Caput mortuum (pigment)

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Ferric oxide

Caput mortuum (Latin for 'dead head', and variously spelled caput mortum or caput mortem), also known as cardinal purple, is the name given to a purple variety of hematite iron oxide pigment, used in oil paints and paper dyes. Due to the cultural significance of its deep purple colour, it was very popular for painting the robes of religious figures and important personages (e.g. art patrons), with its popularity peaking in the 18th and 19th centuries. [1] [2]

The name for this pigment may have come from the alchemical usage, since iron oxide (rust) is the useless residue ( caput mortuum ) of oxidization. It was originally a byproduct of sulfuric acid manufacture during the 17th and 18th centuries, and was possibly an early form of the copperas process used for the manufacture of Venetian red and copperas red. [3] [4]

Related Research Articles

<span class="mw-page-title-main">Hematite</span> Common iron oxide mineral

Hematite, also spelled as haematite, is a common iron oxide compound with the formula, Fe2O3 and is widely found in rocks and soils. Hematite crystals belong to the rhombohedral lattice system which is designated the alpha polymorph of Fe
2
O
3
. It has the same crystal structure as corundum (Al
2
O
3
) and ilmenite (FeTiO
3
). With this it forms a complete solid solution at temperatures above 950 °C (1,740 °F).

Sienna is an earth pigment containing iron oxide and manganese oxide. In its natural state, it is yellowish brown, and it is called raw sienna. When heated, it becomes a reddish brown, and it is called burnt sienna. It takes its name from the city-state of Siena, where it was produced during the Renaissance. Along with ochre and umber, it was one of the first pigments to be used by humans, and is found in many cave paintings. Since the Renaissance, it has been one of the brown pigments most widely used by artists.

<span class="mw-page-title-main">Violet (color)</span> Color between blue and ultraviolet on the electromagnetic spectrum

Violet is the color of light at the short wavelength end of the visible spectrum. It is one of the seven colors that Isaac Newton labeled when dividing the spectrum of visible light in 1672. Violet light has a wavelength between approximately 380 and 435 nanometers. The color's name is derived from the Viola genus of flowers.

<span class="mw-page-title-main">Purple</span> Range of colors with the hues between blue and red

Purple is a color similar in appearance to violet light. In the RYB color model historically used in the arts, purple is a secondary color created by combining red and blue pigments. In the CMYK color model used in modern printing, purple is made by combining magenta pigment with either cyan pigment, black pigment, or both. In the RGB color model used in computer and television screens, purple is created by mixing red and blue light in order to create colors that appear similar to violet light.

<span class="mw-page-title-main">Brown</span> Color

Brown is a color. It can be considered a composite color, but it is mainly a darker shade of orange. In the CMYK color model used in printing and painting, brown is usually made by combining the colors orange and black.

<span class="mw-page-title-main">Pigment</span> Colored material

A pigment is a powder used to add color or change visual appearance. Pigments are completely or nearly insoluble and chemically unreactive in water or another medium; in contrast, dyes are colored substances which are soluble or go into solution at some stage in their use. Dyes are often organic compounds whereas pigments are often inorganic. Pigments of prehistoric and historic value include ochre, charcoal, and lapis lazuli.

<span class="mw-page-title-main">Tyrian purple</span> Natural dye extracted from Murex sea snails

Tyrian purple, also known as royal purple, imperial purple, or imperial dye, is a reddish-purple natural dye. The name Tyrian refers to Tyre, Lebanon, once Phoenicia. It is secreted by several species of predatory sea snails in the family Muricidae, rock snails originally known by the name Murex. In ancient times, extracting this dye involved tens of thousands of snails and substantial labour, and as a result, the dye was highly valued. The colored compound is 6,6'-dibromoindigo.

<span class="mw-page-title-main">Iron(II) sulfate</span> Chemical compound

Iron(II) sulfate (British English: iron(II) sulphate) or ferrous sulfate denotes a range of salts with the formula FeSO4·xH2O. These compounds exist most commonly as the heptahydrate (x = 7) but several values for x are known. The hydrated form is used medically to treat or prevent iron deficiency, and also for industrial applications. Known since ancient times as copperas and as green vitriol (vitriol is an archaic name for hydrated sulfate minerals), the blue-green heptahydrate (hydrate with 7 molecules of water) is the most common form of this material. All the iron(II) sulfates dissolve in water to give the same aquo complex [Fe(H2O)6]2+, which has octahedral molecular geometry and is paramagnetic. The name copperas dates from times when the copper(II) sulfate was known as blue copperas, and perhaps in analogy, iron(II) and zinc sulfate were known respectively as green and white copperas.

<span class="mw-page-title-main">Prussian blue</span> Synthetic pigment

Prussian blue is a dark blue pigment produced by oxidation of ferrous ferrocyanide salts. It has the chemical formula FeIII
4
[FeII
(CN)
6
]
3
. Turnbull's blue is chemically identical, but is made from different reagents, and its slightly different color stems from different impurities and particle sizes.

<span class="mw-page-title-main">Iron(III) oxide</span> Chemical compound

Iron(III) oxide or ferric oxide is the inorganic compound with the formula Fe2O3. It occurs in nature as the mineral hematite, which serves as the primary source of iron for the steel industry. It is also known as red iron oxide, especially when used in pigments.

<span class="mw-page-title-main">Alizarin</span> Chemical compound and histologic stain

Alizarin is an organic compound with formula C
14
H
8
O
4
that has been used throughout history as a red dye, principally for dyeing textile fabrics. Historically it was derived from the roots of plants of the madder genus. In 1869, it became the first natural dye to be produced synthetically.

<span class="mw-page-title-main">Iron oxide</span> Class of chemical compounds composed of iron and oxygen

Iron oxides are chemical compounds composed of iron and oxygen. Several iron oxides are recognized. Often they are non-stoichiometric. Ferric oxyhydroxides are a related class of compounds, perhaps the best known of which is rust.

Carmine – also called cochineal, cochineal extract, crimson lake, or carmine lake – is a pigment of a bright-red color obtained from the aluminium complex derived from carminic acid. Specific code names for the pigment include natural red 4, C.I. 75470, or E120. Carmine is also a general term for a particularly deep-red color.

<span class="mw-page-title-main">Ochre</span> Earth pigment of characteristic colour

Ochre, iron ochre, or ocher in American English, is a natural clay earth pigment, a mixture of ferric oxide and varying amounts of clay and sand. It ranges in colour from yellow to deep orange or brown. It is also the name of the colours produced by this pigment, especially a light brownish-yellow. A variant of ochre containing a large amount of hematite, or dehydrated iron oxide, has a reddish tint known as red ochre.

<span class="mw-page-title-main">Umber</span> Earth pigment

Umber is a natural earth pigment consisting of iron oxide and manganese oxide; it has a brownish color that can vary among shades of yellow, red, and green. Umber is considered one of the oldest pigments known to humans, first seen in Ajanta Caves in 200 BC – 600 AD. Umber's advantages are its highly versatile color, warm tone, and quick drying abilities. While some sources indicate that umber's name comes from its geographic origin in Umbria, other scholars suggest that it derives from the Latin word umbra, which means "shadow". The belief that its name derives from the word for shadow is fitting, as the color helps create shadows. The color is primarily produced in Cyprus. Umber is typically mined from open pits or underground mines and ground into a fine powder that is washed to remove impurities. In the 20th century, the rise of synthetic dyes decreased the demand for natural pigments such as umber.

Venetian red is a light and warm (somewhat unsaturated) pigment that is a darker shade of red. The composition of Venetian red changed over time. Originally it consisted of natural ferric oxide (Fe2O3, partially hydrated) obtained from the red hematite. Modern versions are frequently made with synthetic red iron oxide produced via calcination of green vitriol (a.k.a. copperas) mixed with white chalk. The pigment contains up to 50% of the ferric oxide.

<span class="mw-page-title-main">Mummy brown</span> Historical pigment made with mummified remains

Mummy brown, also known as Egyptian brown or Caput Mortuum, was a rich brown bituminous pigment with good transparency, sitting between burnt umber and raw umber in tint. The pigment was made from the flesh of mummies mixed with white pitch and myrrh. Mummy brown was extremely popular from the mid-eighteenth to the nineteenth centuries. However, fresh supplies of mummies diminished, and artists were less satisfied with the pigment's permanency and finish. By 1915, demand had significantly declined. Suppliers ceased to offer it by the middle of the twentieth century.

<span class="mw-page-title-main">Glossary of dyeing terms</span>

Dyeing is the craft of imparting colors to textiles in loose fiber, yarn, cloth or garment form by treatment with a dye. Archaeologists have found evidence of textile dyeing with natural dyes dating back to the Neolithic period. In China, dyeing with plants, barks and insects has been traced back more than 5,000 years. Natural insect dyes such as Tyrian purple and kermes and plant-based dyes such as woad, indigo and madder were important elements of the economies of Asia and Europe until the discovery of man-made synthetic dyes in the mid-19th century. Synthetic dyes quickly superseded natural dyes for the large-scale commercial textile production enabled by the Industrial Revolution, but natural dyes remained in use by traditional cultures around the world.

<span class="mw-page-title-main">Red pigments</span> Materials used to make red colors in painting

Red pigments are materials, usually made from minerals, used to create the red colors in painting and other arts. The color of red and other pigments is determined by the way it absorbs certain parts of the spectrum of visible light and reflects the others. The brilliant opaque red of vermillion, for example, results because vermillion reflects the major part of red light, but absorbs the blue, green and yellow parts of white light.

References

  1. "Caput Mortuum, An Earthy Brown Made of Bodies (or Minerals!)". The Awl. Retrieved 2022-12-27.
  2. Oliveira, Luiz F. C. de; Edwards, Howell G. M.; Frost, Ray L.; Kloprogge, J. Theo; Middleton, Paul S. (2002-04-04). "Caput mortuum: spectroscopic and structural studies of an ancient pigment". Analyst. 127 (4): 536–541. Bibcode:2002Ana...127..536D. doi:10.1039/B111473P. ISSN   1364-5528. PMID   12022655.
  3. Harley, R.D. (2001). Artists' Pigments: c. 1600-1836. JG Publishing : Archetype Publications. ISBN   1-873132-91-3.
  4. Castagnotto, Elena; Locardi, Federico; Slimani, Sawssen; Peddis, Davide; Gaggero, Laura; Ferretti, Maurizio (2021-02-01). "Characterization of the Caput Mortuum purple hematite pigment and synthesis of a modern analogue". Dyes and Pigments. 185: 108881. doi:10.1016/j.dyepig.2020.108881. ISSN   0143-7208. S2CID   225140429.