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| OFFICE | NAME | TERM |
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| Lord President of the Council | Thomas Herbert, 8th Earl of Pembroke | 18 May 1699 – 29 January 1702 |
| Charles Seymour, 6th Duke of Somerset | 29 January – 13 July 1702 |
| First Lord of the Treasury | Charles Montagu, 1st Earl of Halifax | 1 May 1697 – 15 November 1699 |
| Ford Grey, 1st Earl of Tankerville | 15 November 1699 – 9 December 1700 |
| Sidney Godolphin, 1st Earl of Godolphin | 9 December 1700 – 30 December 1701 |
| Charles Howard, 3rd Earl of Carlisle | 30 December 1701 – 8 May 1702 |
| Chancellor of the Exchequer | John Smith | 2 June 1699 – 27 March 1701 |
| Henry Boyle, 1st Baron Carleton | 1701–1708 |
| Lord Chancellor | John Somers, 1st Baron Somers | 1697–1700 |
| In Commission | |
| Nathan Wright | 1700–1705 |
| Northern Secretary | James Vernon | 26 December 1694–3 March 1695 |
| Charles Hedges | 2 December 1697–5 November 1700 |
| James Vernon | 5 November 1700–29 December 1701 |
| Southern Secretary | Edward Villiers, 1st Earl of Jersey | 14 May 1699–27 June 1700 |
| James Vernon | align="left"27 June 1700–4 January 1702 |
| Sir Charles Montagu, 1st Duke of Manchester | 4 January 1702–1 May 1702 |
| Archbishop of Canterbury | Thomas Tenison | 6 December 1694–14 December 1715 |
| Lord Privy Seal | John Lowther, 1st Viscount Lonsdale | 1699–1700 |
| Ford Grey, 1st Earl of Tankerville | 1700–1701 |
| In Commission | |
| Lord Steward | William Cavendish, 1st Duke of Devonshire | 1689–1707 |
| Lord Chamberlain | Charles Talbot, 1st Duke of Shrewsbury | 1699–1700 |
| Edward Villiers, 1st Earl of Jersey | 1700–1704 |
| Comptroller of the Household | Thomas Wharton, 5th Baron Wharton | 1689–1702 |
| Master-General of the Ordnance | Henry Sydney, 1st Earl of Romney | 1693–1702 |
| First Lord of the Admiralty | John Egerton, 3rd Earl of Bridgewater | 1699–1701 |
| Thomas Herbert, 8th Earl of Pembroke | 1701–1702 |
| Chancellor of the Duchy of Lancaster | Thomas Grey, 2nd Earl of Stamford | 4 May 1697–12 May 1702 |
| First Lord of Trade | Thomas Grey, 2nd Earl of Stamford | 9 June 1699–19 June 1702 |
| Secretary at War | George Clarke | 1690–1704 |
| Treasurer of the Navy | Sir Thomas de Littleton | 1699–1710 |
| Paymaster of the Forces | Richard Jones, 1st Earl of Ranelagh | 26 December 1685–22 December 1702 |
| Master of the Horses | Henry de Nassau, Lord Overkirk | 1689–1702 |
