Pelagic red clay

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Pelagic red clay, also known as simply red clay, brown clay or pelagic clay, is a type of pelagic sediment. [1] [2]

Pelagic sediment or pelagite is a fine-grained sediment that accumulates as the result of the settling of particles to the floor of the open ocean, far from land. These particles consist primarily of either the microscopic, calcareous or siliceous shells of phytoplankton or zooplankton; clay-size siliciclastic sediment; or some mixture of these. Trace amounts of meteoric dust and variable amounts of volcanic ash also occur within pelagic sediments. Based upon the composition of the ooze, there are three main types of pelagic sediments: siliceous oozes, calcareous oozes, and red clays.

Pelagic clay accumulates in the deepest and most remote areas of the ocean. It covers 38% of the ocean floor and accumulates more slowly than any other sediment type, at only 0.1–0.5 cm/1000 yr. [1] Containing less than 30% biogenic material, it consists of sediment that remains after the dissolution of both calcareous and siliceous biogenic particles while they settled through the water column. These sediments consist of eolian quartz, clay minerals, volcanic ash, subordinate residue of siliceous microfossils, and authigenic minerals such as zeolites, limonite and manganese oxides. The bulk of red clay consists of eolian dust. Accessory constituents found in red clay include meteorite dust, fish bones and teeth, whale ear bones, and manganese micro-nodules. [2]

Calcareous An adjective meaning mostly or partly composed of calcium carbonate

Calcareous is an adjective meaning "mostly or partly composed of calcium carbonate", in other words, containing lime or being chalky. The term is used in a wide variety of scientific disciplines.

A water column is a conceptual column of water from the surface of a sea, river or lake to the bottom sediment. Descriptively, the deep sea water column is divided into five parts—pelagic zones —from the surface to below the floor, as follows: epipelagic, from the surface to 200 meters below the surface; mesopelagic, from 200 to 1000 meters below the surface; bathypelagic, from 1000 to 4000 meters below the surface; abyssopelagic, from 4000 meters below the surface to the level sea floor; hadopelagic, depressions and crevices below the level sea floor.

Aeolian processes Processes due to wind activity

Aeolian processes, also spelled eolian or æolian, pertain to wind activity in the study of geology and weather and specifically to the wind's ability to shape the surface of the Earth. Winds may erode, transport, and deposit materials and are effective agents in regions with sparse vegetation, a lack of soil moisture and a large supply of unconsolidated sediments. Although water is a much more powerful eroding force than wind, aeolian processes are important in arid environments such as deserts.

These pelagic sediments are typically bright red to chocolate brown in color. The color results from coatings of iron oxide and manganese oxide on the sediment particles. In the absence of organic carbon, iron and manganese remain in their oxidized states and these clays remain brown after burial. When more deeply buried, brown clay may change into red clay due to the conversion of iron hydroxides to hematite. [2]

Iron oxide class of chemical compounds composed of iron and oxygen

Iron oxides are chemical compounds composed of iron and oxygen. There are sixteen known iron oxides and oxyhydroxides, the best known of which is rust, a form of iron(III) oxide.

Manganese oxide is any of a variety of manganese oxides and hydroxides. These include

Hematite oxide mineral

Hematite, also spelled as haematite, is a common iron oxide with the formula Fe2O3 and is widespread in rocks and soils. Hematite crystallizes in the rhombohedral lattice system, and it has the same crystal structure as ilmenite and corundum. Hematite and ilmenite form a complete solid solution at temperatures above 950 °C (1,740 °F).

These sediments accumulate on the ocean floor within areas characterized by little planktonic production. The clays which comprise them are transported into the deep ocean in suspension, either in the air over the oceans or in surface waters. Both wind and ocean currents transport these sediments in suspension thousands of kilometers from their terrestrial source. As they are transported, the finer clays may stay in suspension for a hundred years or more within the water column before they settle to the ocean bottom. The settling of this clay-size sediment occurs primarily by the formation of clay aggregates by flocculation and by their incorporation into fecal pellets by pelagic organisms. [2]

Plankton Organisms that live in the water column and are incapable of swimming against a current

Plankton are the diverse collection of organisms that live in large bodies of water and are unable to swim against a current. The individual organisms constituting plankton are called plankters. They provide a crucial source of food to many large aquatic organisms, such as fish and whales.

Aggregate (geology) mass of crystals or rock particles or soil particles

In the Earth sciences, aggregrate has three possible meanings.

Flocculation, in the field of chemistry, is a process in which colloids come out of suspension in the form of floc or flake, either spontaneously or due to the addition of a clarifying agent. The action differs from precipitation in that, prior to flocculation, colloids are merely suspended in a liquid and not actually dissolved in a solution. In the flocculated system, there is no formation of a cake, since all the flocs are in the suspension.

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Shale A fine-grained, clastic sedimentary rock

Shale is a fine-grained, clastic sedimentary rock, composed of mud that is a mix of flakes of clay minerals and tiny fragments of other minerals, especially quartz and calcite. Shale is characterized by breaks along thin laminae or parallel layering or bedding less than one centimeter in thickness, called fissility. It is the most common sedimentary rock.

Sedimentary rock Rock formed by the deposition and subsequent cementation of material

Sedimentary rocks are types of rock that are formed by the accumulation or deposition of small particles and subsequent cementation of mineral or organic particles on the floor of oceans or other bodies of water at the Earth's surface. Sedimentation is the collective name for processes that cause these particles to settle in place. The particles that form a sedimentary rock are called sediment, and may be composed of geological detritus (minerals) or biological detritus. Before being deposited, the geological detritus was formed by weathering and erosion from the source area, and then transported to the place of deposition by water, wind, ice, mass movement or glaciers, which are called agents of denudation. Biological detritus was formed by bodies and parts of dead aquatic organisms, as well as their fecal mass, suspended in water and slowly piling up on the floor of water bodies. Sedimentation may also occur as dissolved minerals precipitate from water solution.

Sediment Particulate solid matter that is deposited on the surface of land

Sediment is a naturally occurring material that is broken down by processes of weathering and erosion, and is subsequently transported by the action of wind, water, or ice or by the force of gravity acting on the particles. For example, sand and silt can be carried in suspension in river water and on reaching the sea bed deposited by sedimentation. If buried, they may eventually become sandstone and siltstone through lithification.

Greywacke A hard, dark sandstone with poorly sorted angular grains in a compact, clay-fine matrix

Greywacke or graywacke is a variety of sandstone generally characterized by its hardness, dark color, and poorly sorted angular grains of quartz, feldspar, and small rock fragments or lithic fragments set in a compact, clay-fine matrix. It is a texturally immature sedimentary rock generally found in Paleozoic strata. The larger grains can be sand- to gravel-sized, and matrix materials generally constitute more than 15% of the rock by volume. The term "greywacke" can be confusing, since it can refer to either the immature aspect of the rock or its fine-grained (clay) component.

Seabed The bottom of the ocean

The seabed is the bottom of the ocean.

Phosphorite non-detrital sedimentary rock which contains high amounts of phosphate bearing minerals

Phosphorite,phosphate rock or rock phosphate is a non-detrital sedimentary rock which contains high amounts of phosphate minerals. The phosphate content of phosphorite (or grade of phosphate rock) varies greatly, from 4% to 20% phosphorus pentoxide (P2O5). Marketed phosphate rock is enriched ("beneficiated") to at least 28%, often more than 30% P2O5. This occurs through washing, screening, de-liming, magnetic separation or flotation. By comparison, the average phosphorus content of sedimentary rocks is less than 0.2%. The phosphate is present as fluorapatite Ca5(PO4)3F typically in cryptocrystalline masses (grain sizes < 1 μm) referred to as collophane-sedimentary apatite deposits of uncertain origin. It is also present as hydroxyapatite Ca5(PO4)3OH or Ca10(PO4)6(OH)2, which is often dissolved from vertebrate bones and teeth, whereas fluorapatite can originate from hydrothermal veins. Other sources also include chemically dissolved phosphate minerals from igneous and metamorphic rocks. Phosphorite deposits often occur in extensive layers, which cumulatively cover tens of thousands of square kilometres of the Earth's crust.

Birnessite hydroxide mineral

Birnessite (Na0.3Ca0.1K0.1)(Mn4+,Mn3+)2O4 · 1.5 H2O is an oxide mineral of manganese along with calcium, potassium and sodium. It has a dark brown to black color with a submetallic luster. It is also very soft, with a Mohs hardness of 1.5. Birnessite is formed by precipitation in lakes, oceans and groundwater and is a major component of desert varnish and deep sea manganese nodules.

Mudrock Class of fine grained siliciclastic sedimentary rocks

Mudrocks are a class of fine grained siliciclastic sedimentary rocks. The varying types of mudrocks include: siltstone, claystone, mudstone, slate, and shale. Most of the particles of which the stone is composed are less than 0.0625 mm and are too small to study readily in the field. At first sight the rock types look quite similar; however, there are important differences in composition and nomenclature. There has been a great deal of disagreement involving the classification of mudrocks. There are a few important hurdles to classification, including:

  1. Mudrocks are the least understood, and one of the most understudied sedimentary rocks to date
  2. It is difficult to study mudrock constituents, due to their diminutive size and susceptibility to weathering on outcrops
  3. And most importantly, there is more than one classification scheme accepted by scientists

In biogeochemistry, remineralization refers to the breakdown or transformation of organic matter into its simplest inorganic forms. These transformations form a crucial link within ecosystems as they are responsible for liberating the energy stored in organic molecules and recycling matter within the system to be reused as nutrients by other organisms.

Biogenic silica

Biogenic silica (bSi), also referred to as opal, biogenic opal, or amorphous opaline silica, forms one of the most widespread biogenic minerals. For example, microscopic particles of silica called phytoliths can be found in grasses and other plants. Silica is an amorphous metal oxide formed by complex inorganic polymerization processes. This is opposed to the other major biogenic minerals, comprising carbonate and phosphate, which occur in nature as crystalline iono-covalent solids (e.g. salts) whose precipitation is dictated by solubility equilibria. Chemically, bSi is hydrated silica (SiO2·nH2O), which is essential to many plants and animals.

Clastic rock type of sedimentary rock

Clastic rocks are composed of fragments, or clasts, of pre-existing minerals and rock. A clast is a fragment of geological detritus, chunks and smaller grains of rock broken off other rocks by physical weathering. Geologists use the term clastic with reference to sedimentary rocks as well as to particles in sediment transport whether in suspension or as bed load, and in sediment deposits.

Radiolarite

Radiolarite is a siliceous, comparatively hard, fine-grained, chert-like, and homogeneous sedimentary rock that is composed predominantly of the microscopic remains of radiolarians. This term is also used for indurated radiolarian oozes and sometimes as a synonym of radiolarian earth. However, radiolarian earth is typically regarded by Earth scientists to be the unconsolidated equivalent of a radiolarite. A radiolarian chert is well-bedded, microcrystalline radiolarite that has a well-developed siliceous cement or groundmass.

Siliceous ooze

Siliceous ooze is a type of biogenic pelagic sediment located on the deep ocean floor. Siliceous oozes are the least common of the deep sea sediments, and make up approximately 15% of the ocean floor. Oozes are defined as sediments which contain at least 30% skeletal remains of pelagic microorganisms. Siliceous oozes are largely composed of the silica based skeletons of microscopic marine organisms such as diatoms and radiolarians. Other components of siliceous oozes near continental margins may include terrestrially derived silica particles and sponge spicules. Siliceous oozes are composed of skeletons made from opal silica Si(O2), as opposed to calcareous oozes, which are made from skeletons of calcium carbonate organisms (i.e. coccolithophores). Silica (Si) is a bioessential element and is efficiently recycled in the marine environment through the silica cycle. Distance from land masses, water depth and ocean fertility are all factors that affect the opal silica content in seawater and the presence of siliceous oozes.

Marine snow Shower of mostly organic detritus falling from the upper layers of the water column

In the deep ocean, marine snow is a continuous shower of mostly organic detritus falling from the upper layers of the water column. It is a significant means of exporting energy from the light-rich photic zone to the aphotic zone below which is referred to as the biological pump. Export production is the amount of organic matter produced in the ocean by primary production that is not recycled (remineralised) before it sinks into the aphotic zone. Because of the role of export production in the ocean's biological pump, it is typically measured in units of carbon .The term was first coined by the explorer William Beebe as he observed it from his bathysphere. As the origin of marine snow lies in activities within the productive photic zone, the prevalence of marine snow changes with seasonal fluctuations in photosynthetic activity and ocean currents. Marine snow can be an important food source for organisms living in the aphotic zone, particularly for organisms which live very deep in the water column.

The Southern Pacific Gyre is part of the Earth’s system of rotating ocean currents, bounded by the Equator to the north, Australia to the west, the Antarctic Circumpolar Current to the south, and South America to the east. The center of the South Pacific Gyre is the oceanic pole of inaccessibility, the site on Earth farthest from any continents and productive ocean regions and is regarded as Earth’s largest oceanic desert. The gyre, as with Earth's other four gyres, contains an area with elevated concentrations of pelagic plastics, chemical sludge, and other debris known as the South Pacific garbage patch.

Hemipelagic sediment, or hemipelagite, is a type of marine sediment that consists of clay and silt-sized grains that are terrigenous and some biogenic material derived from the landmass nearest the deposits or from organisms living in the water. Hemipelagic sediments are deposited on continental shelves and continental rises, and differ from pelagic sediment compositionally. Pelagic sediment is composed of primarily biogenic material from organisms living in the water column or on the seafloor and contains little to no terrigenous material. Terrigenous material includes minerals from the lithosphere like feldspar or quartz. Volcanism on land, wind blown sediments as well as particulates discharged from rivers can contribute to Hemipelagic deposits. These deposits can be used to qualify climatic changes and identify changes in sediment provenances.

Reverse weathering generally refers to the formation of a clay neoformation that utilizes cations and alkalinity in a process unrelated to the weathering of silicates. More specifically reverse weathering refers to the formation of authigenic clay minerals from the reaction of 1) biogenic silica with aqueous cations or cation bearing oxides or 2) cation poor precursor clays with dissolved cations or cation bearing oxides.

References

  1. 1 2 Rothwell, R.G., (2005) Deep Ocean Pelagic Oozes, Vol. 5. of Selley, Richard C., L. Robin McCocks, and Ian R. Plimer, Encyclopedia of Geology, Oxford: Elsevier Limited. ISBN   0-12-636380-3
  2. 1 2 3 4 HüNeke, H., and T. Mulder (2011) Deep-Sea Sediments. Developments in Sedimentology, vol. 63. Elsiever, New York. 849 pp. ISBN   978-0-444-53000-4
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