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34S abundances vary greatly (between 3.96 and 4.77 percent) in natural samples. | ||||||||||||||||||||||||||||||||||||
Standard atomic weight Ar°(S) | ||||||||||||||||||||||||||||||||||||
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Sulfur (16S) has 23 known isotopes with mass numbers ranging from 27 to 49, four of which are stable: 32S (95.02%), 33S (0.75%), 34S (4.21%), and 36S (0.02%). The preponderance of sulfur-32 is explained by its production from carbon-12 plus successive fusion capture of five helium-4 nuclei, in the so-called alpha process of exploding type II supernovas (see silicon burning).
Other than 35S, the radioactive isotopes of sulfur are all comparatively short-lived. 35S is formed from cosmic ray spallation of 40 Ar in the atmosphere. It has a half-life of 87 days. The next longest-lived radioisotope is sulfur-38, with a half-life of 170 minutes. Isotopes lighter than 32S mostly decay to isotopes of phosphorus or silicon, while 35S and heavier radioisotopes decay to isotopes of chlorine.
The beams of several radioactive isotopes (such as those of 44S) have been studied theoretically within the framework of the synthesis of superheavy elements, especially those ones in the vicinity of island of stability. [3] [4]
When sulfide minerals are precipitated, isotopic equilibration among solids and liquid may cause small differences in the δ34S values of co-genetic minerals. The differences between minerals can be used to estimate the temperature of equilibration. The δ13C and δ34S of coexisting carbonates and sulfides can be used to determine the pH and oxygen fugacity of the ore-bearing fluid during ore formation.[ citation needed ]
In most forest ecosystems, sulfate is derived mostly from the atmosphere; weathering of ore minerals and evaporites also contribute some sulfur. Sulfur with a distinctive isotopic composition has been used to identify pollution sources, and enriched sulfur has been added as a tracer in hydrologic studies. Differences in the natural abundances can also be used in systems where there is sufficient variation in the 34S of ecosystem components. Rocky Mountain lakes thought to be dominated by atmospheric sources of sulfate have been found to have different δ34S values from oceans believed to be dominated by watershed sources of sulfate.[ citation needed ]
Nuclide [n 1] | Z | N | Isotopic mass (Da) [5] [n 2] [n 3] | Half-life [6] | Decay mode [6] [n 4] | Daughter isotope [n 5] | Spin and parity [6] [n 6] [n 7] | Natural abundance (mole fraction) | |||||||||||
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Excitation energy | Normal proportion [6] | Range of variation | |||||||||||||||||
27S | 16 | 11 | 27.01878(43)# | 16.3(2) ms | β+, p (61%) | 26Si | (5/2+) | ||||||||||||
β+ (36%) | 27P | ||||||||||||||||||
β+, 2p (3.0%) | 25Al | ||||||||||||||||||
28S | 16 | 12 | 28.00437(17) | 125(10) ms | β+ (79.3%) | 28P | 0+ | ||||||||||||
β+, p (20.7%) | 27Si | ||||||||||||||||||
29S | 16 | 13 | 28.996678(14) | 188(4) ms | β+ (53.6%) | 29P | 5/2+# | ||||||||||||
β+, p (46.4%) | 28Si | ||||||||||||||||||
30S | 16 | 14 | 29.98490677(22) | 1.1798(3) s | β+ | 30P | 0+ | ||||||||||||
31S | 16 | 15 | 30.97955700(25) | 2.5534(18) s | β+ | 31P | 1/2+ | ||||||||||||
32S [n 8] | 16 | 16 | 31.9720711735(14) | Stable | 0+ | 0.9485(255) | |||||||||||||
33S | 16 | 17 | 32.9714589086(14) | Stable | 3/2+ | 0.00763(20) | |||||||||||||
34S | 16 | 18 | 33.967867011(47) | Stable | 0+ | 0.04365(235) | |||||||||||||
35S | 16 | 19 | 34.969032321(43) | 87.37(4) d | β− | 35Cl | 3/2+ | Trace [n 9] | |||||||||||
36S | 16 | 20 | 35.96708069(20) | Stable | 0+ | 1.58(17)×10−4 | |||||||||||||
37S | 16 | 21 | 36.97112550(21) | 5.05(2) min | β− | 37Cl | 7/2− | ||||||||||||
38S | 16 | 22 | 37.9711633(77) | 170.3(7) min | β− | 38Cl | 0+ | ||||||||||||
39S | 16 | 23 | 38.975134(54) | 11.5(5) s | β− | 39Cl | (7/2)− | ||||||||||||
40S | 16 | 24 | 39.9754826(43) | 8.8(22) s | β− | 40Cl | 0+ | ||||||||||||
41S | 16 | 25 | 40.9795935(44) | 1.99(5) s | β− | 41Cl | 7/2−# | ||||||||||||
42S | 16 | 26 | 41.9810651(30) | 1.016(15) s | β− (>96%) | 42Cl | 0+ | ||||||||||||
β−, n (<1%) | 41Cl | ||||||||||||||||||
43S | 16 | 27 | 42.9869076(53) | 265(13) ms | β− (60%) | 43Cl | 3/2− | ||||||||||||
β−, n (40%) | 42Cl | ||||||||||||||||||
43mS | 320.7(5) keV | 415.0(26) ns | IT | 43S | (7/2−) | ||||||||||||||
44S | 16 | 28 | 43.9901188(56) | 100(1) ms | β− (82%) | 44Cl | 0+ | ||||||||||||
β−, n (18%) | 43Cl | ||||||||||||||||||
44mS | 1365.0(8) keV | 2.619(26) μs | IT | 44S | 0+ | ||||||||||||||
45S | 16 | 29 | 44.99641(32)# | 68(2) ms | β−, n (54%) | 44Cl | 3/2−# | ||||||||||||
β− (46%) | 45Cl | ||||||||||||||||||
46S | 16 | 30 | 46.00069(43)# | 50(8) ms | β− | 46Cl | 0+ | ||||||||||||
47S | 16 | 31 | 47.00773(43)# | 24# ms [>200 ns] | 3/2−# | ||||||||||||||
48S | 16 | 32 | 48.01330(54)# | 10# ms [>200 ns] | 0+ | ||||||||||||||
49S | 16 | 33 | 49.02189(63)# | 4# ms [>400 ns] | 1/2−# | ||||||||||||||
This table header & footer: |
IT: | Isomeric transition |
n: | Neutron emission |
p: | Proton emission |
Hydrogen (1H) has three naturally occurring isotopes: 1H, 2H, and 3H. 1H and 2H are stable, while 3H has a half-life of 12.32(2) years. Heavier isotopes also exist; all are synthetic and have a half-life of less than 1 zeptosecond (10−21 s). Of these, 5H is the least stable, while 7H is the most.
Fluorine (9F) has 19 known isotopes ranging from 13
F
to 31
F
and two isomers. Only fluorine-19 is stable and naturally occurring in more than trace quantities; therefore, fluorine is a monoisotopic and mononuclidic element.
Thallium (81Tl) has 41 isotopes with atomic masses that range from 176 to 216. 203Tl and 205Tl are the only stable isotopes and 204Tl is the most stable radioisotope with a half-life of 3.78 years. 207Tl, with a half-life of 4.77 minutes, has the longest half-life of naturally occurring Tl radioisotopes. All isotopes of thallium are either radioactive or observationally stable, meaning that they are predicted to be radioactive but no actual decay has been observed.
There are seven stable isotopes of mercury (80Hg) with 202Hg being the most abundant (29.86%). The longest-lived radioisotopes are 194Hg with a half-life of 444 years, and 203Hg with a half-life of 46.612 days. Most of the remaining 40 radioisotopes have half-lives that are less than a day. 199Hg and 201Hg are the most often studied NMR-active nuclei, having spin quantum numbers of 1/2 and 3/2 respectively. All isotopes of mercury are either radioactive or observationally stable, meaning that they are predicted to be radioactive but no actual decay has been observed. These isotopes are predicted to undergo either alpha decay or double beta decay.
Gold (79Au) has one stable isotope, 197Au, and 40 radioisotopes, with 195Au being the most stable with a half-life of 186 days. Gold is currently considered the heaviest monoisotopic element. Bismuth formerly held that distinction until alpha-decay of the 209Bi isotope was observed. All isotopes of gold are either radioactive or, in the case of 197Au, observationally stable, meaning that 197Au is predicted to be radioactive but no actual decay has been observed.
Naturally occurring platinum (78Pt) consists of five stable isotopes (192Pt, 194Pt, 195Pt, 196Pt, 198Pt) and one very long-lived (half-life 4.83×1011 years) radioisotope (190Pt). There are also 34 known synthetic radioisotopes, the longest-lived of which is 193Pt with a half-life of 50 years. All other isotopes have half-lives under a year, most under a day. All isotopes of platinum are either radioactive or observationally stable, meaning that they are predicted to be radioactive but no actual decay has been observed. Platinum-195 is the most abundant isotope.
There are two natural isotopes of iridium (77Ir), and 37 radioisotopes, the most stable radioisotope being 192Ir with a half-life of 73.83 days, and many nuclear isomers, the most stable of which is 192m2Ir with a half-life of 241 years. All other isomers have half-lives under a year, most under a day. All isotopes of iridium are either radioactive or observationally stable, meaning that they are predicted to be radioactive but no actual decay has been observed.
Naturally occurring erbium (68Er) is composed of six stable isotopes, with 166Er being the most abundant. Thirty-nine radioisotopes have been characterized with between 74 and 112 neutrons, or 142 to 180 nucleons, with the most stable being 169Er with a half-life of 9.4 days, 172Er with a half-life of 49.3 hours, 160Er with a half-life of 28.58 hours, 165Er with a half-life of 10.36 hours, and 171Er with a half-life of 7.516 hours. All of the remaining radioactive isotopes have half-lives that are less than 3.5 hours, and the majority of these have half-lives that are less than 4 minutes. This element also has numerous meta states, with the most stable being 167mEr.
Natural holmium (67Ho) contains one observationally stable isotope, 165Ho. The below table lists 39 isotopes spanning 140Ho through 178Ho as well as 40 nuclear isomers. Among the known synthetic radioactive isotopes; the most stable one is 163Ho, with a half-life of 4,570 years. All other radioisotopes have half-lives not greater than 1.117 days in their ground states, and most have half-lives under 3 hours.
Naturally occurring praseodymium (59Pr) is composed of one stable isotope, 141Pr. Thirty-eight radioisotopes have been characterized with the most stable being 143Pr, with a half-life of 13.57 days and 142Pr, with a half-life of 19.12 hours. All of the remaining radioactive isotopes have half-lives that are less than six hours and the majority of these have half-lives that are less than 33 seconds. This element also has 15 meta states with the most stable being 138mPr, 142mPr and 134mPr.
Naturally occurring silver (47Ag) is composed of the two stable isotopes 107Ag and 109Ag in almost equal proportions, with 107Ag being slightly more abundant. Notably, silver is the only element with all stable istopes having nuclear spins of 1/2. Thus both 107Ag and 109Ag nuclei produce narrow lines in nuclear magnetic resonance spectra.
The alkaline earth metal strontium (38Sr) has four stable, naturally occurring isotopes: 84Sr (0.56%), 86Sr (9.86%), 87Sr (7.0%) and 88Sr (82.58%). Its standard atomic weight is 87.62(1).
Germanium (32Ge) has five naturally occurring isotopes, 70Ge, 72Ge, 73Ge, 74Ge, and 76Ge. Of these, 76Ge is very slightly radioactive, decaying by double beta decay with a half-life of 1.78 × 1021 years (130 billion times the age of the universe).
Naturally occurring vanadium (23V) is composed of one stable isotope 51V and one radioactive isotope 50V with a half-life of 2.71×1017 years. 24 artificial radioisotopes have been characterized (in the range of mass number between 40 and 65) with the most stable being 49V with a half-life of 330 days, and 48V with a half-life of 15.9735 days. All of the remaining radioactive isotopes have half-lives shorter than an hour, the majority of them below 10 seconds, the least stable being 42V with a half-life shorter than 55 nanoseconds, with all of the isotopes lighter than it, and none of the heavier, have unknown half-lives. In 4 isotopes, metastable excited states were found (including 2 metastable states for 60V), which adds up to 5 meta states.
Potassium has 25 known isotopes from 34
K to 57
K as well as 31
K, as well as an unconfirmed report of 59
K. Three of those isotopes occur naturally: the two stable forms 39
K (93.3%) and 41
K (6.7%), and a very long-lived radioisotope 40
K (0.012%)
Although phosphorus (15P) has 22 isotopes from 26P to 47P. Only 31P is stable, thus phosphorus is considered a monoisotopic element. The longest-lived radioactive isotopes are 33P with a half-life of 25.34 days and 32P with a half-life of 14.268 days. All others have half-lives of under 2.5 minutes, most under a second. The least stable known isotope is 47P, with a half-life of 2 milliseconds.
Magnesium (12Mg) naturally occurs in three stable isotopes: 24
Mg, 25
Mg, and 26
Mg. There are 19 radioisotopes that have been discovered, ranging from 18
Mg to 40
Mg. The longest-lived radioisotope is 28
Mg with a half-life of 20.915(9) h. The lighter isotopes mostly decay to isotopes of sodium while the heavier isotopes decay to isotopes of aluminium. The shortest-lived is proton-unbound 18
Mg with a half-life of 4.0(3.4) zeptoseconds.
Natural nitrogen (7N) consists of two stable isotopes: the vast majority (99.6%) of naturally occurring nitrogen is nitrogen-14, with the remainder being nitrogen-15. Thirteen radioisotopes are also known, with atomic masses ranging from 9 to 23, along with three nuclear isomers. All of these radioisotopes are short-lived, the longest-lived being nitrogen-13 with a half-life of 9.965(4) min. All of the others have half-lives below 7.15 seconds, with most of these being below 620 milliseconds. Most of the isotopes with atomic mass numbers below 14 decay to isotopes of carbon, while most of the isotopes with masses above 15 decay to isotopes of oxygen. The shortest-lived known isotope is nitrogen-10, with a half-life of 143(36) yoctoseconds, though the half-life of nitrogen-9 has not been measured exactly.
Fermium (100Fm) is a synthetic element, and thus a standard atomic weight cannot be given. Like all artificial elements, it has no stable isotopes. The first isotope to be discovered was 255Fm in 1952. 250Fm was independently synthesized shortly after the discovery of 255Fm. There are 20 known radioisotopes ranging in atomic mass from 241Fm to 260Fm, and 4 nuclear isomers, 247mFm, 250mFm, 251mFm, and 253mFm. The longest-lived isotope is 257Fm with a half-life of 100.5 days, and the longest-lived isomer is 247mFm with a half-life of 5.1 seconds.
An alpha nuclide is a nuclide that consists of an integer number of alpha particles. Alpha nuclides have equal, even numbers of protons and neutrons; they are important in stellar nucleosynthesis since the energetic environment within stars is amenable to fusion of alpha particles into heavier nuclei. Stable alpha nuclides, and stable decay products of radioactive alpha nuclides, are some of the most common metals in the universe.