Most toners work by replacing the metallic silver in the emulsion with a silver compound, such as silver sulfide (Ag2S) in the case of sepia toning. The compound may be more stable than metallic silver and may also have a different color or tone. Different toning processes give different colors to the final print. In some cases, the printer may choose to tone some parts of a print more than others.[1]
Toner also can increase the range of shades visible in a print without reducing the contrast. Selenium toning is especially effective in this regard. Some toning processes can improve the chemical stability of the print, increasing its potential longevity. Other toning processes, such as those including iron and copper, can make the print less stable. Many chemical toners are highly toxic, some even containing chemicals that are carcinogenic. It is therefore extremely important that the chemicals be used in a well ventilated area, and rubber gloves and face protection should be worn when handling them.
Selenium toning
Selenium toning is a popular archival toning process, converting metallic silver to silver selenide. In a diluted toning solution, selenium toning gives a red-brown tone, while a strong solution gives a purple-brown tone. The change in color depends upon the chemical make-up of the photographic emulsion being toned. Chloro-bromide papers change dramatically, whilst pure bromide papers change little. Fibre-based papers are more responsive to selenium toning.[2]
Selenium toning may not produce prints quite as stable as sepia or gold toning. Recently, doubts have surfaced as to the effectiveness of selenium toner in ensuring print longevity.[3]
Sepia toning is a specialized treatment to give a black-and-white photographic print a warmer tone and to enhance its archival qualities. The metallic silver in the print is converted to a sulfide compound, which is much more resistant to the effects of environmental pollutants such as atmospheric sulfur compounds. Silver sulfide is at least 50% more stable than silver.[4]
There are three types of sepia toner in modern use;
Sodium sulfide toners – the traditional 'rotten egg' toners (sodium sulfide smells of rotten eggs when exposed to moisture);
Thiourea (or 'thiocarbamide') toners – these are odorless and the tone can be varied according to the chemical mixture;
Polysulfide or 'direct' toners – these do not require a bleaching stage.
Except for polysulfide toners, sepia toning is done in three stages. The print is first soaked in a potassium ferricyanide bleach to reconvert the metallic silver to silver halide. The print is washed to remove excess potassium ferricyanide and then immersed into a bath of toner, which converts the silver halides to silver sulfide.
Incomplete bleaching creates a multi-toned image with sepia highlights and gray mid-tones and shadows. This is called split toning. The untoned silver in the print can be treated with a different toner, such as gold or selenium.[5]
Fred Judge FRPS made extensive use of sepia toning for postcards produced by the British picture postcards manufacturer Judges Postcards.
Metal replacement toning
Metal replacement toners replace the metallic silver, through a series of chemical reactions, with a ferrocyanide salt of a transition metal. Some metals, such as platinum or gold, can protect the image. Others, such as iron (blue toner) or copper (red toner), may reduce the life of the image.[citation needed]
Metal-replacement toning with gold alone results in a blue-black tone. It is often combined with a sepia toner to produce a more attractive orange-red tone. The archival Gold Protective Solution (GP-1) formula uses a 1% gold chloride stock solution with sodium or potassium thiocyanate.[6] It is sometimes used to split tone photographs previously toned in selenium for artistic purposes.[7]
Dye toning
Dye toners replace the metallic silver with a dye. The image will have a reduced lifetime compared with an ordinary silver print.[citation needed]
Digital toning
Toning can be simulated digitally, either in-camera or in post-processing. The in-camera effect, as well as beginner tutorials given for software like Photoshop or GIMP, use a simple tint. More sophisticated software tends to implement sepia tones using the duotone feature. Simpler photo-editing software usually has an option to sepia-tone an image in one step.
Examples
The examples below show a digital color photograph, a black-and-white version and a sepia-toned version.
Color image
Grayscale image
Sepia-toned image
The following are examples of the three types using film:
A blueprint is a reproduction of a technical drawing or engineering drawing using a contact print process on light-sensitive sheets introduced by Sir John Herschel in 1842. The process allowed rapid and accurate production of an unlimited number of copies. It was widely used for over a century for the reproduction of specification drawings used in construction and industry. Blueprints were characterized by white lines on a blue background, a negative of the original. Color or shades of grey could not be reproduced.
Potassium ferricyanide is the chemical compound with the formula K3[Fe(CN)6]. This bright red salt contains the octahedrally coordinated [Fe(CN)6]3− ion. It is soluble in water and its solution shows some green-yellow fluorescence. It was discovered in 1822 by Leopold Gmelin.
Photographic processing or photographic development is the chemical means by which photographic film or paper is treated after photographic exposure to produce a negative or positive image. Photographic processing transforms the latent image into a visible image, makes this permanent and renders it insensitive to light.
Photographic paper is a paper coated with a light-sensitive chemical formula, like photographic film, used for making photographic prints. When photographic paper is exposed to light, it captures a latent image that is then developed to form a visible image; with most papers the image density from exposure can be sufficient to not require further development, aside from fixing and clearing, though latent exposure is also usually present. The light-sensitive layer of the paper is called the emulsion. The most common chemistry was based on silver halide but other alternatives have also been used.
The cyanotype is a slow-reacting, economical photographic printing formulation sensitive to a limited near ultraviolet and blue light spectrum, the range 300 nm to 400 nm known as UVA radiation. It produces a monochrome, blue coloured print on a range of supports, often used for art, and for reprography in the form of blueprints. For any purpose, the process usually uses two chemicals: ferric ammonium citrate or ferric ammonium oxalate, and potassium ferricyanide, and only water to develop and fix. Announced in 1842, it is still in use.
In the processing of photographic films, plates or papers, the photographic developer is one or more chemicals that convert the latent image to a visible image. Developing agents achieve this conversion by reducing the silver halides, which are pale-colored, into silver metal, which is black when in the form of fine particles. The conversion occurs within the gelatine matrix. The special feature of photography is that the developer acts more quickly on those particles of silver halide that have been exposed to light. When left in developer, all the silver halides will eventually be reduced and turn black. Generally, the longer a developer is allowed to work, the darker the image.
The albumen print, also called albumen silver print, is a method of producing a photographic print using egg whites. Published in January 1847 by Louis Désiré Blanquart-Evrard, it was the first commercial process of producing a photo on a paper base from a negative, previous methods - such as the daguerreotype and the tintype - having been printed on metal. It became the dominant form of photographic positives from 1855 to the start of the 20th century, with a peak in the 1860–90 period. During the mid-19th century, the carte de visite became one of the more popular uses of the albumen method. In the 19th century, E. & H. T. Anthony & Company were the largest makers and distributors of albumen photographic prints and paper in the United States.
The gelatin silver process is the most commonly used chemical process in black-and-white photography, and is the fundamental chemical process for modern analog color photography. As such, films and printing papers available for analog photography rarely rely on any other chemical process to record an image. A suspension of silver salts in gelatin is coated onto a support such as glass, flexible plastic or film, baryta paper, or resin-coated paper. These light-sensitive materials are stable under normal keeping conditions and are able to be exposed and processed even many years after their manufacture. The "dry plate" gelatin process was an improvement on the collodion wet-plate process dominant from the 1850s–1880s, which had to be exposed and developed immediately after coating.
Platinum prints, also called platinotypes, are photographic prints made by a monochrome printing process involving platinum.
Sun printing may refer to various printing techniques which use sunlight as a developing or fixative agent.
Print permanence refers to the longevity of printed material, especially photographs, and preservation issues. Over time, the optical density, color balance, lustre, and other qualities of a print will degrade. The rate at which deterioration occurs depends primarily on two main factors: the print itself, that is, the colorants used to form the image and the medium on which image resides, and the type of environment the print is exposed to.
Kallitype is a process for making photographic prints.
The conservation and restoration of photographs is the study of the physical care and treatment of photographic materials. It covers both efforts undertaken by photograph conservators, librarians, archivists, and museum curators who manage photograph collections at a variety of cultural heritage institutions, as well as steps taken to preserve collections of personal and family photographs. It is an umbrella term that includes both preventative preservation activities such as environmental control and conservation techniques that involve treating individual items. Both preservation and conservation require an in-depth understanding of how photographs are made, and the causes and prevention of deterioration. Conservator-restorers use this knowledge to treat photographic materials, stabilizing them from further deterioration, and sometimes restoring them for aesthetic purposes.
Ammonium ferric citrate has the formula [NH+4]5[Fe(C6H4O7)2]5−. The iron in this compound is trivalent. All three carboxyl groups and the central hydroxyl group of citric acid are deprotonated. A distinguishing feature of this compound is that it is very soluble in water, in contrast to ferric citrate which is not very soluble.
Black and white photography is a form of photography that captures scenes or subjects with a grayscale of brightness, without recording any natural colors. The resulting images, often referred to as monochrome, display a range of shades of gray, from black to white. This style of photography predates color photography and has remained a significant, timeless and versatile artistic and documentary medium for over a century.
Architectural reprography, the reprography of architectural drawings, covers a variety of technologies, media, and supports typically used to make multiple copies of original technical drawings and related records created by architects, landscape architects, engineers, surveyors, mapmakers and other professionals in building and engineering trades.
Photographic emulsion is a light-sensitive colloid used in film-based photography. Most commonly, in silver-gelatin photography, it consists of silver halide crystals dispersed in gelatin. The emulsion is usually coated onto a substrate of glass, films, paper, or fabric. The substrate is often flexible and known as a film base.
Monochrome photography is photography where each position on an image can record and show a different amount of light, but not a different hue. It includes all forms of black-and-white photography, which produce images containing shades of neutral grey ranging from black to white. Other hues besides grey, such as sepia, cyan, blue, or brown can also be used in monochrome photography. In the contemporary world, monochrome photography is mostly used for artistic purposes and certain technical imaging applications, rather than for visually accurate reproduction of scenes.
Glass coloring and color marking may be obtained in several ways.
by the addition of coloring ions,
by precipitation of nanometer-sized colloids, Ancient Roman enamelled glass, 1st century, Begram Hoard
by colored inclusions
by light scattering
by dichroic coatings, or
by colored coatings
A heliographic copier or heliographic duplicator is an apparatus used in the world of reprography for making contact prints on paper from original drawings made with that purpose on tracing paper, parchment paper or any other transparent or translucent material using different procedures. In general terms some type of heliographic copier is used for making: Hectographic prints, Ferrogallic prints, Gel-lithographs or Silver halide prints. All of them, until a certain size, can be achieved using a contact printer with an appropriate lamp but for big engineering and architectural plans, the heliographic copiers used with the cyanotype and the diazotype technologies, are of the roller type, which makes them completely different from contact printers.
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