regulate the speed and volume of the medium as it leaves the pump.

References

  1. 1 2 3 Mattson, Bruce. Microscale Gas Chemistry: Determination of the Molar Mass of Gas. Microscale Gas Chemistry. Bruce Mattson, 15 Mar. 2010. Web. 17 Nov. 2011. <http://www.hkbu.edu.hk/~micschem/emanual/Expt%205-Molar_Volume%20final-english.pdf%5B%5D>.
  2. 1 2 UCLA, comp. Procedures for Safe Use of Pyrophoric Liquid Reagents. Procedures for Safe Use of Pyrophoric Liquid Reagents. UCLA Chemistry & Biochemistry, Sept. 2009. Web. 17 Nov. 2011. <http://www.chemistry.ucla.edu/file-storage/publicview/pdfs/SOPLiquidReagents.pdf Archived 2012-04-25 at the Wayback Machine >.
  3. 1 2 VICI. "Pressure Lok® Glass Syringe Features." Valco Instruments Company Incorporated. Valco Instruments Company Incorporated, Jan. 2011. Web. 17 Nov. 2011. <http://www.vici.com/syr/pres_lok.php>.
  4. Valco. "Gas/Liquid Syringes." Valco Instruments Company Incorporated. Valco Instruments Corporation In., Jan. 2011. Web. 17 Nov. 2011. <http://www.vici.com/syr/gasfeatures.php>.
  5. Plambeck, James A. "Introductory University Chemistry I. Henry's Law and the Solubility of Gases." D. W. Brooks Site. James A. Plambeck, 03 Nov. 1995. Web. 17 Nov. 2011. <http://dwb.unl.edu/teacher/nsf/c09/c09links/www.chem.ualberta.ca/courses/plambeck/p101/p01182.htm Archived 2011-11-27 at the Wayback Machine >.
  6. Schmid, H. P. "Pressure and Gas Laws." Indiana University. Indiana University, 18 Sept. 1997. Web. 17 Nov. 2011. <http://www.indiana.edu/~geog109/topics/10_Forces>.
  7. Norton, Jack. "The Safe Use of Pyrophoric Reagents." Pyrophoric Reagents. Columbia University, May 2010. Web. 17 Nov. 2011. <http://ehs.columbia.edu/pyrophorics.pdf>.