Praseodymium(III) hydroxide

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Praseodymium(III) hydroxide
Praseodymium(III) hydroxide.jpg
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.036.815 OOjs UI icon edit-ltr-progressive.svg
EC Number
  • 240-513-9
PubChem CID
  • InChI=1S/3H2O.Pr/h3*1H2;/q;;;+3/p-3
    Key: ZLGIGTLMMBTXIY-UHFFFAOYSA-K
  • [Pr+3].[OH-].[OH-].[OH-]
Properties
Pr(OH)3
Molar mass 191.932
Appearancegreen solid [1]
Melting point 220 °C (493 K)(dissolves) [2]
Virtually insoluble in water
3.39×1024 [3]
Related compounds
Other anions
Praseodymium(III) oxide
Other cations
Cerium(III) hydroxide
Neodymium(III) hydroxide
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

Praseodymium(III) hydroxide is an inorganic compound with a chemical formula Pr(OH)3.

Contents

Production

The reaction between ammonia water and praseodymium(III) nitrate produces praseodymium(III) hydroxide: [2]

Pr(NO3)3 + 3 NH3·H2O → Pr(OH)3↓ + 3 NH4NO3

Chemical properties

Praseodymium(III) hydroxide can react with acid and produce praseodymium salts:

Pr(OH)3 + 3 H+ → Pr3+ + 3 H2O, for example;

Pr(OH)3 + 3CH3COOH forms Pr(CH3CO2)3 + 3H2O;

Praseodymium(III) hydroxide + Acetic acid forms praseodymium(III) acetate and water.

Related Research Articles

<span class="mw-page-title-main">Potassium hydroxide</span> Inorganic compound (KOH)

Potassium hydroxide is an inorganic compound with the formula KOH, and is commonly called caustic potash.

<span class="mw-page-title-main">Praseodymium</span> Chemical element, symbol Pr and atomic number 59

Praseodymium is a chemical element; it has symbol Pr and the atomic number 59. It is the third member of the lanthanide series and is considered one of the rare-earth metals. It is a soft, silvery, malleable and ductile metal, valued for its magnetic, electrical, chemical, and optical properties. It is too reactive to be found in native form, and pure praseodymium metal slowly develops a green oxide coating when exposed to air.

<span class="mw-page-title-main">Praseodymium(III) chloride</span> Chemical compound

Praseodymium(III) chloride is the inorganic compound with the formula PrCl3. Like other lanthanide trichlorides, it exists both in the anhydrous and hydrated forms. It is a blue-green solid that rapidly absorbs water on exposure to moist air to form a light green heptahydrate.

<span class="mw-page-title-main">Aluminium chloride</span> Chemical compound

Aluminium chloride, also known as aluminium trichloride, is an inorganic compound with the formula AlCl3. It forms a hexahydrate with the formula [Al(H2O)6]Cl3, containing six water molecules of hydration. Both the anhydrous form and the hexahydrate are colourless crystals, but samples are often contaminated with iron(III) chloride, giving them a yellow colour.

<span class="mw-page-title-main">Iron(II) hydroxide</span> Chemical compound

Iron(II) hydroxide or ferrous hydroxide is an inorganic compound with the formula Fe(OH)2. It is produced when iron(II) salts, from a compound such as iron(II) sulfate, are treated with hydroxide ions. Iron(II) hydroxide is a white solid, but even traces of oxygen impart a greenish tinge. The air-oxidised solid is sometimes known as "green rust".

<span class="mw-page-title-main">Ferrate(VI)</span> Ion

Ferrate(VI) is the inorganic anion with the chemical formula [FeO4]2−. It is photosensitive, contributes a pale violet colour to compounds and solutions containing it and is one of the strongest water-stable oxidizing species known. Although it is classified as a weak base, concentrated solutions containing ferrate(VI) are corrosive and attack the skin and are only stable at high pH. It is similar to the somewhat more stable permanganate.

<span class="mw-page-title-main">Beryllium hydroxide</span> Chemical compound

Beryllium hydroxide, Be(OH)2, is an amphoteric hydroxide, dissolving in both acids and alkalis. Industrially, it is produced as a by-product in the extraction of beryllium metal from the ores beryl and bertrandite. The natural pure beryllium hydroxide is rare (in form of the mineral behoite, orthorhombic) or very rare (clinobehoite, monoclinic). When alkali is added to beryllium salt solutions the α-form (a gel) is formed. If this left to stand or boiled, the rhombic β-form precipitates. This has the same structure as zinc hydroxide, Zn(OH)2, with tetrahedral beryllium centers.

Basic oxides are oxides that show basic properties, in opposition to acidic oxides. A basic oxide can either react with water to form a base, or with an acid to form a salt and water in a neutralization reaction.

<span class="mw-page-title-main">Nickel(II) hydroxide</span> Chemical compound

Nickel(II) hydroxide is the inorganic compound with the formula Ni(OH)2. It is a lime-green solid that dissolves with decomposition in ammonia and amines and is attacked by acids. It is electroactive, being converted to the Ni(III) oxy-hydroxide, leading to widespread applications in rechargeable batteries.

<span class="mw-page-title-main">Cadmium hydroxide</span> Chemical compound

Cadmium hydroxide is an inorganic compound with the formula Cd(OH)2. It is a white crystalline ionic compound that is a key component of nickel–cadmium battery.

<span class="mw-page-title-main">Gold(III) hydroxide</span> Chemical compound

Gold(III) hydroxide, gold trihydroxide, or gold hydroxide is an inorganic compound, a hydroxide of gold, with formula Au(OH)3. It is also called auric acid with formula H3AuO3. It is easily dehydrated above 140 °C to gold(III) oxide. Salts of auric acid are termed aurates.

<span class="mw-page-title-main">Praseodymium(IV) oxide</span> Chemical compound

Praseodymium(IV) oxide is an inorganic compound with chemical formula PrO2.

<span class="mw-page-title-main">Cerium(IV) hydroxide</span> Chemical compound

Cerium(IV) hydroxide, also known as ceric hydroxide, is an inorganic compound with the chemical formula Ce(OH)4. It is a yellowish powder that is insoluble in water but soluble in concentrated acids.

<span class="mw-page-title-main">Neodymium(III) hydroxide</span> Chemical compound

Neodymium(III) hydroxide is an insoluble inorganic compound with the chemical formula Nd(OH)3.

<span class="mw-page-title-main">Europium(III) hydroxide</span> Chemical compound

Europium(III) hydroxide is an inorganic compound with a chemical formula Eu(OH)3.

Yttrium(III) hydroxide is an inorganic compound and an alkali with the chemical formula Y(OH)3.

Praseodymium compounds are compounds formed by the lanthanide metal praseodymium (Pr). In these compounds, praseodymium generally exhibits the +3 oxidation state, such as PrCl3, Pr(NO3)3 and Pr(CH3COO)3. However, compounds with praseodymium in the +2 and +4 oxidation states, and unlike other lanthanides, the +5 oxidation state, are also known.

<span class="mw-page-title-main">Praseodymium(III) iodide</span> Chemical compound

Praseodymium(III) iodide is an inorganic salt, consisting of the rare-earth metal praseodymium and iodine, with the chemical formula PrI3. It forms green crystals. It is soluble in water.

Praseodymium(III) carbonate is an inorganic compound, with a chemical formula of Pr2(CO3)3. The anhydrous form is olive green, and many of its hydrates such as heptahydrate and octahydrate are known. They are all insoluble in water.

<span class="mw-page-title-main">Europium compounds</span> Compounds with at least one europium atom

Europium compounds are compounds formed by the lanthanide metal europium (Eu). In these compounds, europium generally exhibits the +3 oxidation state, such as EuCl3, Eu(NO3)3 and Eu(CH3COO)3. Compounds with europium in the +2 oxidation state are also known. The +2 ion of europium is the most stable divalent ion of lanthanide metals in aqueous solution. Many europium compounds fluoresce under ultraviolet light due to the excitation of electrons to higher energy levels. Lipophilic europium complexes often feature acetylacetonate-like ligands, e.g., Eufod.

References

  1. Yi, Xianwu. Series of Inorganic Chemistry - Vol 7 (in Chinese). Science Press. pp. 168-171. (2) Hydroxides
  2. 1 2 《无机化合物制备手册》. 朱文祥 主编. 化学工业出版社. P98~99. 【III-103】氢氧化镨(praseodymium hydroxide)
  3. John Rumble (June 18, 2018). CRC Handbook of Chemistry and Physics (99 ed.). CRC Press. pp. 5–189. ISBN   978-1138561632.