An O-ring, also known as a packing or a toric joint, is a mechanical gasket in the shape of a torus; it is a loop of elastomer with a round cross-section, designed to be seated in a groove and compressed during assembly between two or more parts, forming a seal at the interface.
The O-ring may be used in static applications or in dynamic applications where there is relative motion between the parts and the O-ring. Dynamic examples include rotating pump shafts and hydraulic cylinder pistons. Static applications of O-rings may include fluid or gas sealing applications in which: (1) the O-ring is compressed resulting in zero clearance, (2) the O-ring material is vulcanized solid such that it is impermeable to the fluid or gas, and (3) the O-ring material is resistant to degradation by the fluid or gas. [1] The wide range of potential liquids and gases that need to be sealed has necessitated the development of a wide range of O-ring materials. [2]
O-rings are one of the most common seals used in machine design because they are inexpensive, easy to make, reliable and have simple mounting requirements. They have been tested to seal up to 5,000 psi (34 MPa ) of pressure. [3] The maximum recommended pressure of an O-ring seal depends on the seal hardness, material, cross-sectional diameter, and radial clearance. [4]
O-rings can be produced by extrusion, injection molding, pressure molding or transfer molding. [5]
The first patent for the O-ring is dated May 12, 1896, as a Swedish patent. J. O. Lundberg, the inventor of the O-ring, received the patent. [6] The US patent [7] [8] for the O-ring was filed in 1937 by a then 72-year-old Danish-born machinist, Niels Christensen. [9] In his previously filed application in 1933, resulting in Patent 2115383, [10] he opens by saying, "This invention relates to new and useful improvements in hydraulic brakes and more particularly to an improved seal for the pistons of power conveying cylinders." He describes "a circular section ring ... made of solid rubber or rubber composition", and explains, "this sliding or partial rolling of the ring ... kneads or works the material of the ring to keep it alive and pliable without deleterious effects of scuffing which are caused by purely static sliding of rubber upon a surface. By this slight turning or kneading action, the life of the ring is prolonged." His application filed in 1937 says that it "is a continuation-in-part of my copending application Serial No. 704,463 for Hydraulic brakes, filed December 29, 1933, now U. S. Patent No. 2,115,383 granted April 26, 1938".
Soon after migrating to the United States in 1891, he patented an air brake system for streetcars (trams). Despite his legal efforts, the patents were passed from company to company until they ended up at Westinghouse. [9] During World War II, the US government commandeered the O-ring patent as a critical war-related item and gave the right to manufacture to other organizations. Christensen received a lump sum payment of US$75,000 for his efforts. Litigation resulted in a $100,000 payment to his heirs in 1971, 19 years after his death. [9]
O-rings are available in various metric and inch standard sizes. Sizes are specified by the inside diameter and the cross section diameter (thickness). In the US the most common standard inch sizes are per SAE AS568C specification (e.g. AS568-214). ISO 3601-1:2012 contains the most commonly used standard sizes, both inch and metric, worldwide. The UK also has standards sizes known as BS sizes, typically ranging from BS001 to BS932. Several other size specifications also exist.
Successful O-ring joint design requires a rigid mechanical mounting that applies a predictable deformation to the O-ring. This introduces a calculated mechanical stress at the O-ring contacting surfaces. As long as the pressure of the fluid being contained does not exceed the contact stress of the O-ring, leaking cannot occur. The pressure of the contained fluid transfers through the essentially incompressible O-ring material, and the contact stress rises with increasing pressure. For this reason, an O-ring can easily seal high pressure as long as it does not fail mechanically. The most common failure is extrusion through the mating parts.
The seal is designed to have a point contact between the O-ring and sealing faces. This allows a high local stress, able to contain high pressure, without exceeding the yield stress of the O-ring body. The flexible nature of O-ring materials accommodates imperfections in the mounting parts. But it is still important to maintain good surface finish of those mating parts, especially at low temperatures where the seal rubber reaches its glass transition temperature and becomes increasingly inflexible and glassy. Surface finish is also especially important in dynamic applications. A surface finish that is too rough will abrade the surface of the O-ring, and a surface that is too smooth will not allow the seal to be adequately lubricated by a fluid film.
In vacuum applications, the permeability of the material renders the point contacts unusable. Instead, higher mounting forces are used and the ring fills the whole groove. Also, round back-up rings are used to save the ring from excessive deformation. [12] [13] [14] Because the ring is subject to the ambient pressure and the partial pressure of gases only at the seal, their gradients will be steep near the seal and shallow in the bulk (opposite to the gradient of the contact stress [15] (See Vacuum flange#KF.2FQF.) High-vacuum systems below 10−9 Torr use copper or nickel O-rings. Also, vacuum systems that have to be immersed in liquid nitrogen use indium O-rings, because rubber becomes hard and brittle at low temperatures.
In some high-temperature applications, O-rings may need to be mounted in a tangentially compressed state, to compensate for the Gow-Joule effect.
O-rings come in a variety of sizes. Society of Automotive Engineers (SAE) Aerospace Standard 568 (AS568) [16] specifies the inside diameters, cross-sections, tolerances, and size identification codes (dash numbers) for O-rings used in sealing applications and for straight thread tube fitting boss gaskets. British Standard (BS) which are imperial sizes or metric sizes. Typical dimensions of an O-ring are internal dimension (id), outer dimension (od) and thickness / cross section (cs)
Metric O-rings are usually defined by the internal dimension x the cross section. Typical part number for a metric O-ring - ID x CS [material & shore hardness] 2x1N70 = defines this O-ring as 2mm id with 1mm cross section made from Nitrile rubber which is 70Sh. BS O-rings are defined by a standard reference.
The World's Largest O-ring was produced in a successful Guinness World Record attempt by Trelleborg Sealing Solutions Tewkesbury partnered with a group of 20 students from Tewkesbury School. The O-ring once finished and placed around the Medieval Tewkesbury Abbey had a 364 m (1,194 ft) circumference, an approximately 116 m (381 ft) inner diameter, and a cross section of 7.2 mm (0.28 in). [17]
O-ring selection is based on chemical compatibility, application temperature, sealing pressure, lubrication requirements, durometer, size and cost. [18]
Synthetic rubbers - Thermosets:
Although the O-ring was originally so named because of its circular cross section, there are now variations in cross-section design. The shape can have different profiles, such as an x-shaped profile, commonly called the X-ring, Q-ring, or by the trademarked name Quad Ring. When squeezed upon installation, they seal with 4 contact surfaces—2 small contact surfaces on the top and bottom. [21] This contrasts with the standard O-ring's comparatively larger single contact surfaces top and bottom. X-rings are most commonly used in reciprocating applications, where they provide reduced running and breakout friction and reduced risk of spiraling when compared to O-rings.
There are also rings with a square profile, commonly called square-cuts, lathe cuts, tabular cut or Square rings. When O-rings were selling at a premium because of the novelty, lack of efficient manufacturing processes and high labor content, Square rings were introduced as an economical substitution for O-rings. The square ring is typically manufactured by molding an elastomer sleeve which is then lathe-cut. This style of seal is sometimes less expensive to manufacture with certain materials and molding technologies (compression molding, transfer molding, injection molding), especially in low volumes. The physical sealing performance of square rings in static applications is superior to that of O-rings, however in dynamic applications it is inferior to that of O-rings. Square rings are usually used only in dynamic applications as energizers in cap seal assemblies. Square rings can also be more difficult to install than O-rings.
Similar devices with a non-round cross-sections are called seals, packings or gaskets. See also washers. [22]
Automotive cylinder heads are typically sealed by flat gaskets faced with copper.
Knife edges pressed into copper gaskets are used for high vacuum.
Elastomers or soft metals that solidify in place are used as seals.
O-ring materials may be subjected to high or low temperatures, chemical attack, vibration, abrasion, and movement. Elastomers are selected according to the situation.
There are O-ring materials which can tolerate temperatures as low as −330 °F (−200 °C) or as high as 480 °F (250 °C). At the low end, nearly all engineering materials become rigid and fail to seal; at the high end, the materials often burn or decompose. Chemical attack can degrade the material, start brittle cracks or cause it to swell. For example, NBR seals can crack when exposed to ozone gas at very low concentrations, unless protected. Swelling by contact with a low viscosity fluid causes an increase in dimensions, and also lowers the tensile strength of the rubber. Other failures can be caused by using the wrong size of ring for a specific recess, which may cause extrusion of the rubber.
Elastomers are sensitive to ionizing radiation. In typical applications, O-rings are well-protected from less-penetrating radiation such as ultraviolet and soft X-rays, but more-penetrating radiation such as neutrons may cause rapid deterioration. In such environments, soft metal seals are used.
There are a few common reasons for O-ring failure:
The failure of an O-ring seal was determined to be the cause of the Space Shuttle Challenger disaster on January 28, 1986. A crucial factor was cold weather prior to the launch. This was famously demonstrated on television by Caltech physics professor Richard Feynman, when he placed a small O-ring into ice-cold water, and subsequently showed its loss of flexibility before an investigative committee.
The material of the failed O-ring was FKM, which was specified by the shuttle motor contractor, Morton-Thiokol. When an O-ring is cooled below its glass transition temperature Tg, it loses its elasticity and becomes brittle. More importantly, when an O-ring is cooled near (but not beyond) its Tg, the cold O-ring, once compressed, will take longer than normal to return to its original shape. O-rings (and all other seals) work by producing positive pressure against a surface, thereby preventing leaks. On the night before the launch, exceedingly low air temperatures were recorded. Due to this, NASA technicians performed an inspection; the ambient temperature was within launch parameters, and the launch sequence was allowed to proceed. However, the temperature of the rubber O-rings remained significantly lower than that of the surrounding air. During his investigation of the launch footage, Feynman observed a small out-gassing event from the Solid Rocket Booster at the joint between two segments in the moments immediately preceding the disaster. This was blamed on a failed O-ring seal. The escaping high-temperature gas impinged upon the external tank, and the entire vehicle was destroyed as a result.
Since the accident, rubber production companies have enacted changes. Many O-rings now come with batch and cure date coding, as is done in medicine production, to precisely track and control distribution. For aerospace and military applications, O-rings are usually individually packaged and labeled with the material, cure date, and batch information. O-rings can, if needed, be recalled off the shelf. [23] Furthermore, O-rings and other seals are routinely batch-tested for quality control by the manufacturers, and often undergo quality assurance testing several more times by the distributor and ultimate end-users.
As for the boosters themselves, NASA and Morton-Thiokol redesigned them with a new joint design, which now incorporated three O-rings instead of two, with the joints themselves having onboard heaters that can be turned on when temperatures drop below 50 °F (10 °C). No O-ring issues have occurred since Challenger, and they did not play a role in the Space Shuttle Columbia disaster of 2003.
Polyurethane refers to a class of polymers composed of organic units joined by carbamate (urethane) links. In contrast to other common polymers such as polyethylene and polystyrene, polyurethane is produced from a wide range of starting materials. This chemical variety produces polyurethanes with different chemical structures leading to many different applications. These include rigid and flexible foams, and coatings, adhesives, electrical potting compounds, and fibers such as spandex and polyurethane laminate (PUL). Foams are the largest application accounting for 67% of all polyurethane produced in 2016.
In organosilicon and polymer chemistry, a silicone or polysiloxane is a polymer composed of repeating units of siloxane. They are typically colorless oils or rubber-like substances. Silicones are used in sealants, adhesives, lubricants, medicine, cooking utensils, thermal insulation, and electrical insulation. Some common forms include silicone oil, grease, rubber, resin, and caulk.
A peristaltic pump, also commonly known as a roller pump, is a type of positive displacement pump used for pumping a variety of fluids. The fluid is contained in a flexible tube fitted inside a circular pump casing. Most peristaltic pumps work through rotary motion, though linear peristaltic pumps have also been made. The rotor has a number of "wipers" or "rollers" attached to its external circumference, which compress the flexible tube as they rotate by. The part of the tube under compression is closed, forcing the fluid to move through the tube. Additionally, as the tube opens to its natural state after the rollers pass, more fluid is drawn into the tube. This process is called peristalsis and is used in many biological systems such as the gastrointestinal tract. Typically, there will be two or more rollers compressing the tube, trapping a body of fluid between them. The body of fluid is transported through the tube, toward the pump outlet. Peristaltic pumps may run continuously, or they may be indexed through partial revolutions to deliver smaller amounts of fluid.
A gasket is a mechanical seal which fills the space between two or more mating surfaces, generally to prevent leakage from or into the joined objects while under compression. It is a deformable material that is used to create a static seal and maintain that seal under various operating conditions in a mechanical assembly.
An elastomer is a polymer with viscoelasticity and with weak intermolecular forces, generally low Young's modulus (E) and high failure strain compared with other materials. The term, a portmanteau of elastic polymer, is often used interchangeably with rubber, although the latter is preferred when referring to vulcanisates. Each of the monomers which link to form the polymer is usually a compound of several elements among carbon, hydrogen, oxygen and silicon. Elastomers are amorphous polymers maintained above their glass transition temperature, so that considerable molecular reconformation is feasible without breaking of covalent bonds. At ambient temperatures, such rubbers are thus relatively compliant and deformable. Their primary uses are for seals, adhesives and molded flexible parts.
EPDM rubber is a type of synthetic rubber that is used in many applications.
A hermetic seal is any type of sealing that makes a given object airtight. The term originally applied to airtight glass containers, but as technology advanced it applied to a larger category of materials, including rubber and plastics. Hermetic seals are essential to the correct and safe functionality of many electronic and healthcare products. Used technically, it is stated in conjunction with a specific test method and conditions of use. Colloquially, the exact requirements of such a seal varies with the application.
A synthetic rubber is an artificial elastomer. They are polymers synthesized from petroleum byproducts. About 32 million metric tons of rubbers are produced annually in the United States, and of that amount two thirds are synthetic. Synthetic rubber, just like natural rubber, has many uses in the automotive industry for tires, door and window profiles, seals such as O-rings and gaskets, hoses, belts, matting, and flooring. They offer a different range of physical and chemical properties which can improve the reliability of a given product or application. Synthetic rubbers are superior to natural rubbers in two major respects: thermal stability, and resistance to oils and related compounds. They are more resistant to oxidizing agents, such as oxygen and ozone which can reduce the life of products like tires.
Silicone grease, sometimes called dielectric grease, is a waterproof grease made by combining a silicone oil with a thickener. Most commonly, the silicone oil is polydimethylsiloxane (PDMS) and the thickener is amorphous fumed silica. Using this formulation, silicone grease is a translucent white viscous paste, with exact properties dependent on the type and proportion of the components. More specialized silicone greases are made from fluorinated silicones or, for low-temperature applications, PDMS containing some phenyl substituents in place of methyl groups. Other thickeners may be used, including stearates and powdered polytetrafluorethylene (PTFE). Greases formulated from silicone oils with silica thickener are sometimes referred to as silicone paste to distinguish them from silicone grease made with silicone oil and a soap thickener.
Nitrile rubber, also known as nitrile butadiene rubber, NBR, Buna-N, and acrylonitrile butadiene rubber, is a synthetic rubber derived from acrylonitrile (ACN) and butadiene. Trade names include Perbunan, Nipol, Krynac and Europrene. This rubber is unusual in being resistant to oil, fuel, and other chemicals.
Silicone rubber is an elastomer composed of silicone—itself a polymer—containing silicon together with carbon, hydrogen, and oxygen. Silicone rubbers are widely used in industry, and there are multiple formulations. Silicone rubbers are often one- or two-part polymers, and may contain fillers to improve properties or reduce cost. Silicone rubber is generally non-reactive, stable, and resistant to extreme environments and temperatures from −55 to 300 °C while still maintaining its useful properties. Due to these properties and its ease of manufacturing and shaping, silicone rubber can be found in a wide variety of products, including voltage line insulators; automotive applications; cooking, baking, and food storage products; apparel such as undergarments, sportswear, and footwear; electronics; medical devices and implants; and in home repair and hardware, in products such as silicone sealants.
Thermoplastic elastomers (TPE), sometimes referred to as thermoplastic rubbers (TPR), are a class of copolymers or a physical mix of polymers that consist of materials with both thermoplastic and elastomeric properties.
FKM is a family of fluorocarbon-based fluoroelastomer materials defined by ASTM International standard D1418, and ISO standard 1629. It is commonly called fluorine rubber or fluoro-rubber. FKM is an abbreviation of Fluorine Kautschuk Material. All FKMs contain vinylidene fluoride as the common monomer, to which different other monomers are added for specific types and functionalities, fitting the desired application.
Sealant is a substance used to block the passage of fluids through openings in materials, a type of mechanical seal. In building construction sealant is sometimes synonymous with caulk and also serve the purposes of blocking dust, sound and heat transmission. Sealants may be weak or strong, flexible or rigid, permanent or temporary. Sealants are not adhesives but some have adhesive qualities and are called adhesive-sealants or structural sealants.
Injection molding of liquid silicone rubber (LSR) is a process to produce pliable, durable parts in high volume.
Phenyl ether polymers are a class of polymers that contain a phenoxy or a thiophenoxy group as the repeating group in ether linkages. Commercial phenyl ether polymers belong to two chemical classes: polyphenyl ethers (PPEs) and polyphenylene oxides (PPOs). The phenoxy groups in the former class of polymers do not contain any substituents whereas those in the latter class contain 2 to 4 alkyl groups on the phenyl ring. The structure of an oxygen-containing PPE is provided in Figure 1 and that of a 2, 6-xylenol derived PPO is shown in Figure 2. Either class can have the oxygen atoms attached at various positions around the rings.
Thermoplastic vulcanizates (TPV) are dynamically vulcanized alloys consisting mostly of fully cured EPDM rubber particles encapsulated in a polypropylene (PP) matrix. They are part of the thermoplastic elastomer (TPE) family of polymers but are closest in elastomeric properties to EPDM thermoset rubber, combining the characteristics of vulcanized rubber with the processing properties of thermoplastics. There are almost 100 grades in the S portfolio that are used globally in the automotive, household appliance, electrical, construction, and healthcare markets. The name Santoprene was trademarked in 1977 by Monsanto, and the trademark is now owned by Celanese. Similar material is available from Elastron and others.
FFKMs are perfluoroelastomeric compounds containing an even higher amount of fluorine than FKM fluoroelastomers.
Materials for use in vacuum are materials that show very low rates of outgassing in vacuum and, where applicable, are tolerant to bake-out temperatures. The requirements grow increasingly stringent with the desired degree of vacuum to be achieved in the vacuum chamber. The materials can produce gas by several mechanisms. Molecules of gases and water can be adsorbed on the material surface. Materials may sublimate in vacuum. Or the gases can be released from porous materials or from cracks and crevices. Traces of lubricants, residues from machining, can be present on the surfaces. A specific risk is outgassing of solvents absorbed in plastics after cleaning.
A flexible impeller pump is a positive-displacement pump that, by deforming impeller vanes, draws the liquid into the pump housing and moves it to the discharge port with a constant flow rate. The flexibility of the vanes enables a tight seal to the internal housing, making the pump self-priming, while also permitting bi-directional operation. The output from these pumps tends to be smooth or gentle when compared to the operation of a reciprocating pump. In 1938, Arthur M. Briggs filed a patent for this type of pump.