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Promethium (61Pm) is an artificial element, except in trace quantities as a product of spontaneous fission of 238U and 235U and alpha decay of 151Eu, and thus a standard atomic weight cannot be given. Like all artificial elements, it has no stable isotopes. It was first synthesized in 1945.
Forty-one radioisotopes have been characterized, with the most stable being 145Pm with a half-life of 17.7 years, 146Pm with a half-life of 5.53 years, and 147Pm with a half-life of 2.6234 years. All of the remaining radioactive isotopes have half-lives that are less than 365 days, and the majority of these have half-lives that are less than 30 seconds. This element also has 18 meta states with the most stable being 148mPm (t1/2 41.29 days), 152m2Pm (t1/2 13.8 minutes) and 152mPm (t1/2 7.52 minutes).
The isotopes of promethium range in mass number from 126 to 166. The primary decay mode for 146Pm and lighter isotopes is electron capture, and the primary mode for heavier isotopes is beta decay. The primary decay products before 146Pm are isotopes of neodymium, and the primary products after are isotopes of samarium.
Nuclide [n 1] | Z | N | Isotopic mass (Da) [n 2] [n 3] | Half-life [n 4] | Decay mode [n 5] | Daughter isotope [n 6] [n 7] | Spin and parity [n 8] [n 4] | Isotopic abundance | |||||||||||
---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
Excitation energy [n 4] | |||||||||||||||||||
126Pm | 61 | 65 | 125.95752(54)# | 0.5# s | |||||||||||||||
127Pm | 61 | 66 | 126.95163(64)# | 1# s | 5/2+# | ||||||||||||||
128Pm | 61 | 67 | 127.94842(43)# | 1.0(3) s | β+ | 128Nd | 6+# | ||||||||||||
p | 127Nd | ||||||||||||||||||
129Pm | 61 | 68 | 128.94316(43)# | 3# s [>200 ns] | β+ | 129Nd | 5/2+# | ||||||||||||
130Pm | 61 | 69 | 129.94045(32)# | 2.6(2) s | β+ | 130Nd | (5+, 6+, 4+) | ||||||||||||
β+, p (rare) | 129Pr | ||||||||||||||||||
131Pm | 61 | 70 | 130.93587(21)# | 6.3(8) s | β+, p | 130Pr | 5/2+# | ||||||||||||
β+ | 131Nd | ||||||||||||||||||
132Pm | 61 | 71 | 131.93375(21)# | 6.2(6) s | β+ | 132Nd | (3+) | ||||||||||||
β+, p (5×10−5%) | 131Pr | ||||||||||||||||||
133Pm | 61 | 72 | 132.92978(5) | 15(3) s | β+ | 133Nd | (3/2+) | ||||||||||||
133mPm | 130.4(10) keV | 10# s | β+ | 133Nd | (11/2−) | ||||||||||||||
IT | 133Pm | ||||||||||||||||||
134Pm | 61 | 73 | 133.92835(6) | 22(1) s | β+ | 134Nd | (5+) | ||||||||||||
134mPm | 0(100)# keV | ~5 s | IT | 134Pm | (2+) | ||||||||||||||
135Pm | 61 | 74 | 134.92488(6) | 49(3) s | β+ | 135Nd | (5/2+, 3/2+) | ||||||||||||
135mPm | 50(100)# keV | 40(3) s | β+ | 135Nd | (11/2−) | ||||||||||||||
136Pm | 61 | 75 | 135.92357(8) | 107(6) s | β+ | 136Nd | (5−) | ||||||||||||
136mPm | 130(120) keV | 47(2) s | β+ | 136Nd | (2+) | ||||||||||||||
137Pm | 61 | 76 | 136.920479(14) | 2# min | β+ | 137Nd | 5/2+# | ||||||||||||
137mPm | 150(50) keV | 2.4(1) min | β+ | 137Nd | 11/2− | ||||||||||||||
138Pm | 61 | 77 | 137.919548(30) | 10(2) s | β+ | 138Nd | 1+# | ||||||||||||
138mPm | 30(30) keV | 3.24(5) min | β+ | 138Nd | 5−# | ||||||||||||||
139Pm | 61 | 78 | 138.916804(14) | 4.15(5) min | β+ | 139Nd | (5/2)+ | ||||||||||||
139mPm | 188.7(3) keV | 180(20) ms | IT (99.83%) | 139Pm | (11/2)− | ||||||||||||||
β+ (0.17%) | 139Nd | ||||||||||||||||||
140Pm | 61 | 79 | 139.91604(4) | 9.2(2) s | β+ | 140Nd | 1+ | ||||||||||||
140mPm | 420(40) keV | 5.95(5) min | β+ | 140Nd | 8− | ||||||||||||||
141Pm | 61 | 80 | 140.913555(15) | 20.90(5) min | β+ | 141Nd | 5/2+ | ||||||||||||
141m1Pm | 628.40(10) keV | 630(20) ns | 11/2− | ||||||||||||||||
141m2Pm | 2530.9(5) keV | >2 μs | |||||||||||||||||
142Pm | 61 | 81 | 141.912874(27) | 40.5(5) s | β+ | 142Nd | 1+ | ||||||||||||
142mPm | 883.17(16) keV | 2.0(2) ms | IT | 142Pm | (8)− | ||||||||||||||
143Pm | 61 | 82 | 142.910933(4) | 265(7) d | EC | 143Nd | 5/2+ | ||||||||||||
β+ (<5.7×10−6%) [1] | |||||||||||||||||||
144Pm | 61 | 83 | 143.912591(3) | 363(14) d | EC | 144Nd | 5− | ||||||||||||
β+ (<8×10−5%) [1] | |||||||||||||||||||
144m1Pm | 840.90(5) keV | 780(200) ns | (9)+ | ||||||||||||||||
144m2Pm | 8595.8(22) keV | ~2.7 μs | (27+) | ||||||||||||||||
145Pm | 61 | 84 | 144.912749(3) | 17.7(4) y | EC | 145Nd | 5/2+ | ||||||||||||
α (2.8×10−7%) | 141Pr | ||||||||||||||||||
146Pm | 61 | 85 | 145.914696(5) | 5.53(5) y | EC (66%) | 146Nd | 3− | ||||||||||||
β− (34%) | 146Sm | ||||||||||||||||||
147Pm [n 9] | 61 | 86 | 146.9151385(26) | 2.6234(2) y | β− | 147Sm | 7/2+ | Trace [n 10] | |||||||||||
148Pm | 61 | 87 | 147.917475(7) | 5.368(2) d | β− | 148Sm | 1− | ||||||||||||
148mPm | 137.9(3) keV | 41.29(11) d | β− (95%) | 148Sm | 5−, 6− | ||||||||||||||
IT (5%) | 148Pm | ||||||||||||||||||
149Pm [n 9] | 61 | 88 | 148.918334(4) | 53.08(5) h | β− | 149Sm | 7/2+ | ||||||||||||
149mPm | 240.214(7) keV | 35(3) μs | 11/2− | ||||||||||||||||
150Pm | 61 | 89 | 149.920984(22) | 2.68(2) h | β− | 150Sm | (1−) | ||||||||||||
151Pm [n 9] | 61 | 90 | 150.921207(6) | 28.40(4) h | β− | 151Sm | 5/2+ | ||||||||||||
152Pm | 61 | 91 | 151.923497(28) | 4.12(8) min | β− | 152Sm | 1+ | ||||||||||||
152m1Pm | 140(90) keV | 7.52(8) min | 4− | ||||||||||||||||
152m2Pm | 250(150)# keV | 13.8(2) min | (8) | ||||||||||||||||
153Pm | 61 | 92 | 152.924117(12) | 5.25(2) min | β− | 153Sm | 5/2− | ||||||||||||
154Pm | 61 | 93 | 153.92646(5) | 1.73(10) min | β− | 154Sm | (0, 1) | ||||||||||||
154mPm | 120(120) keV | 2.68(7) min | β− | 154Sm | (3, 4) | ||||||||||||||
155Pm | 61 | 94 | 154.92810(3) | 41.5(2) s | β− | 155Sm | (5/2−) | ||||||||||||
156Pm | 61 | 95 | 155.93106(4) | 26.70(10) s | β− | 156Sm | 4− | ||||||||||||
157Pm | 61 | 96 | 156.93304(12) | 10.56(10) s | β− | 157Sm | (5/2−) | ||||||||||||
158Pm | 61 | 97 | 157.93656(14) | 4.8(5) s | β− | 158Sm | |||||||||||||
159Pm | 61 | 98 | 158.93897(21)# | 1.648+0.43 −0.42 s [2] | β− | 159Sm | 5/2−# | ||||||||||||
160Pm | 61 | 99 | 159.94299(32)# | 874+16 −12 ms [2] | β− | 160Sm | |||||||||||||
161Pm | 61 | 100 | 160.94586(54)# | 724+20 −12 ms [2] | β− (98.91%) | 161Sm | 5/2−# | ||||||||||||
β−, n (1.09%) | 160Sm | ||||||||||||||||||
162Pm | 61 | 101 | 161.95029(75)# | 467+38 −18 ms [2] | β− (98.21%) | 162Sm | |||||||||||||
β−, n (1.79%) | 161Sm | ||||||||||||||||||
163Pm | 61 | 102 | 162.95368(86)# | 362+42 −30 ms [2] | β− (95%) | 163Sm | 5/2−# | ||||||||||||
β−, n (1.79%) | 162Sm | ||||||||||||||||||
164Pm | 61 | 103 | 280+38 −33 ms [2] | β− (93.82%) | 164Sm | ||||||||||||||
β−, n (6.18%) | 163Sm | ||||||||||||||||||
165Pm | 61 | 104 | 297+111 −101 ms [2] | β− (86.74%) | 165Sm | ||||||||||||||
β−, n (13.26%) | 164Sm | ||||||||||||||||||
166Pm | 61 | 105 | 228+131 −112 ms [2] | β− | 166Sm | ||||||||||||||
β−, n | 165Sm | ||||||||||||||||||
This table header & footer: |
EC: | Electron capture |
IT: | Isomeric transition |
p: | Proton emission |
Promethium is one of the two elements of the first 82 elements that has no stable isotopes. This is a rarely occurring effect of the liquid drop model. Namely, promethium does not have any beta-stable isotopes, as for any mass number, it is energetically favorable for a promethium isotope to undergo positron emission or beta decay, respectively forming a neodymium or samarium isotope which has a higher binding energy per nucleon. The other element for which this happens is technetium (Z = 43).
Promethium-147 has a half-life of 2.62 years, and is a fission product produced in nuclear reactors via beta decay from neodymium-147. The isotopes 142Nd, 143Nd, 144Nd, 145Nd, 146Nd, 148Nd, and 150Nd are all stable with respect to beta decay, so the isotopes of promethium with those masses cannot be produced by beta decay and therefore are not fission products in significant quantities (they could only be produced directly, rather than along a beta-decay chain). 149Pm and 151Pm have half-lives of only 53.08 and 28.40 hours, so are not found in spent nuclear fuel that has been cooled for months or years. It is found naturally mostly from the spontaneous fission of uranium-238 and less often from the alpha decay of europium-151. [3]
Promethium-147 is used as a beta particle source and a radioisotope thermoelectric generator (RTG) fuel; its power density is about 2 watts per gram. Mixed with a phosphor, it was used to illuminate Apollo Lunar Module electrical switch tips and painted on control panels of the Lunar Roving Vehicle. [4]
Protactinium (91Pa) has no stable isotopes. The four naturally occurring isotopes allow a standard atomic weight to be given.
Francium (87Fr) has no stable isotopes. A standard atomic weight cannot be given. Its most stable isotope is 223Fr with a half-life of 22 minutes, occurring in trace quantities in nature as an intermediate decay product of 235U.
There are 39 known isotopes of radon (86Rn), from 193Rn to 231Rn; all are radioactive. The most stable isotope is 222Rn with a half-life of 3.823 days, which decays into 218
Po
. Six isotopes of radon, 217, 218, 219, 220, 221, 222Rn, occur in trace quantities in nature as decay products of, respectively, 217At, 218At, 223Ra, 224Ra, 225Ra, and 226Ra. 217Rn and 221Rn are produced in rare branches in the decay chain of trace quantities of 237Np; 222Rn is an intermediate step in the decay chain of 238U; 219Rn is an intermediate step in the decay chain of 235U; and 220Rn occurs in the decay chain of 232Th.
Astatine (85At) has 41 known isotopes, all of which are radioactive; their mass numbers range from 188 to 229. There are also 24 known metastable excited states. The longest-lived isotope is 210At, which has a half-life of 8.1 hours; the longest-lived isotope existing in naturally occurring decay chains is 219At with a half-life of 56 seconds.
There are 42 isotopes of polonium (84Po). They range in size from 186 to 227 nucleons. They are all radioactive. 210Po with a half-life of 138.376 days has the longest half-life of any naturally-occurring isotope of polonium and is the most common isotope of polonium. It is also the most easily synthesized polonium isotope. 209Po, which does not occur naturally, has the longest half-life of all isotopes of polonium at 124 years. 209Po can be made by using a cyclotron to bombard bismuth with protons, as can 208Po.
Thallium (81Tl) has 41 isotopes with atomic masses that range from 176 to 216. 203Tl and 205Tl are the only stable isotopes and 204Tl is the most stable radioisotope with a half-life of 3.78 years. 207Tl, with a half-life of 4.77 minutes, has the longest half-life of naturally occurring Tl radioisotopes. All isotopes of thallium are either radioactive or observationally stable, meaning that they are predicted to be radioactive but no actual decay has been observed.
Naturally occurring terbium (65Tb) is composed of one stable isotope, 159Tb. Thirty-seven radioisotopes have been characterized, with the most stable being 158Tb with a half-life of 180 years, 157Tb with a half-life of 71 years, and 160Tb with a half-life of 72.3 days. All of the remaining radioactive isotopes have half-lives that are less than 6.907 days, and the majority of these have half-lives that are less than 24 seconds. This element also has 27 meta states, with the most stable being 156m1Tb, 154m2Tb and 154m1Tb.
Naturally occurring europium (63Eu) is composed of two isotopes, 151Eu and 153Eu, with 153Eu being the most abundant (52.2% natural abundance). While 153Eu is observationally stable (theoretically can undergo alpha decay with half-life over 5.5×1017 years), 151Eu was found in 2007 to be unstable and undergo alpha decay. The half-life is measured to be (4.62 ± 0.95(stat.) ± 0.68(syst.)) × 1018 years which corresponds to 1 alpha decay per two minutes in every kilogram of natural europium. Besides the natural radioisotope 151Eu, 36 artificial radioisotopes have been characterized, with the most stable being 150Eu with a half-life of 36.9 years, 152Eu with a half-life of 13.516 years, 154Eu with a half-life of 8.593 years, and 155Eu with a half-life of 4.7612 years. The majority of the remaining radioactive isotopes, which range from 130Eu to 170Eu, have half-lives that are less than 12.2 seconds. This element also has 18 metastable isomers, with the most stable being 150mEu (t1/2 12.8 hours), 152m1Eu (t1/2 9.3116 hours) and 152m5Eu (t1/2 96 minutes).
Naturally occurring samarium (62Sm) is composed of five stable isotopes, 144Sm, 149Sm, 150Sm, 152Sm and 154Sm, and two extremely long-lived radioisotopes, 147Sm and 148Sm, with 152Sm being the most abundant. 146Sm is also fairly long-lived, but is not long-lived enough to have survived in significant quantities from the formation of the Solar System on Earth, although it remains useful in radiometric dating in the Solar System as an extinct radionuclide. It is the longest-lived nuclide that has not yet been confirmed to be primordial.
Naturally occurring neodymium (60Nd) is composed of 5 stable isotopes, 142Nd, 143Nd, 145Nd, 146Nd and 148Nd, with 142Nd being the most abundant (27.2% natural abundance), and 2 long-lived radioisotopes, 144Nd and 150Nd. In all, 33 radioisotopes of neodymium have been characterized up to now, with the most stable being naturally occurring isotopes 144Nd (alpha decay, a half-life (t1/2) of 2.29×1015 years) and 150Nd (double beta decay, t1/2 of 7×1018 years), and for practical purposes they can be considered to be stable as well. All of the remaining radioactive isotopes have half-lives that are less than 12 days, and the majority of these have half-lives that are less than 70 seconds; the most stable artificial isotope is 147Nd with a half-life of 10.98 days. This element also has 13 known meta states with the most stable being 139mNd (t1/2 5.5 hours), 135mNd (t1/2 5.5 minutes) and 133m1Nd (t1/2 ~70 seconds).
Naturally occurring praseodymium (59Pr) is composed of one stable isotope, 141Pr. Thirty-eight radioisotopes have been characterized with the most stable being 143Pr, with a half-life of 13.57 days and 142Pr, with a half-life of 19.12 hours. All of the remaining radioactive isotopes have half-lives that are less than 5.985 hours and the majority of these have half-lives that are less than 33 seconds. This element also has 15 meta states with the most stable being 138mPr, 142mPr and 134mPr.
Naturally occurring lanthanum (57La) is composed of one stable (139La) and one radioactive (138La) isotope, with the stable isotope, 139La, being the most abundant (99.91% natural abundance). There are 39 radioisotopes that have been characterized, with the most stable being 138La, with a half-life of 1.02×1011 years; 137La, with a half-life of 60,000 years and 140La, with a half-life of 1.6781 days. The remaining radioactive isotopes have half-lives that are less than a day and the majority of these have half-lives that are less than 1 minute. This element also has 12 nuclear isomers, the longest-lived of which is 132mLa, with a half-life of 24.3 minutes. Lighter isotopes mostly decay to isotopes of barium and heavy ones mostly decay to isotopes of cerium. 138La can decay to both.
Antimony (51Sb) occurs in two stable isotopes, 121Sb and 123Sb. There are 37 artificial radioactive isotopes, the longest-lived of which are 125Sb, with a half-life of 2.75856 years; 124Sb, with a half-life of 60.2 days; and 126Sb, with a half-life of 12.35 days. All other isotopes have half-lives less than 4 days, most less than an hour. There are also many isomers, the longest-lived of which is 120m1Sb with a half-life of 5.76 days.
Tin (50Sn) is the element with the greatest number of stable isotopes. This is probably related to the fact that 50 is a "magic number" of protons. In addition, twenty-nine unstable tin isotopes are known, including tin-100 (100Sn) and tin-132 (132Sn), which are both "doubly magic". The longest-lived tin radioisotope is tin-126 (126Sn), with a half-life of 230,000 years. The other 28 radioisotopes have half-lives of less than a year.
Naturally occurring cadmium (48Cd) is composed of 8 isotopes. For two of them, natural radioactivity was observed, and three others are predicted to be radioactive but their decays have not been observed, due to extremely long half-lives. The two natural radioactive isotopes are 113Cd (beta decay, half-life is 8.04 × 1015 years) and 116Cd (two-neutrino double beta decay, half-life is 2.8 × 1019 years). The other three are 106Cd, 108Cd (double electron capture), and 114Cd (double beta decay); only lower limits on their half-life times have been set. Three isotopes—110Cd, 111Cd, and 112Cd—are theoretically stable. Among the isotopes absent in natural cadmium, the most long-lived are 109Cd with a half-life of 462.6 days, and 115Cd with a half-life of 53.46 hours. All of the remaining radioactive isotopes have half-lives that are less than 2.5 hours and the majority of these have half-lives that are less than 5 minutes. This element also has 12 known meta states, with the most stable being 113mCd (t1/2 14.1 years), 115mCd (t1/2 44.6 days) and 117mCd (t1/2 3.36 hours).
Naturally occurring rhodium (45Rh) is composed of only one stable isotope, 103Rh. The most stable radioisotopes are 101Rh with a half-life of 3.3 years, 102Rh with a half-life of 207 days, and 99Rh with a half-life of 16.1 days. Thirty other radioisotopes have been characterized with atomic weights ranging from 88.949 u (89Rh) to 121.943 u (122Rh). Most of these have half-lives that are less than an hour except 100Rh and 105Rh. There are also numerous meta states with the most stable being 102mRh (0.141 MeV) with a half-life of about 3.7 years and 101mRh (0.157 MeV) with a half-life of 4.34 days.
Natural yttrium (39Y) is composed of a single isotope yttrium-89. The most stable radioisotopes are 88Y, which has a half-life of 106.6 days, and 91Y, with a half-life of 58.51 days. All the other isotopes have half-lives of less than a day, except 87Y, which has a half-life of 79.8 hours, and 90Y, with 64 hours. The dominant decay mode below the stable 89Y is electron capture and the dominant mode after it is beta emission. Thirty-five unstable isotopes have been characterized.
Rubidium (37Rb) has 36 isotopes, with naturally occurring rubidium being composed of just two isotopes; 85Rb (72.2%) and the radioactive 87Rb (27.8%).
Arsenic (33As) has 32 known isotopes and at least 10 isomers. Only one of these isotopes, 75As, is stable; as such, it is considered a monoisotopic element. The longest-lived radioisotope is 73As with a half-life of 80 days.
Naturally occurring scandium (21Sc) is composed of one stable isotope, 45Sc. Twenty-seven radioisotopes have been characterized, with the most stable being 46Sc with a half-life of 83.8 days, 47Sc with a half-life of 3.35 days, and 48Sc with a half-life of 43.7 hours and 44Sc with a half-life of 3.97 hours. All the remaining isotopes have half-lives that are less than four hours, and the majority of these have half-lives that are less than two minutes, the least stable being proton unbound 39Sc with a half-life shorter than 300 nanoseconds. This element also has 13 meta states with the most stable being 44m2Sc.