Copper(II) oxalate

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Copper(II) oxalate
Copper (II) Oxalate Structural Formula V1.svg
Kupfer(II)-oxalat.jpg
Names
Other names
Copper (II) oxalate, cupric oxalate, copper(2+) ethanedioate
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.011.283 OOjs UI icon edit-ltr-progressive.svg
EC Number
  • 212-411-4
PubChem CID
UNII
UN number 3077
  • Key: QYCVHILLJSYYBD-UHFFFAOYSA-N
  • InChI=1S/C2H2O4.Cu/c3-1(4)2(5)6;/h(H,3,4)(H,5,6);/q;+2
  • O=C([O-])C([O-])=O.[Cu+2]
Properties
CuC
2
O
4
Molar mass 151.56
Appearanceblue solid
Density 6.57 g/cm3
insoluble
4.43×10−10 [1]
Hazards
GHS labelling:
GHS-pictogram-exclam.svg [2]
Warning
H302, H302+H312, H312
P264, P270, P280, P301+P312, P302+P352, P312, P322, P330, P363, P501
Related compounds
Related compounds
Calcium oxalate
Sodium oxalate
Magnesium oxalate
Strontium oxalate
Barium oxalate
Iron(II) oxalate
Iron(III) oxalate
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

Copper(II) oxalate are inorganic compounds with the chemical formula CuC2O4(H2O)x. The value of x can be 0, 0.44, and 1. Two of these species are found as secondary minerals (degradation of minerals), whewellite (monohydrate) and moolooite (0.44 hydrate). [3] The anhydrous compound has been characterized by X-ray crystallography. [4] Many transition metal oxalate complexes are known.

Contents

Copper(II) monooxalates are practically insoluble in all solvents. They are coordination polymers. [5]

Synthesis

Copper(II) oxalate can be produced by precipitation from acidified aqueous copper(II) salts and oxalic acid. [6] [7]

CuSO4 + H2C2O4 + H2O → CuC2O4·H2O + H2SO4

Reactions

Upon heating to 130 °C, the hydrated copper(II) oxalates convert to the anhydrous cupric oxalate. Further heating at higher temperatures under an atmosphere of hydrogen gives copper metal, suitable as a reagent. [6]

The hydrates bind Lewis bases.

Hydrated copper(II) oxalate reacts with alkali metal oxalates and ammonium oxalate to give bis(oxalato)cuprate: [8]

CuC2O4)(H2O)x + C2O2−4[Cu(C2O4)2]2− + x H2O

Uses

Copper oxalate is used as a catalyst for organic reactions, as a stabilizer for acetylated polyformaldehyde. [9] [10]

Related Research Articles

Iron(III) chloride describes the inorganic compounds with the formula FeCl3(H2O)x. Also called ferric chloride, these compounds are some of the most important and commonplace compounds of iron. They are available both in anhydrous and in hydrated forms, which are both hygroscopic. They feature iron in its +3 oxidation state. The anhydrous derivative is a Lewis acid, while all forms are mild oxidizing agents. It is used as a water cleaner and as an etchant for metals.

<span class="mw-page-title-main">Copper(II) sulfate</span> Chemical compound

Copper(II) sulfate is an inorganic compound with the chemical formula CuSO4. It forms hydrates CuSO4·nH2O, where n can range from 1 to 7. The pentahydrate (n = 5), a bright blue crystal, is the most commonly encountered hydrate of copper(II) sulfate, while its anhydrous form is white. Older names for the pentahydrate include blue vitriol, bluestone, vitriol of copper, and Roman vitriol. It exothermically dissolves in water to give the aquo complex [Cu(H2O)6]2+, which has octahedral molecular geometry. The structure of the solid pentahydrate reveals a polymeric structure wherein copper is again octahedral but bound to four water ligands. The Cu(II)(H2O)4 centers are interconnected by sulfate anions to form chains.

<span class="mw-page-title-main">Copper(II) nitrate</span> Chemical compound

Copper(II) nitrate describes any member of the family of inorganic compounds with the formula Cu(NO3)2(H2O)x. The hydrates are blue solids. Anhydrous copper nitrate forms blue-green crystals and sublimes in a vacuum at 150-200 °C. Common hydrates are the hemipentahydrate and trihydrate.

<span class="mw-page-title-main">Calcium sulfate</span> Laboratory and industrial chemical

Calcium sulfate (or calcium sulphate) is the inorganic compound with the formula CaSO4 and related hydrates. In the form of γ-anhydrite (the anhydrous form), it is used as a desiccant. One particular hydrate is better known as plaster of Paris, and another occurs naturally as the mineral gypsum. It has many uses in industry. All forms are white solids that are poorly soluble in water. Calcium sulfate causes permanent hardness in water.

<span class="mw-page-title-main">Zinc chloride</span> Chemical compound

Zinc chloride is an inorganic chemical compound with the formula ZnCl2·nH2O, with n ranging from 0 to 4.5, forming hydrates. Zinc chloride, anhydrous and its hydrates, are colorless or white crystalline solids, and are highly soluble in water. Five hydrates of zinc chloride are known, as well as four forms of anhydrous zinc chloride.

<span class="mw-page-title-main">Copper(II) oxide</span> Chemical compound – an oxide of copper with formula CuO

Copper(II) oxide or cupric oxide is an inorganic compound with the formula CuO. A black solid, it is one of the two stable oxides of copper, the other being Cu2O or copper(I) oxide (cuprous oxide). As a mineral, it is known as tenorite, or sometimes black copper. It is a product of copper mining and the precursor to many other copper-containing products and chemical compounds.

In chemistry, water(s) of crystallization or water(s) of hydration are water molecules that are present inside crystals. Water is often incorporated in the formation of crystals from aqueous solutions. In some contexts, water of crystallization is the total mass of water in a substance at a given temperature and is mostly present in a definite (stoichiometric) ratio. Classically, "water of crystallization" refers to water that is found in the crystalline framework of a metal complex or a salt, which is not directly bonded to the metal cation.

<span class="mw-page-title-main">Aluminium chloride</span> Chemical compound

Aluminium chloride, also known as aluminium trichloride, is an inorganic compound with the formula AlCl3. It forms a hexahydrate with the formula [Al(H2O)6]Cl3, containing six water molecules of hydration. Both the anhydrous form and the hexahydrate are colourless crystals, but samples are often contaminated with iron(III) chloride, giving them a yellow colour.

<span class="mw-page-title-main">Copper(II) chloride</span> Chemical compound

Copper(II) chloride, also known as cupric chloride, is an inorganic compound with the chemical formula CuCl2. The monoclinic yellowish-brown anhydrous form slowly absorbs moisture to form the orthorhombic blue-green dihydrate CuCl2·2H2O, with two water molecules of hydration. It is industrially produced for use as a co-catalyst in the Wacker process.

<span class="mw-page-title-main">Nickel(II) chloride</span> Chemical compound

Nickel(II) chloride (or just nickel chloride) is the chemical compound NiCl2. The anhydrous salt is yellow, but the more familiar hydrate NiCl2·6H2O is green. Nickel(II) chloride, in various forms, is the most important source of nickel for chemical synthesis. The nickel chlorides are deliquescent, absorbing moisture from the air to form a solution. Nickel salts have been shown to be carcinogenic to the lungs and nasal passages in cases of long-term inhalation exposure.

<span class="mw-page-title-main">Tin(II) oxide</span> Chemical compound, stannous oxide (SnO)

Tin(II) oxide is a compound with the formula SnO. It is composed of tin and oxygen where tin has the oxidation state of +2. There are two forms, a stable blue-black form and a metastable red form.

<span class="mw-page-title-main">Copper(I) iodide</span> Chemical compound

Copper(I) iodide is an inorganic compound with the chemical formula CuI. It is also known as cuprous iodide. It is useful in a variety of applications ranging from organic synthesis to cloud seeding.

<span class="mw-page-title-main">Copper(II) acetate</span> Chemical compound

Copper(II) acetate, also referred to as cupric acetate, is the chemical compound with the formula Cu(OAc)2 where AcO is acetate (CH
3
CO
2
). The hydrated derivative, Cu2(OAc)4(H2O)2, which contains one molecule of water for each copper atom, is available commercially. Anhydrous copper(II) acetate is a dark green crystalline solid, whereas Cu2(OAc)4(H2O)2 is more bluish-green. Since ancient times, copper acetates of some form have been used as fungicides and green pigments. Today, copper acetates are used as reagents for the synthesis of various inorganic and organic compounds. Copper acetate, like all copper compounds, emits a blue-green glow in a flame.

<span class="mw-page-title-main">Aluminium fluoride</span> Chemical compound

Aluminium fluoride is an inorganic compound with the formula AlF3. It forms hydrates AlF3·xH2O. Anhydrous AlF3 and its hydrates are all colorless solids. Anhydrous AlF3 is used in the production of aluminium. Several occur as minerals.

<span class="mw-page-title-main">Trimagnesium phosphate</span> Chemical compound

Trimagnesium phosphate describes inorganic compounds with formula Mg3(PO4)2.xH2O. They are magnesium acid salts of phosphoric acid, with varying amounts of water of crystallization: x = 0, 5, 8, 22.

<span class="mw-page-title-main">Copper(II) phosphate</span> Chemical compound

Copper(II) phosphate are inorganic compounds with the formula Cu3(PO4)2. They can be regarded as the cupric salts of phosphoric acid. Anhydrous copper(II) phosphate and a trihydrate are blue solids.

<span class="mw-page-title-main">Iron(II) oxalate</span> Chemical compound

Ferrous oxalate (iron(II) oxalate) are inorganic compound with the formula FeC2O4(H2O)x where x is 0 or 2. These are orange compounds, poorly soluble in water.

<span class="mw-page-title-main">Yttrium oxalate</span> Chemical compound

Yttrium oxalate is an inorganic compound, a salt of yttrium and oxalic acid with the chemical formula Y2(C2O4)3. The compound does not dissolve in water and forms crystalline hydrates—colorless crystals.

An oxalate nitrate is a chemical compound or salt that contains oxalate and nitrate anions (NO3- and C2O42-). These are mixed anion compounds. Some have third anions. Oxalate acts as a ligand, which normally complexes two metal atoms.

<span class="mw-page-title-main">Europium compounds</span> Chemical compounds

Europium compounds are compounds formed by the lanthanide metal europium (Eu). In these compounds, europium generally exhibits the +3 oxidation state, such as EuCl3, Eu(NO3)3 and Eu(CH3COO)3. Compounds with europium in the +2 oxidation state are also known. The +2 ion of europium is the most stable divalent ion of lanthanide metals in aqueous solution. Many europium compounds fluoresce under ultraviolet light due to the excitation of electrons to higher energy levels. Lipophilic europium complexes often feature acetylacetonate-like ligands, e.g., Eufod.

References

  1. John Rumble (June 18, 2018). CRC Handbook of Chemistry and Physics (99 ed.). CRC Press. pp. 5–188. ISBN   978-1138561632.
  2. "Copper oxalate - Substance Information - ECHA". European Chemical Agency . Retrieved 17 June 2021.
  3. Christensen, Axel Nørlund; Lebech, Bente; Andersen, Niels Hessel; Grivel, Jean-Claude (2014). "The Crystal structure of paramagnetic copper(<SCP>ii</SCP>) oxalate (CuC2O4): Formation and thermal decomposition of randomly stacked anisotropic nano-sized crystallites" (PDF). Dalton Trans. 43 (44): 16754–16768. doi:10.1039/C4DT01689K. PMID   25278188.
  4. Schmittler, H. (1968). "Zum Strukturprinzip des fehlgeordneten Kupfer(II)-Oxalats CuC2O4·nH2O". Monatsberichte der Deutschen Akademie der Wissenschaften zu Berlin. 10: 581-604.
  5. "Hazardous Substances Data Bank (HSDB) : 265". National Library of Medicine . Retrieved 17 June 2021.
  6. 1 2 O. Glemser; R. Sauer (1963). "Copper(II) Sulfide". In G. Brauer (ed.). Handbook of Preparative Inorganic Chemistry, 2nd Ed. Vol. 2pages=1017-1018. NY,NY: Academic Press.
  7. Gooch, Frank Austin (1909). The precipitation of copper oxalate in analysis. p. 448. OCLC   890741677.
  8. Kirschner, Stanley; McLean, John A.; Meerman, Gerardine (1960). "Potassium Dioxalatocuprate(II) 2-Hydrate". Inorganic Syntheses. Vol. 6. pp. 1–2. doi:10.1002/9780470132371.ch1. ISBN   978-0-470-13165-7.
  9. Richardson, H. Wayne (1997). Handbook of Copper Compounds and Applications. CRC Press. p. 84. ISBN   978-0-8247-8998-5.
  10. Richardson, H. Wayne (2000). "Copper Compounds". Ullmann's Encyclopedia of Industrial Chemistry. doi:10.1002/14356007.a07_567. ISBN   978-3-527-30385-4.
  11. Royappa, A. Timothy; Royappa, Andrew D.; Moral, Raphael F.; Rheingold, Arnold L.; Papoular, Robert J.; Blum, Deke M.; Duong, Tien Q.; Stepherson, Jacob R.; Vu, Oliver D.; Chen, Banghao; Suchomel, Matthew R.; Golen, James A.; André, Gilles; Kourkoumelis, Nikolaos; Mercer, Andrew D.; Pekarek, Allegra M.; Kelly, Dylan C. (November 2016). "Copper(I) oxalate complexes: Synthesis, structures and surprises". Polyhedron. 119: 563–574. doi: 10.1016/j.poly.2016.09.043 .