Isotopes of promethium

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Isotopes of promethium  (61Pm)
Main isotopes [1] Decay
abun­dance half-life (t1/2) mode pro­duct
145Pm synth 17.7 y ε 145Nd
α 141Pr
146Pmsynth5.53 yε 146Nd
β 146Sm
147Pm trace 2.6234 yβ 147Sm

Promethium (61Pm) is an artificial element, except in trace quantities as a product of spontaneous fission of 238U and 235U and alpha decay of 151Eu, and thus a standard atomic weight cannot be given. Like all artificial elements, it has no stable isotopes. It was first synthesized in 1945.

Contents

Forty-one radioisotopes have been characterized, with the most stable being 145Pm with a half-life of 17.7 years, 146Pm with a half-life of 5.53 years, and 147Pm with a half-life of 2.6234 years. All of the remaining radioactive isotopes have half-lives that are less than 365 days, and the majority of these have half-lives that are less than 30 seconds. This element also has 18 meta states with the most stable being 148mPm (t1/2 41.29 days), 152m2Pm (t1/2 13.8 minutes) and 152mPm (t1/2 7.52 minutes).

The isotopes of promethium range in mass number from 126 to 166. The primary decay mode for 146Pm and lighter isotopes is electron capture, and the primary mode for heavier isotopes is beta decay. The primary decay products before 146Pm are isotopes of neodymium, and the primary products after are isotopes of samarium.

List of isotopes

Nuclide
[n 1]
Z N Isotopic mass (Da)
[n 2] [n 3]
Half-life
[n 4]
Decay
mode

[n 5]
Daughter
isotope

[n 6] [n 7]
Spin and
parity
[n 8] [n 4]
Isotopic
abundance
Excitation energy [n 4]
126Pm6165125.95752(54)#0.5# s
127Pm6166126.95163(64)#1# s5/2+#
128Pm6167127.94842(43)#1.0(3) s β+ 128Nd6+#
p 127Nd
129Pm6168128.94316(43)#3# s [>200 ns]β+129Nd5/2+#
130Pm6169129.94045(32)#2.6(2) sβ+130Nd(5+, 6+, 4+)
β+, p (rare)129Pr
131Pm6170130.93587(21)#6.3(8) sβ+, p130Pr5/2+#
β+131Nd
132Pm6171131.93375(21)#6.2(6) sβ+132Nd(3+)
β+, p (5×10−5%)131Pr
133Pm6172132.92978(5)15(3) sβ+133Nd(3/2+)
133mPm130.4(10) keV10# sβ+133Nd(11/2−)
IT 133Pm
134Pm6173133.92835(6)22(1) sβ+134Nd(5+)
134mPm0(100)# keV~5 sIT134Pm(2+)
135Pm6174134.92488(6)49(3) sβ+135Nd(5/2+, 3/2+)
135mPm50(100)# keV40(3) sβ+135Nd(11/2−)
136Pm6175135.92357(8)107(6) sβ+136Nd(5−)
136mPm130(120) keV47(2) sβ+136Nd(2+)
137Pm6176136.920479(14)2# minβ+137Nd5/2+#
137mPm150(50) keV2.4(1) minβ+137Nd11/2−
138Pm6177137.919548(30)10(2) sβ+138Nd1+#
138mPm30(30) keV3.24(5) minβ+138Nd5−#
139Pm6178138.916804(14)4.15(5) minβ+139Nd(5/2)+
139mPm188.7(3) keV180(20) msIT (99.83%)139Pm(11/2)−
β+ (0.17%)139Nd
140Pm6179139.91604(4)9.2(2) sβ+140Nd1+
140mPm420(40) keV5.95(5) minβ+140Nd8−
141Pm6180140.913555(15)20.90(5) minβ+141Nd5/2+
141m1Pm628.40(10) keV630(20) ns11/2−
141m2Pm2530.9(5) keV>2 µs
142Pm6181141.912874(27)40.5(5) sβ+142Nd1+
142mPm883.17(16) keV2.0(2) msIT142Pm(8)−
143Pm6182142.910933(4)265(7) d EC 143Nd5/2+
β+ (<5.7×10−6%) [1]
144Pm6183143.912591(3)363(14) dEC144Nd5−
β+ (<8×10−5%) [1]
144m1Pm840.90(5) keV780(200) ns(9)+
144m2Pm8595.8(22) keV~2.7 µs(27+)
145Pm6184144.912749(3)17.7(4) yEC145Nd5/2+
α (2.8×10−7%)141Pr
146Pm6185145.914696(5)5.53(5) yEC (66%)146Nd3−
β (34%)146Sm
147Pm [n 9] 6186146.9151385(26)2.6234(2) yβ147Sm7/2+Trace [n 10]
148Pm6187147.917475(7)5.368(2) dβ148Sm1−
148mPm137.9(3) keV41.29(11) dβ (95%)148Sm5−, 6−
IT (5%)148Pm
149Pm [n 9] 6188148.918334(4)53.08(5) hβ149Sm7/2+
149mPm240.214(7) keV35(3) µs11/2−
150Pm6189149.920984(22)2.68(2) hβ150Sm(1−)
151Pm [n 9] 6190150.921207(6)28.40(4) hβ151Sm5/2+
152Pm6191151.923497(28)4.12(8) minβ152Sm1+
152m1Pm140(90) keV7.52(8) min4−
152m2Pm250(150)# keV13.8(2) min(8)
153Pm6192152.924117(12)5.25(2) minβ153Sm5/2−
154Pm6193153.92646(5)1.73(10) minβ154Sm(0, 1)
154mPm120(120) keV2.68(7) minβ154Sm(3, 4)
155Pm6194154.92810(3)41.5(2) sβ155Sm(5/2−)
156Pm6195155.93106(4)26.70(10) sβ156Sm4−
157Pm6196156.93304(12)10.56(10) sβ157Sm(5/2−)
158Pm6197157.93656(14)4.8(5) sβ158Sm
159Pm6198158.93897(21)#1.648+0.43
−0.42
 s
[2]
β159Sm5/2−#
160Pm6199159.94299(32)#874+16
−12
 ms
[2]
β160Sm
161Pm61100160.94586(54)#724+20
−12
 ms
[2]
β (98.91%)161Sm5/2−#
β, n (1.09%)160Sm
162Pm61101161.95029(75)#467+38
−18
 ms
[2]
β (98.21%)162Sm
β, n (1.79%)161Sm
163Pm61102162.95368(86)#362+42
−30
 ms
[2]
β (95%)163Sm5/2−#
β, n (1.79%)162Sm
164Pm61103280+38
−33
 ms
[2]
β (93.82%)164Sm
β, n (6.18%)163Sm
165Pm61104297+111
−101
 ms
[2]
β (86.74%)165Sm
β, n (13.26%)164Sm
166Pm61105228+131
−112
 ms
[2]
β166Sm
β, n165Sm
This table header & footer:
  1. mPm  Excited nuclear isomer.
  2. ()  Uncertainty (1σ) is given in concise form in parentheses after the corresponding last digits.
  3. #  Atomic mass marked #: value and uncertainty derived not from purely experimental data, but at least partly from trends from the Mass Surface (TMS).
  4. 1 2 3 #  Values marked # are not purely derived from experimental data, but at least partly from trends of neighboring nuclides (TNN).
  5. Modes of decay:
    EC: Electron capture
    IT: Isomeric transition
    p: Proton emission
  6. Bold italics symbol as daughter  Daughter product is nearly stable.
  7. Bold symbol as daughter  Daughter product is stable.
  8. () spin value  Indicates spin with weak assignment arguments.
  9. 1 2 3 Fission product
  10. Alpha decay daughter of primordial 151Eu

Stability of promethium isotopes

Promethium is one of the two elements of the first 82 elements that has no stable isotopes. This is a rarely occurring effect of the liquid drop model. Namely, promethium does not have any beta-stable isotopes, as for any mass number, it is energetically favorable for a promethium isotope to undergo positron emission or beta decay, respectively forming a neodymium or samarium isotope which has a higher binding energy per nucleon. The other element for which this happens is technetium (Z = 43).

Promethium-147

Promethium-147 has a half-life of 2.62 years, and is a fission product produced in nuclear reactors via beta decay from neodymium-147. The isotopes 142Nd, 143Nd, 144Nd, 145Nd, 146Nd, 148Nd, and 150Nd are either stable or nearly so, so the isotopes of promethium with those masses cannot be produced by beta decay and therefore are not fission products in significant quantities. 149Pm and 151Pm have half-lives of only 53.08 and 28.40 hours, so are not found in spent nuclear fuel that has been cooled for months or years. It is found naturally mostly from the spontaneous fission of uranium-238 and less often from the alpha decay of europium-151. [3]

Promethium-147 is used as a beta particle source and a radioisotope thermoelectric generator (RTG) fuel; its power density is about 2 watts per gram. Mixed with a phosphor, it was used to illuminate Apollo Lunar Module electrical switch tips and painted on control panels of the Lunar Roving Vehicle. [4]

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<span class="mw-page-title-main">Isotopes of thallium</span> Nuclides with atomic number of 81 but with different mass numbers

Thallium (81Tl) has 41 isotopes with atomic masses that range from 176 to 216. 203Tl and 205Tl are the only stable isotopes and 204Tl is the most stable radioisotope with a half-life of 3.78 years. 207Tl, with a half-life of 4.77 minutes, has the longest half-life of naturally occurring Tl radioisotopes. All isotopes of thallium are either radioactive or observationally stable, meaning that they are predicted to be radioactive but no actual decay has been observed.

There are seven stable isotopes of mercury (80Hg) with 202Hg being the most abundant (29.86%). The longest-lived radioisotopes are 194Hg with a half-life of 444 years, and 203Hg with a half-life of 46.612 days. Most of the remaining 40 radioisotopes have half-lives that are less than a day. 199Hg and 201Hg are the most often studied NMR-active nuclei, having spin quantum numbers of 1/2 and 3/2 respectively. All isotopes of mercury are either radioactive or observationally stable, meaning that they are predicted to be radioactive but no actual decay has been observed. These isotopes are predicted to undergo either alpha decay or double beta decay.

Naturally occurring platinum (78Pt) consists of five stable isotopes (192Pt, 194Pt, 195Pt, 196Pt, 198Pt) and one very long-lived (half-life 4.83×1011 years) radioisotope (190Pt). There are also 34 known synthetic radioisotopes, the longest-lived of which is 193Pt with a half-life of 50 years. All other isotopes have half-lives under a year, most under a day. All isotopes of platinum are either radioactive or observationally stable, meaning that they are predicted to be radioactive but no actual decay has been observed. Platinum-195 is the most abundant isotope.

Naturally occurring tungsten (74W) consists of five isotopes. Four are considered stable (182W, 183W, 184W, and 186W) and one is slightly radioactive, 180W, with an extremely long half-life of 1.8 ± 0.2 exayears (1018 years). On average, two alpha decays of 180W occur per gram of natural tungsten per year, so for most practical purposes, 180W can be considered stable. Theoretically, all five can decay into isotopes of element 72 (hafnium) by alpha emission, but only 180W has been observed to do so. The other naturally occurring isotopes have not been observed to decay (they are observationally stable), and lower bounds for their half-lives have been established:

Naturally occurring ytterbium (70Yb) is composed of seven stable isotopes: 168Yb, 170Yb–174Yb, and 176Yb, with 174Yb being the most abundant. 30 radioisotopes have been characterized, with the most stable being 169Yb with a half-life of 32.014 days, 175Yb with a half-life of 4.185 days, and 166Yb with a half-life of 56.7 hours. All of the remaining radioactive isotopes have half-lives that are less than 2 hours, and the majority of these have half-lives that are less than 20 minutes. This element also has 18 meta states, with the most stable being 169mYb.

Naturally occurring terbium (65Tb) is composed of one stable isotope, 159Tb. Thirty-seven radioisotopes have been characterized, with the most stable being 158Tb with a half-life of 180 years, 157Tb with a half-life of 71 years, and 160Tb with a half-life of 72.3 days. All of the remaining radioactive isotopes have half-lives that are less than 6.907 days, and the majority of these have half-lives that are less than 24 seconds. This element also has 27 meta states, with the most stable being 156m1Tb, 154m2Tb and 154m1Tb.

Naturally occurring europium (63Eu) is composed of two isotopes, 151Eu and 153Eu, with 153Eu being the most abundant (52.2% natural abundance). While 153Eu is observationally stable (theoretically can undergo alpha decay with half-life over 5.5×1017 years), 151Eu was found in 2007 to be unstable and undergo alpha decay. The half-life is measured to be (4.62 ± 0.95(stat.) ± 0.68(syst.)) × 1018 years which corresponds to 1 alpha decay per two minutes in every kilogram of natural europium. Besides the natural radioisotope 151Eu, 36 artificial radioisotopes have been characterized, with the most stable being 150Eu with a half-life of 36.9 years, 152Eu with a half-life of 13.516 years, 154Eu with a half-life of 8.593 years, and 155Eu with a half-life of 4.7612 years. The majority of the remaining radioactive isotopes, which range from 130Eu to 170Eu, have half-lives that are less than 12.2 seconds. This element also has 18 meta states, with the most stable being 150mEu (t1/2 12.8 hours), 152m1Eu (t1/2 9.3116 hours) and 152m2Eu (t1/2 96 minutes).

Naturally occurring samarium (62Sm) is composed of five stable isotopes, 144Sm, 149Sm, 150Sm, 152Sm and 154Sm, and two extremely long-lived radioisotopes, 147Sm (half life: 1.06×1011 y) and 148Sm (6.3×1015 y), with 152Sm being the most abundant (26.75% natural abundance). 146Sm is also fairly long-lived, but is not long-lived enough to have survived in significant quantities from the formation of the Solar System on Earth, although it remains useful in radiometric dating in the Solar System as an extinct radionuclide. A 2012 paper revising the estimated half-life of 146Sm from 10.3(5)×107 y to 6.8(7)×107 y was retracted in 2023. It is the longest-lived nuclide that has not yet been confirmed to be primordial.

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Naturally occurring lanthanum (57La) is composed of one stable (139La) and one radioactive (138La) isotope, with the stable isotope, 139La, being the most abundant (99.91% natural abundance). There are 39 radioisotopes that have been characterized, with the most stable being 138La, with a half-life of 1.02×1011 years; 137La, with a half-life of 60,000 years and 140La, with a half-life of 1.6781 days. The remaining radioactive isotopes have half-lives that are less than a day and the majority of these have half-lives that are less than 1 minute. This element also has 12 nuclear isomers, the longest-lived of which is 132mLa, with a half-life of 24.3 minutes.

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References

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