The Hazardous Materials Identification System (HMIS) is a numerical hazard rating that incorporates the use of labels with color developed by the American Coatings Association as a compliance aid for the OSHA Hazard Communication (HazCom) Standard. [1] [2]
The HMIS Color Bar is similar to the safety square, created by the National Fire Protection Association (NFPA). Before 2002 the safety square and the color bar both had sections colored blue, red, white, and yellow. After April 2002, with the release of HMIS III, yellow in the color bar (which stood for reactivity) was replaced by orange, standing for physical hazard. The safety square is designed for emergencies when information about the effects of short, or acute, exposure is needed. The color bar is not for emergencies and is used to convey broader health warning information. Both systems were developed at a time when there was no mandated labeling system for communicating hazards of workplace chemicals (OSHA only required some system be used without specifying a format). In 2012, OSHA introduced an updated version of their HazCom standard known as HazCom 2012, which mandates GHS Labels on shipped containers, and updated requirements for workplace labels, which are compatible with GHS, although it does not mandate the use of GHS in the workplace. HMIS Color Bar is compliant with these new standards. Specifically, when using HMIS III, which accounts for the increased flammability hazard of aerosols. [3]
The four bars are color-coded, using the modern color bar symbols with blue indicating the level of health hazard, red for flammability, orange for a physical hazard, and white for Personal Protection. The number ratings range from 0 to 4.
The Health section conveys the health hazards of the material. In the latest version of HMIS, the Health bar has two spaces, one for an asterisk and one for a numeric hazard rating. If present, the asterisk signifies a chronic health hazard, meaning that long-term exposure to the material could cause a health problem such as emphysema or kidney damage. According to NPCA, the numeric hazard assessment procedure differs from that used by NFPA. [4]
For HMIS I and II, the criteria used to assign numeric values (0 = low hazard to 4 = high hazard) are identical to those used by NFPA. In other words, in this category, HMIS I & II are identical to NFPA. [4] For HMIS III, the flammability criteria are defined according to OSHA standards (which add elevated flammability ratings for aerosols). [5] (HMIS II descriptions, excluding the new aerosol criteria, are shown below)
Reactivity hazards are assessed using the OSHA criterion of physical hazard. Seven such hazard classes are recognized: Water Reactives, Organic Peroxides, Explosives, Compressed gases, Pyrophoric materials, Oxidizers, and Unstable Reactives. The numerical ratings are very similar to NFPA's yellow "Reactivity/Instability" rating according to the publicly available data, which is limited to "hazard statements" intended to accompany each rating (as shown below). [6] However, HMIS is a proprietary system, and without referring to the actual criteria for each rating, it is not clear how similar they are.
This is by far the largest area of difference between the NFPA and HMIS systems. In the NFPA system, the white area is used to convey special hazards whereas HMIS uses the white section to indicate which personal protective equipment (PPE) should be used when working with the material. [7] [8]
Personal protective equipment (PPE) is protective clothing, helmets, goggles, or other garments or equipment designed to protect the wearer's body from injury or infection. The hazards addressed by protective equipment include physical, electrical, heat, chemical, biohazards, and airborne particulate matter. Protective equipment may be worn for job-related occupational safety and health purposes, as well as for sports and other recreational activities. Protective clothing is applied to traditional categories of clothing, and protective gear applies to items such as pads, guards, shields, or masks, and others. PPE suits can be similar in appearance to a cleanroom suit.
Tetrahydrofuran (THF), or oxolane, is an organic compound with the formula (CH2)4O. The compound is classified as heterocyclic compound, specifically a cyclic ether. It is a colorless, water-miscible organic liquid with low viscosity. It is mainly used as a precursor to polymers. Being polar and having a wide liquid range, THF is a versatile solvent.
A boiling liquid expanding vapor explosion is an explosion caused by the rupture of a vessel containing a pressurized liquid that is or has reached a temperature sufficiently higher than its boiling point. Because the boiling point of a liquid rises with pressure, the contents of the pressurized vessel can remain a liquid as long as the vessel is intact. If the vessel's integrity is compromised, the loss of pressure drops the boiling point, which can cause the liquid to convert to gas expanding rapidly. BLEVEs are manifestations of explosive boiling.
"NFPA 704: Standard System for the Identification of the Hazards of Materials for Emergency Response" is a standard maintained by the U.S.-based National Fire Protection Association. First "tentatively adopted as a guide" in 1960, and revised several times since then, it defines the "Safety Square" or "Fire Diamond" which is used to quickly and easily identify the risks posed by hazardous materials. This helps determine what, if any, special equipment should be used, procedures followed, or precautions taken during the initial stages of an emergency response. It is an internationally accepted safety standard, and is crucial while transporting chemicals.
A confined space is a space with limited entry and egress and not suitable for human inhabitants. An example is the interior of a storage tank, occasionally entered by maintenance workers but not intended for human occupancy. Hazards in a confined space often include harmful dust or gases, asphyxiation, submersion in liquids or free-flowing granular solids, electrocution, or entrapment.
Dangerous goods, abbreviated DG, are substances that when transported are a risk to health, safety, property or the environment. Certain dangerous goods that pose risks even when not being transported are known as hazardous materials. An example for dangerous goods is hazardous waste which is waste that has substantial or potential threats to public health or the environment.
Chloroprene (IUPAC name 2-chlorobuta-1,3-diene) is a chemical compound with the molecular formula CH2=CCl−CH=CH2. Chloroprene is a colorless volatile liquid, almost exclusively used as a monomer for the production of the polymer polychloroprene, better known as neoprene, a type of synthetic rubber.
A flash fire is a sudden, intense fire caused by ignition of a mixture of air and a dispersed flammable substance such as a solid, flammable or combustible liquid, or a flammable gas. It is characterized by high temperature, short duration, and a rapidly moving flame front.
In electrical and safety engineering, hazardous locations are places where fire or explosion hazards may exist. Sources of such hazards include gases, vapors, dust, fibers, and flyings, which are combustible or flammable. Electrical equipment installed in such locations can provide an ignition source, due to electrical arcing, or high temperatures. Standards and regulations exist to identify such locations, classify the hazards, and design equipment for safe use in such locations.
Mixtures of dispersed combustible materials and oxygen in the air will burn only if the fuel concentration lies within well-defined lower and upper bounds determined experimentally, referred to as flammability limits or explosive limits. Combustion can range in violence from deflagration through detonation.
A flammable liquid is a liquid which can be easily ignited in air at ambient temperatures, i.e. it has a flash point at or below nominal threshold temperatures defined by a number of national and international standards organisations.
The Globally Harmonized System of Classification and Labelling of Chemicals (GHS) is an internationally agreed-upon standard managed by the United Nations that was set up to replace the assortment of hazardous material classification and labelling schemes previously used around the world. Core elements of the GHS include standardized hazard testing criteria, universal warning pictograms, and safety data sheets which provide users of dangerous goods relevant information with consistent organization. The system acts as a complement to the UN numbered system of regulated hazardous material transport. Implementation is managed through the UN Secretariat. Although adoption has taken time, as of 2017, the system has been enacted to significant extents in most major countries of the world. This includes the European Union, which has implemented the United Nations' GHS into EU law as the CLP Regulation, and United States Occupational Safety and Health Administration standards.
Potassium nitrate is an oxidizer so storing it near fire hazards or reducing agents should be avoided to minimise risk in case of a fire.
A combustible material is a material that can burn in air under certain conditions. A material is flammable if it ignites easily at ambient temperatures. In other words, a combustible material ignites with some effort and a flammable material catches fire immediately on exposure to flame.
Hazard statements form part of the Globally Harmonized System of Classification and Labelling of Chemicals (GHS). They are intended to form a set of standardized phrases about the hazards of chemical substances and mixtures that can be translated into different languages. As such, they serve the same purpose as the well-known R-phrases, which they are intended to replace.
Many laboratories contain significant risks, and the prevention of laboratory accidents requires great care and constant vigilance. Examples of risk factors include high voltages, high and low pressures and temperatures, corrosive and toxic chemicals and chemical vapours, radiation, fire, explosions, and biohazards including infective organisms and their toxins.
Chemical storage is the storage of controlled substances or hazardous materials in chemical stores, chemical storage cabinets, or similar devices.
In the process industry, chemical industry, manufacturing industry, and other commercial and industrial contexts, pipe marking is used to identify the contents, properties and flow direction of fluids in piping. It is typically carried out by marking piping through labels and color codes. Pipe marking helps personnel and fire response teams identify the correct pipes for operational, maintenance or emergency response purposes.
Chemical protective clothing (CPC) is clothing worn to shield those who work with chemicals from the effects of chemical hazards that can cause injuries on the job. It provides a last line of defense for chemical safety; it does not replace more proactive measures like engineering controls.
A safety cabinet is used for the safe storage of flammable chemical substance or compressed gas cylinders.
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