Conservation and restoration of photographic plates

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Glass plate negative Glass plate negative.jpg
Glass plate negative

The conservation and restoration of photographic plates is the practice of caring for and maintaining photographic plates to preserve their materials and content. The practice includes the measures that can be taken by conservators, curators, collection managers, and other professionals to conserve the material unique to photographic plate processes. This practice includes understanding the composition and agents of deterioration of photographic plates, as well as the preventive, and interventive conservational measures that can be taken to increase a photographic image's longevity.

Contents

History

Composition

In general, black and white photographic negatives are made up of fine silver particles (or color dyes for color negatives), which are embedded in a thin layer called a binder; the two together comprising the emulsion. This emulsion layer sits upon what is called the support, which can be paper, metal, film, or, as in the case of photographic plates, glass. [1] Before exposure, a photographic plate consists of a photosensitive substance layered on a support medium. Glass plates emerged as a common support medium for photographic negatives from the mid-nineteenth century to the 1920s. Depending upon the period, there can be variants to the binder and, thus, the chemistry of the image. In the case of the Wet Plate Collodion, the image is run under a wash bath to stop the development of the image after exposure. An important part of the photographic process, "fixing", is then used to wash the silver particles that are not part of the image, which then produces a stable negative image. The fix bath will ensure that the remaining silver halide crystals are no longer sensitive to additional light exposure, removing all excess. This negative image can then be used over many years to produce paper positives. It is important for the conservator to understand the chemistry, in order to prevent further chemical reactions. [2]

Processes

Early wet-plate collodion portrait of a lady Early wet plate collodion portrait of lady -1 (4984137358).jpg
Early wet-plate collodion portrait of a lady

Agents of deterioration

There are ten accepted agents of deterioration: dissociation, fire, incorrect relative humidity, incorrect temperature, light, pests, pollutants, physical forces, thieves, and water. [9] Photographic plates face risks of damage from both external forces and from their own chemical composition. For a conservator to create an appropriate plan to protect against agents of deterioration, they must understand what might impact a photographic plate. The following list addresses how each agent of deterioration harms photographic glass plates.

Relative humidity and temperature

Relative humidity (RH) and temperature are two of the most common threats to photographic plates. [10] As with all material collections, high temperature in combination with high humidity can cause mold growth and attract pests.

Photographic plates face significant structural and chemical challenges unique to their makeup. There are two types of photographic glass plates: collodion wet plates and gelatin dry plates. Structurally, collodion wet plates are held together with a specific emulsion type, made using a silver halide mixture in gelatin. Fluctuations in RH can strain the adhesive emulsion, causing the gelatin to expand and contract. The strain from incorrect RH can also cause the emulsion to crack or separate along the plates' edges. [10] With gelatin dry plates, high humidity can cause mold to grow on the emulsion. [11] High levels of humidity can cause glass plates that have been stored incorrectly to stick together, compromising the image on the plate. Increasing RH can cause deterioration of other elements; these include the silver halide, varnish, and glass support. Decreasing the RH will cause deterioration by eventually leading to the flaking of the binder and dehydration of the glass. [12]

Much like RH, temperatures must be precise and closely monitored for the correct storage of photographic glass plates. A safe temperature to keep glass plates is 65 °F (18 °C); however, a fluctuation of +/- 2 °F (−17 °C) would not cause a significant impact, making the safest range 63 to 67 °F (17 to 19 °C). [13] Low temperatures aid in slowing a plate's inherent fragility by delaying the chemical reactions that cause decay of the plate's structure. Increasing temperatures or frequently high fluctuations will speed up the decay process.

Theft and dissociation

Although theft and dissociation can occur separately, it is not uncommon for the two to go hand-and-hand. Dissociation typically results in overtime from an ordered system falling apart due to lack of routine maintenance updates or from a catastrophic event leading to data loss. [14] If an inventory is not regularly updated it could become easy for a single, or several, glass plates to go missing. Regular inventory maintenance can also serve as a deterrent against theft. Ensuring glass plates are locked and stored where only designated museum staff can access them is the best preventative measure against theft.

Water and pests

Deterioration in glass is often directly related to moisture, from humidity or direct contact. [13] Enough moisture over time will result in the chemical composition of the image to change. In the 1990s, The United States National Archive began to notice that some glass plates featured in their collection, on the non-photo bearing side of the scale, a crystalline deposit, known as sick-glass, was present. [13]

If a glass plate has been subject to large amounts of moisture, it could grow mold on the plate's emulsion. Mold will eat away at the emulsion and attract other living pests. Insects will be more likely to appear in areas already compromised by inappropriate storage conditions. Insects will produce waste materials that, like dust, build up over time, causing further damage. Pests eat glass plate storage materials such as paper envelopes or cardboard boxes.

Light

Photographic plates and all photographic materials are susceptible to light. Extensive and ongoing exposure to light can cause significant and irreversible deterioration. Sunlight is the type of light most damaging to photographic plates. However, indoor lighting and other forms of UV lighting all pose a threat to photographic plates, causing fading and yellowing. [15] Light is especially threatening to color photographic materials as it causes accelerated fading of the color dyes. [16] Exposure to light could lead to deterioration and discoloration of the pigments present on the plate.

Pollutants and fire

Air pollution can threaten photographic plates through poor air quality and dirt that can damage the materials. This can include dust and gaseous pollution in an urban environment. Air pollution can cause fading of photographic materials. If a plate is subject to poor air quality, debris removal must be done with care using a cotton cloth; if done incorrectly, the glass might be subject to abrasions. [17] Other sources of air pollution include "photocopying machines, construction materials, paint fumes, cardboard, carpets, and janitorial supplies". [15]

Fire can cause severe damage to photographic glass plates. The heat produced by a fire can aid in increasing the chemical decomposition rate of the plate's emulsion. Pollutants in the air produced by the fire—such as smoke and debris—can also attach to or rest upon plates. The same care should be taken removing trash from the aftermath of a fire that would be used to remove dust and other air pollutants.

Material and chemical

The glass composition of photographic plates can be a factor of deterioration. Due to poor quality or an inherent fragility, "sick glass" can occur. Environmental conditions are usually linked to the increase or presence of this glass corrosion. The effect of "sick glass" can be weeping and crizzling caused by excessive alkali and a lack of stabilizers. [12] Weeping involves droplets forming on the glass that appear as tiny crystals. This deterioration is especially threatening to cased photographs because the cover glass could be corroded and damage the image underneath. [18] Corrosion of the glass plate support can also damage the image layer by causing the lifting of the binder and varnish layers. [13]

The other chemical components of glass-plate negatives can also be threatening agents of deterioration. For instance, the silver image layer could undergo oxidative deterioration, leading to fading and discoloration. Additionally, the collodion binder itself is made up of cellulose nitrate, which is known to be a highly flammable compound. Most of these agents of deterioration are the result of poor chemical processing as a result of inherent frgility, but poor environmental and storage conditions usually accelerate them. [13]

Broken glass plate - Avdella, izgorena, 1905 Avdella, izgorena, 1905.jpg
Broken glass plate – Avdella, izgorena, 1905

Physical

Glass plates are relatively stable dimensionally but also very fragile and brittle. [10] Glass is highly susceptible to breakage, cracks, and fractures. This can be caused by human error, including dropping or bumping the glass plate, or it can be caused by failure of storage equipment, housing, shelves, etc., which may lead to an impact against the glass. Different breakage and stress states affect the image layer and binder differently.

Types of breakage: [12]

Preventive conservation

Environment

Environmental controls are a crucial part of the preservation of photographic glass plates. Relative humidity (RH), temperature, and light play a significant role in keeping the multiple materials in photographic glass plates maintained. The following environmentally regulatory measures are taken for their preservation:

Handling

Photographic glass plates are handled carefully to avoid physical or chemical deterioration and damage – the following measures aid in their preservation through proper handling:

Storage

Storage of photographic glass plates is important to their preservation. Museums and other cultural institutions take the following measures to ensure their glass plates are properly housed:

Storage of broken photographic plates

Broken or cracked glass plates are stored specially, separate from other photographic plates, and in the following ways:

  • Broken glass plates are stored flat, unlike intact plates stored vertically. Stacking broken plates only five plates high is recommended due to the plates' weight. This will prevent further breakage and damage. [29]
  • Photographic glass plates with cracked or damaged binder are stored on sink-mats. [30] Those with minor flaking are still housed in the four-flap enclosure that is labeled appropriately, describing the damage. Glass plates with extensive flaking are stored on sink-mats horizontally and placed in a storage box with a label that reads "Caution: Broken glass. Carry Horizontally." [12]
  • Broken glass plate shards are "sandwiched" in between two pieces of buffered board and placed inside the four-flap enclosure. [24]
  • AIC advises that form-fit support should be created for broken glass shards by cutting out two pieces of 4-ply mat board that fit each shard. These pieces are then glued to each side of the buffered board with either wheat starch paste or 3M #415 double-stick tape, placing each shard in between the form-fit support to help prevent further damage. These broken shards are then placed in individual four-flap enclosures and stored flat, with appropriate labeling that warns of their broken condition. [12]
  • Another method of storing broken shards is to place them on sink mats. If this method is used, each piece is separated with paperboard spacers to prevent the pieces from touching. These paperboard spacers are sometimes attached with adhesives to the mat so that physical damage does not occur to the shards. They are stored horizontally and placed in a storage box with a label that reads "Caution: Broken glass. Carry Horizontally." [12]

Maintenance/housekeeping

Maintenance/housekeeping of photographic plates requires minimal intervention:

Conservation treatment

Many broken or cracked glass plates may benefit from conservation treatment. There are various actions taken in reassembling and restoring these plates using the following materials and methods:

Handling

Adhesives

Conservators use various adhesives; each adhesive type has benefits and disadvantages for different situations.

Backing material

Application

Repair methods and techniques

Projects

The vertical assembly method along with a light line is used in The Glass Plate Negative Project at the Heritage Conservation Centre, as outlined in the case study. This study shows how conservators also deal with other conservation issues, including accretions and residue. For instance, while the plates were considered structurally stable, they may have needed surface cleaning. This was completed by using swabs dampened with water/ethanol solutions to reduce stains or do away with any tape residue. Pressure-sensitive labels were removed mechanically. Conservators used Whatman lens tissues to wipe off any other residue marks. [35]

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