Isotopes of phosphorus

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Isotopes of phosphorus  (15P)
Main isotopes Decay
abun­dance half-life (t1/2) mode pro­duct
31P100% stable
32P trace 14.269 d β− 32S
33Ptrace25.35 dβ− 33S
Standard atomic weight Ar°(P)

Although phosphorus (15P) has 22 isotopes from 26P to 47P. Only 31P is stable, thus phosphorus is considered a monoisotopic element. The longest-lived radioactive isotopes are 33P with a half-life of 25.34 days and 32P with a half-life of 14.268 days. [3] [4] All others have half-lives of under 2.5 minutes, most under a second. The least stable known isotope is 47P, with a half-life of 2 milliseconds.

Contents

List of isotopes


Nuclide
[n 1] 		Z N Isotopic mass (Da) [5]
[n 2] [n 3] 		Half-life [6]
[n 4] 		Decay
mode [6]
[n 5] 		Daughter
isotope
[n 6] 		Spin and
parity [6]
[n 7] [n 4] 		Isotopic
abundance
Excitation energy
26P151126.01178(21)#43.6(3) ms β+ (62.9%)26Si(3)+
β+, p (35.1%)25Al
β+, 2p (1.99%)24Mg
26mP164.4(1) keV115(8) ns IT 26P(1+)
27P151226.9992925(97)260(80) msβ+ (99.93%)27Si1/2+
β+, p (0.07%)26Al
28P151327.9923265(12)270.3(5) msβ+28Si3+
β+, p (.0013%)27Al
β+, α (8.6×10−4%)24Mg
29P151428.98180037(39)4.102(4) sβ+29Si1/2+
30P151529.978313490(69)2.5000(17) minβ+30Si1+
31P151630.97376199768(80)Stable1/2+1.0000
32P 151731.973907643(42)14.269(7) dβ−32S1+ Trace
33P151832.9717257(12)25.35(11) dβ−33S1/2+
34P151933.97364589(87)12.43(10) sβ−34S1+
35P152034.9733140(20)47.3(8) sβ−35S1/2+
36P152135.978260(14)5.6(3) sβ−36S4−
β−, n?35S
37P152236.979607(41)2.31(13) sβ−37S(1/2+)
β−, n?36S
38P152337.984303(78)0.64(14) sβ− (88%)38S(2−)
β−, n (12%)37S
39P152438.98629(12)282(24) msβ− (74%)39S(1/2+)
β−, n (26%)38S
40P152539.991262(90)150(8) msβ− (84.2%)40S(2−,3−)
β−, n (15.8%)39S
β−, 2n?38S
41P152640.99465(13)101(5) msβ− (70%)41S1/2+#
β−, n (30%)40S
β−, 2n?39S
42P152742.00117(10)48.5(15) msβ− (50%)42S
β−, n (50%)41S
β−, 2n?40S
43P152843.00541(32)#35.8(13) msβ−, n42S(1/2+)
β−, 2n ?41S
44P152944.01193(43)#18.5(25) msβ−, n (55% [7] )43S
β− (24%)44S
β−, 2n (21%)42S
45P153045.01713(54)#24(7 (stat), 9 (sys)) ms [7] β−, n (79%)44S1/2+#
β−, 2n (21%)43S
46P153146.02452(54)#9# ms
[>200 ns]		β−?46S
β−, n?45S
β−, 2n?44S
47P153247.03093(64)#4# ms
[>400 ns]		β−47S1/2+#
β−, n?46S
β−, 2n?45S
This table header & footer:
  1. ↑ mP – Excited nuclear isomer.
  2. ↑ ( ) – Uncertainty (1σ) is given in concise form in parentheses after the corresponding last digits.
  3. ↑ # – Atomic mass marked #: value and uncertainty derived not from purely experimental data, but at least partly from trends from the Mass Surface (TMS).
  4. 1 2 # – Values marked # are not purely derived from experimental data, but at least partly from trends of neighboring nuclides (TNN).
  5. ↑ Modes of decay:
    IT: Isomeric transition
    n: Neutron emission
    p: Proton emission
  6. ↑ Bold symbol as daughter – Daughter product is stable.
  7. ↑ ( ) spin value – Indicates spin with weak assignment arguments.

Radioactive isotopes

Phosphorus-32

32P is a radioactive isotope of phosphorus with relative atomic mass 31.973907 and half-life of 14.26 days. 32P is a radioactive isotope of phosphorus with beta particle-emitting radiocytotoxic activity. Emitted by 32P, beta particles directly damage cellular DNA and, by ionizing intracellular water to produce several types of cytotoxic free radicals and superoxides, indirectly damage intracellular biological macromolecules, resulting in tumor cell death. [8]

Phosphorus-33

33P is an artificial radioactive element. It is produced with a low yield by the neutron bombardment of 31P (stable). The 33P has a radioactive period of 25.3 days. It is a pure β-transmitter. 33P is used as an alternative to 32P in research in molecular biology. Indeed, its longer life time and especially its less energetic β spectrum make its manipulation simpler in the laboratory. In the medical field, 33P has been used in the treatment of arterial stenosis but is no longer indicated at this time. [9]

Related Research Articles

Phosphorus-32 (32P) is a radioactive isotope of phosphorus. The nucleus of phosphorus-32 contains 15 protons and 17 neutrons, one more neutron than the most common isotope of phosphorus, phosphorus-31. Phosphorus-32 only exists in small quantities on Earth as it has a short half-life of 14 days and so decays rapidly.

There are 39 known isotopes of radon (86Rn), from 193Rn to 231Rn; all are radioactive. The most stable isotope is 222Rn with a half-life of 3.8235 days, which decays into 218
Po
. Six isotopes of radon, 217, 218, 219, 220, 221, 222Rn, occur in trace quantities in nature as decay products of, respectively, 217At, 218At, 223Ra, 224Ra, 225Ra, and 226Ra. 217Rn and 221Rn are produced in rare branches in the decay chain of trace quantities of 237Np; 222Rn is an intermediate step in the decay chain of 238U; 219Rn is an intermediate step in the decay chain of 235U; and 220Rn occurs in the decay chain of 232Th.

Astatine (85At) has 41 known isotopes, all of which are radioactive; their mass numbers range from 188 to 229. There are also 24 known metastable excited states. The longest-lived isotope is 210At, which has a half-life of 8.1 hours; the longest-lived isotope existing in naturally occurring decay chains is 219At with a half-life of 56 seconds.

There are 42 isotopes of polonium (84Po). They range in size from 186 to 227 nucleons. They are all radioactive. 210Po with a half-life of 138.376 days has the longest half-life of any naturally-occurring isotope of polonium and is the most common isotope of polonium. It is also the most easily synthesized polonium isotope. 209Po, which does not occur naturally, has the longest half-life of all isotopes of polonium at 124 years. 209Po can be made by using a cyclotron to bombard bismuth with protons, as can 208Po.

<span class="mw-page-title-main">Isotopes of thallium</span>

Thallium (81Tl) has 41 isotopes with atomic masses that range from 176 to 216. 203Tl and 205Tl are the only stable isotopes and 204Tl is the most stable radioisotope with a half-life of 3.78 years. 207Tl, with a half-life of 4.77 minutes, has the longest half-life of naturally occurring Tl radioisotopes. All isotopes of thallium are either radioactive or observationally stable, meaning that they are predicted to be radioactive but no actual decay has been observed.

There are seven stable isotopes of mercury (80Hg) with 202Hg being the most abundant (29.86%). The longest-lived radioisotopes are 194Hg with a half-life of 444 years, and 203Hg with a half-life of 46.612 days. Most of the remaining 40 radioisotopes have half-lives that are less than a day. 199Hg and 201Hg are the most often studied NMR-active nuclei, having spin quantum numbers of 1/2 and 3/2 respectively. All isotopes of mercury are either radioactive or observationally stable, meaning that they are predicted to be radioactive but no actual decay has been observed. These isotopes are predicted to undergo either alpha decay or double beta decay.

Naturally occurring ytterbium (70Yb) is composed of seven stable isotopes: 168Yb, 170Yb–174Yb, and 176Yb, with 174Yb being the most abundant. 30 radioisotopes have been characterized, with the most stable being 169Yb with a half-life of 32.014 days, 175Yb with a half-life of 4.185 days, and 166Yb with a half-life of 56.7 hours. All of the remaining radioactive isotopes have half-lives that are less than 2 hours, and the majority of these have half-lives that are less than 20 minutes. This element also has 18 meta states, with the most stable being 169mYb.

Naturally occurring erbium (68Er) is composed of six stable isotopes, with 166Er being the most abundant. Thirty-nine radioisotopes have been characterized with between 74 and 112 neutrons, or 142 to 180 nucleons, with the most stable being 169Er with a half-life of 9.4 days, 172Er with a half-life of 49.3 hours, 160Er with a half-life of 28.58 hours, 165Er with a half-life of 10.36 hours, and 171Er with a half-life of 7.516 hours. All of the remaining radioactive isotopes have half-lives that are less than 3.5 hours, and the majority of these have half-lives that are less than 4 minutes. This element also has numerous meta states, with the most stable being 167mEr.

Naturally occurring cerium (58Ce) is composed of 4 stable isotopes: 136Ce, 138Ce, 140Ce, and 142Ce, with 140Ce being the most abundant and the only one theoretically stable; 136Ce, 138Ce, and 142Ce are predicted to undergo double beta decay but this process has never been observed. There are 35 radioisotopes that have been characterized, with the most stable being 144Ce, with a half-life of 284.893 days; 139Ce, with a half-life of 137.640 days and 141Ce, with a half-life of 32.501 days. All of the remaining radioactive isotopes have half-lives that are less than 4 days and the majority of these have half-lives that are less than 10 minutes. This element also has 10 meta states.

Naturally occurring silver (47Ag) is composed of the two stable isotopes 107Ag and 109Ag in almost equal proportions, with 107Ag being slightly more abundant. Notably, silver is the only element with all stable istopes having nuclear spins of 1/2. Thus both 107Ag and 109Ag nuclei produce narrow lines in nuclear magnetic resonance spectra.

The alkaline earth metal strontium (38Sr) has four stable, naturally occurring isotopes: 84Sr (0.56%), 86Sr (9.86%), 87Sr (7.0%) and 88Sr (82.58%). Its standard atomic weight is 87.62(1).

Bromine (35Br) has two stable isotopes, 79Br and 81Br, and 35 known radioisotopes, the most stable of which is 77Br, with a half-life of 57.036 hours.

Germanium (32Ge) has five naturally occurring isotopes, 70Ge, 72Ge, 73Ge, 74Ge, and 76Ge. Of these, 76Ge is very slightly radioactive, decaying by double beta decay with a half-life of 1.78 × 1021 years (130 billion times the age of the universe).

Naturally occurring zinc (30Zn) is composed of the 5 stable isotopes 64Zn, 66Zn, 67Zn, 68Zn, and 70Zn with 64Zn being the most abundant. Twenty-eight radioisotopes have been characterised with the most stable being 65Zn with a half-life of 244.26 days, and then 72Zn with a half-life of 46.5 hours. All of the remaining radioactive isotopes have half-lives that are less than 14 hours and the majority of these have half-lives that are less than 1 second. This element also has 10 meta states.

Naturally occurring chromium (24Cr) is composed of four stable isotopes; 50Cr, 52Cr, 53Cr, and 54Cr with 52Cr being the most abundant (83.789% natural abundance). 50Cr is suspected of decaying by β+β+ to 50Ti with a half-life of (more than) 1.8×1017 years. Twenty-two radioisotopes, all of which are entirely synthetic, have been characterized, the most stable being 51Cr with a half-life of 27.7 days. All of the remaining radioactive isotopes have half-lives that are less than 24 hours and the majority of these have half-lives that are less than 1 minute. This element also has two meta states, 45mCr, the more stable one, and 59mCr, the least stable isotope or isomer.

Naturally occurring scandium (21Sc) is composed of one stable isotope, 45Sc. Twenty-seven radioisotopes have been characterized, with the most stable being 46Sc with a half-life of 83.8 days, 47Sc with a half-life of 3.35 days, and 48Sc with a half-life of 43.7 hours and 44Sc with a half-life of 3.97 hours. All the remaining isotopes have half-lives that are less than four hours, and the majority of these have half-lives that are less than two minutes, the least stable being proton unbound 39Sc with a half-life shorter than 300 nanoseconds. This element also has 13 meta states with the most stable being 44m2Sc.

Potassium has 25 known isotopes from 34
K to 57
K as well as 31
K, as well as an unconfirmed report of 59
K. Three of those isotopes occur naturally: the two stable forms 39
K (93.3%) and 41
K (6.7%), and a very long-lived radioisotope 40
K (0.012%)

Sulfur (16S) has 23 known isotopes with mass numbers ranging from 27 to 49, four of which are stable: 32S (95.02%), 33S (0.75%), 34S (4.21%), and 36S (0.02%). The preponderance of sulfur-32 is explained by its production from carbon-12 plus successive fusion capture of five helium-4 nuclei, in the so-called alpha process of exploding type II supernovas.

<span class="mw-page-title-main">Isotopes of magnesium</span>

Magnesium (12Mg) naturally occurs in three stable isotopes: 24
Mg, 25
Mg, and 26
Mg. There are 19 radioisotopes that have been discovered, ranging from 18
Mg to 40
Mg. The longest-lived radioisotope is 28
Mg with a half-life of 20.915(9) h. The lighter isotopes mostly decay to isotopes of sodium while the heavier isotopes decay to isotopes of aluminium. The shortest-lived is proton-unbound 18
Mg with a half-life of 4.0(3.4) zeptoseconds.

Fermium (100Fm) is a synthetic element, and thus a standard atomic weight cannot be given. Like all artificial elements, it has no stable isotopes. The first isotope to be discovered was 255Fm in 1952. 250Fm was independently synthesized shortly after the discovery of 255Fm. There are 20 known radioisotopes ranging in atomic mass from 241Fm to 260Fm, and 4 nuclear isomers, 247mFm, 250mFm, 251mFm, and 253mFm. The longest-lived isotope is 257Fm with a half-life of 100.5 days, and the longest-lived isomer is 247mFm with a half-life of 5.1 seconds.

References

  1. ↑ "Standard Atomic Weights: Phosphorus". CIAAW. 2013.
  2. ↑ Prohaska, Thomas; Irrgeher, Johanna; Benefield, Jacqueline; Böhlke, John K.; Chesson, Lesley A.; Coplen, Tyler B.; Ding, Tiping; Dunn, Philip J. H.; Gröning, Manfred; Holden, Norman E.; Meijer, Harro A. J. (2022-05-04). "Standard atomic weights of the elements 2021 (IUPAC Technical Report)". Pure and Applied Chemistry. doi:10.1515/pac-2019-0603. ISSN   1365-3075.
  3. ↑ PubChem. "Phosphorus Radioisotopes". pubchem.ncbi.nlm.nih.gov. Retrieved 2022-04-08.
  4. ↑ "phosphorus-33 atom (CHEBI:37973)". www.ebi.ac.uk. Retrieved 2022-04-08.
  5. ↑ Wang, Meng; Huang, W.J.; Kondev, F.G.; Audi, G.; Naimi, S. (2021). "The AME 2020 atomic mass evaluation (II). Tables, graphs and references*". Chinese Physics C. 45 (3): 030003. doi:10.1088/1674-1137/abddaf.
  6. 1 2 3 Kondev, F. G.; Wang, M.; Huang, W. J.; Naimi, S.; Audi, G. (2021). "The NUBASE2020 evaluation of nuclear properties" (PDF). Chinese Physics C. 45 (3): 030001. doi:10.1088/1674-1137/abddae.
  7. 1 2 Crawford, H. L.; Tripathi, V.; Allmond, J. M.; et al. (2022). "Crossing N = 28 toward the neutron drip line: first measurement of half-lives at FRIB". Physical Review Letters. 129 (212501): 212501. Bibcode:2022PhRvL.129u2501C. doi: 10.1103/PhysRevLett.129.212501 . PMID   36461950. S2CID   253600995.
  8. ↑ "Phosphorus-32".
  9. ↑ "Phosphorus 33 (P-33)".
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