Isotopes of rubidium

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Isotopes of rubidium  (37Rb)
Main isotopes [1] Decay
abun­dance half-life (t1/2) mode pro­duct
82Rb synth 1.2575 m β+ 82Kr
83Rbsynth86.2 d ε 83Kr
γ
84Rbsynth32.9 dε 84Kr
β+84Kr
γ
β 84Sr
85Rb72.2%stable
86Rbsynth18.7 dβ 86Sr
γ
87Rb27.8%4.923×1010 yβ 87Sr
Standard atomic weight Ar°(Rb)

Rubidium (37Rb) has 36 isotopes, with naturally occurring rubidium being composed of just two isotopes; 85Rb (72.2%) and the radioactive 87Rb (27.8%).

Contents

87Rb has a half-life of 4.92×1010 years. It readily substitutes for potassium in minerals, and is therefore fairly widespread. 87Rb has been used extensively in dating rocks; 87Rb decays to stable strontium-87 by emission of a beta particle (an electron ejected from the nucleus). During fractional crystallization, Sr tends to become concentrated in plagioclase, leaving Rb in the liquid phase. Hence, the Rb/Sr ratio in residual magma may increase over time, resulting in rocks with increasing Rb/Sr ratios with increasing differentiation. The highest ratios (10 or higher) occur in pegmatites. If the initial amount of Sr is known or can be extrapolated, the age can be determined by measurement of the Rb and Sr concentrations and the 87Sr/86Sr ratio. The dates indicate the true age of the minerals only if the rocks have not been subsequently altered. See rubidium–strontium dating for a more detailed discussion.

Other than 87Rb, the longest-lived radioisotopes are 83Rb with a half-life of 86.2 days, 84Rb with a half-life of 33.1 days, and 86Rb with a half-life of 18.642 days. All other radioisotopes have half-lives less than a day.

82Rb is used in some cardiac positron emission tomography scans to assess myocardial perfusion. It has a half-life of 1.273 minutes. It does not exist naturally, but can be made from the decay of 82Sr.

List of isotopes


Nuclide
[n 1]
Z N Isotopic mass (Da)
[n 2] [n 3]
Half-life
[n 4] [n 5]
Decay
mode

[n 6]
Daughter
isotope

[n 7] [n 8]
Spin and
parity
[n 9] [n 5]
Natural abundance (mole fraction)
Excitation energy [n 5] Normal proportionRange of variation
71Rb373470.96532(54)# p 70Kr5/2−#
72Rb373571.95908(54)#<1.5 μsp71Kr3+#
72mRb100(100)# keV1# μsp71Kr1−#
73Rb373672.95056(16)#<30 nsp72Kr3/2−#
74Rb373773.944265(4)64.76(3) ms β+ 74Kr(0+)
75Rb373874.938570(8)19.0(12) sβ+75Kr(3/2−)
76Rb373975.9350722(20)36.5(6) sβ+76Kr1(−)
β+, α (3.8×10−7%)72Se
76mRb316.93(8) keV3.050(7) μs(4+)
77Rb374076.930408(8)3.77(4) minβ+77Kr3/2−
78Rb374177.928141(8)17.66(8) minβ+78Kr0(+)
78mRb111.20(10) keV5.74(5) minβ+ (90%)78Kr4(−)
IT (10%)78Rb
79Rb374278.923989(6)22.9(5) minβ+79Kr5/2+
80Rb374379.922519(7)33.4(7) sβ+80Kr1+
80mRb494.4(5) keV1.6(2) μs6+
81Rb374480.918996(6)4.570(4) hβ+81Kr3/2−
81mRb86.31(7) keV30.5(3) minIT (97.6%)81Rb9/2+
β+ (2.4%)81Kr
82 Rb 374581.9182086(30)1.273(2) minβ+82Kr1+
82mRb69.0(15) keV6.472(5) hβ+ (99.67%)82Kr5−
IT (.33%)82Rb
83Rb374682.915110(6)86.2(1) d EC 83Kr5/2−
83mRb42.11(4) keV7.8(7) msIT83Rb9/2+
84Rb374783.914385(3)33.1(1) dβ+ (96.2%)84Kr2−
β (3.8%)84Sr
84mRb463.62(9) keV20.26(4) minIT (>99.9%)84Rb6−
β+ (<.1%)84Kr
85Rb [n 10] 374884.911789738(12)Stable5/2−0.7217(2)
86Rb374985.91116742(21)18.642(18) dβ (99.9948%)86Sr2−
EC (.0052%)86Kr
86mRb556.05(18) keV1.017(3) minIT86Rb6−
87Rb [n 11] [n 12] [n 10] 375086.909180527(13)4.923(22)×1010 yβ87Sr3/2−0.2783(2)
88Rb375187.91131559(17)17.773(11) minβ88Sr2−
89Rb375288.912278(6)15.15(12) minβ89Sr3/2−
90Rb375389.914802(7)158(5) sβ90Sr0−
90mRb106.90(3) keV258(4) sβ (97.4%)90Sr3−
IT (2.6%)90 Rb
91Rb375490.916537(9)58.4(4) sβ91Sr3/2(−)
92Rb375591.919729(7)4.492(20) sβ (99.98%)92Sr0−
β, n (.0107%)91Sr
93Rb375692.922042(8)5.84(2) sβ (98.65%)93Sr5/2−
β, n (1.35%)92Sr
93mRb253.38(3) keV57(15) μs(3/2−,5/2−)
94Rb375793.926405(9)2.702(5) sβ (89.99%)94Sr3(−)
β, n (10.01%)93Sr
95Rb375894.929303(23)377.5(8) msβ (91.27%)95Sr5/2−
β, n (8.73%)94Sr
96Rb375995.93427(3)202.8(33) msβ (86.6%)96Sr2+
β, n (13.4%)95Sr
96mRb0(200)# keV200# ms [>1 ms]β96Sr1(−#)
IT96Rb
β, n95Sr
97Rb376096.93735(3)169.9(7) msβ (74.3%)97Sr3/2+
β, n (25.7%)96Sr
98Rb376197.94179(5)114(5) msβ(86.14%)98Sr(0,1)(−#)
β, n (13.8%)97Sr
β, 2n (.051%)96Sr
98mRb290(130) keV96(3) msβ97Sr(3,4)(+#)
99Rb376298.94538(13)50.3(7) msβ (84.1%)99Sr(5/2+)
β, n (15.9%)98Sr
100Rb376399.94987(32)#51(8) msβ (94.25%)100Sr(3+)
β, n (5.6%)99Sr
β, 2n (.15%)98Sr
101Rb3764100.95320(18)32(5) msβ (69%)101Sr(3/2+)#
β, n (31%)100Sr
102Rb3765101.95887(54)#37(5) msβ (82%)102Sr
β, n (18%)101Sr
103Rb [4] 376626 msβ103Sr
104Rb [5] 376735# ms (>550 ns)β?104Sr
105Rb [6] 3768
106Rb [6] 3769
This table header & footer:
  1. mRb  Excited nuclear isomer.
  2. ()  Uncertainty (1σ) is given in concise form in parentheses after the corresponding last digits.
  3. #  Atomic mass marked #: value and uncertainty derived not from purely experimental data, but at least partly from trends from the Mass Surface (TMS).
  4. Bold half-life  nearly stable, half-life longer than age of universe.
  5. 1 2 3 #  Values marked # are not purely derived from experimental data, but at least partly from trends of neighboring nuclides (TNN).
  6. Modes of decay:
    EC: Electron capture
    IT: Isomeric transition
    n: Neutron emission
    p: Proton emission
  7. Bold italics symbol as daughter  Daughter product is nearly stable.
  8. Bold symbol as daughter  Daughter product is stable.
  9. () spin value  Indicates spin with weak assignment arguments.
  10. 1 2 Fission product
  11. Primordial radionuclide
  12. Used in rubidium–strontium dating

Rubidium-87

Rubidium-87 was the first and the most popular atom for making Bose–Einstein condensates in dilute atomic gases. Even though rubidium-85 is more abundant, rubidium-87 has a positive scattering length, which means it is mutually repulsive, at low temperatures. This prevents a collapse of all but the smallest condensates. It is also easy to evaporatively cool, with a consistent strong mutual scattering. There is also a strong supply of cheap uncoated diode lasers typically used in CD writers, which can operate at the correct wavelength.

Rubidium-87 has an atomic mass of 86.9091835 u, and a binding energy of 757,853 keV. Its atomic percent abundance is 27.835%, and has a half-life of 4.92×1010 years.

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Thallium (81Tl) has 41 isotopes with atomic masses that range from 176 to 216. 203Tl and 205Tl are the only stable isotopes and 204Tl is the most stable radioisotope with a half-life of 3.78 years. 207Tl, with a half-life of 4.77 minutes, has the longest half-life of naturally occurring Tl radioisotopes. All isotopes of thallium are either radioactive or observationally stable, meaning that they are predicted to be radioactive but no actual decay has been observed.

Naturally occurring gadolinium (64Gd) is composed of 6 stable isotopes, 154Gd, 155Gd, 156Gd, 157Gd, 158Gd and 160Gd, and 1 radioisotope, 152Gd, with 158Gd being the most abundant (24.84% natural abundance). The predicted double beta decay of 160Gd has never been observed; only a lower limit on its half-life of more than 1.3×1021 years has been set experimentally.

Promethium (61Pm) is an artificial element, except in trace quantities as a product of spontaneous fission of 238U and 235U and alpha decay of 151Eu, and thus a standard atomic weight cannot be given. Like all artificial elements, it has no stable isotopes. It was first synthesized in 1945.

Naturally occurring praseodymium (59Pr) is composed of one stable isotope, 141Pr. Thirty-eight radioisotopes have been characterized with the most stable being 143Pr, with a half-life of 13.57 days and 142Pr, with a half-life of 19.12 hours. All of the remaining radioactive isotopes have half-lives that are less than 5.985 hours and the majority of these have half-lives that are less than 33 seconds. This element also has 15 meta states with the most stable being 138mPr, 142mPr and 134mPr.

Naturally occurring barium (56Ba) is a mix of six stable isotopes and one very long-lived radioactive primordial isotope, barium-130, identified as being unstable by geochemical means (from analysis of the presence of its daughter xenon-130 in rocks) in 2001. This nuclide decays by double electron capture (absorbing two electrons and emitting two neutrinos), with a half-life of (0.5–2.7)×1021 years (about 1011 times the age of the universe).

There are 39 known isotopes and 17 nuclear isomers of tellurium (52Te), with atomic masses that range from 104 to 142. These are listed in the table below.

Antimony (51Sb) occurs in two stable isotopes, 121Sb and 123Sb. There are 37 artificial radioactive isotopes, the longest-lived of which are 125Sb, with a half-life of 2.75856 years; 124Sb, with a half-life of 60.2 days; and 126Sb, with a half-life of 12.35 days. All other isotopes have half-lives less than 4 days, most less than an hour. There are also many isomers, the longest-lived of which is 120m1Sb with a half-life of 5.76 days.

Tin (50Sn) is the element with the greatest number of stable isotopes. This is probably related to the fact that 50 is a "magic number" of protons. In addition, twenty-nine unstable tin isotopes are known, including tin-100 (100Sn) and tin-132 (132Sn), which are both "doubly magic". The longest-lived tin radioisotope is tin-126 (126Sn), with a half-life of 230,000 years. The other 28 radioisotopes have half-lives of less than a year.

Naturally occurring rhodium (45Rh) is composed of only one stable isotope, 103Rh. The most stable radioisotopes are 101Rh with a half-life of 3.3 years, 102Rh with a half-life of 207 days, and 99Rh with a half-life of 16.1 days. Thirty other radioisotopes have been characterized with atomic weights ranging from 88.949 u (89Rh) to 121.943 u (122Rh). Most of these have half-lives that are less than an hour except 100Rh and 105Rh. There are also numerous meta states with the most stable being 102mRh (0.141 MeV) with a half-life of about 3.7 years and 101mRh (0.157 MeV) with a half-life of 4.34 days.

Naturally occurring ruthenium (44Ru) is composed of seven stable isotopes. Additionally, 27 radioactive isotopes have been discovered. Of these radioisotopes, the most stable are 106Ru, with a half-life of 373.59 days; 103Ru, with a half-life of 39.26 days and 97Ru, with a half-life of 2.9 days.

Naturally occurring niobium (41Nb) is composed of one stable isotope (93Nb). The most stable radioisotope is 92Nb with a half-life of 34.7 million years. The next longest-lived niobium isotopes are 94Nb and 91Nb with a half-life of 680 years. There is also a meta state of 93Nb at 31 keV whose half-life is 16.13 years. Twenty-seven other radioisotopes have been characterized. Most of these have half-lives that are less than two hours, except 95Nb, 96Nb and 90Nb. The primary decay mode before stable 93Nb is electron capture and the primary mode after is beta emission with some neutron emission occurring in 104–110Nb.

Naturally occurring zirconium (40Zr) is composed of four stable isotopes (of which one may in the future be found radioactive), and one very long-lived radioisotope (96Zr), a primordial nuclide that decays via double beta decay with an observed half-life of 2.0×1019 years; it can also undergo single beta decay, which is not yet observed, but the theoretically predicted value of t1/2 is 2.4×1020 years. The second most stable radioisotope is 93Zr, which has a half-life of 1.53 million years. Thirty other radioisotopes have been observed. All have half-lives less than a day except for 95Zr (64.02 days), 88Zr (83.4 days), and 89Zr (78.41 hours). The primary decay mode is electron capture for isotopes lighter than 92Zr, and the primary mode for heavier isotopes is beta decay.

Natural yttrium (39Y) is composed of a single isotope yttrium-89. The most stable radioisotopes are 88Y, which has a half-life of 106.6 days, and 91Y, with a half-life of 58.51 days. All the other isotopes have half-lives of less than a day, except 87Y, which has a half-life of 79.8 hours, and 90Y, with 64 hours. The dominant decay mode below the stable 89Y is electron capture and the dominant mode after it is beta emission. Thirty-five unstable isotopes have been characterized.

The alkaline earth metal strontium (38Sr) has four stable, naturally occurring isotopes: 84Sr (0.56%), 86Sr (9.86%), 87Sr (7.0%) and 88Sr (82.58%). Its standard atomic weight is 87.62(1).

There are 34 known isotopes of krypton (36Kr) with atomic mass numbers from 69 through 102. Naturally occurring krypton is made of five stable isotopes and one which is slightly radioactive with an extremely long half-life, plus traces of radioisotopes that are produced by cosmic rays in the atmosphere.

Arsenic (33As) has 32 known isotopes and at least 10 isomers. Only one of these isotopes, 75As, is stable; as such, it is considered a monoisotopic element. The longest-lived radioisotope is 73As with a half-life of 80 days.

Naturally occurring zinc (30Zn) is composed of the 5 stable isotopes 64Zn, 66Zn, 67Zn, 68Zn, and 70Zn with 64Zn being the most abundant. Twenty-eight radioisotopes have been characterised with the most stable being 65Zn with a half-life of 244.26 days, and then 72Zn with a half-life of 46.5 hours. All of the remaining radioactive isotopes have half-lives that are less than 14 hours and the majority of these have half-lives that are less than 1 second. This element also has 10 meta states.

Naturally occurring vanadium (23V) is composed of one stable isotope 51V and one radioactive isotope 50V with a half-life of 2.71×1017 years. 24 artificial radioisotopes have been characterized (in the range of mass number between 40 and 65) with the most stable being 49V with a half-life of 330 days, and 48V with a half-life of 15.9735 days. All of the remaining radioactive isotopes have half-lives shorter than an hour, the majority of them below 10 seconds, the least stable being 42V with a half-life shorter than 55 nanoseconds, with all of the isotopes lighter than it, and none of the heavier, have unknown half-lives. In 4 isotopes, metastable excited states were found (including 2 metastable states for 60V), which adds up to 5 meta states.

Naturally occurring scandium (21Sc) is composed of one stable isotope, 45Sc. Twenty-seven radioisotopes have been characterized, with the most stable being 46Sc with a half-life of 83.8 days, 47Sc with a half-life of 3.35 days, and 48Sc with a half-life of 43.7 hours and 44Sc with a half-life of 3.97 hours. All the remaining isotopes have half-lives that are less than four hours, and the majority of these have half-lives that are less than two minutes, the least stable being proton unbound 39Sc with a half-life shorter than 300 nanoseconds. This element also has 13 meta states with the most stable being 44m2Sc.

Berkelium (97Bk) is an artificial element, and thus a standard atomic weight cannot be given. Like all artificial elements, it has no stable isotopes. The first isotope to be synthesized was 243Bk in 1949. There are twenty known radioisotopes, from 233Bk and 233Bk to 253Bk, and six nuclear isomers. The longest-lived isotope is 247Bk with a half-life of 1,380 years.

References

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