Erbium(III) oxide

Last updated
Erbium oxide [1]
Tl2O3structure.jpg
ErOPulver.jpg
Names
Other names
Erbium oxide, erbia
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.031.847 OOjs UI icon edit-ltr-progressive.svg
EC Number
  • 235-045-7
PubChem CID
  • InChI=1S/2Er.3O Yes check.svgY
    Key: VQCBHWLJZDBHOS-UHFFFAOYSA-N Yes check.svgY
  • InChI=1/2Er.3O/rEr2O3/c3-1-5-2-4
    Key: VQCBHWLJZDBHOS-YMHUIQTEAQ
  • O=[Er]O[Er]=O
  • ionic:[O-2].[Er+3].[O-2].[Er+3].[O-2]
Properties
Er2O3
Molar mass 382.56 g/mol
Appearancepink crystals
Density 8.64 g/cm3
Melting point 2,344 °C (4,251 °F; 2,617 K)
Boiling point 3,290 °C (5,950 °F; 3,560 K)
insoluble in water
+73,920·10−6 cm3/mol
Structure
Cubic, cI80
Ia-3, No. 206
Thermochemistry
108.5 J·mol−1·K−1
Std molar
entropy
(S298)
155.6 J·mol−1·K−1
−1897.9 kJ·mol−1
Related compounds
Other anions
Erbium(III) chloride
Other cations
Holmium(III) oxide, Thulium(III) oxide
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Yes check.svgY  verify  (what is  Yes check.svgYX mark.svgN ?)

Erbium(III) oxide is the inorganic compound with the formula Er2O3. It is a pink paramagnetic solid. It finds uses in various optical materials. [2]

Contents

Structure

Erbium(III) oxide has a cubic structure resembling the bixbyite motif. The Er3+ centers are octahedral. [2]

Reactions

Erbium oxide is produced by burning erbium metal. [3] Erbium oxide is insoluble in water but soluble in mineral acids. Er2O3 does not readily absorb moisture and carbon dioxide from the atmosphere. It can react with acids to form the corresponding erbium(III) salts. For example, with hydrochloric acid, the oxide follows the following idealized reaction leading to erbium chloride:

Er2O3 + 6 HCl → 2 ErCl3 + 3 H2O

In practice, such simple acid-base reactions are accompanied by hydration:

ErCl3 + 9 H2O → [Er(H2O)9]Cl3

Properties

One interesting property of erbium oxides is their ability to up convert photons. Photon upconversion takes place when infrared or visible radiation, low energy light, is converted to ultraviolet or violet radiation higher energy light via multiple transfer or absorption of energy. [4] Erbium oxide nanoparticles also possess photoluminescence properties. Erbium oxide nanoparticles can be formed by applying ultrasound (20 kHz, 29 W·cm−2) in the presence of multiwall carbon nanotubes. The erbium oxide nanoparticles that have been produced using ultrasound are erbium carboxioxide, hexagonal and spherical geometry erbium oxide. Each ultrasonically formed erbium oxide exhibits photoluminescence in the visible region of the electromagnetic spectrum under excitation of wavelength 379 nm in water. Hexagonal erbium oxide photoluminescence is long-lived and allows higher energy transitions (4S3/24I15/2). Spherical erbium oxide does not undergo 4S3/24I15/2 energy transitions. [5]

Uses

The applications of Er2O3 are varied due to their electrical, optical and photoluminescence properties. Nanoscale materials doped with Er3+ are of much interest because they have special particle-size-dependent optical and electrical properties. [6] Erbium oxide doped nanoparticle materials can be dispersed in glass or plastic for display purposes, such as display monitors. The spectroscopy of Er3+ electronic transitions in host crystals lattices[ clarification needed ][ words missing? ] of nanoparticles combined with ultrasonically formed geometries in aqueous solution of carbon nanotubes is of great interest for synthesis of photoluminescence nanoparticles in "green" chemistry. [5]

Erbium oxide is widely used in interferometers that require high-power lasers. [7] These interferometers often employ erbium-doped fiber amplifiers (EDFAs) to enhance the power of the laser beams. [8] EDFAs, which utilize erbium ions, provide low noise and high gain, making them ideal for long-distance signal transmission and high-resolution measurements in interferometry. [9]

Erbium oxide is among the most important rare earth metals used in biomedicine. [10] The photoluminescence property of erbium oxide nanoparticles on carbon nanotubes makes them useful in biomedical applications. For example, erbium oxide nanoparticles can be surface modified for distribution into aqueous and non-aqueous media for bioimaging. [6] Erbium oxides are also used as gate dielectrics in semiconductor devices since it has a high dielectric constant (10–14) and a large band gap. Erbium is sometimes used as a coloring for glasses, [1] and erbium oxide can also be used as a burnable neutron poison for nuclear fuel.

History

Impure erbium(III) oxide was isolated by Carl Gustaf Mosander in 1843, and first obtained in pure form in 1905 by Georges Urbain and Charles James. [11]

Related Research Articles

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Erbium is a chemical element; it has symbol Er and atomic number 68. A silvery-white solid metal when artificially isolated, natural erbium is always found in chemical combination with other elements. It is a lanthanide, a rare-earth element, originally found in the gadolinite mine in Ytterby, Sweden, which is the source of the element's name.

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Neodymium(III) chloride or neodymium trichloride is a chemical compound of neodymium and chlorine with the formula NdCl3. This anhydrous compound is a mauve-colored solid that rapidly absorbs water on exposure to air to form a purple-colored hexahydrate, NdCl3·6H2O. Neodymium(III) chloride is produced from minerals monazite and bastnäsite using a complex multistage extraction process. The chloride has several important applications as an intermediate chemical for production of neodymium metal and neodymium-based lasers and optical fibers. Other applications include a catalyst in organic synthesis and in decomposition of waste water contamination, corrosion protection of aluminium and its alloys, and fluorescent labeling of organic molecules (DNA).

<span class="mw-page-title-main">Erbium(III) chloride</span> Chemical compound

Erbium(III) chloride is a violet solid with the formula ErCl3. It is used in the preparation of erbium metal.

<span class="mw-page-title-main">Holmium(III) oxide</span> Chemical compound

Holmium(III) oxide, or holmium oxide is a chemical compound of the rare-earth element holmium and oxygen with the formula Ho2O3. Together with dysprosium(III) oxide (Dy2O3), holmium oxide is one of the most powerfully paramagnetic substances known. The oxide, also called holmia, occurs as a component of the related erbium oxide mineral called erbia. Typically, the oxides of the trivalent lanthanides coexist in nature, and separation of these components requires specialized methods. Holmium oxide is used in making specialty colored glasses. Glass containing holmium oxide and holmium oxide solutions have a series of sharp optical absorption peaks in the visible spectral range. They are therefore traditionally used as a convenient calibration standard for optical spectrophotometers.

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Lanthanum(III) oxide, also known as lanthana, chemical formula La2O3, is an inorganic compound containing the rare earth element lanthanum and oxygen. It is used in some ferroelectric materials, as a component of optical materials, and is a feedstock for certain catalysts, among other uses.

<span class="mw-page-title-main">Tantalum pentoxide</span> Chemical compound

Tantalum pentoxide, also known as tantalum(V) oxide, is the inorganic compound with the formula Ta
2
O
5
. It is a white solid that is insoluble in all solvents but is attacked by strong bases and hydrofluoric acid. Ta
2
O
5
is an inert material with a high refractive index and low absorption, which makes it useful for coatings. It is also extensively used in the production of capacitors, due to its high dielectric constant.

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Gadolinium(III) oxide (archaically gadolinia) is an inorganic compound with the formula Gd2O3. It is one of the most commonly available forms of the rare-earth element gadolinium, derivatives, of which are potential contrast agents for magnetic resonance imaging.

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An erbium-doped waveguide amplifier is a type of an optical amplifier enhanced with erbium. It is a close relative of an EDFA, erbium-doped fiber amplifier, and in fact EDWA's basic operating principles are identical to those of the EDFA. Both of them can be used to amplify infrared light at wavelengths in optical communication bands between 1500 and 1600 nm. However, whereas an EDFA is made using a free-standing fiber, an EDWA is typically produced on a planar substrate, sometimes in ways that are very similar to the methods used in electronic integrated circuit manufacturing. Therefore, the main advantage of EDWAs over EDFAs lies in their potential to be intimately integrated with other optical components on the same planar substrate and thus making EDFAs unnecessary.

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Erbium compounds are compounds containing the element erbium (Er). These compounds are usually dominated by erbium in the +3 oxidation state, although the +2, +1 and 0 oxidation states have also been reported.

References

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  7. Li, Chunfei; Wang, Fei (2007). "Optimization of all-optical EDFA-based Sagnac-interferometer switch". Optics Express. 15 (21): 14234–14243. Bibcode:2007OExpr..1514234W. doi: 10.1364/OE.15.014234 . PMID   19550698.
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