Isotopes of rhodium

Last updated

Isotopes of rhodium  (45Rh)
Main isotopes [1] Decay
abun­dance half-life (t1/2) mode pro­duct
99Rh synth 16.1 d β+ 99Ru
101Rhsynth4.07 y ε 101Ru
101mRhsynth4.343 dε 101Ru
IT 101Rh
102Rhsynth207 dβ+ 102Ru
β 102Pd
102mRhsynth3.742 yβ+102Ru
IT102Rh
103Rh100% stable
105Rhsynth35.341 hβ 105Pd
Standard atomic weight Ar°(Rh)

Naturally occurring rhodium (45Rh) is composed of only one stable isotope, 103Rh. [4] The most stable radioisotopes are 101Rh with a half-life of 3.3 years, 102Rh with a half-life of 207 days, and 99Rh with a half-life of 16.1 days. Thirty other radioisotopes have been characterized with atomic weights ranging from 88.949  u (89Rh) to 121.943 u (122Rh). Most of these have half-lives that are less than an hour except 100Rh (half-life: 20.8 hours) and 105Rh (half-life: 35.36 hours). There are also numerous meta states with the most stable being 102mRh (0.141 MeV) with a half-life of about 3.7 years and 101mRh (0.157 MeV) with a half-life of 4.34 days.

The primary decay mode before the only stable isotope, 103Rh, is electron capture and the primary mode after is beta emission. The primary decay product before 103Rh is ruthenium and the primary product after is palladium.

List of isotopes


Nuclide
[n 1]
Z N Isotopic mass (Da) [5]
[n 2] [n 3]
Half-life [1]
[n 4]
Decay
mode
[1]
[n 5]
Daughter
isotope

[n 6]
Spin and
parity [1]
[n 7] [n 4]
Isotopic
abundance
Excitation energy [n 4]
90Rh454589.94457(22)#29(3) ms β+ 90Ru(0+)
β+, p? (<0.7%)89Tc
90mRh [n 8] 0(500)# keV0.56(2) sβ+ (90.4%)90Ru(7+)
β+, p (9.6%)89Tc
91Rh454690.93712(32)#1.47(22) sβ+ (98.7%)91Ru(9/2+)
β+, p (1.3%)90Tc
91mRh172.9(4) keV1.8# sβ+?91Ru1/2−#
β+, p?90Tc
IT?91Rh
92Rh454791.9323677(47)5.61(8) sβ+ (97.95%)92Ru(6+)
β+, p (2.05%)91Tc
92m1Rh50(100)# keV3.18(22) sβ+ (98.3%)92Ru(2+)
β+, p (1.7%)91Tc
92m2Rh105(100)# keV232(15) nsIT92Rh(4+)
93Rh454892.9259128(28)13.9(16) sβ+93Ru9/2+#
94Rh454993.9217305(36)70.6(6) sβ+ (98.2%)94Ru(4+)
β+, p (1.8%)93Tc
94m1Rh54.60(20)# keV480(30) nsIT94Rh(2+)
94m2Rh [n 8] 300(200)# keV25.8(2) sβ+94Ru(8+)
95Rh455094.9158979(42)5.02(10) minβ+95Ru(9/2)+
95mRh543.3(3) keV1.96(4) minIT (88%)95Rh(1/2)−
β+ (12%)95Ru
96Rh455195.914452(11)9.90(10) minβ+96Ru6+
96mRh51.98(9) keV1.51(2) minIT (60%)96Rh3+
β+ (40%)96Ru
97Rh455296.911328(38)30.7(6) minβ+97Ru9/2+
97mRh258.76(18) keV46.2(16) minβ+ (94.4%)97Ru1/2−
IT (5.6%)97Rh
98Rh455397.910708(13)8.72(12) minβ+98Ru(2)+
98mRh [n 8] 56.3(10) keV3.6(2) minIT (89%)98Rh(5+)
β+ (11%)98Ru
99Rh455498.908121(21)16.1(2) dβ+99Ru1/2−
99mRh64.4(5) keV4.7(1) hβ+99Ru9/2+
IT?99Rh
100Rh455599.908114(19)20.8(1) h EC (95.1%)100Ru1−
β+ (4.9%)100Ru
100m1Rh74.782(14) keV214.0(20) nsIT100Rh(2)+
100m2Rh107.6(2) keV4.6(2) minIT (98.3%)100Rh(5+)
β+ (1.7%)100Ru
100m3Rh219.61(22) keV130(10) nsIT100Rh(7+)
101Rh4556100.9061589(63)4.07(5) yEC101Ru1/2−
101mRh157.32(3) keV4.343(10) dEC (92.80%)101Ru9/2+
IT (7.20%)101Rh
102Rh4557101.9068343(69)207.0(15) dβ+ (78%)102Ru2−
β (22%)102Pd
102mRh140.73(9) keV3.742(10) yβ+ (99.77%)102Ru6+
IT (0.233%)102Rh
103Rh [n 9] 4558102.9054941(25)Stable1/2−1.0000
103mRh39.753(6) keV56.114(9) minIT103Rh7/2+
104Rh4559103.9066453(25)42.3(4) sβ (99.55%)104Pd1+
β+ (0.45%)104Ru
104mRh128.9679(5) keV4.34(3) minIT (99.87%)104Rh5+
β (0.13%)104Pd
105Rh [n 9] 4560104.9056878(27)35.341(19) hβ105Pd7/2+
105mRh129.742(4) keV42.8(3) sIT105Rh1/2−
106Rh4561105.9072859(58)30.07(35) sβ106Pd1+
106mRh132(11) keV131(2) minβ106Pd(6)+
107Rh4562106.906748(13)21.7(4) minβ107Pd7/2+
107mRh268.36(4) keV>10 μsIT107Rh1/2−
108Rh4563107.908715(15)16.8(5) sβ108Pd1+
108mRh115(18) keV6.0(3) minβ108Pd(5+)
109Rh4564108.9087496(43)80.8(7) sβ109Pd7/2+
109mRh225.873(19) keV1.66(4) μsIT109Pd3/2+
110Rh4565109.911080(19)3.35(12) sβ110Pd(1+)
110mRh [n 8] 220(150)# keV28.5(13) sβ110Pd(6+)
111Rh4566110.9116432(74)11(1) sβ111Pd(7/2+)
112Rh4567111.914405(47)3.4(4) sβ112Pd(1+)
112mRh340(70) keV6.73(15) sβ112Pd(6+)
113Rh4568112.9154402(77)2.80(12) sβ113Pd(7/2+)
114Rh4569113.918722(77)1.85(5) sβ114Pd1+
114mRh [n 8] 200(150)# keV1.85(5) sβ114Pd(7−)
115Rh4570114.9203116(79)1.03(3) sβ115Pd(7/2+)
β, n?114Pd
116Rh4571115.924062(79)685(39) msβ (>97.9%)116Pd1+
β, n? (<2.1%)115Pd
116mRh [n 8] 200(150)# keV570(50) msβ (>97.9%)116Pd(6−)
β, n? (<2.1%)115Pd
117Rh4572116.9260363(95)421(30) msβ117Pd7/2+#
β, n? (<7.6%)115Pd
117mRh321.2(10) keV138(17) nsIT117Rh3/2+#
118Rh4573117.930341(26)282(9) msβ (96.9%)118Pd1+#
β, n (3.1%)117Pd
118mRh [n 8] 200(150)# keV310(30) msβ (96.9%)118Pd6−#
β, n (3.1%)117Pd
IT?118Rh
119Rh4574118.932557(10)190(6) msβ (93.6%)119Pd7/2+#
β, n (6.4%)118Pd
120Rh4575119.93707(22)#129.6(42) msβ120Pd8−#
β, n (<9.3%)119Pd
β, 2n?118Pd
120mRh157.2(7) keV295(16) nsIT120Rh6#
121Rh4576120.93961(67)74(4) msβ121Pd7/2+#
β, n (>11%)120Pd
122Rh4577121.94431(32)#51(6) msβ122Pd7−#
β, n (<3.9%)121Pd
β, 2n?120Pd
122mRh271.0(7) keV830(120) nsIT122Rh4+#
123Rh4578122.94719(43)#42(4) msβ123Pd7/2+#
β, n (>24%)122Pd
β, 2n?121Pd
124Rh4579123.95200(43)#30(2) msβ124Pd2+#
β, n (<31%)123Pd
β, 2n?122Pd
125Rh4580124.95509(54)#26.5(20) msβ125Pd7/2+#
β, n?124Pd
β, 2n?123Pd
126Rh4581125.96006(54)#19(3) msβ126Pd1−#
β, n?125Pd
β, 2n?124Pd
127Rh4582126.96379(64)#28(14) msβ127Pd7/2+#
β, n?126Pd
β, 2n?125Pd
128Rh4583127.97065(32)#8# ms
[>550 ns]
β?128Pd
β, n?127Pd
β, 2n?126Pd
This table header & footer:
  1. mRh  Excited nuclear isomer.
  2. ()  Uncertainty (1σ) is given in concise form in parentheses after the corresponding last digits.
  3. #  Atomic mass marked #: value and uncertainty derived not from purely experimental data, but at least partly from trends from the Mass Surface (TMS).
  4. 1 2 3 #  Values marked # are not purely derived from experimental data, but at least partly from trends of neighboring nuclides (TNN).
  5. Modes of decay:
    EC: Electron capture
    IT: Isomeric transition
    n: Neutron emission
    p: Proton emission
  6. Bold symbol as daughter  Daughter product is stable.
  7. () spin value  Indicates spin with weak assignment arguments.
  8. 1 2 3 4 5 6 7 Order of ground state and isomer is uncertain.
  9. 1 2 Fission product

References

  1. 1 2 3 4 Kondev, F. G.; Wang, M.; Huang, W. J.; Naimi, S.; Audi, G. (2021). "The NUBASE2020 evaluation of nuclear properties" (PDF). Chinese Physics C. 45 (3): 030001. doi:10.1088/1674-1137/abddae.
  2. "Standard Atomic Weights: Rhodium". CIAAW. 2017.
  3. Prohaska, Thomas; Irrgeher, Johanna; Benefield, Jacqueline; Böhlke, John K.; Chesson, Lesley A.; Coplen, Tyler B.; Ding, Tiping; Dunn, Philip J. H.; Gröning, Manfred; Holden, Norman E.; Meijer, Harro A. J. (2022-05-04). "Standard atomic weights of the elements 2021 (IUPAC Technical Report)". Pure and Applied Chemistry. doi:10.1515/pac-2019-0603. ISSN   1365-3075.
  4. John W. Arblaster (April 2011). "The Discoverers of the Rhodium Isotopes. The thirty-eight known rhodium isotopes found between 1934 and 2010". Platinum Metals Review. 55 (2): 124–134. doi: 10.1595/147106711X555656 .
  5. Wang, Meng; Huang, W.J.; Kondev, F.G.; Audi, G.; Naimi, S. (2021). "The AME 2020 atomic mass evaluation (II). Tables, graphs and references*". Chinese Physics C. 45 (3): 030003. doi:10.1088/1674-1137/abddaf.