| Date | Opponent | Stadium | Result | Goals for Europe XI | Reason | 
|---|
| 26 October 1938 |  England | Arsenal Stadium, London | 0–3 |  | 75th anniversary of the FA  [a]  [6]  [7] | 
| 10 May 1947 |  Great Britain | Hampden Park, Glasgow | 1–6 | Gunnar Nordahl | Home Nations return to FIFA  [6]  [9]  [10]  [11] | 
| 21 October 1953 |  England | Wembley, London | 4–4 | Laszlo Kubala (2×), Giampiero Boniperti (2×) | 90th anniversary of the FA  [12]  [13] | 
| 13 August 1955 |  Great Britain | Windsor Park, Belfast | 4–1 | Jean Vincent, Bernard Vukas (3×) | 75th anniversary of the Irish Football Association  [12]  [9] | 
| 20 May 1964 | Scandinavia | Idrætsparken, Copenhagen | 4–2 | Jimmy Greaves (2×), Denis Law, Eusébio | 75th anniversary of the DBU  [14]  [9] | 
| 23 September 1964 |  Yugoslavia | Marakana, Belgrade | 7–2 | Uwe Seeler (2×), Eusébio (4×), Jose Augusto | Skopje earthquake appeal fund [14] | 
| 28 April 1965 |  Great Britain | Victoria Ground, Stoke | 6–4 | Godfried van den Boer, Ferenc Puskás (2×), Josef Masopust, Laszlo Kubala, Jackie Henderson | Stanley Matthews testimonial [15]  [9] | 
| 27 September 1967 |  Spain | Santiago Bernabéu, Madrid | 3–0 | Sandro Mazzola, Eusébio, Fernand Goyvaerts | Ricardo Zamora testimonial | 
| 8 December 1970 |  Benfica | Estádio da Luz, Lisbon | 2–3 | Uwe Seeler, José Eulogio Gárate | Mário Coluna testimonial [16]  [9] | 
| 23 November 1971 |  West Ham United | Upton Park, London | 4–4 | Frank McDougall, Rodney Marsh (2×), Jimmy Greaves | Geoff Hurst testimonial [16] | 
| 1 May 1972 |  Hamburger SV | Volksparkstadion, Hamburg | 7–3 | Geoff Hurst, Ferenc Bene, Franz Beckenbauer, Gerd Müller, Kálmán Mészöly, George Best, Eusébio | Uwe Seeler testimonial [17]  [9] | 
| 3 October 1972 | South America | St. Jakob-Park, Basel | 0–2 |  | Pestalozzi charity match [18] | 
| 31 October 1973 | South America | Camp Nou, Barcelona | 4–4 | Eusébio, Salif Keïta, Juan Manuel Asensi, Kurt Jara | FIFA charity match [19] | 
| 28 December 1979 |  Borussia Dortmund | Westfalenstadion, Dortmund | 2–3 | Safet Sušić, Vladimir Petrović | Match for UNICEF  [20] | 
| 25 February 1981 |  Italy | Stadio Olimpico, Rome | 3–0 | Allan Simonsen, Vahid Halilhodžić, Tony Woodcock | Flood disaster appeal [21] | 
| 2 June 1981 |  Fenerbahçe | Şükrü Saracoğlu, Istanbul | 0–3 |  | 75th anniversary of Fenerbahçe  [21] | 
| 18 August 1981 |  Czechoslovakia | Letná-Stadion, Prague | 0–4 |  | 80th anniversary of the Czechoslovak Football Association  [21] | 
| 7 August 1982 | World XI | Giants Stadium, New York City | 3–2 | Kevin Keegan, Bruno Pezzey, Giancarlo Antognoni | FIFA charity match for  UNICEF  [22] | 
| 7 November 1995 | Americas | Camp Nou, Barcelona | 3–4 | Hristo Stoichkov, Arteaga, Igor Korneev | UNICEF charity match. [23]  [25] | 
| 4 December 1997 | World XI | Stade Vélodrome, Marseille | 2–5 | Marius Lacatus, Zinedine Zidane | Match played before 1998 FIFA World Cup draw [26] | 
| 18 August 1998 |  Manchester United | Old Trafford, Manchester | 4–8 | Jean-Pierre Papin, Laurent Blanc, Martin Dahlin, Mark Wilson | 40th anniversary of the Munich air disaster and Eric Cantona testimonial [27] | 
| 16 February 2005 | World XI (Ronaldinho XI)
 | Camp Nou, Barcelona | 3–6 | Alessandro Del Piero, Gianfranco Zola | Football for Hope (Indian Ocean Tsunami funds) [3]  [28]  [29]  [9] | 
| 14 March 2007 |  Manchester United | Old Trafford, Manchester | 3–4 | Florent Malouda, El Hadji Diouf (2×) | UEFA Celebration Match  [30]  [31]  [32]  [33]  [34] |