Isotopes of tantalum

Last updated
Isotopes of tantalum  (73Ta)
Main isotopes [1] Decay
abun­dance half-life (t1/2) mode pro­duct
177Ta synth 56.56 h β+ 177Hf
178Tasynth2.36 hβ+ 178Hf
179Tasynth1.82 y ε 179Hf
180Tasynth8.125 hε 180Hf
β 180W
180mTa0.0120% stable
181Ta99.988%stable
182Tasynth114.43 dβ 182W
183Tasynth5.1 dβ 183W
Standard atomic weight Ar°(Ta)

Natural tantalum (73Ta) consists of two stable isotopes: 181Ta (99.988%) and 180m
Ta
(0.012%).

Contents

There are also 35 known artificial radioisotopes, the longest-lived of which are 179Ta with a half-life of 1.82 years, 182Ta with a half-life of 114.43 days, 183Ta with a half-life of 5.1 days, and 177Ta with a half-life of 56.56 hours. All other isotopes have half-lives under a day, most under an hour. There are also numerous isomers, the most stable of which (other than 180mTa) is 178m1Ta with a half-life of 2.36 hours. All isotopes and nuclear isomers of tantalum are either radioactive or observationally stable, meaning that they are predicted to be radioactive but no actual decay has been observed.

Tantalum has been proposed as a "salting" material for nuclear weapons (cobalt is another, better-known salting material). A jacket of 181Ta, irradiated by the intense high-energy neutron flux from an exploding thermonuclear weapon, would transmute into the radioactive isotope 182
Ta
with a half-life of 114.43 days and produce approximately 1.12  MeV of gamma radiation, significantly increasing the radioactivity of the weapon's fallout for several months. Such a weapon is not known to have ever been built, tested, or used. [4] While the conversion factor from absorbed dose (measured in Grays) to effective dose (measured in Sievert) for gamma rays is 1 while it is 50 for alpha radiation (i.e., a gamma dose of 1 Gray is equivalent to 1 Sievert whereas an alpha dose of 1 Gray is equivalent to 50 Sievert), gamma rays are only attenuated by shielding, not stopped. As such, alpha particles require incorporation to have an effect while gamma rays can have an effect via mere proximity. In military terms, this allows a gamma ray weapon to deny an area to either side as long as the dose is high enough, whereas radioactive contamination by alpha emitters which do not release significant amounts of gamma rays can be counteracted by ensuring the material is not incorporated.

List of isotopes

Nuclide
[n 1]
Z N Isotopic mass (Da)
[n 2] [n 3]
Half-life
[n 4]
Decay
mode

[n 5]
Daughter
isotope

[n 6] [n 7]
Spin and
parity
[n 8] [n 4]
Natural abundance (mole fraction)
Excitation energy [n 4] Normal proportionRange of variation
155
Ta
7382154.97459(54)#2.9+1.5
−1.1
 ms
[5]
p 154Hf(11/2−)
155m
Ta
~323 keV12+4
−3
 μs
[6]
p154Hf11/2−?
156
Ta
[7]
7383155.97230(43)#106(4) msp (71%)155Hf(2−)
β+ (29%)156Hf
156m
Ta
102(7) keV0.36(4) sp155Hf9+
157
Ta
7384156.96819(22)10.1(4) ms α (91%)153Lu1/2+
β+ (9%)157Hf
157m1
Ta
22(5) keV4.3(1) ms11/2−
157m2
Ta
1593(9) keV1.7(1) msα153Lu(25/2−)
158
Ta
7385157.96670(22)#49(8) msα (96%)154Lu(2−)
β+ (4%)158Hf
158m
Ta
141(9) keV36.0(8) msα (93%)154Lu(9+)
IT 158Ta
β+158Hf
159
Ta
7386158.963018(22)1.04(9) sβ+ (66%)159Hf(1/2+)
α (34%)155Lu
159m
Ta
64(5) keV514(9) msα (56%)155Lu(11/2−)
β+ (44%)159Hf
160
Ta
7387159.96149(10)1.70(20) sα156Lu(2#)−
β+160Hf
160m
Ta
310(90)# keV1.55(4) sβ+ (66%)160Hf(9)+
α (34%)156Lu
161
Ta
7388160.95842(6)#3# sβ+ (95%)161Hf1/2+#
α (5%)157Lu
161m
Ta
50(50)# keV2.89(12) s11/2−#
162
Ta
7389161.95729(6)3.57(12) sβ+ (99.92%)162Hf3+#
α (.073%)158Lu
163
Ta
7390162.95433(4)10.6(18) sβ+ (99.8%)163Hf1/2+#
α (.2%)159Lu
164
Ta
7391163.95353(3)14.2(3) sβ+164Hf(3+)
165
Ta
7392164.950773(19)31.0(15) sβ+165Hf5/2−#
165m
Ta
60(30) keV9/2−#
166
Ta
7393165.95051(3)34.4(5) sβ+166Hf(2)+
167
Ta
7394166.94809(3)1.33(7) minβ+167Hf(3/2+)
168
Ta
7395167.94805(3)2.0(1) minβ+168Hf(2−,3+)
169
Ta
7396168.94601(3)4.9(4) minβ+169Hf(5/2+)
170
Ta
7397169.94618(3)6.76(6) minβ+170Hf(3)(+#)
171
Ta
7398170.94448(3)23.3(3) minβ+171Hf(5/2−)
172
Ta
7399171.94490(3)36.8(3) minβ+172Hf(3+)
173
Ta
73100172.94375(3)3.14(13) hβ+173Hf5/2−
174
Ta
73101173.94445(3)1.14(8) hβ+174Hf3+
175
Ta
73102174.94374(3)10.5(2) hβ+175Hf7/2+
176
Ta
73103175.94486(3)8.09(5) hβ+176Hf(1)−
176m1
Ta
103.0(10) keV1.1(1) msIT176Ta(+)
176m2
Ta
1372.6(11)+X keV3.8(4) µs(14−)
176m3
Ta
2820(50) keV0.97(7) ms(20−)
177
Ta
73104176.944472(4)56.56(6) hβ+177Hf7/2+
177m1
Ta
73.36(15) keV410(7) ns9/2−
177m2
Ta
186.15(6) keV3.62(10) µs5/2−
177m3
Ta
1355.01(19) keV5.31(25) µs21/2−
177m4
Ta
4656.3(5) keV133(4) µs49/2−
178
Ta
73105177.945778(16)9.31(3) minβ+178Hf1+
178m1
Ta
100(50)# keV2.36(8) hβ+178Hf(7)−
178m2
Ta
1570(50)# keV59(3) ms(15−)
178m3
Ta
3000(50)# keV290(12) ms(21−)
179
Ta
73106178.9459295(23)1.82(3) y EC 179Hf7/2+
179m1
Ta
30.7(1) keV1.42(8) µs(9/2)−
179m2
Ta
520.23(18) keV335(45) ns(1/2)+
179m3
Ta
1252.61(23) keV322(16) ns(21/2−)
179m4
Ta
1317.3(4) keV9.0(2) msIT179Ta(25/2+)
179m5
Ta
1327.9(4) keV1.6(4) µs(23/2−)
179m6
Ta
2639.3(5) keV54.1(17) ms(37/2+)
180
Ta
73107179.9474648(24)8.152(6) hEC (86%)180Hf1+
β (14%)180W
180m1
Ta
77.1(8) keVObservationally stable [n 9] [n 10] 9−1.2(2)×10−4
180m2
Ta
1452.40(18) keV31.2(14) µs15−
180m3
Ta
3679.0(11) keV2.0(5) µs(22−)
180m4
Ta
4171.0+X keV17(5) µs(23, 24, 25)
181
Ta
73108180.9479958(20)Observationally stable [n 11] 7/2+0.99988(2)
181m1
Ta
6.238(20) keV6.05(12) µs9/2−
181m2
Ta
615.21(3) keV18(1) µs1/2+
181m3
Ta
1485(3) keV25(2) µs21/2−
181m4
Ta
2230(3) keV210(20) µs29/2−
182
Ta
73109181.9501518(19)114.43(3) dβ182W3−
182m1
Ta
16.263(3) keV283(3) msIT182Ta5+
182m2
Ta
519.572(18) keV15.84(10) min10−
183
Ta
73110182.9513726(19)5.1(1) dβ183W7/2+
183m
Ta
73.174(12) keV107(11) ns9/2−
184
Ta
73111183.954008(28)8.7(1) hβ184W(5−)
185
Ta
73112184.955559(15)49.4(15) minβ185W(7/2+)#
185m
Ta
1308(29) keV>1 ms(21/2−)
186
Ta
73113185.95855(6)10.5(3) minβ186W(2−,3−)
186m
Ta
1.54(5) min
187
Ta
73114186.96053(21)#2# min
[>300 ns]
β187W7/2+#
188
Ta
73115187.96370(21)#20# s
[>300 ns]
β188W
189
Ta
73116188.96583(32)#3# s
[>300 ns]
7/2+#
190
Ta
73117189.96923(43)#0.3# s
This table header & footer:
  1. mTa  Excited nuclear isomer.
  2. ()  Uncertainty (1σ) is given in concise form in parentheses after the corresponding last digits.
  3. #  Atomic mass marked #: value and uncertainty derived not from purely experimental data, but at least partly from trends from the Mass Surface (TMS).
  4. 1 2 3 #  Values marked # are not purely derived from experimental data, but at least partly from trends of neighboring nuclides (TNN).
  5. Modes of decay:
    EC: Electron capture
    IT: Isomeric transition
    p: Proton emission
  6. Bold italics symbol as daughter  Daughter product is nearly stable.
  7. Bold symbol as daughter  Daughter product is stable.
  8. () spin value  Indicates spin with weak assignment arguments.
  9. Only known observationally stable nuclear isomer, believed to decay by isomeric transition to 180Ta, β decay to 180W, or electron capture to 180Hf with a half-life over 2.9×1017 years; [8] also theorized to undergo α decay to 176Lu
  10. One of the few (observationally) stable odd-odd nuclei
  11. Believed to undergo α decay to 177Lu

Tantalum-180m

The nuclide 180m
Ta
(m denotes a metastable state) has sufficient energy to decay in three ways: isomeric transition to the ground state of 180
Ta
, beta decay to 180
W
, and electron capture to 180
Hf
. However, no radioactivity from any decay mode of this nuclear isomer has ever been observed. As of 2023, the half-life of 180mTa is calculated from experimental observation to be at least 2.9×1017 (290 quadrillion) years. [8] [9] [10] The very slow decay of 180m
Ta
is attributed to its high spin (9 units) and the low spin of lower-lying states. Gamma or beta decay would require many units of angular momentum to be removed in a single step, so that the process would be very slow. [11]

The very unusual nature of 180mTa is that the ground state of this isotope is less stable than the isomer. This phenomenon is exhibited in bismuth-210m (210mBi) and americium-242m (242mAm), among other nuclides. 180
Ta
has a half-life of only 8 hours. 180m
Ta
is the only naturally occurring nuclear isomer (excluding radiogenic and cosmogenic short-living nuclides). It is also the rarest primordial nuclide in the Universe observed for any element that has any stable isotopes. In an s-process stellar environment with a thermal energy kBT = 26 keV (i.e. a temperature of 300 million kelvin), the nuclear isomers are expected to be fully thermalized, meaning that 180Ta rapidly transitions between spin states and its overall half-life is predicted to be 11 hours. [12]

It is one of only five stable nuclides to have both an odd number of protons and an odd number of neutrons, the other four stable odd-odd nuclides being 2H, 6Li, 10B and 14N. [13]

Related Research Articles

<span class="mw-page-title-main">Stable nuclide</span> Nuclide that does not undergo radioactive decay

Stable nuclides are nuclides that are not radioactive and so do not spontaneously undergo radioactive decay. When such nuclides are referred to in relation to specific elements, they are usually termed stable isotopes.

<span class="mw-page-title-main">Nuclear isomer</span> Metastable excited state of a nuclide

A nuclear isomer is a metastable state of an atomic nucleus, in which one or more nucleons (protons or neutrons) occupy excited state (higher energy) levels. "Metastable" describes nuclei whose excited states have half-lives 100 to 1000 times longer than the half-lives of the excited nuclear states that decay with a "prompt" half life (ordinarily on the order of 10−12 seconds). The term "metastable" is usually restricted to isomers with half-lives of 10−9 seconds or longer. Some references recommend 5 × 10−9 seconds to distinguish the metastable half life from the normal "prompt" gamma-emission half-life. Occasionally the half-lives are far longer than this and can last minutes, hours, or years. For example, the 180m
73
Ta
nuclear isomer survives so long (at least 1015 years) that it has never been observed to decay spontaneously. The half-life of a nuclear isomer can even exceed that of the ground state of the same nuclide, as shown by 180m
73
Ta
as well as 192m2
77
Ir
, 210m
83
Bi
, 242m
95
Am
and multiple holmium isomers.

In physics, induced gamma emission (IGE) refers to the process of fluorescent emission of gamma rays from excited nuclei, usually involving a specific nuclear isomer. It is analogous to conventional fluorescence, which is defined as the emission of a photon by an excited electron in an atom or molecule. In the case of IGE, nuclear isomers can store significant amounts of excitation energy for times long enough for them to serve as nuclear fluorescent materials. There are over 800 known nuclear isomers but almost all are too intrinsically radioactive to be considered for applications. As of 2006 there were two proposed nuclear isomers that appeared to be physically capable of IGE fluorescence in safe arrangements: tantalum-180m and hafnium-178m2.

Thorium (90Th) has seven naturally occurring isotopes but none are stable. One isotope, 232Th, is relatively stable, with a half-life of 1.405×1010 years, considerably longer than the age of the Earth, and even slightly longer than the generally accepted age of the universe. This isotope makes up nearly all natural thorium, so thorium was considered to be mononuclidic. However, in 2013, IUPAC reclassified thorium as binuclidic, due to large amounts of 230Th in deep seawater. Thorium has a characteristic terrestrial isotopic composition and thus a standard atomic weight can be given.

Radium (88Ra) has no stable or nearly stable isotopes, and thus a standard atomic weight cannot be given. The longest lived, and most common, isotope of radium is 226Ra with a half-life of 1600 years. 226Ra occurs in the decay chain of 238U. Radium has 34 known isotopes from 201Ra to 234Ra.

There are 39 known isotopes of radon (86Rn), from 193Rn to 231Rn; all are radioactive. The most stable isotope is 222Rn with a half-life of 3.823 days, which decays into 218
Po
. Six isotopes of radon, 217, 218, 219, 220, 221, 222Rn, occur in trace quantities in nature as decay products of, respectively, 217At, 218At, 223Ra, 224Ra, 225Ra, and 226Ra. 217Rn and 221Rn are produced in rare branches in the decay chain of trace quantities of 237Np; 222Rn is an intermediate step in the decay chain of 238U; 219Rn is an intermediate step in the decay chain of 235U; and 220Rn occurs in the decay chain of 232Th.

Bismuth (83Bi) has 41 known isotopes, ranging from 184Bi to 224Bi. Bismuth has no stable isotopes, but does have one very long-lived isotope; thus, the standard atomic weight can be given as 208.98040(1). Although bismuth-209 is now known to be radioactive, it has classically been considered to be a stable isotope because it has a half-life of approximately 2.01×1019 years, which is more than a billion times the age of the universe. Besides 209Bi, the most stable bismuth radioisotopes are 210mBi with a half-life of 3.04 million years, 208Bi with a half-life of 368,000 years and 207Bi, with a half-life of 32.9 years, none of which occurs in nature. All other isotopes have half-lives under 1 year, most under a day. Of naturally occurring radioisotopes, the most stable is radiogenic 210Bi with a half-life of 5.012 days. 210mBi is unusual for being a nuclear isomer with a half-life multiple orders of magnitude longer than that of the ground state.

There are two natural isotopes of iridium (77Ir), and 37 radioisotopes, the most stable radioisotope being 192Ir with a half-life of 73.83 days, and many nuclear isomers, the most stable of which is 192m2Ir with a half-life of 241 years. All other isomers have half-lives under a year, most under a day. All isotopes of iridium are either radioactive or observationally stable, meaning that they are predicted to be radioactive but no actual decay has been observed.

Naturally occurring rhenium (75Re) is 37.4% 185Re, which is stable (although it is predicted to decay), and 62.6% 187Re, which is unstable but has a very long half-life (4.12×1010 years). Among elements with a known stable isotope, only indium and tellurium similarly occur with a stable isotope in lower abundance than the long-lived radioactive isotope.

Naturally occurring xenon (54Xe) consists of seven stable isotopes and two very long-lived isotopes. Double electron capture has been observed in 124Xe and double beta decay in 136Xe, which are among the longest measured half-lives of all nuclides. The isotopes 126Xe and 134Xe are also predicted to undergo double beta decay, but this has never been observed in these isotopes, so they are considered to be stable. Beyond these stable forms, 32 artificial unstable isotopes and various isomers have been studied, the longest-lived of which is 127Xe with a half-life of 36.345 days. All other isotopes have half-lives less than 12 days, most less than 20 hours. The shortest-lived isotope, 108Xe, has a half-life of 58 μs, and is the heaviest known nuclide with equal numbers of protons and neutrons. Of known isomers, the longest-lived is 131mXe with a half-life of 11.934 days. 129Xe is produced by beta decay of 129I ; 131mXe, 133Xe, 133mXe, and 135Xe are some of the fission products of both 235U and 239Pu, so are used as indicators of nuclear explosions.

There are 39 known isotopes and 17 nuclear isomers of tellurium (52Te), with atomic masses that range from 104 to 142. These are listed in the table below.

Naturally occurring chromium (24Cr) is composed of four stable isotopes; 50Cr, 52Cr, 53Cr, and 54Cr with 52Cr being the most abundant (83.789% natural abundance). 50Cr is suspected of decaying by β+β+ to 50Ti with a half-life of (more than) 1.8×1017 years. Twenty-two radioisotopes, all of which are entirely synthetic, have been characterized, the most stable being 51Cr with a half-life of 27.7 days. All of the remaining radioactive isotopes have half-lives that are less than 24 hours and the majority of these have half-lives that are less than 1 minute. This element also has two meta states, 45mCr, the more stable one, and 59mCr, the least stable isotope or isomer.

Americium (95Am) is an artificial element, and thus a standard atomic weight cannot be given. Like all artificial elements, it has no known stable isotopes. The first isotope to be synthesized was 241Am in 1944. The artificial element decays by ejecting alpha particles. Americium has an atomic number of 95. Despite 243
Am
being an order of magnitude longer lived than 241
Am
, the former is harder to obtain than the latter as more of it is present in spent nuclear fuel.

Curium (96Cm) is an artificial element with an atomic number of 96. Because it is an artificial element, a standard atomic weight cannot be given, and it has no stable isotopes. The first isotope synthesized was 242Cm in 1944, which has 146 neutrons.

Mendelevium (101Md) is a synthetic element, and thus a standard atomic weight cannot be given. Like all artificial elements, it has no stable isotopes. The first isotope to be synthesized was 256Md in 1955. There are 17 known radioisotopes, ranging in atomic mass from 244Md to 260Md, and 5 isomers. The longest-lived isotope is 258Md with a half-life of 51.3 days, and the longest-lived isomer is 258mMd with a half-life of 57 minutes.

Dubnium (105Db) is a synthetic element, thus a standard atomic weight cannot be given. Like all synthetic elements, it has no stable isotopes. The first isotope to be synthesized was 261Db in 1968. Thirteen radioisotopes are known, ranging from 255Db to 270Db, along with one isomer (257mDb); two more isomers have been reported but are unconfirmed. The longest-lived known isotope is 268Db with a half-life of 16 hours.

Seaborgium (106Sg) is a synthetic element and so has no stable isotopes. A standard atomic weight cannot be given. The first isotope to be synthesized was 263Sg in 1974. There are 13 known radioisotopes from 258Sg to 271Sg and 4 known isomers. The longest-lived isotope is 269Sg with a half-life of 14 minutes.

Yrast is a technical term in nuclear physics that refers to a state of a nucleus with a minimum of energy for a given angular momentum. Yr is a Swedish adjective sharing the same root as the English whirl. Yrast is the superlative of yr and can be translated whirlingest, although it literally means "dizziest" or "most bewildered". The yrast levels are vital to understanding reactions, such as off-center heavy ion collisions, that result in high-spin states.

<span class="mw-page-title-main">Even and odd atomic nuclei</span> Nuclear physics classification method

In nuclear physics, properties of a nucleus depend on evenness or oddness of its atomic number Z, neutron number N and, consequently, of their sum, the mass number A. Most importantly, oddness of both Z and N tends to lower the nuclear binding energy, making odd nuclei generally less stable. This effect is not only experimentally observed, but is included in the semi-empirical mass formula and explained by some other nuclear models, such as the nuclear shell model. This difference of nuclear binding energy between neighbouring nuclei, especially of odd-A isobars, has important consequences for beta decay.

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