Vanadium(III) oxide

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Vanadium(III) oxide
Kristallstruktur Aluminiumoxid.png
Oksid vanadiia(III).jpg
Names
Other names
Vanadium sesquioxide, Vanadic oxide
Identifiers
3D model (JSmol)
ECHA InfoCard 100.013.847 OOjs UI icon edit-ltr-progressive.svg
PubChem CID
RTECS number
  • YW3050000
UNII
  • [O-2].[V+3].[O-2].[V+3].[O-2]
Properties
V2O3
Molar mass 149.881 g/mol
AppearanceBlack powder
Density 4.87 g/cm3
Melting point 1,940 °C (3,520 °F; 2,210 K)
Solubility in other solventsInsoluble
+1976.0·10−6 cm3/mol
Structure [1]
Corundum, hR30
R3c (No. 167)
a = 547 pm
α = 53.74°, β = 90°, γ = 90°
Thermochemistry
Std molar
entropy
(S298)
98.07 J/mol·K [2]
-1218.800 kJ/mol [2]
-1139.052 kJ/mol [2]
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Vanadium(III) oxide is the inorganic compound with the formula V2O3. It is a black solid prepared by reduction of V2O5 with hydrogen or carbon monoxide. [3] [4] It is a basic oxide dissolving in acids to give solutions of vanadium (III) complexes. [4] V2O3 has the corundum structure. [4] It is antiferromagnetic with a critical temperature of 160 K. [5] At this temperature there is an abrupt change in conductivity from metallic to insulating. [5] This also distorts the crystal structure to a monoclinic space group: C2/c. [1]

Upon exposure to air it gradually converts into indigo-blue V2O4. [5]

In nature it occurs as the rare mineral karelianite. [6]

Related Research Articles

<span class="mw-page-title-main">Inorganic chemistry</span> Field of chemistry

Inorganic chemistry deals with synthesis and behavior of inorganic and organometallic compounds. This field covers chemical compounds that are not carbon-based, which are the subjects of organic chemistry. The distinction between the two disciplines is far from absolute, as there is much overlap in the subdiscipline of organometallic chemistry. It has applications in every aspect of the chemical industry, including catalysis, materials science, pigments, surfactants, coatings, medications, fuels, and agriculture.

<span class="mw-page-title-main">Vanadium</span> Chemical element with atomic number 23 (V)

Vanadium is a chemical element; it has symbol V and atomic number 23. It is a hard, silvery-grey, malleable transition metal. The elemental metal is rarely found in nature, but once isolated artificially, the formation of an oxide layer (passivation) somewhat stabilizes the free metal against further oxidation.

<span class="mw-page-title-main">Iron(III) oxide</span> Chemical compound

Iron(III) oxide or ferric oxide is the inorganic compound with the formula Fe2O3. It occurs in nature as the mineral hematite, which serves as the primary source of iron for the steel industry. It is also known as red iron oxide, especially when used in pigments.

<span class="mw-page-title-main">Group 5 element</span> Group of elements in the periodic table

Group 5 is a group of elements in the periodic table. Group 5 contains vanadium (V), niobium (Nb), tantalum (Ta) and dubnium (Db). This group lies in the d-block of the periodic table. This group is sometimes called the vanadium group or vanadium family after its lightest member; however, the group itself has not acquired a trivial name because it belongs to the broader grouping of the transition metals.

<span class="mw-page-title-main">Vanadium(V) oxide</span> Precursor to vanadium alloys and industrial catalyst

Vanadium(V) oxide (vanadia) is the inorganic compound with the formula V2O5. Commonly known as vanadium pentoxide, it is a dark yellow solid, although when freshly precipitated from aqueous solution, its colour is deep orange. Because of its high oxidation state, it is both an amphoteric oxide and an oxidizing agent. From the industrial perspective, it is the most important compound of vanadium, being the principal precursor to alloys of vanadium and is a widely used industrial catalyst.

<span class="mw-page-title-main">Antimony trioxide</span> Chemical compound

Antimony(III) oxide is the inorganic compound with the formula Sb2O3. It is the most important commercial compound of antimony. It is found in nature as the minerals valentinite and senarmontite. Like most polymeric oxides, Sb2O3 dissolves in aqueous solutions with hydrolysis. A mixed arsenic-antimony oxide occurs in nature as the very rare mineral stibioclaudetite.

<span class="mw-page-title-main">Ytterbium(III) oxide</span> Chemical compound

Ytterbium(III) oxide is the chemical compound with the formula Yb2O3. It is one of the more commonly encountered compounds of ytterbium. It occurs naturally in trace amounts in the mineral gadolinite. It was first isolated from this in 1878 by Jean Charles Galissard de Marignac.

<span class="mw-page-title-main">Chromium(III) oxide</span> Chemical compound

Chromium(III) oxide is an inorganic compound with the formula Cr
2
O
3
. It is one of the principal oxides of chromium and is used as a pigment. In nature, it occurs as the rare mineral eskolaite.

<span class="mw-page-title-main">Vanadium oxytrichloride</span> Chemical compound

Vanadium oxytrichloride is the inorganic compound with the formula VOCl3. This yellow distillable liquid hydrolyzes readily in air. It is an oxidizing agent. It is used as a reagent in organic synthesis. Samples often appear red or orange owing to an impurity of vanadium tetrachloride.

<span class="mw-page-title-main">Vanadium(III) chloride</span> Chemical compound

Vanadium(III) chloride describes the inorganic compound with the formula VCl3 and its hydrates. It forms a purple anhydrous form and a green hexahydrate [VCl2(H2O)4]Cl·2H2O. These hygroscopic salts are common precursors to other vanadium(III) complexes and is used as a mild reducing agent.

<span class="mw-page-title-main">Vanadium(II) oxide</span> Chemical compound

Vanadium(II) oxide is the inorganic compound with the idealized formula VO. It is one of the several binary vanadium oxides. It adopts a distorted NaCl structure and contains weak V−V metal to metal bonds. VO is a semiconductor owing to delocalisation of electrons in the t2g orbitals. VO is a non-stoichiometric compound, its composition varying from VO0.8 to VO1.3.

<span class="mw-page-title-main">Vanadium(III) fluoride</span> Chemical compound

Vanadium(III) fluoride is the chemical compound with the formula VF3. This yellow-green, refractory solid is obtained in a two-step procedure from V2O3. Similar to other transition-metal fluorides (such as MnF2), it exhibits magnetic ordering at low temperatures (e.g. V2F6.4H2O orders below 12 K).

<span class="mw-page-title-main">Vanadium compounds</span>

Vanadium compounds are compounds formed by the element vanadium (V). The chemistry of vanadium is noteworthy for the accessibility of the four adjacent oxidation states 2–5, whereas the chemistry of the other group 5 elements, niobium and tantalum, are somewhat more limited to the +5 oxidation state. In aqueous solution, vanadium forms metal aquo complexes of which the colours are lilac [V(H2O)6]2+, green [V(H2O)6]3+, blue [VO(H2O)5]2+, yellow-orange oxides [VO(H2O)5]3+, the formula for which depends on pH. Vanadium(II) compounds are reducing agents, and vanadium(V) compounds are oxidizing agents. Vanadium(IV) compounds often exist as vanadyl derivatives, which contain the VO2+ center.

There are three sets of Indium halides, the trihalides, the monohalides, and several intermediate halides. In the monohalides the oxidation state of indium is +1 and their proper names are indium(I) fluoride, indium(I) chloride, indium(I) bromide and indium(I) iodide.

Vanadium oxide mainly refers to:

<span class="mw-page-title-main">Cobalt(II) sulfate</span> Inorganic compound

Cobalt(II) sulfate is any of the inorganic compounds with the formula CoSO4(H2O)x. Usually cobalt sulfate refers to the hexa- or heptahydrates CoSO4.6H2O or CoSO4.7H2O, respectively. The heptahydrate is a red solid that is soluble in water and methanol. Since cobalt(II) has an odd number of electrons, its salts are paramagnetic.

<span class="mw-page-title-main">Potassium azide</span> Chemical compound

Potassium azide is the inorganic compound having the formula KN3. It is a white, water-soluble salt. It is used as a reagent in the laboratory.

<span class="mw-page-title-main">Nitrosyl azide</span> Chemical compound

Nitrosyl azide is an inorganic compound of nitrogen and oxygen with the chemical formula N3−N=O. It is a highly labile nitrogen oxide with the empirical formula N4O.

<span class="mw-page-title-main">Karelianite</span>

Karelianite is an rare mineral, a natural form of vanadium(III) oxide, V2O3. In terms of chemistry it is vanadium-analogue of hematite, corundum, eskolaite, tistarite, bixbyite, avicennite, and yttriaite-(Y). The name comes from Karelia, a region on the Finnish-Russian border. It may be associated with magnesium-rich rocks.

<span class="mw-page-title-main">Indium(III) iodide</span> Chemical compound

Indium(III) iodide or indium triiodide is a chemical compound of indium and iodine with the formula InI3.

References

  1. 1 2 Shvets, Petr; Dikaya, Olga; Maksimova, Ksenia; Goikhman, Alexander (2019-05-15). "A review of Raman spectroscopy of vanadium oxides". Journal of Raman Spectroscopy. 50 (8). Wiley: 1226–1244. Bibcode:2019JRSp...50.1226S. doi:10.1002/jrs.5616. ISSN   0377-0486. S2CID   182370875.
  2. 1 2 3 R. Robie, B. Hemingway, and J. Fisher, “Thermodynamic Properties of Minerals and Related Substances at 298.15K and 1bar Pressure and at Higher Temperatures,” US Geol. Surv., vol. 1452, 1978.
  3. Handbook of Preparative Inorganic Chemistry, 2nd Ed. Edited by G. Brauer, Academic Press, 1963, NY. Vol. 1. p. 1267.
  4. 1 2 3 Greenwood, Norman N.; Earnshaw, Alan (1997). Chemistry of the Elements (2nd ed.). Butterworth-Heinemann. ISBN   978-0-08-037941-8.
  5. 1 2 3 E.M. Page, S.A.Wass (1994),Vanadium:Inorganic and Coordination chemistry, Encyclopedia of Inorganic Chemistry, John Wiley & Sons, ISBN   0-471-93620-0
  6. "Karelianite". www.mindat.org.