Unbihexium

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Unbihexium, 126Ubh
Theoretical element
Unbihexium
Pronunciation /ˌuːnbaɪˈhɛksiəm/ ​(OON-by-HEK-see-əm)
Alternative nameselement 126, eka-plutonium
Unbihexium in the periodic table
Hydrogen Helium
Lithium Beryllium Boron Carbon Nitrogen Oxygen Fluorine Neon
Sodium Magnesium Aluminium Silicon Phosphorus Sulfur Chlorine Argon
Potassium Calcium Scandium Titanium Vanadium Chromium Manganese Iron Cobalt Nickel Copper Zinc Gallium Germanium Arsenic Selenium Bromine Krypton
Rubidium Strontium Yttrium Zirconium Niobium Molybdenum Technetium Ruthenium Rhodium Palladium Silver Cadmium Indium Tin Antimony Tellurium Iodine Xenon
Caesium Barium Lanthanum Cerium Praseodymium Neodymium Promethium Samarium Europium Gadolinium Terbium Dysprosium Holmium Erbium Thulium Ytterbium Lutetium Hafnium Tantalum Tungsten Rhenium Osmium Iridium Platinum Gold Mercury (element) Thallium Lead Bismuth Polonium Astatine Radon
Francium Radium Actinium Thorium Protactinium Uranium Neptunium Plutonium Americium Curium Berkelium Californium Einsteinium Fermium Mendelevium Nobelium Lawrencium Rutherfordium Dubnium Seaborgium Bohrium Hassium Meitnerium Darmstadtium Roentgenium Copernicium Nihonium Flerovium Moscovium Livermorium Tennessine Oganesson
Ununennium Unbinilium
Unquadtrium Unquadquadium Unquadpentium Unquadhexium Unquadseptium Unquadoctium Unquadennium Unpentnilium Unpentunium Unpentbium Unpenttrium Unpentquadium Unpentpentium Unpenthexium Unpentseptium Unpentoctium Unpentennium Unhexnilium Unhexunium Unhexbium Unhextrium Unhexquadium Unhexpentium Unhexhexium Unhexseptium Unhexoctium Unhexennium Unseptnilium Unseptunium Unseptbium
Unbiunium Unbibium Unbitrium Unbiquadium Unbipentium Unbihexium Unbiseptium Unbioctium Unbiennium Untrinilium Untriunium Untribium Untritrium Untriquadium Untripentium Untrihexium Untriseptium Untrioctium Untriennium Unquadnilium Unquadunium Unquadbium
—
↑
Ubh
↓
—
unbipentium ← unbihexium → unbiseptium
Atomic number (Z)126
Group g-block groups (no number)
Period period 8 (theoretical, extended table)
Block   g-block
Electron configuration predictions vary, see text
Physical properties
Phase at  STP unknown
Atomic properties
Oxidation states (+1), (+2), (+4), (+6), (+8)(predicted) [1]
Other properties
CAS Number 54500-77-5
History
Naming IUPAC systematic element name
| references

Unbihexium, also known as element 126 or eka-plutonium, is a hypothetical chemical element; it has atomic number 126 and placeholder symbol Ubh. Unbihexium and Ubh are the temporary IUPAC name and symbol, respectively, until the element is discovered, confirmed, and a permanent name is decided upon. In the periodic table, unbihexium is expected to be a g-block superactinide and the eighth element in the 8th period. Unbihexium has attracted attention among nuclear physicists, especially in early predictions targeting properties of superheavy elements, for 126 may be a magic number of protons near the center of an island of stability, leading to longer half-lives, especially for 310Ubh or 354Ubh which may also have magic numbers of neutrons. [2]

Contents

Early interest in possible increased stability led to the first attempted synthesis of unbihexium in 1971 and searches for it in nature in subsequent years. Despite several reported observations, more recent studies suggest that these experiments were insufficiently sensitive; hence, no unbihexium has been found naturally or artificially. Predictions of the stability of unbihexium vary greatly among different models; some suggest the island of stability may instead lie at a lower atomic number, closer to copernicium and flerovium.

Unbihexium is predicted to be a chemically active superactinide, exhibiting a variety of oxidation states from +1 to +8, and possibly being a heavier congener of plutonium. An overlap in energy levels of the 5g, 6f, 7d, and 8p orbitals is also expected, which complicates predictions of chemical properties for this element.

Introduction

This section is an excerpt from Superheavy element § Introduction.[ edit ]

Synthesis of superheavy nuclei

A graphic depiction of a nuclear fusion reaction. Two nuclei fuse into one, emitting a neutron. Reactions that created new elements to this moment were similar, with the only possible difference that several singular neutrons sometimes were released, or none at all. Deuterium-tritium fusion.svg
A graphic depiction of a nuclear fusion reaction. Two nuclei fuse into one, emitting a neutron. Reactions that created new elements to this moment were similar, with the only possible difference that several singular neutrons sometimes were released, or none at all.

A superheavy [lower-alpha 1] atomic nucleus is created in a nuclear reaction that combines two other nuclei of unequal size [lower-alpha 2] into one; roughly, the more unequal the two nuclei in terms of mass, the greater the possibility that the two react. [8] The material made of the heavier nuclei is made into a target, which is then bombarded by the beam of lighter nuclei. Two nuclei can only fuse into one if they approach each other closely enough; normally, nuclei (all positively charged) repel each other due to electrostatic repulsion. The strong interaction can overcome this repulsion but only within a very short distance from a nucleus; beam nuclei are thus greatly accelerated in order to make such repulsion insignificant compared to the velocity of the beam nucleus. [9] The energy applied to the beam nuclei to accelerate them can cause them to reach speeds as high as one-tenth of the speed of light. However, if too much energy is applied, the beam nucleus can fall apart. [9]

Coming close enough alone is not enough for two nuclei to fuse: when two nuclei approach each other, they usually remain together for approximately 10−20 seconds and then part ways (not necessarily in the same composition as before the reaction) rather than form a single nucleus. [9] [10] This happens because during the attempted formation of a single nucleus, electrostatic repulsion tears apart the nucleus that is being formed. [9] Each pair of a target and a beam is characterized by its cross section—the probability that fusion will occur if two nuclei approach one another expressed in terms of the transverse area that the incident particle must hit in order for the fusion to occur. [lower-alpha 3] This fusion may occur as a result of the quantum effect in which nuclei can tunnel through electrostatic repulsion. If the two nuclei can stay close for past that phase, multiple nuclear interactions result in redistribution of energy and an energy equilibrium. [9]

External videos
Nuvola apps kaboodle.svg Visualization of unsuccessful nuclear fusion, based on calculations from the Australian National University [12]

The resulting merger is an excited state [13] —termed a compound nucleus—and thus it is very unstable. [9] To reach a more stable state, the temporary merger may fission without formation of a more stable nucleus. [14] Alternatively, the compound nucleus may eject a few neutrons, which would carry away the excitation energy; if the latter is not sufficient for a neutron expulsion, the merger would produce a gamma ray. This happens in approximately 10−16 seconds after the initial nuclear collision and results in creation of a more stable nucleus. [14] The definition by the IUPAC/IUPAP Joint Working Party (JWP) states that a chemical element can only be recognized as discovered if a nucleus of it has not decayed within 10−14 seconds. This value was chosen as an estimate of how long it takes a nucleus to acquire its outer electrons and thus display its chemical properties. [15] [lower-alpha 4]

Decay and detection

The beam passes through the target and reaches the next chamber, the separator; if a new nucleus is produced, it is carried with this beam. [17] In the separator, the newly produced nucleus is separated from other nuclides (that of the original beam and any other reaction products) [lower-alpha 5] and transferred to a surface-barrier detector, which stops the nucleus. The exact location of the upcoming impact on the detector is marked; also marked are its energy and the time of the arrival. [17] The transfer takes about 10−6 seconds; in order to be detected, the nucleus must survive this long. [20] The nucleus is recorded again once its decay is registered, and the location, the energy, and the time of the decay are measured. [17]

Stability of a nucleus is provided by the strong interaction. However, its range is very short; as nuclei become larger, its influence on the outermost nucleons (protons and neutrons) weakens. At the same time, the nucleus is torn apart by electrostatic repulsion between protons, and its range is not limited. [21] Total binding energy provided by the strong interaction increases linearly with the number of nucleons, whereas electrostatic repulsion increases with the square of the atomic number, i.e. the latter grows faster and becomes increasingly important for heavy and superheavy nuclei. [22] [23] Superheavy nuclei are thus theoretically predicted [24] and have so far been observed [25] to predominantly decay via decay modes that are caused by such repulsion: alpha decay and spontaneous fission. [lower-alpha 6] Almost all alpha emitters have over 210 nucleons, [27] and the lightest nuclide primarily undergoing spontaneous fission has 238. [28] In both decay modes, nuclei are inhibited from decaying by corresponding energy barriers for each mode, but they can be tunnelled through. [22] [23]

Scheme of an apparatus for creation of superheavy elements, based on the Dubna Gas-Filled Recoil Separator set up in the Flerov Laboratory of Nuclear Reactions in JINR. The trajectory within the detector and the beam focusing apparatus changes because of a dipole magnet in the former and quadrupole magnets in the latter. Apparatus for creation of superheavy elements en.svg
Scheme of an apparatus for creation of superheavy elements, based on the Dubna Gas-Filled Recoil Separator set up in the Flerov Laboratory of Nuclear Reactions in JINR. The trajectory within the detector and the beam focusing apparatus changes because of a dipole magnet in the former and quadrupole magnets in the latter.

Alpha particles are commonly produced in radioactive decays because mass of an alpha particle per nucleon is small enough to leave some energy for the alpha particle to be used as kinetic energy to leave the nucleus. [30] Spontaneous fission is caused by electrostatic repulsion tearing the nucleus apart and produces various nuclei in different instances of identical nuclei fissioning. [23] As the atomic number increases, spontaneous fission rapidly becomes more important: spontaneous fission partial half-lives decrease by 23 orders of magnitude from uranium (element 92) to nobelium (element 102), [31] and by 30 orders of magnitude from thorium (element 90) to fermium (element 100). [32] The earlier liquid drop model thus suggested that spontaneous fission would occur nearly instantly due to disappearance of the fission barrier for nuclei with about 280 nucleons. [23] [33] The later nuclear shell model suggested that nuclei with about 300 nucleons would form an island of stability in which nuclei will be more resistant to spontaneous fission and will primarily undergo alpha decay with longer half-lives. [23] [33] Subsequent discoveries suggested that the predicted island might be further than originally anticipated; they also showed that nuclei intermediate between the long-lived actinides and the predicted island are deformed, and gain additional stability from shell effects. [34] Experiments on lighter superheavy nuclei, [35] as well as those closer to the expected island, [31] have shown greater than previously anticipated stability against spontaneous fission, showing the importance of shell effects on nuclei. [lower-alpha 7]

Alpha decays are registered by the emitted alpha particles, and the decay products are easy to determine before the actual decay; if such a decay or a series of consecutive decays produces a known nucleus, the original product of a reaction can be easily determined. [lower-alpha 8] (That all decays within a decay chain were indeed related to each other is established by the location of these decays, which must be in the same place.) [17] The known nucleus can be recognized by the specific characteristics of decay it undergoes such as decay energy (or more specifically, the kinetic energy of the emitted particle). [lower-alpha 9] Spontaneous fission, however, produces various nuclei as products, so the original nuclide cannot be determined from its daughters. [lower-alpha 10]

The information available to physicists aiming to synthesize a superheavy element is thus the information collected at the detectors: location, energy, and time of arrival of a particle to the detector, and those of its decay. The physicists analyze this data and seek to conclude that it was indeed caused by a new element and could not have been caused by a different nuclide than the one claimed. Often, provided data is insufficient for a conclusion that a new element was definitely created and there is no other explanation for the observed effects; errors in interpreting data have been made. [lower-alpha 11]

History

Synthesis attempts

The first and only attempt to synthesize unbihexium, which was unsuccessful, was performed in 1971 at CERN (European Organization for Nuclear Research) by René Bimbot and John M. Alexander using the hot fusion reaction: [2] [46]

232
90Th
 + 84
36Kr
 → 316
126Ubh
* → no atoms

High-energy (13-15 MeV) alpha particles were observed and taken as possible evidence for the synthesis of unbihexium. Subsequent unsuccessful experiments with higher sensitivity suggest that the 10 mb sensitivity of this experiment was too low; hence, the formation of unbihexium nuclei in this reaction was deemed highly unlikely. [47]

Possible natural occurrence

A study in 1976 by a group of American researchers from several universities proposed that primordial superheavy elements, mainly livermorium, unbiquadium, unbihexium, and unbiseptium, with half-lives exceeding 500 million years [48] could be a cause of unexplained radiation damage (particularly radiohalos) in minerals. [49] This prompted many researchers to search for them in nature from 1976 to 1983. A group led by Tom Cahill, a professor at the University of California at Davis, claimed in 1976 that they had detected alpha particles and X-rays with the right energies to cause the damage observed, supporting the presence of these elements, especially unbihexium. Others claimed that none had been detected, and questioned the proposed characteristics of primordial superheavy nuclei. [50] In particular, they cited that the magic number N = 228 necessary for enhanced stability would create a neutron-excessive nucleus in unbihexium that might not be beta-stable, although several calculations suggest that 354Ubh may indeed be stable against beta decay. [51] This activity was also proposed to be caused by nuclear transmutations in natural cerium, raising further ambiguity upon this claimed observation of superheavy elements. [52]

Unbihexium has received particular attention in these investigations, for its speculated location in the island of stability may increase its abundance relative to other superheavy elements. [48] Any naturally occurring unbihexium is predicted to be chemically similar to plutonium and may exist with primordial 244Pu in the rare earth mineral bastnäsite. [48] In particular, plutonium and unbihexium are predicted to have similar valence configurations, leading to the existence of unbihexium in the +4 oxidation state. Therefore, should unbihexium occur naturally, it may be possible to extract it using similar techniques for the accumulation of cerium and plutonium. [48] Likewise, unbihexium could also exist in monazite with other lanthanides and actinides that would be chemically similar. [52] Recent doubt on the existence of primordial 244Pu casts uncertainty on these predictions, however, [53] as the nonexistence (or minimal existence) of plutonium in bastnäsite will inhibit possible identification of unbihexium as its heavier congener.

The possible extent of primordial superheavy elements on Earth today is uncertain. Even if they are confirmed to have caused the radiation damage long ago, they might now have decayed to mere traces, or even be completely gone. [54] It is also uncertain if such superheavy nuclei may be produced naturally at all, as spontaneous fission is expected to terminate the r-process responsible for heavy element formation between mass number 270 and 290, well before elements such as unbihexium may be formed. [55]

A recent hypothesis tries to explain the spectrum of Przybylski's Star by naturally occurring flerovium, unbinilium, and unbihexium. [56] [57]

Naming

Using the 1979 IUPAC recommendations, the element should be temporarily called unbihexium (symbol Ubh) until it is discovered, the discovery is confirmed, and a permanent name chosen. [58] Although widely used in the chemical community on all levels, from chemistry classrooms to advanced textbooks, the recommendations are mostly ignored among scientists who work theoretically or experimentally on superheavy elements, who call it "element 126", with the symbol E126, (126), or 126. [59] Some researchers have also referred to unbihexium as eka-plutonium, [60] [61] a name derived from the system Dmitri Mendeleev used to predict unknown elements, though such an extrapolation might not work for g-block elements with no known congeners, and eka-plutonium would instead refer to element 146 [62] or 148 [63] when the term is meant to denote the element directly below plutonium.

Prospects for future synthesis

Every element from mendelevium onward was produced in fusion-evaporation reactions, culminating in the discovery of the heaviest known element, oganesson, in 2002 [64] [65] and most recently tennessine in 2010. [66] These reactions approached the limit of current technology; for example, the synthesis of tennessine required 22 milligrams of 249Bk and an intense 48Ca beam for six months. The intensity of beams in superheavy element research cannot exceed 1012 projectiles per second without damaging the target and detector, and producing larger quantities of increasingly rare and unstable actinide targets is impractical. [67] Consequently, future experiments must be done at facilities such as the superheavy element factory (SHE-factory) at the Joint Institute for Nuclear Research (JINR) or RIKEN, which will allow experiments to run for longer time periods with increased detection capabilities and enable otherwise inaccessible reactions. [68] Even so, it will likely be a great challenge to synthesize elements beyond unbinilium (120) or unbiunium (121), given their short predicted half-lives and low predicted cross sections. [69]

It has been suggested that fusion-evaporation will not be feasible to reach unbihexium. As 48Ca cannot be used for synthesis of elements beyond atomic number 118 or possibly 119, the only alternatives are increasing the atomic number of the projectile or studying symmetric or near-symmetric reactions. [70] One calculation suggests that the cross section for producing unbihexium from 249Cf and 64Ni may be as low as nine orders of magnitude lower than the detection limit; such results are also suggested by the non-observation of unbinilium and unbibium in reactions with heavier projectiles and experimental cross section limits. [71] If Z = 126 represents a closed proton shell, compound nuclei may have greater survival probability and the use of 64Ni may be more feasible for producing nuclei with 122 < Z < 126, especially for compound nuclei near the closed shell at N = 184. [72] However, the cross section still might not exceed 1  fb, posing an obstacle that may only be overcome with more sensitive equipment. [73]

Predicted properties

Nuclear stability and isotopes

This nuclear chart used by the Japan Atomic Energy Agency predicts the decay modes of nuclei up to Z = 149 and N = 256. At Z = 126 (top right), the beta-stability line passes through a region of instability towards spontaneous fission (half-lives less than 1 nanosecond) and extends into a "cape" of stability near the N = 228 shell closure, where an island of stability centered at the possibly doubly magic isotope Ubh may exist. Nuclear chart from KTUY model.svg
This nuclear chart used by the Japan Atomic Energy Agency predicts the decay modes of nuclei up to Z = 149 and N = 256. At Z = 126 (top right), the beta-stability line passes through a region of instability towards spontaneous fission (half-lives less than 1 nanosecond) and extends into a "cape" of stability near the N = 228 shell closure, where an island of stability centered at the possibly doubly magic isotope Ubh may exist.
This diagram depicts shell gaps in the nuclear shell model. Shell gaps are created when more energy is required to reach the shell at the next higher energy level, thus resulting in a particularly stable configuration. For protons, the shell gap at Z = 82 corresponds to the peak of stability at lead, and while there is disagreement of the magicity of Z = 114 and Z = 120, a shell gap appears at Z = 126, thus suggesting that there may be a proton shell closure at unbihexium. Next proton shell.svg
This diagram depicts shell gaps in the nuclear shell model. Shell gaps are created when more energy is required to reach the shell at the next higher energy level, thus resulting in a particularly stable configuration. For protons, the shell gap at Z = 82 corresponds to the peak of stability at lead, and while there is disagreement of the magicity of Z = 114 and Z = 120, a shell gap appears at Z = 126, thus suggesting that there may be a proton shell closure at unbihexium.

Extensions of the nuclear shell model predicted that the next magic numbers after Z = 82 and N = 126 (corresponding to 208Pb, the heaviest stable nucleus) were Z = 126 and N = 184, making 310Ubh the next candidate for a doubly magic nucleus. These speculations led to interest in the stability of unbihexium as early as 1957; Gertrude Scharff Goldhaber was one of the first physicists to predict a region of increased stability in the vicinity of, and possibly centered at, unbihexium. [2] This notion of an "island of stability" comprising longer-lived superheavy nuclei was popularized by University of California professor Glenn Seaborg in the 1960s. [76]

In this region of the periodic table, N = 184 and N = 228 have been suggested as closed neutron shells, [77] and various atomic numbers, including Z = 126, have been proposed as closed proton shells. [lower-alpha 12] The extent of stabilizing effects in the region of unbihexium is uncertain, however, due to predictions of shifting or weakening of the proton shell closure and possible loss of double magicity. [77] More recent research predicts the island of stability to instead be centered at beta-stable isotopes of copernicium (291Cn and 293Cn) [70] [78] or flerovium (Z = 114), which would place unbihexium well above the island and result in short half-lives regardless of shell effects.

Earlier models suggested the existence of long-lived nuclear isomers resistant to spontaneous fission in the region near 310Ubh, with half-lives on the order of millions or billions of years. [79] However, more rigorous calculations as early as the 1970s yielded contradictory results; it is now believed that the island of stability is not centered at 310Ubh, and thus will not enhance the stability of this nuclide. Instead, 310Ubh is thought to be very neutron-deficient and susceptible to alpha decay and spontaneous fission in less than a microsecond, and it may even lie at or beyond the proton drip line. [2] [69] [74] A 2016 calculation on the decay properties of 288–339Ubh upholds these predictions; the isotopes lighter than 313Ubh (including 310Ubh) may indeed lie beyond the drip line and decay by proton emission, 313–327Ubh will alpha decay, possibly reaching flerovium and livermorium isotopes, and heavier isotopes will decay by spontaneous fission. [80] This study and a quantum tunneling model predict alpha-decay half-lives under a microsecond for isotopes lighter than 318Ubh, rendering them impossible to identify experimentally. [80] [81] [lower-alpha 13] Hence, the isotopes 318–327Ubh may be synthesized and detected, and may even constitute a region of increased stability against fission around N ~ 198 with half-lives up to several seconds, though such a region of increased stability is completely absent in other models. [78]

A "sea of instability" defined by very low fission barriers (caused by greatly increasing Coulomb repulsion in superheavy elements) and consequently fission half-lives on the order of 10−18 seconds is predicted across various models. Although the exact limit of stability for half-lives over one microsecond varies, stability against fission is strongly dependent on the N = 184 and N = 228 shell closures and rapidly drops off immediately beyond the influence of the shell closure. [69] [74] Such an effect may be reduced, however, if nuclear deformation in intermediate isotopes may lead to a shift in magic numbers; [82] a similar phenomenon was observed in the deformed doubly magic nucleus 270Hs. [83] This shift could then lead to longer half-lives, perhaps on the order of days, for isotopes such as 342Ubh that would also lie on the beta-stability line. [82] A second island of stability for spherical nuclei may exist in unbihexium isotopes with many more neutrons, centered at 354Ubh and conferring additional stability in N = 228 isotones near the beta-stability line. [74] Originally, a short half-life of 39 milliseconds was predicted for 354Ubh toward spontaneous fission, though a partial alpha half-life for this isotope was predicted to be 18 years. [2] More recent analysis suggests that this isotope may have a half-life on the order of 100 years should the closed shells have strong stabilizing effects, placing it at the peak of an island of stability. [74] It may also be possible that 354Ubh is not doubly magic, as the Z = 126 shell is predicted to be relatively weak, or in some calculations, completely nonexistent. This suggests that any relative stability in unbihexium isotopes would be only due to neutron shell closures that may or may not have a stabilizing effect at Z = 126. [51] [77]

Chemical

Unbihexium is expected to be the sixth member of a superactinide series. It may have similarities to plutonium, as both elements have eight valence electrons over a noble gas core. In the superactinide series, the Aufbau principle is expected to break down due to relativistic effects, and an overlap of the energy levels of the 7d, 8p, and especially 5g and 6f orbitals is expected, which renders predictions of chemical and atomic properties of these elements very difficult. [84] The ground state electron configuration of unbihexium is thus predicted to be [Og] 5g2 6f2 7d1 8s2 8p1 [85] or 5g1 6f4 8s2 8p1, [86] in contrast to [Og] 5g6 8s2 derived from Aufbau.

As with the other early superactinides, it is predicted that unbihexium will be able to lose all eight valence electrons in chemical reactions, rendering a variety of oxidation states up to +8 possible. [1] The +4 oxidation state is predicted to be most common, in addition to +2 and +6. [85] [62] Unbihexium should be able to form the tetroxide UbhO4 and hexahalides UbhF6 and UbhCl6, the latter with a fairly strong bond dissociation energy of 2.68 eV. [87] Calculations suggest that a diatomic UbhF molecule will feature a bond between the 5g orbital in unbihexium and the 2p orbital in fluorine, thus characterizing unbihexium as an element whose 5g electrons should actively participate in bonding. [60] [61] It is also predicted that the Ubh6+ (in particular, in UbhF6) and Ubh7+ ions will have the electron configurations [Og] 5g2 and [Og] 5g1, respectively, in contrast to the [Og] 6f1 configuration seen in Ubt4+ and Ubq5+ that bears more resemblance to their actinide homologs. [1] The activity of 5g electrons may influence the chemistry of superactinides such as unbihexium in new ways that are difficult to predict, as no known elements have electrons in a g orbital in the ground state. [62]

See also

Notes

  1. ↑ In nuclear physics, an element is called heavy if its atomic number is high; lead (element 82) is one example of such a heavy element. The term "superheavy elements" typically refers to elements with atomic number greater than 103 (although there are other definitions, such as atomic number greater than 100 [3] or 112; [4] sometimes, the term is presented an equivalent to the term "transactinide", which puts an upper limit before the beginning of the hypothetical superactinide series). [5] Terms "heavy isotopes" (of a given element) and "heavy nuclei" mean what could be understood in the common language—isotopes of high mass (for the given element) and nuclei of high mass, respectively.
  2. ↑ In 2009, a team at the JINR led by Oganessian published results of their attempt to create hassium in a symmetric 136Xe + 136Xe reaction. They failed to observe a single atom in such a reaction, putting the upper limit on the cross section, the measure of probability of a nuclear reaction, as 2.5  pb. [6] In comparison, the reaction that resulted in hassium discovery, 208Pb + 58Fe, had a cross section of ~20 pb (more specifically, 19+19
    -11     pb), as estimated by the discoverers. [7]
  3. ↑ The amount of energy applied to the beam particle to accelerate it can also influence the value of cross section. For example, in the 28
    14    Si
     + 1
    0    n
     → 28
    13    Al
     + 1
    1    p
     reaction, cross section changes smoothly from 370 mb at 12.3 MeV to 160 mb at 18.3 MeV, with a broad peak at 13.5 MeV with the maximum value of 380 mb. [11]
  4. ↑ This figure also marks the generally accepted upper limit for lifetime of a compound nucleus. [16]
  5. ↑ This separation is based on that the resulting nuclei move past the target more slowly then the unreacted beam nuclei. The separator contains electric and magnetic fields whose effects on a moving particle cancel out for a specific velocity of a particle. [18] Such separation can also be aided by a time-of-flight measurement and a recoil energy measurement; a combination of the two may allow to estimate the mass of a nucleus. [19]
  6. ↑ Not all decay modes are caused by electrostatic repulsion. For example, beta decay is caused by the weak interaction. [26]
  7. ↑ It was already known by the 1960s that ground states of nuclei differed in energy and shape as well as that certain magic numbers of nucleons corresponded to greater stability of a nucleus. However, it was assumed that there was no nuclear structure in superheavy nuclei as they were too deformed to form one. [31]
  8. ↑ Since mass of a nucleus is not measured directly but is rather calculated from that of another nucleus, such measurement is called indirect. Direct measurements are also possible, but for the most part they have remained unavailable for superheavy nuclei. [36] The first direct measurement of mass of a superheavy nucleus was reported in 2018 at LBNL. [37] Mass was determined from the location of a nucleus after the transfer (the location helps determine its trajectory, which is linked to the mass-to-charge ratio of the nucleus, since the transfer was done in presence of a magnet). [38]
  9. ↑ If the decay occurred in a vacuum, then since total momentum of an isolated system before and after the decay must be preserved, the daughter nucleus would also receive a small velocity. The ratio of the two velocities, and accordingly the ratio of the kinetic energies, would thus be inverse to the ratio of the two masses. The decay energy equals the sum of the known kinetic energy of the alpha particle and that of the daughter nucleus (an exact fraction of the former). [27] The calculations hold for an experiment as well, but the difference is that the nucleus does not move after the decay because it is tied to the detector.
  10. ↑ Spontaneous fission was discovered by Soviet physicist Georgy Flerov, [39] a leading scientist at JINR, and thus it was a "hobbyhorse" for the facility. [40] In contrast, the LBL scientists believed fission information was not sufficient for a claim of synthesis of an element. They believed spontaneous fission had not been studied enough to use it for identification of a new element, since there was a difficulty of establishing that a compound nucleus had only ejected neutrons and not charged particles like protons or alpha particles. [16] They thus preferred to link new isotopes to the already known ones by successive alpha decays. [39]
  11. ↑ For instance, element 102 was mistakenly identified in 1957 at the Nobel Institute of Physics in Stockholm, Stockholm County, Sweden. [41] There were no earlier definitive claims of creation of this element, and the element was assigned a name by its Swedish, American, and British discoverers, nobelium. It was later shown that the identification was incorrect. [42] The following year, RL was unable to reproduce the Swedish results and announced instead their synthesis of the element; that claim was also disproved later. [42] JINR insisted that they were the first to create the element and suggested a name of their own for the new element, joliotium; [43] the Soviet name was also not accepted (JINR later referred to the naming of the element 102 as "hasty"). [44] This name was proposed to IUPAC in a written response to their ruling on priority of discovery claims of elements, signed 29 September 1992. [44] The name "nobelium" remained unchanged on account of its widespread usage. [45]
  12. ↑ Atomic numbers 114, 120, 122, 124 have also been suggested as closed proton shells in different models.
  13. ↑ While such nuclei may be synthesized and a series of decay signals may be registered, decays faster than one microsecond may pile up with subsequent signals and thus be indistinguishable, especially when multiple uncharacterized nuclei may be formed and emit a series of similar alpha particles. The main difficulty is thus attributing the decays to the correct parent nucleus, as a superheavy atom that decays before reaching the detector will not be registered at all.

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Bohrium is a synthetic chemical element; it has symbol Bh and atomic number 107. It is named after Danish physicist Niels Bohr. As a synthetic element, it can be created in particle accelerators but is not found in nature. All known isotopes of bohrium are highly radioactive; the most stable known isotope is 270Bh with a half-life of approximately 2.4 minutes, though the unconfirmed 278Bh may have a longer half-life of about 11.5 minutes.

<span class="mw-page-title-main">Lawrencium</span> Chemical element, symbol Lr and atomic number 103

Lawrencium is a synthetic chemical element; it has symbol Lr and atomic number 103. It is named in honor of Ernest Lawrence, inventor of the cyclotron, a device that was used to discover many artificial radioactive elements. A radioactive metal, lawrencium is the eleventh transuranic element and the last member of the actinide series. Like all elements with atomic number over 100, lawrencium can only be produced in particle accelerators by bombarding lighter elements with charged particles. Fourteen isotopes of lawrencium are currently known; the most stable is 266Lr with half-life 11 hours, but the shorter-lived 260Lr is most commonly used in chemistry because it can be produced on a larger scale.

<span class="mw-page-title-main">Meitnerium</span> Chemical element, symbol Mt and atomic number 109

Meitnerium is a synthetic chemical element; it has symbol Mt and atomic number 109. It is an extremely radioactive synthetic element. The most stable known isotope, meitnerium-278, has a half-life of 4.5 seconds, although the unconfirmed meitnerium-282 may have a longer half-life of 67 seconds. The GSI Helmholtz Centre for Heavy Ion Research near Darmstadt, Germany, first created this element in 1982. It is named after Lise Meitner.

<span class="mw-page-title-main">Nobelium</span> Chemical element, symbol No and atomic number 102

Nobelium is a synthetic chemical element; it has symbol No and atomic number 102. It is named in honor of Alfred Nobel, the inventor of dynamite and benefactor of science. A radioactive metal, it is the tenth transuranic element and is the penultimate member of the actinide series. Like all elements with atomic number over 100, nobelium can only be produced in particle accelerators by bombarding lighter elements with charged particles. A total of twelve nobelium isotopes are known to exist; the most stable is 259No with a half-life of 58 minutes, but the shorter-lived 255No is most commonly used in chemistry because it can be produced on a larger scale.

<span class="mw-page-title-main">Rutherfordium</span> Chemical element, symbol Rf and atomic number 104

Rutherfordium is a synthetic chemical element; it has symbol Rf and atomic number 104. It is named after physicist Ernest Rutherford. As a synthetic element, it is not found in nature and can only be made in a particle accelerator. It is radioactive; the most stable known isotope, 267Rf, has a half-life of about 48 minutes.

<span class="mw-page-title-main">Darmstadtium</span> Chemical element, symbol Ds and atomic number 110

Darmstadtium is a synthetic chemical element; it has symbol Ds and atomic number 110. It is extremely radioactive: the most stable known isotope, darmstadtium-281, has a half-life of approximately 14 seconds. Darmstadtium was first created in 1994 by the GSI Helmholtz Centre for Heavy Ion Research in the city of Darmstadt, Germany, after which it was named.

<span class="mw-page-title-main">Roentgenium</span> Chemical element, symbol Rg and atomic number 111

Roentgenium is a synthetic chemical element; it has symbol Rg and atomic number 111. It is extremely radioactive and can only be created in a laboratory. The most stable known isotope, roentgenium-282, has a half-life of 120 seconds, although the unconfirmed roentgenium-286 may have a longer half-life of about 10.7 minutes. Roentgenium was first created in 1994 by the GSI Helmholtz Centre for Heavy Ion Research near Darmstadt, Germany. It is named after the physicist Wilhelm Röntgen, who discovered X-rays. Only a few roentgenium atoms have ever been synthesized, and they have no practical application.

Livermorium is a synthetic chemical element; it has symbol Lv and atomic number 116. It is an extremely radioactive element that has only been created in a laboratory setting and has not been observed in nature. The element is named after the Lawrence Livermore National Laboratory in the United States, which collaborated with the Joint Institute for Nuclear Research (JINR) in Dubna, Russia, to discover livermorium during experiments conducted between 2000 and 2006. The name of the laboratory refers to the city of Livermore, California, where it is located, which in turn was named after the rancher and landowner Robert Livermore. The name was adopted by IUPAC on May 30, 2012. Five isotopes of livermorium are known, with mass numbers of 288 and 290–293 inclusive; the longest-lived among them is livermorium-293 with a half-life of about 60 milliseconds. A sixth possible isotope with mass number 294 has been reported but not yet confirmed.

<span class="mw-page-title-main">Oganesson</span> Chemical element, symbol Og and atomic number 118

Oganesson is a synthetic chemical element; it has symbol Og and atomic number 118. It was first synthesized in 2002 at the Joint Institute for Nuclear Research (JINR) in Dubna, near Moscow, Russia, by a joint team of Russian and American scientists. In December 2015, it was recognized as one of four new elements by the Joint Working Party of the international scientific bodies IUPAC and IUPAP. It was formally named on 28 November 2016. The name honors the nuclear physicist Yuri Oganessian, who played a leading role in the discovery of the heaviest elements in the periodic table. It is one of only two elements named after a person who was alive at the time of naming, the other being seaborgium, and the only element whose eponym is alive as of 2023.

<span class="mw-page-title-main">Island of stability</span> Predicted set of isotopes of relatively more stable superheavy elements

In nuclear physics, the island of stability is a predicted set of isotopes of superheavy elements that may have considerably longer half-lives than known isotopes of these elements. It is predicted to appear as an "island" in the chart of nuclides, separated from known stable and long-lived primordial radionuclides. Its theoretical existence is attributed to stabilizing effects of predicted "magic numbers" of protons and neutrons in the superheavy mass region.

<span class="mw-page-title-main">Unbinilium</span> Chemical element, symbol Ubn and atomic number 120

Unbinilium, also known as eka-radium or element 120, is a hypothetical chemical element; it has symbol Ubn and atomic number 120. Unbinilium and Ubn are the temporary systematic IUPAC name and symbol, which are used until the element is discovered, confirmed, and a permanent name is decided upon. In the periodic table of the elements, it is expected to be an s-block element, an alkaline earth metal, and the second element in the eighth period. It has attracted attention because of some predictions that it may be in the island of stability.

Moscovium is a synthetic chemical element; it has symbol Mc and atomic number 115. It was first synthesized in 2003 by a joint team of Russian and American scientists at the Joint Institute for Nuclear Research (JINR) in Dubna, Russia. In December 2015, it was recognized as one of four new elements by the Joint Working Party of international scientific bodies IUPAC and IUPAP. On 28 November 2016, it was officially named after the Moscow Oblast, in which the JINR is situated.

Tennessine is a synthetic chemical element; it has symbol Ts and atomic number 117. It is the second-heaviest known element and the penultimate element of the 7th period of the periodic table.

<span class="mw-page-title-main">Copernicium</span> Chemical element, symbol Cn and atomic number 112

Copernicium is a synthetic chemical element; it has symbol Cn and atomic number 112. Its known isotopes are extremely radioactive, and have only been created in a laboratory. The most stable known isotope, copernicium-285, has a half-life of approximately 30 seconds. Copernicium was first created in 1996 by the GSI Helmholtz Centre for Heavy Ion Research near Darmstadt, Germany. It was named after the astronomer Nicolaus Copernicus.

Flerovium is a superheavy synthetic chemical element; it has symbol Fl and atomic number 114. It is an extremely radioactive synthetic element, named after the Flerov Laboratory of Nuclear Reactions of the Joint Institute for Nuclear Research in Dubna, Russia, where the element was discovered in 1999. The lab's name, in turn, honours Russian physicist Georgy Flyorov. IUPAC adopted the name on 30 May 2012. The name and symbol had previously been proposed for element 102 (nobelium), but was not accepted by IUPAC at that time.

<span class="mw-page-title-main">Nihonium</span> Chemical element, symbol Nh and atomic number 113

Nihonium is a synthetic chemical element; it has symbol Nh and atomic number 113. It is extremely radioactive: its most stable known isotope, nihonium-286, has a half-life of about 10 seconds. In the periodic table, nihonium is a transactinide element in the p-block. It is a member of period 7 and group 13.

Unbibium, also known as element 122 or eka-thorium, is a hypothetical chemical element; it has placeholder symbol Ubb and atomic number 122. Unbibium and Ubb are the temporary systematic IUPAC name and symbol respectively, which are used until the element is discovered, confirmed, and a permanent name is decided upon. In the periodic table of the elements, it is expected to follow unbiunium as the second element of the superactinides and the fourth element of the 8th period. Similarly to unbiunium, it is expected to fall within the range of the island of stability, potentially conferring additional stability on some isotopes, especially 306Ubb which is expected to have a magic number of neutrons (184).

Superheavy elements, also known as transactinide elements, transactinides, or super-heavy elements, are the chemical elements with atomic number greater than 103. The superheavy elements are those beyond the actinides in the periodic table; the last actinide is lawrencium. By definition, superheavy elements are also transuranium elements, i.e., having atomic numbers greater than that of uranium (92). Depending on the definition of group 3 adopted by authors, lawrencium may also be included to complete the 6d series.

Unbiunium, also known as eka-actinium or element 121, is a hypothetical chemical element; it has symbol Ubu and atomic number 121. Unbiunium and Ubu are the temporary systematic IUPAC name and symbol respectively, which are used until the element is discovered, confirmed, and a permanent name is decided upon. In the periodic table of the elements, it is expected to be the first of the superactinides, and the third element in the eighth period. It has attracted attention because of some predictions that it may be in the island of stability. It is also likely to be the first of a new g-block of elements.

Unbiquadium, also known as element 124 or eka-uranium, is a hypothetical chemical element; it has placeholder symbol Ubq and atomic number 124. Unbiquadium and Ubq are the temporary IUPAC name and symbol, respectively, until the element is discovered, confirmed, and a permanent name is decided upon. In the periodic table, unbiquadium is expected to be a g-block superactinide and the sixth element in the 8th period. Unbiquadium has attracted attention, as it may lie within the island of stability, leading to longer half-lives, especially for 308Ubq which is predicted to have a magic number of neutrons (184).

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