K-14 was the most recent version of the developing process for Kodak's Kodachrome transparency film before its discontinuation (the last revision having been designated Process K-14M). [1] It superseded previous versions of the Kodachrome process used with older films (such as K-12 for Kodachrome II and Kodachrome-X). [2]
The K-14 process differed significantly from its contemporary, the E-6 process, in both complexity and length. Kodachrome film has no integral color couplers; dyes are produced during processing (each color in a separate step) by the reaction of the color couplers with the oxidised developer. [3]
Due to declining sales, Kodak discontinued production of all K-14 chemistry in 2009, [4] concurrently with Kodachrome 64 film. Dwayne's Photo, in Parsons, Kansas, operated the last K-14 line in the world, discontinued sales on 30 December 2010; [5] [6] [7] the last roll was processed on 18 January 2011. [8]
The cross-section of Kodachrome film consists of layers which are, from top-to-bottom: blue sensitive (of which the non-sensitized portions will be dyed yellow), yellow filter, blue-green sensitive (dyed magenta), blue-red sensitive (dyed cyan), acetate base, rem-jet anti-halation backing. [1] [9]
The blue-green and blue-red sensitive layers are primarily sensitive to green and red light, respectively, but are sensitive to blue light as well. The yellow filter layer is added to prevent blue light from penetrating to these layers during exposure. [1]
Step | Action | Schematic | Description |
---|---|---|---|
1 | Backing removal | An alkaline bath softens the cellulose acetate phthalate binder. A spray wash and buffer removes the rem-jet anti-halation backing. | |
2 | First Developer | All exposed silver halide crystals are developed to metallic silver via a PQ (phenidone/hydroquinone) developer. The yellow filter layer becomes opaque because it has a combination of Lippmann emulsion (very tiny grains) and Carey Lea silver (metallic silver particles that are small enough that they are yellow rather than gray.) | |
3 | Wash | Stops development and removes the PQ developer. | |
4 | Red light re-exposure through the base | This makes the remaining undeveloped silver halide in the cyan layer developable. | |
5 | Cyan developer | The solution contains a color developer and a cyan coupler. These are colorless in solution. After the color developer develops the silver, the oxidized developer reacts with the cyan coupler to form cyan dye. The dye is much less soluble than either the developer or the coupler so it stays in the blue-red sensitive layer of the film. | |
6 | Wash | ||
7 | Blue light re-exposure from the top | This makes the remaining undeveloped silver halide grains in the blue sensitive layer (the yellow layer) developable. The now opaque yellow filter layers prevents the blue light from exposing the magenta layer (the green sensitive layer, which is also sensitive to blue light). It is important to avoid stray printing light exposing the film base of film. | |
8 | Yellow developer | Analogous to the cyan developer. | |
9 | Wash | ||
10 | Magenta developer | This contains a chemical fogging agent that makes all of the remaining undeveloped silver halide developable. If everything has worked correctly, nearly all of this silver halide is in the magenta layers. The developer and magenta coupler work just like the cyan and yellow developers to produce magenta dye that is insoluble and stays in the film. | |
11 | Wash | ||
12 | Conditioner | Prepares the metallic silver for the bleach step. | |
13 | Bleach | Oxidises the metallic silver to silver halide. The bleach (ferric EDTA) must be aerated. The former ferricyanide bleach did not require aeration and did not require a conditioner. | |
14 | Fix | Converts the silver halide to soluble silver compounds which are then dissolved and washed from the film. | |
15 | Wash | Washes the fixer out of the film. | |
16 | Rinse | Contains a wetting agent to reduce water spots. | |
17 | Dry |
The result is three different color records each with the appropriate dye, just like other color films. The original Kodachrome process in 1935 used dye bleaches and was a far more complex process; the dyes themselves were unstable and faded at high temperature. Although the formulae have changed over the years, the basic process steps have followed a similar pattern since the introduction of "selective re-exposure" Kodachrome in 1938. [11] : 163, 189
Film stock is an analog medium that is used for recording motion pictures or animation. It is recorded on by a movie camera, developed, edited, and projected onto a screen using a movie projector. It is a strip or sheet of transparent plastic film base coated on one side with a gelatin emulsion containing microscopically small light-sensitive silver halide crystals. The sizes and other characteristics of the crystals determine the sensitivity, contrast and resolution of the film. The emulsion will gradually darken if left exposed to light, but the process is too slow and incomplete to be of any practical use. Instead, a very short exposure to the image formed by a camera lens is used to produce only a very slight chemical change, proportional to the amount of light absorbed by each crystal. This creates an invisible latent image in the emulsion, which can be chemically developed into a visible photograph. In addition to visible light, all films are sensitive to X-rays and high-energy particles. Most are at least slightly sensitive to invisible ultraviolet (UV) light. Some special-purpose films are sensitive into the infrared (IR) region of the spectrum.
The following list comprises significant milestones in the development of photography technology.
Kodachrome is the brand name for a color reversal film introduced by Eastman Kodak in 1935. It was one of the first successful color materials and was used for both cinematography and still photography. For many years, Kodachrome was widely used for professional color photography, especially for images intended for publication in print media.
Photographic paper is a paper coated with a light-sensitive chemical formula, like photographic film, used for making photographic prints. When photographic paper is exposed to light, it captures a latent image that is then developed to form a visible image; with most papers the image density from exposure can be sufficient to not require further development, aside from fixing and clearing, though latent exposure is also usually present. The light-sensitive layer of the paper is called the emulsion. The most common chemistry was based on silver halide but other alternatives have also been used.
In photography, reversal film or slide film is a type of photographic film that produces a positive image on a transparent base. Instead of negatives and prints, reversal film is processed to produce transparencies or diapositives. Reversal film is produced in various sizes, from 35 mm to roll film to 8×10 inch sheet film.
The E-6 process is a chromogenic photographic process for developing Ektachrome, Fujichrome and other color reversal photographic film.
A Bayer filter mosaic is a color filter array (CFA) for arranging RGB color filters on a square grid of photosensors. Its particular arrangement of color filters is used in most single-chip digital image sensors used in digital cameras, and camcorders to create a color image. The filter pattern is half green, one quarter red and one quarter blue, hence is also called BGGR,RGBG, GRBG, or RGGB.
Velvia is a brand of daylight-balanced color reversal film produced by the Japanese company Fujifilm. The name is a portmanteau of "Velvet Media", a reference to its smooth image structure. The original incarnation of the film was called "Velvia for Professionals", known as RVP, a classification code meaning "Reversal/Velvia/Professional series". It is known for its extremely high level of color saturation and image quality.
C-41 is a chromogenic color print film developing process introduced by Kodak in 1972, superseding the C-22 process. C-41, also known as CN-16 by Fuji, CNK-4 by Konica, and AP-70 by AGFA, is the most popular film process in use, with most, if not all photofinishing labs devoting at least one machine to this development process.
Instant film is a type of photographic film that was introduced by Polaroid Corporation to produce a visible image within minutes or seconds of the photograph's exposure. The film contains the chemicals needed for developing and fixing the photograph, and the camera exposes and initiates the developing process after a photo has been taken.
In infrared photography, the photographic film or image sensor used is sensitive to infrared light. The part of the spectrum used is referred to as near-infrared to distinguish it from far-infrared, which is the domain of thermal imaging. Wavelengths used for photography range from about 700 nm to about 900 nm. Film is usually sensitive to visible light too, so an infrared-passing filter is used; this lets infrared (IR) light pass through to the camera, but blocks all or most of the visible light spectrum.
Leopold Godowsky Jr. was an American violinist and chemist, who together with Leopold Mannes created the first practical color transparency film, Kodachrome.
The E-4 process is a now outdated process for developing color reversal (transparency) photographic film, which was introduced in 1966.
A chromogenic print, also known as a C-print or C-type print, a silver halide print, or a dye coupler print, is a photographic print made from a color negative, transparency or digital image, and developed using a chromogenic process. They are composed of three layers of gelatin, each containing an emulsion of silver halide, which is used as a light-sensitive material, and a different dye coupler of subtractive color which together, when developed, form a full-color image.
Color motion picture film refers both to unexposed color photographic film in a format suitable for use in a motion picture camera, and to finished motion picture film, ready for use in a projector, which bears images in color.
The E-2 process and E-3 process are outdated processes for developing Ektachrome reversal photographic film. The two processes are very similar, and differ depending on the film. Kodak sold kits that could process either kind of film.
Leopold Damrosch Mannes was an American musician, who, together with Leopold Godowsky Jr., created the first practical color transparency film, Kodachrome.
Redscale is a technique of shooting photographic film where the film is exposed from the wrong side, i.e. the emulsion is exposed through the base of the film. Normally, this is done by winding the film upside-down into an empty film canister. The name "redscale" comes because there is a strong color shift to red due to the red-sensitive layer of the film being exposed first, rather than last [the red layer is normally the bottom layer in C-41 film]. All layers are sensitive to blue light, so normally the blue layer is on top, followed by a filter. In this technique, blue light exposes the layers containing cyan and magenta dyes, but the layer containing yellow dye is left unexposed due to the filter. E-6 film has also been used for this technique.
Photographic film is a strip or sheet of transparent film base coated on one side with a gelatin emulsion containing microscopically small light-sensitive silver halide crystals. The sizes and other characteristics of the crystals determine the sensitivity, contrast, and resolution of the film. Film is typically segmented in frames, that give rise to separate photographs.
Technicolor is a series of color motion picture processes, the first version dating back to 1916, and followed by improved versions over several decades.
[reference to another publication] "Manual for procesing Kodachrome II film and Kodachrome-X film (process K-12)
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