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Names | |
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IUPAC name Potassium tetrahydroborate | |
Other names Potassium tetrahydridoborate Borate(1-), tetrahydro-, potassium (1:1) | |
Identifiers | |
3D model (JSmol) | |
ChemSpider | |
ECHA InfoCard | 100.033.949 |
EC Number |
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PubChem CID | |
UNII | |
UN number | 1870 (POTASSIUM BOROHYDRIDE) |
CompTox Dashboard (EPA) | |
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Properties | |
K[BH4] | |
Molar mass | 53.94 g·mol−1 |
Appearance | colorless solid |
Density | 1.17 g/mL |
Melting point | 607 °C (1,125 °F; 880 K) decomposes |
19g/100g | |
Solubility in methanol | 3.9g/100g |
Hazards | |
GHS labelling: | |
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Danger | |
H261, H301, H311, H314, H331 | |
P280, P305+P351+P338, P309, P310, P370+P378, P402+P404 | |
Related compounds | |
Other anions | Potassium hydride |
Other cations | |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). |
Potassium borohydride, also known as potassium tetrahydroborate, is an inorganic compound with the formula KBH4.
It can be obtained through the reaction of sodium borohydride with aqueous potassium hydroxide in a methanol or water solvent: [1]
Potassium is a colorless solid that is stable at room temperature and in an aqueous alkaline solution. [2] Potassium borohydride has a hydrogen desorption temperature of 584 °C, higher than for lithium borohydride or sodium borohydride. [1]
Like the related Na+, Rb+, and Cs+ salts, potassium borohydride crystallizes in a sodium chloride lattice type, space group Fm3m. [3] [4]
Often potassium borohydride behaves similarly to the more common sodium borohydride, but solubility considerations sometimes recommend the potassium salt. One example is the synthesis of potassium trispyrazolylborate (KTp). The procedure involves heating potassium borohydride and pyrazole without a solvent. [5]
Diborane is produced by treating potassium borohydride with phosphoric acid. [6]
In combination with bismuth trichloride, it forms a reagent for the reduction of nitro group to the hydroxylamine. [7]
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