Isotopes of palladium

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Isotopes of palladium  (46Pd)
Main isotopes [1] Decay
abun­dance half-life (t1/2) mode pro­duct
100Pd synth 3.63 d ε 100Rh
γ
102Pd1.02% stable
103Pdsynth16.991 dε 103Rh
104Pd11.1%stable
105Pd22.3%stable
106Pd27.3%stable
107Pd trace 6.5×106 y β 107Ag
108Pd26.5%stable
110Pd11.7%stable
Standard atomic weight Ar°(Pd)

Natural palladium (46Pd) is composed of six stable isotopes, 102Pd, 104Pd, 105Pd, 106Pd, 108Pd, and 110Pd, although 102Pd and 110Pd are theoretically unstable. The most stable radioisotopes are 107Pd with a half-life of 6.5 million years, 103Pd with a half-life of 17 days, and 100Pd with a half-life of 3.63 days. Twenty-three other radioisotopes have been characterized with atomic weights ranging from 90.949 u (91Pd) to 128.96 u (129Pd). Most of these have half-lives that are less than 30 minutes except 101Pd (half-life: 8.47 hours), 109Pd (half-life: 13.7 hours), and 112Pd (half-life: 21 hours).

Contents

The primary decay mode before the most abundant stable isotope, 106Pd, is electron capture and the primary mode after is beta decay. The primary decay product before 106Pd is rhodium and the primary product after is silver.

Radiogenic 107Ag is a decay product of 107Pd and was first discovered in the Santa Clara meteorite of 1978. [4] The discoverers suggest that the coalescence and differentiation of iron-cored small planets may have occurred 10 million years after a nucleosynthetic event. 107Pd versus Ag correlations observed in bodies, which have clearly been melted since accretion of the Solar System, must reflect the presence of short-lived nuclides in the early Solar System. [5]

List of isotopes

Nuclide
[n 1]
Z N Isotopic mass (Da) [6]
[n 2] [n 3]
Half-life [1]
[n 4]
Decay
mode
[1]
[n 5]
Daughter
isotope

[n 6]
Spin and
parity [1]
[n 7] [n 4]
Natural abundance (mole fraction)
Excitation energy [n 4] Normal proportion [1] Range of variation
90Pd464489.95737(43)#10# ms
[>400 ns]
β+?90Rh0+
β+, p?89Ru
2p?88Ru
91Pd464590.95044(45)#32(3) msβ+ (96.9%)91Rh7/2+#
β+, p (3.1%)90Ru
92Pd464691.94119(37)1.06(3) sβ+ (98.4%)92Rh0+
β+, p (1.6%)91Ru
93Pd464792.93668(40)1.17(2) sβ+ (92.6%)93Rh(9/2+)
β+, p (7.4%)91Ru
94Pd464893.9290363(46)9.1(3) sβ+ (>99.87%)94Rh0+
β+, p (<0.13%)93Ru
94m1Pd4883.1(4) keV515(1) ns IT 94Pd(14+)
94m2Pd7209.8(8) keV206(18) nsIT94Pd(19−)
95Pd464994.9248885(33)7.4(4) sβ+ (99.77%)95Rh9/2+#
β+, p (0.23%)95Rh
95mPd1875.13(14) keV13.3(2) sβ+ (88%)95Rh(21/2+)
IT (11%)95Pd
β+, p (0.71%)94Ru
96Pd465095.9182137(45)122(2) sβ+96Rh0+
96mPd2530.57(23) keV1.804(7) μsIT96Pd8+#
97Pd465196.9164720(52)3.10(9) minβ+97Rh5/2+#
98Pd465297.9126983(51)17.7(4) minβ+98Rh0+
99Pd465398.9117731(55)21.4(2) minβ+99Rh(5/2)+
100Pd465499.908520(19)3.63(9) d EC 100Rh0+
101Pd4655100.9082848(49)8.47(6) hβ+101Rh5/2+
102Pd4656101.90563229(45) Observationally Stable [n 8] 0+0.0102(1)
103Pd4657102.90611107(94)16.991(19) dEC103Rh5/2+
104Pd4658103.9040304(14)Stable0+0.1114(8)
105Pd [n 9] 4659104.9050795(12)Stable5/2+0.2233(8)
105mPd489.1(3) keV35.5(5) μsIT105Pd11/2−
106Pd [n 9] 4660105.9034803(12)Stable0+0.2733(3)
107Pd [n 10] 4661106.9051281(13)6.5(3)×106 yβ107Ag5/2+trace [n 11]
107m1Pd115.74(12) keV0.85(10) μsIT107Pd1/2+
107m2Pd214.6(3) keV21.3(5) sIT107Pd11/2−
108Pd [n 9] 4662107.9038918(12)Stable0+0.2646(9)
109Pd [n 9] 4663108.9059506(12)13.59(12) hβ109Ag5/2+
109m1Pd113.4000(14) keV380(50) nsIT109Pd1/2+
109m2Pd188.9903(10) keV4.703(9) minIT109Pd11/2−
110Pd [n 9] 4664109.90517288(66)Observationally Stable [n 12] 0+0.1172(9)
111Pd4665110.90769036(79)23.56(9) minβ111Ag5/2+
111mPd172.18(8) keV5.563(13) hIT (76.8%)111Pd11/2−
β (23.2%)111Ag
112Pd4666111.9073306(70)21.04(17) hβ112Ag0+
113Pd4667112.9102619(75)93(5) sβ113Ag(5/2+)
113mPd81.1(3) keV0.3(1) sIT113Pd(9/2−)
114Pd4668113.9103694(75)2.42(6) minβ114Ag0+
115Pd4669114.9136650(19) [7] 25(2) sβ115Ag(1/2)+
115mPd86.8(29) keV [7] 50(3) sβ (92.0%)115Ag(7/2−)
IT (8.0%)115Pd
116Pd4670115.9142979(77)11.8(4) sβ116Ag0+
117Pd4671116.9179556(78)4.3(3) sβ117Ag(3/2+)
117mPd203.3(3) keV19.1(7) msIT117Pd(9/2−)
118Pd4672117.9190673(27)1.9(1) sβ118Ag0+
119Pd4673118.9231238(45) [7] 0.88(2) sβ119Ag1/2+, 3/2+ [8]
β, n?118Ag
119mPd [7] 199.1(30) keV0.85(1) sIT119Pd(11/2−) [8]
120Pd4674119.9245517(25)492(33) msβ (>99.3%)120Ag0+
β, n (<0.7%)119Ag
121Pd4675120.9289513(40) [7] 290(1) msβ (>99.2%)121Ag3/2+#
β, n (<0.8%)120Ag
121m1Pd135.5(5) keV460(90) nsIT121Pd7/2+#
121m2Pd160(14) keV460(90) nsIT121Pd11/2−#
122Pd4676121.930632(21)193(5) msβ122Ag0+
β, n (<2.5%)121Ag
123Pd4677122.93513(85)108(1) msβ (90%)123Ag3/2+#
β, n (10%)122Ag
123mPd100(50)# keV100# msβ123Ag11/2−#
IT?123Pd
124Pd4678123.93731(32)#88(15) msβ (83%)124Ag0+
β, n (17%)123Ag
124mPd1000(800)# keV>20 μsIT124Pd11/2−#
125Pd4679124.94207(43)#60(6) msβ (88%)125Ag3/2+#
β, n (12%)124Ag
125m1Pd100(50)# keV50# msβ125Ag11/2−#
IT?125Pd
125m2Pd1805.23(18) keV144(4) nsIT125Pd(23/2+)
126Pd4680125.94440(43)#48.6(8) msβ (78%)126Ag0+
β, n (22%)125Ag
126m1Pd2023.5(7) keV330(40) nsIT126Pd(5−)
126m2Pd2109.7(9) keV440(30) nsIT126Pd(7−)
126m3Pd2406.0(10) keV23.0(8) msβ (72%)126Ag(10+)
IT (28%)126Pd
127Pd4681126.94931(54)#38(2) msβ (>81%)127Ag11/2−#
β, n (<19%)126Ag
β, 2n?125Ag
127mPd1717.91(23) keV39(6) μsIT127Pd(19/2+)
128Pd4682127.95235(54)#35(3) msβ128Ag0+
β, n?127Ag
128mPd2151.0(10) keV5.8(8) μsIT128Pd(8+)
129Pd4683128.95933(64)#31(7) msβ129Ag7/2−#
β, n?128Ag
β, 2n?127Ag
130Pd4684129.96486(32)#27# ms
[>550 ns]
β130Ag0+
β, n?129Ag
β, 2n?128Ag
131Pd4685130.97237(32)#20# ms
[>550 ns]
β131Ag7/2−#
β, n?130Ag
β, 2n?129Ag
This table header & footer:
  1. mPd  Excited nuclear isomer.
  2. ()  Uncertainty (1σ) is given in concise form in parentheses after the corresponding last digits.
  3. #  Atomic mass marked #: value and uncertainty derived not from purely experimental data, but at least partly from trends from the Mass Surface (TMS).
  4. 1 2 3 #  Values marked # are not purely derived from experimental data, but at least partly from trends of neighboring nuclides (TNN).
  5. Modes of decay:
    EC: Electron capture
    IT: Isomeric transition
    p: Proton emission
  6. Bold symbol as daughter  Daughter product is stable.
  7. () spin value  Indicates spin with weak assignment arguments.
  8. Believed to decay by β+β+ to 102Ru with a half-life over 7.6×1018 y
  9. 1 2 3 4 5 Fission product
  10. Long-lived fission product
  11. Cosmogenic nuclide, also found as nuclear contamination
  12. Believed to decay by ββ to 110Cd with a half-life over 2.9×1020 years

Palladium-103

Palladium-103 is a radioisotope of the element palladium that has uses in radiation therapy for prostate cancer and uveal melanoma. Palladium-103 may be created from palladium-102 or from rhodium-103 using a cyclotron. Palladium-103 has a half-life of 16.99 [9] days and decays by electron capture to rhodium-103, emitting characteristic x-rays with 21 keV of energy.

Palladium-107

Nuclide t12 Yield Q [a 1] βγ
(Ma)(%) [a 2] (keV)
99Tc 0.2116.1385294β
126Sn 0.2300.10844050 [a 3] βγ
79Se 0.3270.0447151β
135Cs 1.336.9110 [a 4] 269β
93Zr 1.535.457591βγ
107Pd 6.51.249933β
129I 15.70.8410194βγ
  1. Decay energy is split among β, neutrino, and γ if any.
  2. Per 65 thermal neutron fissions of 235U and 35 of 239Pu.
  3. Has decay energy 380 keV, but its decay product 126Sb has decay energy 3.67 MeV.
  4. Lower in thermal reactors because 135Xe, its predecessor, readily absorbs neutrons.

Palladium-107 is the second-longest lived (half-life of 6.5 million years [9] ) and least radioactive (decay energy only 33  keV, specific activity 5×10−5 Ci/g) of the 7 long-lived fission products. It undergoes pure beta decay (without gamma radiation) to 107Ag, which is stable.

Its yield from thermal neutron fission of uranium-235 is 0.14% per fission, [10] only 1/4 that of iodine-129, and only 1/40 those of 99Tc, 93Zr, and 135Cs. Yield from 233U is slightly lower, but yield from 239Pu is much higher, 3.2%. [10] Fast fission or fission of some heavier actinides [which?] will produce palladium-107 at higher yields.

One source [11] estimates that palladium produced from fission contains the isotopes 104Pd (16.9%),105Pd (29.3%), 106Pd (21.3%), 107Pd (17%), 108Pd (11.7%) and 110Pd (3.8%). According to another source, the proportion of 107Pd is 9.2% for palladium from thermal neutron fission of 235U, 11.8% for 233U, and 20.4% for 239Pu (and the 239Pu yield of palladium is about 10 times that of 235U).

Because of this dilution and because 105Pd has 11 times the neutron absorption cross section, 107Pd is not amenable to disposal by nuclear transmutation. However, as a noble metal, palladium is not as mobile in the environment as iodine or technetium.

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Neptunium (93Np) is usually considered an artificial element, although trace quantities are found in nature, so a standard atomic weight cannot be given. Like all trace or artificial elements, it has no stable isotopes. The first isotope to be synthesized and identified was 239Np in 1940, produced by bombarding 238
U
with neutrons to produce 239
U
, which then underwent beta decay to 239
Np
.

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