Isotopes of niobium

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Isotopes of niobium  (41Nb)
Main isotopes [1] Decay
abun­dance half-life (t1/2) mode pro­duct
91Nb synth 680 y ε 91Zr
92Nb trace 3.47×107 y β+ 92Zr
93Nb100% stable
93mNbsynth16.12 yIT 93Nb
94Nbtrace2.04×104 y β− 94Mo
95Nbsynth34.991 dβ− 95Mo
Standard atomic weight Ar°(Nb)

Naturally occurring niobium (41Nb) is composed of one stable isotope (93Nb). The most stable radioisotope is 92Nb with a half-life of 34.7 million years. The next longest-lived niobium isotopes are 94Nb (half-life: 20,300 years) and 91Nb with a half-life of 680 years. There is also a meta state of 93Nb at 31 keV whose half-life is 16.13 years. Twenty-seven other radioisotopes have been characterized. Most of these have half-lives that are less than two hours, except 95Nb (35 days), 96Nb (23.4 hours) and 90Nb (14.6 hours). The primary decay mode before stable 93Nb is electron capture and the primary mode after is beta emission with some neutron emission occurring in 104–110Nb.

Contents

Only 95Nb (35 days) and 97Nb (72 minutes) and heavier isotopes (half-lives in seconds) are fission products in significant quantity, as the other isotopes are shadowed by stable or very long-lived (93Zr) isotopes of the preceding element zirconium from production via beta decay of neutron-rich fission fragments. 95Nb is the decay product of 95Zr (64 days), so disappearance of 95Nb in used nuclear fuel is slower than would be expected from its own 35-day half-life alone. Small amounts of other isotopes may be produced as direct fission products.

List of isotopes

Nuclide
[n 1] 		Z N Isotopic mass (Da)
[n 2] [n 3] 		Half-life
[n 4] 		Decay
mode
[n 5] 		Daughter
isotope
[n 6] [n 7] 		Spin and
parity
[n 8] [n 4] 		Isotopic
abundance
Excitation energy [n 4]
81Nb414080.94903(161)#<44 ns β+, p 80Y3/2−#
p80Zr
β+81Zr
82Nb414181.94313(32)#51(5) msβ+82Zr0+
83Nb414282.93671(34)4.1(3) sβ+83Zr(5/2+)
84Nb414383.93357(32)#9.8(9) sβ+ (>99.9%)84Zr3+
β+, p (<.1%)83Y
84mNb338(10) keV103(19) ns(5−)
85Nb414484.92791(24)20.9(7) sβ+85Zr(9/2+)
85mNb759.0(10) keV12(5) s(1/2−)
86Nb414585.92504(9)88(1) sβ+86Zr(6+)
86mNb250(160)# keV56(8) sβ+86Zrhigh
87Nb414686.92036(7)3.75(9) minβ+87Zr(1/2−)
87mNb3.84(14) keV2.6(1) minβ+87Zr(9/2+)#
88Nb414787.91833(11)14.55(6) minβ+88Zr(8+)
88mNb40(140) keV7.8(1) minβ+88Zr(4−)
89Nb414888.913418(29)2.03(7) hβ+89Zr(9/2+)
89mNb0(30)# keV1.10(3) hβ+89Zr(1/2)−
90Nb414989.911265(5)14.60(5) hβ+90Zr8+
90m1Nb122.370(22) keV63(2) μs6+
90m2Nb124.67(25) keV18.81(6) s IT 90Nb4-
90m3Nb171.10(10) keV<1 μs7+
90m4Nb382.01(25) keV6.19(8) ms1+
90m5Nb1880.21(20) keV472(13) ns(11−)
91Nb415090.906996(4)680(130) a EC (99.98%)91Zr9/2+
β+ (.013%)
91m1Nb104.60(5) keV60.86(22) dIT (93%)91Nb1/2−
EC (7%)91Zr
β+ (.0028%)
91m2Nb2034.35(19) keV3.76(12) μs(17/2−)
92Nb415191.907194(3)3.47(24)×107 aβ+ (99.95%)92Zr(7)+Trace
β− (.05%)92Mo
92m1Nb135.5(4) keV10.15(2) dβ+ [n 9] 92Zr(2)+
92m2Nb225.7(4) keV5.9(2) μs(2)−
92m3Nb2203.3(4) keV167(4) ns(11−)
93Nb415292.9063781(26)Stable9/2+1.0000
93mNb30.77(2) keV16.13(14) aIT93Nb1/2−
94Nb415393.9072839(26)2.03(16)×104 aβ−94Mo(6)+Trace
94mNb40.902(12) keV6.263(4) minIT (99.5%)94Nb3+
β− (.5%)94Mo
95Nb415494.9068358(21)34.991(6) dβ−95Mo9/2+
95mNb235.690(20) keV3.61(3) dIT (94.4%)95Nb1/2−
β− (5.6%)95Mo
96Nb415595.908101(4)23.35(5) hβ−96Mo6+
97Nb415696.9080986(27)72.1(7) minβ−97Mo9/2+
97mNb743.35(3) keV52.7(18) sIT97Nb1/2−
98Nb415797.910328(6)2.86(6) sβ−98Mo1+
98mNb84(4) keV51.3(4) minβ− (99.9%)98Mo(5+)
IT (.1%)98Nb
99Nb415898.911618(14)15.0(2) sβ−99Mo9/2+
99mNb365.29(14) keV2.6(2) minβ− (96.2%)99Mo1/2−
IT (3.8%)99Nb
100Nb415999.914182(28)1.5(2) sβ−100Mo1+
100mNb470(40) keV2.99(11) sβ−100Mo(4+, 5+)
101Nb4160100.915252(20)7.1(3) sβ−101Mo(5/2#)+
102Nb4161101.91804(4)1.3(2) sβ−102Mo1+
102mNb130(50) keV4.3(4) sβ−102Mohigh
103Nb4162102.91914(7)1.5(2) sβ−103Mo(5/2+)
104Nb4163103.92246(11)4.9(3) sβ− (99.94%)104Mo(1+)
β−, n (.06%)103Mo
104mNb220(120) keV940(40) msβ− (99.95%)104Mohigh
β−, n (.05%)103Mo
105Nb4164104.92394(11)2.95(6) sβ− (98.3%)105Mo(5/2+)#
β−, n (1.7%)104Mo
106Nb4165105.92797(21)#920(40) msβ− (95.5%)106Mo2+#
β−, n (4.5%)105Mo
107Nb4166106.93031(43)#300(9) msβ− (94%)107Mo5/2+#
β−, n (6%)106Mo
108Nb4167107.93484(32)#0.193(17) sβ− (93.8%)108Mo(2+)
β−, n (6.2%)107Mo
109Nb4168108.93763(54)#190(30) msβ− (69%)109Mo5/2+#
β−, n (31%)108Mo
110Nb4169109.94244(54)#170(20) msβ− (60%)110Mo2+#
β−, n (40%)109Mo
111Nb4170110.94565(54)#80# ms [>300 ns]5/2+#
112Nb4171111.95083(75)#60# ms [>300 ns]2+#
113Nb4172112.95470(86)#30# ms [>300 ns]5/2+#
114Nb [5] 4173
115Nb [5] 4174
116Nb [6] 4175
117Nb [7] 4176
This table header & footer:
  1. ↑ mNb – Excited nuclear isomer.
  2. ↑ ( ) – Uncertainty (1σ) is given in concise form in parentheses after the corresponding last digits.
  3. ↑ # – Atomic mass marked #: value and uncertainty derived not from purely experimental data, but at least partly from trends from the Mass Surface (TMS).
  4. 1 2 3 # – Values marked # are not purely derived from experimental data, but at least partly from trends of neighboring nuclides (TNN).
  5. ↑ Modes of decay:
    EC: Electron capture
    IT: Isomeric transition
    n: Neutron emission
    p: Proton emission
  6. ↑ Bold italics symbol as daughter – Daughter product is nearly stable.
  7. ↑ Bold symbol as daughter – Daughter product is stable.
  8. ↑ ( ) spin value – Indicates spin with weak assignment arguments.
  9. ↑ Theoretically capable of isomeric transition to 92Nb or β− decay to 92Mo [4]

Niobium-92

Niobium-92 is an extinct radionuclide [8] with a half-life of 34.7 million years, decaying predominantly via β+ decay. Its abundance relative to the stable 93Nb in the early Solar System, estimated at 1.7×10−5, has been measured to investigate the origin of p-nuclei. [8] [9] A higher initial abundance of 92Nb has been estimated for material in the outer protosolar disk (sampled from the meteorite NWA 6704), suggesting that this nuclide was predominantly formed via the gamma process (photodisintegration) in a nearby core-collapse supernova. [10]

Niobium-92, along with niobium-94, has been detected in refined samples of terrestrial niobium and may originate from bombardment by cosmic ray muons in Earth's crust. [11]

Related Research Articles

Natural hafnium (72Hf) consists of five observationally stable isotopes (176Hf, 177Hf, 178Hf, 179Hf, and 180Hf) and one very long-lived radioisotope, 174Hf, with a half-life of 7.0×1016 years. In addition, there are 34 known synthetic radioisotopes, the most stable of which is 182Hf with a half-life of 8.9×106 years. This extinct radionuclide is used in hafnium–tungsten dating to study the chronology of planetary differentiation.

Naturally occurring terbium (65Tb) is composed of one stable isotope, 159Tb. Thirty-seven radioisotopes have been characterized, with the most stable being 158Tb with a half-life of 180 years, 157Tb with a half-life of 71 years, and 160Tb with a half-life of 72.3 days. All of the remaining radioactive isotopes have half-lives that are less than 6.907 days, and the majority of these have half-lives that are less than 24 seconds. This element also has 27 meta states, with the most stable being 156m1Tb, 154m2Tb and 154m1Tb.

Naturally occurring praseodymium (59Pr) is composed of one stable isotope, 141Pr. Thirty-eight radioisotopes have been characterized with the most stable being 143Pr, with a half-life of 13.57 days and 142Pr, with a half-life of 19.12 hours. All of the remaining radioactive isotopes have half-lives that are less than 5.985 hours and the majority of these have half-lives that are less than 33 seconds. This element also has 15 meta states with the most stable being 138mPr, 142mPr and 134mPr.

<span class="mw-page-title-main">Isotopes of lanthanum</span> Nuclides with atomic number of 57 but with different mass numbers

Naturally occurring lanthanum (57La) is composed of one stable (139La) and one radioactive (138La) isotope, with the stable isotope, 139La, being the most abundant (99.91% natural abundance). There are 39 radioisotopes that have been characterized, with the most stable being 138La, with a half-life of 1.02×1011 years; 137La, with a half-life of 60,000 years and 140La, with a half-life of 1.6781 days. The remaining radioactive isotopes have half-lives that are less than a day and the majority of these have half-lives that are less than 1 minute. This element also has 12 nuclear isomers, the longest-lived of which is 132mLa, with a half-life of 24.3 minutes. Lighter isotopes mostly decay to isotopes of barium and heavy ones mostly decay to isotopes of cerium. 138La can decay to both.

Naturally occurring barium (56Ba) is a mix of six stable isotopes and one very long-lived radioactive primordial isotope, barium-130, identified as being unstable by geochemical means (from analysis of the presence of its daughter xenon-130 in rocks) in 2001. This nuclide decays by double electron capture (absorbing two electrons and emitting two neutrinos), with a half-life of (0.5–2.7)×1021 years (about 1011 times the age of the universe).

There are 39 known isotopes and 17 nuclear isomers of tellurium (52Te), with atomic masses that range from 104 to 142. These are listed in the table below.

Antimony (51Sb) occurs in two stable isotopes, 121Sb and 123Sb. There are 35 artificial radioactive isotopes, the longest-lived of which are 125Sb, with a half-life of 2.75856 years; 124Sb, with a half-life of 60.2 days; and 126Sb, with a half-life of 12.35 days. All other isotopes have half-lives less than 4 days, most less than an hour.

Indium (49In) consists of two primordial nuclides, with the most common (~ 95.7%) nuclide (115In) being measurably though weakly radioactive. Its spin-forbidden decay has a half-life of 4.41×1014 years, much longer than the currently accepted age of the Universe.

Naturally occurring cadmium (48Cd) is composed of 8 isotopes. For two of them, natural radioactivity was observed, and three others are predicted to be radioactive but their decays have not been observed, due to extremely long half-lives. The two natural radioactive isotopes are 113Cd (beta decay, half-life is 8.04 × 1015 years) and 116Cd (two-neutrino double beta decay, half-life is 2.8 × 1019 years). The other three are 106Cd, 108Cd (double electron capture), and 114Cd (double beta decay); only lower limits on their half-life times have been set. Three isotopes—110Cd, 111Cd, and 112Cd—are theoretically stable. Among the isotopes absent in natural cadmium, the most long-lived are 109Cd with a half-life of 462.6 days, and 115Cd with a half-life of 53.46 hours. All of the remaining radioactive isotopes have half-lives that are less than 2.5 hours and the majority of these have half-lives that are less than 5 minutes. This element also has 12 known meta states, with the most stable being 113mCd (t1/2 14.1 years), 115mCd (t1/2 44.6 days) and 117mCd (t1/2 3.36 hours).

Natural palladium (46Pd) is composed of six stable isotopes, 102Pd, 104Pd, 105Pd, 106Pd, 108Pd, and 110Pd, although 102Pd and 110Pd are theoretically unstable. The most stable radioisotopes are 107Pd with a half-life of 6.5 million years, 103Pd with a half-life of 17 days, and 100Pd with a half-life of 3.63 days. Twenty-three other radioisotopes have been characterized with atomic weights ranging from 90.949 u (91Pd) to 128.96 u (129Pd). Most of these have half-lives that are less than 30 minutes except 101Pd, 109Pd, and 112Pd.

Technetium (43Tc) is one of the two elements with Z < 83 that have no stable isotopes; the other such element is promethium. It is primarily artificial, with only trace quantities existing in nature produced by spontaneous fission or neutron capture by molybdenum. The first isotopes to be synthesized were 97Tc and 99Tc in 1936, the first artificial element to be produced. The most stable radioisotopes are 97Tc, 98Tc, and 99Tc.

Naturally occurring zirconium (40Zr) is composed of four stable isotopes (of which one may in the future be found radioactive), and one very long-lived radioisotope (96Zr), a primordial nuclide that decays via double beta decay with an observed half-life of 2.0×1019 years; it can also undergo single beta decay, which is not yet observed, but the theoretically predicted value of t1/2 is 2.4×1020 years. The second most stable radioisotope is 93Zr, which has a half-life of 1.53 million years. Thirty other radioisotopes have been observed. All have half-lives less than a day except for 95Zr (64.02 days), 88Zr (83.4 days), and 89Zr (78.41 hours). The primary decay mode is electron capture for isotopes lighter than 92Zr, and the primary mode for heavier isotopes is beta decay.

Natural yttrium (39Y) is composed of a single isotope yttrium-89. The most stable radioisotopes are 88Y, which has a half-life of 106.6 days, and 91Y, with a half-life of 58.51 days. All the other isotopes have half-lives of less than a day, except 87Y, which has a half-life of 79.8 hours, and 90Y, with 64 hours. The dominant decay mode below the stable 89Y is electron capture and the dominant mode after it is beta emission. Thirty-five unstable isotopes have been characterized.

The alkaline earth metal strontium (38Sr) has four stable, naturally occurring isotopes: 84Sr (0.56%), 86Sr (9.86%), 87Sr (7.0%) and 88Sr (82.58%). Its standard atomic weight is 87.62(1).

Rubidium (37Rb) has 36 isotopes, with naturally occurring rubidium being composed of just two isotopes; 85Rb (72.2%) and the radioactive 87Rb (27.8%).

Bromine (35Br) has two stable isotopes, 79Br and 81Br, and 35 known radioisotopes, the most stable of which is 77Br, with a half-life of 57.036 hours.

Arsenic (33As) has 32 known isotopes and at least 10 isomers. Only one of these isotopes, 75As, is stable; as such, it is considered a monoisotopic element. The longest-lived radioisotope is 73As with a half-life of 80 days.

Naturally occurring zinc (30Zn) is composed of the 5 stable isotopes 64Zn, 66Zn, 67Zn, 68Zn, and 70Zn with 64Zn being the most abundant. Twenty-eight radioisotopes have been characterised with the most stable being 65Zn with a half-life of 244.26 days, and then 72Zn with a half-life of 46.5 hours. All of the remaining radioactive isotopes have half-lives that are less than 14 hours and the majority of these have half-lives that are less than 1 second. This element also has 10 meta states.

Naturally occurring chromium (24Cr) is composed of four stable isotopes; 50Cr, 52Cr, 53Cr, and 54Cr with 52Cr being the most abundant (83.789% natural abundance). 50Cr is suspected of decaying by β+β+ to 50Ti with a half-life of (more than) 1.8×1017 years. Twenty-two radioisotopes, all of which are entirely synthetic, have been characterized, the most stable being 51Cr with a half-life of 27.7 days. All of the remaining radioactive isotopes have half-lives that are less than 24 hours and the majority of these have half-lives that are less than 1 minute. This element also has two meta states, 45mCr, the more stable one, and 59mCr, the least stable isotope or isomer.

Naturally occurring vanadium (23V) is composed of one stable isotope 51V and one radioactive isotope 50V with a half-life of 2.71×1017 years. 24 artificial radioisotopes have been characterized (in the range of mass number between 40 and 65) with the most stable being 49V with a half-life of 330 days, and 48V with a half-life of 15.9735 days. All of the remaining radioactive isotopes have half-lives shorter than an hour, the majority of them below 10 seconds, the least stable being 42V with a half-life shorter than 55 nanoseconds, with all of the isotopes lighter than it, and none of the heavier, have unknown half-lives. In 4 isotopes, metastable excited states were found (including 2 metastable states for 60V), which adds up to 5 meta states.

References

  1. ↑ Kondev, F. G.; Wang, M.; Huang, W. J.; Naimi, S.; Audi, G. (2021). "The NUBASE2020 evaluation of nuclear properties" (PDF). Chinese Physics C. 45 (3): 030001. doi:10.1088/1674-1137/abddae.
  2. ↑ "Standard Atomic Weights: Niobium". CIAAW. 2017.
  3. ↑ Prohaska, Thomas; Irrgeher, Johanna; Benefield, Jacqueline; Böhlke, John K.; Chesson, Lesley A.; Coplen, Tyler B.; Ding, Tiping; Dunn, Philip J. H.; Gröning, Manfred; Holden, Norman E.; Meijer, Harro A. J. (2022-05-04). "Standard atomic weights of the elements 2021 (IUPAC Technical Report)". Pure and Applied Chemistry. doi:10.1515/pac-2019-0603. ISSN   1365-3075.
  4. ↑ "Adopted Levels for 92Nb" (PDF). NNDC Chart of Nuclides.
  5. 1 2 Ohnishi, Tetsuya; Kubo, Toshiyuki; Kusaka, Kensuke; et al. (2010). "Identification of 45 New Neutron-Rich Isotopes Produced by In-Flight Fission of a 238U Beam at 345 MeV/nucleon". J. Phys. Soc. Jpn. 79 (7). Physical Society of Japan: 073201. arXiv: 1006.0305 . Bibcode:2010JPSJ...79g3201T. doi: 10.1143/JPSJ.79.073201 .
  6. ↑ Shimizu, Yohei; et al. (2018). "Observation of New Neutron-rich Isotopes among Fission Fragments from In-flight Fission of 345MeV=nucleon 238U: Search for New Isotopes Conducted Concurrently with Decay Measurement Campaigns". Journal of the Physical Society of Japan. 87 (1): 014203. Bibcode:2018JPSJ...87a4203S. doi: 10.7566/JPSJ.87.014203 .
  7. ↑ Sumikama, T.; et al. (2021). "Observation of new neutron-rich isotopes in the vicinity of Zr110". Physical Review C. 103 (1): 014614. Bibcode:2021PhRvC.103a4614S. doi:10.1103/PhysRevC.103.014614. hdl: 10261/260248 . S2CID   234019083.
  8. 1 2 Iizuka, Tsuyoshi; Lai, Yi-Jen; Akram, Waheed; Amelin, Yuri; Schönbächler, Maria (2016). "The initial abundance and distribution of 92Nb in the Solar System". Earth and Planetary Science Letters. 439: 172–181. arXiv: 1602.00966 . Bibcode:2016E&PSL.439..172I. doi:10.1016/j.epsl.2016.02.005. S2CID   119299654.
  9. ↑ Hibiya, Y; Iizuka, T; Enomoto, H (2019). THE INITIAL ABUNDANCE OF NIOBIUM-92 IN THE OUTER SOLAR SYSTEM (PDF). Lunar and Planetary Science Conference (50th ed.). Retrieved 7 September 2019.
  10. ↑ Hibiya, Y.; Iizuka, T.; Enomoto, H.; Hayakawa, T. (2023). "Evidence for enrichment of niobium-92 in the outer protosolar disk". Astrophysical Journal Letters. 942 (L15): L15. Bibcode:2023ApJ...942L..15H. doi: 10.3847/2041-8213/acab5d . S2CID   255414098.
  11. ↑ Clayton, Donald D.; Morgan, John A. (1977). "Muon production of 92,94Nb in the Earth's crust". Nature. 266 (5604): 712–713. doi:10.1038/266712a0. S2CID   4292459.
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