ISO 31-8

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ISO 31-8 is the part of international standard ISO 31 that defines names and symbols for quantities and units related to physical chemistry and molecular physics .

Contents

Quantities and units

QuantityUnitRemarks
NameSymbolDefinitionNameSymbol
relative atomic mass ArRatio of the average mass per atom of an element to 1/12 of the mass of an atom of the nuclide 12Cone1Formerly called atomic/molecular weight.
Example: Ar(Cl) = 35.453.
Both quantities depend on the nuclidic composition.
relative molecular mass MrRatio of the average mass per molecule or specified entity of a substance to 1/12 of the mass of an atom of the nuclide 12C
number of molecules or other elementary entitiesNNumber of molecules or other elementary entities in a systemone1
amount of substance n, (ν) mole molThe mole is the amount of substance of a system which contains as many elementary entities as there are atoms in 0.012 kg of 12C. When the mole is used, the elementary entities must be specified and may be atoms, molecules, ions, electrons, other particles, or specific groups of such particles. The definition applies to unbound atoms of 12C, at rest and in their ground state.
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Notes

In the tables of quantities and their units, the ISO 31-8 standard shows symbols for substances as subscripts (e.g., cB, wB, pB). It also notes that it is generally advisable to put symbols for substances and their states in parentheses on the same line, as in c(H2SO4).

Normative annexes

Annex A: Names and symbols of the chemical elements

This annex contains a list of elements by atomic number, giving the names and standard symbols of the chemical elements from atomic number 1 (hydrogen, H) to 109 (unnilennium, Une).

The list given in ISO 31-8:1992 was quoted from the 1998 IUPAC "Green Book" Quantities, Units and Symbols in Physical Chemistry and adds in some cases in parentheses the Latin name for information, where the standard symbol has no relation to the English name of the element. Since the 1992 edition of the standard was published, some elements with atomic number above 103 have been discovered and renamed.

Annex B: Symbols for chemical elements and nucleides

Symbols for chemical elements shall be written in roman (upright) type. The symbol is not followed by a full-stop.

Examples:

H He C Ca

Attached subscripts or superscripts specifying a nucleotide or molecule have the following meanings and positions:

Annex C: pH

pH is defined operationally as follows. For a solution X, first measure the electromotive force EX of the galvanic cell

reference electrode | concentrated solution of KCl | solution X | H2 | Pt

and then also measure the electromotive force ES of a galvanic cell that differs from the above one only by the replacement of the solution X of unknown pH, pH(X), by a solution S of a known standard pH, pH(S). Then obtain the pH of X as

pH(X) = pH(S) + (ESEX) F / (RT ln 10)

where

F is the Faraday constant;
R is the molar gas constant;
T is the thermodynamic temperature.

Defined this way, pH is a quantity of dimension 1, that is it has no unit. Values pH(S) for a range of standard solutions S are listed in Definitions of pH scales, standard reference values, measurement of pH, and related terminology. Pure Appl. Chem. (1985), 57, pp 531–542, where further details can be found.

pH has no fundamental meaning; its official definition is a practical one. However, in the restricted range of dilute aqueous solutions having amount-of-substance concentrations less than 0.1 mol/L, and being neither strongly alkaline nor strongly acidic (2 < pH < 12), the definition is such that

pH = −log10[c(H+) y1 / (1 mol/L)] ± 0.02

where c(H+) denotes the amount-of-substance concentration of hydrogen ion H+ and y1 denotes the activity coefficient of a typical uni-univalent electrolyte in the solution.

Related Research Articles

In chemistry, an element is a pure substance consisting only of atoms that all have the same numbers of protons in their nuclei. Unlike chemical compounds, chemical elements cannot be broken down into simpler substances by any chemical reaction. The number of protons in the nucleus is the defining property of an element, and is referred to as its atomic number – all atoms with the same atomic number are atoms of the same element. All of the baryonic matter of the universe is composed of chemical elements. When different elements undergo chemical reactions, atoms are rearranged into new compounds held together by chemical bonds. Only a minority of elements, such as silver and gold, are found uncombined as relatively pure native element minerals. Nearly all other naturally occurring elements occur in the Earth as compounds or mixtures. Air is primarily a mixture of the elements nitrogen, oxygen, and argon, though it does contain compounds including carbon dioxide and water.

A chemical formula is a way of presenting information about the chemical proportions of atoms that constitute a particular chemical compound or molecule, using chemical element symbols, numbers, and sometimes also other symbols, such as parentheses, dashes, brackets, commas and plus (+) and minus (−) signs. These are limited to a single typographic line of symbols, which may include subscripts and superscripts. A chemical formula is not a chemical name, and it contains no words. Although a chemical formula may imply certain simple chemical structures, it is not the same as a full chemical structural formula. Chemical formulae can fully specify the structure of only the simplest of molecules and chemical substances, and are generally more limited in power than chemical names and structural formulae.

Molecule Electrically neutral group of two or more atoms

A molecule is a group of two or more atoms held together by attractive forces known as chemical bonds; depending on context, the term may or may not include ions which satisfy this criterion. In quantum physics, organic chemistry, and biochemistry, the distinction from ions is dropped and molecule is often used when referring to polyatomic ions.

A physical quantity is a physical property of a material or system that can be quantified by measurement. A physical quantity can be expressed as a value, which is the algebraic multiplication of a numerical value and a unit. For example, the physical quantity mass can be quantified as n kg, where n is the numerical value and kg is the unit. A physical quantity possesses at least two characteristics in common. One is numerical magnitude and the other is the unit in which it is measured.

The mole, symbol mol, is the SI base unit of amount of substance. The quantity amount of substance is a measure of how many elementary entities of a given substance are in an object or sample. Depending on what the substance is, an elementary entity may be an atom, a molecule, an ion, an ion pair, or a subatomic particle such as an electron. For example, if beaker A contains 10 moles of water and beaker B contains 10 moles of mercury, they contain equal amounts of substance and beaker B contains exactly 1 atom of mercury for each molecule of water in beaker A, despite the 2 beakers containing different volumes and very different masses of liquid.

The dalton or unified atomic mass unit is a unit of mass widely used in physics and chemistry. It is defined as 112 of the mass of an unbound neutral atom of carbon-12 in its nuclear and electronic ground state and at rest. The atomic mass constant, denoted mu is defined identically, giving mu = m(12C)/12 = 1 Da. A unit dalton is also approximately numerically equal to the molar mass of the same expressed in grams per mole. Prior to the 2019 redefinition of the SI base units these were numerically identical by definition and are still treated as such for most purposes.

Chemical symbol Abbreviations used in chemistry

Chemical symbols are the abbreviations used in chemistry for chemical elements, functional groups and chemical compounds. Element symbols for chemical elements normally consist of one or two letters from the Latin alphabet and are written with the first letter capitalised. In Chinese, each chemical element has a dedicated character, usually created for the purpose. However, Latin symbols are also used, especially in formulas.

A mathematical symbol is a figure or a combination of figures that is used to represent a mathematical object, an action on mathematical objects, a relation between mathematical objects, or for structuring the other symbols that occur in a formula. As formulas are entirely constituted with symbols of various types, many symbols are needed for expressing all mathematics.

In chemistry, the molar mass of a chemical compound is defined as the mass of a sample of that compound divided by the amount of substance in that sample, measured in moles. The molar mass is a bulk, not molecular, property of a substance. The molar mass is an average of many instances of the compound, which often vary in mass due to the presence of isotopes. Most commonly, the molar mass is computed from the standard atomic weights and is thus a terrestrial average and a function of the relative abundance of the isotopes of the constituent atoms on Earth. The molar mass is appropriate for converting between the mass of a substance and the amount of a substance for bulk quantities.

Relative atomic mass or atomic weight is a dimensionless physical quantity defined as the ratio of the average mass of atoms of a chemical element in a given sample to the atomic mass constant. The atomic mass constant is defined as being 1/12 of the mass of a carbon-12 atom. Since both quantities in the ratio are masses, the resulting value is dimensionless; hence the value is said to be relative.

In chemistry, the standard state of a material is a reference point used to calculate its properties under different conditions. A superscript circle ° or a Plimsoll (⦵) character is used to designate a thermodynamic quantity in the standard state, such as change in enthalpy (ΔH°), change in entropy (ΔS°), or change in Gibbs free energy (ΔG°). The degree symbol has become widespread, although the Plimsoll is recommended in standards, see discussion about typesetting below.

In chemistry, the amount of substance n in a given sample of matter is defined as the quantity or number of discrete atomic-scale particles in it divided by the Avogadro constant NA. The particles or entities may be molecules, atoms, ions, electrons, or other, depending on the context, and should be specified (e.g. amount of sodium chloride nNaCl). The value of the Avogadro constant NA has been defined as 6.02214076×1023 mol−1. The mole (symbol: mol) is a unit of amount of substance in the International System of Units, defined (since 2019) by fixing the Avogadro constant at the given value. Sometimes, the amount of substance is referred to as the chemical amount.

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Subscript and superscript A character set slightly below and above the normal line of type, respectively

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