Isotopes of francium

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Isotopes of francium  (87Fr)
Main isotopes [1] Decay
abun­dance half-life (t1/2) mode pro­duct
212Fr synth 20.0 min β+ 212Rn
α 208At
221Fr trace 4.801 min α 217At
β 221Ra
222Frsynth14.2 minβ 222Ra
223Frtrace22.00 minβ 223Ra
α 219At

Francium (87Fr) has no stable isotopes, thus a standard atomic weight cannot be given. Its most stable isotope is 223Fr with a half-life of 22 minutes, occurring in trace quantities in nature as an intermediate decay product of 235U.

Of elements whose most stable isotopes have been identified with certainty, francium is the most unstable, though astatine is the rarest in nature due to its naturally occurring isotopes having even shorter half-lives and even smaller branching ratios.

The elements with atomic number of 106 (seaborgium) or greater have their longest known half-life of any isotope shorter than that of francium, but as those elements have only isotopes on the proton-rich side of beta stability discovered, there is a strong possibility that undiscovered isotopes of these elements will have longer half-lives that could exceed that of francium-223.

List of isotopes


Nuclide
[n 1]
Historic
name
Z N Isotopic mass (Da) [2]
[n 2] [n 3]
Half-life [1]
[n 4]
Decay
mode
[1]
[n 5]
Daughter
isotope

Spin and
parity [1]
[n 6] [n 4]
Isotopic
abundance
Excitation energy [n 4]
197Fr87110197.01101(6)2.3(19) msα193At(7/2−)
198Fr87111198.01028(3)15(3) msα194At3+#
198mFr [n 7] 0(50) keV1.1(7) msα194At(10−)
199Fr87112199.007269(15)6.6(22) msα195At1/2+#
199m1Fr45(13) keV6.5(9) msα195At7/2−#
199m2Fr250(50)# keV2.2(12) msα195At13/2+#
200Fr87113200.00658(3)47.5(28) msα196At(3+)
200m1Fr [n 7] 50(60) keV190(120) msα196At10−#
200m2Fr150(50)# keV790(360) ns
201Fr87114201.003852(10)62.8(19) msα197At9/2−
201m1Fr129(10) keV24(6) msα197At1/2+
201m2Fr289.5(4) keV720(40) nsIT201Fr13/2+
202Fr87115202.003330(6)372(12) msα198At3+
202mFr257(6) keV286(13) msα198At10−
IT (?%)202Fr
203Fr87116203.000941(7)550(10) msα199At9/2−
203m1Fr361(6) keV43(4) msIT (80%)203Fr1/2+
α (20%)199At
203m2Fr426.0(10) keV370(50) nsIT203Fr13/2+
204Fr87117204.000652(26)1.75(26) sα (96%)200At3+
β+ (4%)204Rn
204m1Fr50(4) keV2.41(19) sα (90%)200At7+
β+ (10%)204Rn
204m2Fr326(4) keV1.65(15) sα (53%)200At10−
IT (47%)204Fr
205Fr87118204.998594(8)3.90(7) sα (98.5%)201At9/2−
β+ (1.5%)205Rn
205m1Fr544.0(10) keV80(20) nsIT205Fr13/2+
205m2Fr609(6) keV1.15(4) msIT203Fr(1/2+)
206Fr87119205.998661(30)~16 sα (88.4%)202At3+
β+ (11.6%)206Rn
206m1Fr200(40) keV~16 sα (84.7%)202At7+
β+ (?%)206Rn
IT (?%)206Fr
206m2Fr730(40) keV700(100) msIT (87%)206Fr10−
α (13%)202At
207Fr87120206.996941(19)14.8(1) sα (95%)203At9/2−
β+ (5%)207Rn
208Fr87121207.997139(13)59.1(3) sα (89%)204At7+
β+ (11%)208Rn
208mFr826.3(5) keV432(11) nsIT208Fr10−
209Fr87122208.995940(12)50.5(7) sα (89%)205At9/2−
β+ (11%)209Rn
209mFr4659.8(7) keV420(18) nsIT209Fr45/2−
210Fr87123209.996411(14)3.18(6) minα (71%)206At6+
β+ (29%)210Rn
210mFr4417.2(10) keV475(6) nsIT210Fr(23)+
211Fr87124210.995555(13)3.10(2) minα (87%)207At9/2−
β+ (13%)211Rn
211m1Fr2423.16(24) keV146(14) nsIT211Fr29/2+
211m2Fr4657.3(4) keV124.5(12) nsIT211Fr45/2−
212Fr87125211.996225(9)20.0(6) minβ+ (57%)212Rn5+
α (43%)208At
212m1Fr1551.4(3) keV31.9(7) μsIT212Fr11+
212m2Fr2492.2(4) keV604(28) nsIT212Fr15−
212m3Fr5854.7(6) keV312(21) nsIT212Fr27−
212m4Fr8533.4(11) keV23.6(21) μsIT212Fr34+#
213Fr87126212.996184(5)34.14(6) sα (99.44%)209At9/2−
β+ (0.56%)213Rn
213m1Fr1590.41(18) keV505(14) nsIT213Fr21/2−
213m2Fr2537.62(23) keV238(6) nsIT213Fr29/2+
213m3Fr8094.8(7) keV3.1(2) μsIT213Fr(65/2−)
214Fr87127213.998971(9)5.51(13) msα210At(1−)
214m1Fr121(5) keV3.35(5) msα210At(8−)
214m2Fr638(5) keV103(4) nsIT214Fr(11+)
214m3Fr6577(100)# keV108(7) nsIT214Fr(33+)
215Fr87128215.000342(8)90(4) nsα211At9/2−
216Fr87129216.003190(4)700(20) nsα212At(1−)
216mFr219(6) keV850(30) nsα212m1At [3] (9−)
217Fr87130217.004632(7)22(5) μsα213At9/2−
218Fr87131218.007579(5)1.4(5) msα214At1−
218mFr87(4) keV21.9(5) msα214At(8−)
219Fr87132219.009251(7)22.5(17) msα215At9/2−
220Fr87133220.012327(4)27.4(3) sα (99.65%)216At1+
β (0.35%)220Ra
221Fr87134221.014254(5)4.801(5) minα217At5/2−Trace [n 8]
β (0.0048%)221Ra
CD (8.8×10−11%) [n 9] 207Tl
14C
222Fr87135222.017583(8)14.2(3) minβ222Ra2−
223FrActinium K87136223.0197342(21)22.00(7) minβ223Ra3/2−Trace [n 10]
α (0.006%)219At
224Fr87137224.023348(12)3.33(10) minβ224Ra1−
225Fr87138225.025572(13)3.95(14) minβ225Ra3/2−
226Fr87139226.029545(7)48.5(7) sβ226Ra1−
227Fr87140227.031865(6)2.47(3) minβ227Ra1/2+
228Fr87141228.035839(7)38(1) sβ228Ra2−
228mFr1004(30) keV180(110) s
229Fr87142229.038291(5)50.2(4) sβ229Ra(1/2+)
230Fr87143230.042391(7)19.1(5) sβ230Ra2+#
231Fr87144231.045175(8)17.6(6) sβ231Ra(1/2+)
232Fr87145232.049461(15)5.5(6) sβ232Ra(5)
233Fr87146233.052518(21)900(100) msβ233Ra1/2+#
This table header & footer:
  1. mFr  Excited nuclear isomer.
  2. ()  Uncertainty (1σ) is given in concise form in parentheses after the corresponding last digits.
  3. #  Atomic mass marked #: value and uncertainty derived not from purely experimental data, but at least partly from trends from the Mass Surface (TMS).
  4. 1 2 3 #  Values marked # are not purely derived from experimental data, but at least partly from trends of neighboring nuclides (TNN).
  5. Modes of decay:
    α: Alpha decay
    β+: Positron emission
    β: Beta decay
    CD: Cluster decay
    IT: Isomeric transition
  6. () spin value  Indicates spin with weak assignment arguments.
  7. 1 2 Order of ground state and isomer is uncertain.
  8. Intermediate decay product of 237Np
  9. The nuclide with the lowest atomic number known to undergo cluster decay
  10. Intermediate decay product of 235U

References

  1. 1 2 3 4 Kondev, F. G.; Wang, M.; Huang, W. J.; Naimi, S.; Audi, G. (2021). "The NUBASE2020 evaluation of nuclear properties" (PDF). Chinese Physics C. 45 (3): 030001. doi:10.1088/1674-1137/abddae.
  2. Wang, Meng; Huang, W.J.; Kondev, F.G.; Audi, G.; Naimi, S. (2021). "The AME 2020 atomic mass evaluation (II). Tables, graphs and references*". Chinese Physics C. 45 (3): 030003. doi:10.1088/1674-1137/abddaf.
  3. "216Fr α decay (850)" (PDF). NNDC Chart of Nuclides.