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Standard atomic weight Ar°(Se) | ||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||
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Selenium (34Se) has six natural isotopes that occur in significant quantities, along with the trace isotope 79Se, which occurs in minute quantities in uranium ores. Five of these isotopes are stable: 74Se, 76Se, 77Se, 78Se, and 80Se. The last three also occur as fission products, along with 79Se, which has a half-life of 327,000 years, [4] [5] and 82Se, which has a very long half-life (~1020 years, decaying via double beta decay to 82Kr) and for practical purposes can be considered to be stable. There are 23 other unstable isotopes that have been characterized, the longest-lived being 79Se with a half-life 327,000 years, 75Se with a half-life of 120 days, and 72Se with a half-life of 8.40 days. Of the other isotopes, 73Se has the longest half-life, 7.15 hours; most others have half-lives not exceeding 38 seconds.
Nuclide [n 1] | Z | N | Isotopic mass (Da) [6] [n 2] [n 3] | Half-life [1] [n 4] [n 5] | Decay mode [1] [n 6] | Daughter isotope [n 7] | Spin and parity [1] [n 8] [n 5] | Natural abundance (mole fraction) | |||||||||||
---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
Excitation energy | Normal proportion [1] | Range of variation | |||||||||||||||||
63Se | 34 | 29 | 62.98191(54)# | 13.2(39) ms | β+, p (89%) | 62Ge | 3/2−# | ||||||||||||
β+ (11%) | 63As | ||||||||||||||||||
2p? (<0.5%) | 61Ge | ||||||||||||||||||
64Se | 34 | 30 | 63.97117(54)# | 22.6(2) ms | β+? | 64As | 0+ | ||||||||||||
β+, p? | 63Ge | ||||||||||||||||||
65Se | 34 | 31 | 64.96455(32)# | 34.2(7) ms | β+, p (87%) | 64Ge | 3/2−# | ||||||||||||
β+ (13%) | 65As | ||||||||||||||||||
66Se | 34 | 32 | 65.95528(22)# | 54(4) ms | β+ | 66As | 0+ | ||||||||||||
β+, p? | 65Ge | ||||||||||||||||||
67Se | 34 | 33 | 66.949994(72) | 133(4) ms | β+ (99.5%) | 67As | 5/2−# | ||||||||||||
β+, p (0.5%) | 66Ge | ||||||||||||||||||
68Se | 34 | 34 | 67.94182524(53) | 35.5(7) s | β+ | 68As | 0+ | ||||||||||||
69Se | 34 | 35 | 68.9394148(16) | 27.4(2) s | β+ (99.95%) | 69As | 1/2− | ||||||||||||
β+, p (.052%) | 68Ge | ||||||||||||||||||
69m1Se | 38.85(22) keV | 2.0(2) μs | IT | 69Se | 5/2− | ||||||||||||||
69m2Se | 574.0(4) keV | 955(16) ns | IT | 69Se | 9/2+ | ||||||||||||||
70Se | 34 | 36 | 69.9335155(17) | 41.1(3) min | β+ | 70As | 0+ | ||||||||||||
71Se | 34 | 37 | 70.9322094(30) | 4.74(5) min | β+ | 71As | (5/2−) | ||||||||||||
71m1Se | 48.79(5) keV | 5.6(7) μs | IT | 71Se | (1/2−) | ||||||||||||||
71m2Se | 260.48(10) keV | 19.0(5) μs | IT | 71Se | (9/2+) | ||||||||||||||
72Se | 34 | 38 | 71.9271405(21) | 8.40(8) d | EC | 72As | 0+ | ||||||||||||
73Se | 34 | 39 | 72.9267549(80) | 7.15(9) h | β+ | 73As | 9/2+ | ||||||||||||
73mSe | 25.71(4) keV | 39.8(17) min | IT (72.6%) | 73Se | 3/2− | ||||||||||||||
β+ (27.4%) | 73As | ||||||||||||||||||
74Se | 34 | 40 | 73.922475933(15) | Observationally Stable [n 9] | 0+ | 0.0086(3) | |||||||||||||
75Se | 34 | 41 | 74.922522870(78) | 119.78(3) d | EC | 75As | 5/2+ | ||||||||||||
76Se | 34 | 42 | 75.919213702(17) | Stable | 0+ | 0.0923(7) | |||||||||||||
77Se | 34 | 43 | 76.919914150(67) | Stable | 1/2− | 0.0760(7) | |||||||||||||
77mSe | 161.9223(10) keV | 17.36(5) s | IT | 77Se | 7/2+ | ||||||||||||||
78Se | 34 | 44 | 77.91730924(19) | Stable | 0+ | 0.2369 (22) | |||||||||||||
79Se [n 10] | 34 | 45 | 78.91849925(24) | 3.27(28)×105 y | β− | 79Br | 7/2+ | ||||||||||||
79mSe | 95.77(3) keV | 3.900(18) min | IT (99.94%) | 79Se | 1/2− | ||||||||||||||
β− (0.056%) | 79Br | ||||||||||||||||||
80Se | 34 | 46 | 79.9165218(10) | Observationally Stable [n 11] | 0+ | 0.4980(36) | |||||||||||||
81Se | 34 | 47 | 80.9179930(10) | 18.45(12) min | β− | 81Br | 1/2− | ||||||||||||
81mSe | 103.00(6) keV | 57.28(2) min | IT (99.95%) | 81Se | 7/2+ | ||||||||||||||
β− (.051%) | 81Br | ||||||||||||||||||
82Se [n 12] | 34 | 48 | 81.91669953(50) | 8.76(15)×1019 y | β−β− | 82Kr | 0+ | 0.0882(15) | |||||||||||
83Se | 34 | 49 | 82.9191186(33) | 22.25(4) min | β− | 83Br | 9/2+ | ||||||||||||
83mSe | 228.92(7) keV | 70.1(4) s | β− | 83Br | 1/2− | ||||||||||||||
84Se | 34 | 50 | 83.9184668(21) | 3.26(10) min | β− | 84Br | 0+ | ||||||||||||
85Se | 34 | 51 | 84.9222608(28) | 32.9(3) s | β− | 85Br | (5/2)+ | ||||||||||||
86Se | 34 | 52 | 85.9243117(27) | 14.3(3) s | β− | 86Br | 0+ | ||||||||||||
β−, n? | 85Br | ||||||||||||||||||
87Se | 34 | 53 | 86.9286886(24) | 5.50(6) s | β− (99.50%) | 87Br | (3/2+) | ||||||||||||
β−, n (0.60%) | 86Br | ||||||||||||||||||
88Se | 34 | 54 | 87.9314175(36) | 1.53(6) s | β− (99.01%) | 88Br | 0+ | ||||||||||||
β−, n (0.99%) | 87Br | ||||||||||||||||||
89Se | 34 | 55 | 88.9366691(40) | 430(50) ms | β− (92.2%) | 89Br | 5/2+# | ||||||||||||
β−, n (7.8%) | 88Br | ||||||||||||||||||
90Se | 34 | 56 | 89.94010(35) | 210(80) ms | β− | 90Br | 0+ | ||||||||||||
β−, n? | 89Br | ||||||||||||||||||
91Se | 34 | 57 | 90.94570(47) | 270(50) ms | β− (79%) | 91Br | 1/2+# | ||||||||||||
β−, n (21%) | 90Br | ||||||||||||||||||
β−, 2n? | 89Br | ||||||||||||||||||
92Se | 34 | 58 | 91.94984(43)# | 90# ms [>300 ns] | β−? | 92Br | 0+ | ||||||||||||
β−, n? | 91Br | ||||||||||||||||||
β−, 2n? | 90Br | ||||||||||||||||||
92mSe | 3072(2) keV | 15.7(7) μs | IT | 92Se | (9−) | ||||||||||||||
93Se | 34 | 59 | 92.95614(43)# | 130# ms [>300 ns] | β−? | 93Br | 1/2+# | ||||||||||||
β−, n? | 92Br | ||||||||||||||||||
β−, 2n? | 91Br | ||||||||||||||||||
93mSe | 678.2(7) keV | 420(100) ns | IT | 93Se | |||||||||||||||
94Se | 34 | 60 | 93.96049(54)# | 50# ms [>300 ns] | β−? | 94Br | 0+ | ||||||||||||
β−, n? | 93Br | ||||||||||||||||||
β−, 2n? | 92Br | ||||||||||||||||||
94mSe | 2430.0(6) keV | 680(50) ns | IT | 94Se | (7−) | ||||||||||||||
95Se | 34 | 61 | 94.96730(54)# | 70# ms [>400 ns] | β−? | 95Br | 3/2+# | ||||||||||||
β−, n? | 94Br | ||||||||||||||||||
β−, 2n? | 93Br | ||||||||||||||||||
96Se [7] | 34 | 62 | |||||||||||||||||
97Se [7] | 34 | 63 | |||||||||||||||||
This table header & footer: |
EC: | Electron capture |
IT: | Isomeric transition |
n: | Neutron emission |
p: | Proton emission |
The isotope selenium-75 has radiopharmaceutical uses. For example, it is used in high-dose-rate endorectal brachytherapy, as an alternative to iridium-192. [8]
In paleobiogeochemistry, the ratio in amount of selenium-82 to selenium-76 (i.e, the value of δ82/76Se) can be used to track down the redox conditions on Earth during the Neoproterozoic era in order to gain a deeper understanding of the rapid oxygenation that trigger the emergence of complex organisms. [9] [10]
Protactinium (91Pa) has no stable isotopes. The four naturally occurring isotopes allow a standard atomic weight to be given.
Thallium (81Tl) has 41 isotopes with atomic masses that range from 176 to 216. 203Tl and 205Tl are the only stable isotopes and 204Tl is the most stable radioisotope with a half-life of 3.78 years. 207Tl, with a half-life of 4.77 minutes, has the longest half-life of naturally occurring Tl radioisotopes. All isotopes of thallium are either radioactive or observationally stable, meaning that they are predicted to be radioactive but no actual decay has been observed.
Naturally occurring tungsten (74W) consists of five isotopes. Four are considered stable (182W, 183W, 184W, and 186W) and one is slightly radioactive, 180W, with an extremely long half-life of 1.8 ± 0.2 exayears (1018 years). On average, two alpha decays of 180W occur per gram of natural tungsten per year, so for most practical purposes, 180W can be considered stable. Theoretically, all five can decay into isotopes of element 72 (hafnium) by alpha emission, but only 180W has been observed to do so. The other naturally occurring isotopes have not been observed to decay (they are observationally stable), and lower bounds for their half-lives have been established:
Naturally occurring gadolinium (64Gd) is composed of 6 stable isotopes, 154Gd, 155Gd, 156Gd, 157Gd, 158Gd and 160Gd, and 1 radioisotope, 152Gd, with 158Gd being the most abundant (24.84% natural abundance). The predicted double beta decay of 160Gd has never been observed; only a lower limit on its half-life of more than 1.3×1021 years has been set experimentally.
Naturally occurring europium (63Eu) is composed of two isotopes, 151Eu and 153Eu, with 153Eu being the most abundant (52.2% natural abundance). While 153Eu is observationally stable (theoretically can undergo alpha decay with half-life over 5.5×1017 years), 151Eu was found in 2007 to be unstable and undergo alpha decay. The half-life is measured to be (4.62 ± 0.95(stat.) ± 0.68(syst.)) × 1018 years which corresponds to 1 alpha decay per two minutes in every kilogram of natural europium. Besides the natural radioisotope 151Eu, 36 artificial radioisotopes have been characterized, with the most stable being 150Eu with a half-life of 36.9 years, 152Eu with a half-life of 13.516 years, 154Eu with a half-life of 8.593 years, and 155Eu with a half-life of 4.7612 years. The majority of the remaining radioactive isotopes, which range from 130Eu to 170Eu, have half-lives that are less than 12.2 seconds. This element also has 18 metastable isomers, with the most stable being 150mEu (t1/2 12.8 hours), 152m1Eu (t1/2 9.3116 hours) and 152m5Eu (t1/2 96 minutes).
Naturally occurring neodymium (60Nd) is composed of 5 stable isotopes, 142Nd, 143Nd, 145Nd, 146Nd and 148Nd, with 142Nd being the most abundant (27.2% natural abundance), and 2 long-lived radioisotopes, 144Nd and 150Nd. In all, 33 radioisotopes of neodymium have been characterized up to now, with the most stable being naturally occurring isotopes 144Nd (alpha decay, a half-life (t1/2) of 2.29×1015 years) and 150Nd (double beta decay, t1/2 of 7×1018 years), and for practical purposes they can be considered to be stable as well. All of the remaining radioactive isotopes have half-lives that are less than 12 days, and the majority of these have half-lives that are less than 70 seconds; the most stable artificial isotope is 147Nd with a half-life of 10.98 days. This element also has 13 known meta states with the most stable being 139mNd (t1/2 5.5 hours), 135mNd (t1/2 5.5 minutes) and 133m1Nd (t1/2 ~70 seconds).
Naturally occurring cerium (58Ce) is composed of 4 stable isotopes: 136Ce, 138Ce, 140Ce, and 142Ce, with 140Ce being the most abundant and the only one theoretically stable; 136Ce, 138Ce, and 142Ce are predicted to undergo double beta decay but this process has never been observed. There are 35 radioisotopes that have been characterized, with the most stable being 144Ce, with a half-life of 284.893 days; 139Ce, with a half-life of 137.640 days and 141Ce, with a half-life of 32.501 days. All of the remaining radioactive isotopes have half-lives that are less than 4 days and the majority of these have half-lives that are less than 10 minutes. This element also has 10 meta states.
Naturally occurring lanthanum (57La) is composed of one stable (139La) and one radioactive (138La) isotope, with the stable isotope, 139La, being the most abundant (99.91% natural abundance). There are 39 radioisotopes that have been characterized, with the most stable being 138La, with a half-life of 1.02×1011 years; 137La, with a half-life of 60,000 years and 140La, with a half-life of 1.6781 days. The remaining radioactive isotopes have half-lives that are less than a day and the majority of these have half-lives that are less than 1 minute. This element also has 12 nuclear isomers, the longest-lived of which is 132mLa, with a half-life of 24.3 minutes. Lighter isotopes mostly decay to isotopes of barium and heavy ones mostly decay to isotopes of cerium. 138La can decay to both.
Naturally occurring barium (56Ba) is a mix of six stable isotopes and one very long-lived radioactive primordial isotope, barium-130, identified as being unstable by geochemical means (from analysis of the presence of its daughter xenon-130 in rocks) in 2001. This nuclide decays by double electron capture (absorbing two electrons and emitting two neutrinos), with a half-life of (0.5–2.7)×1021 years (about 1011 times the age of the universe).
Naturally occurring xenon (54Xe) consists of seven stable isotopes and two very long-lived isotopes. Double electron capture has been observed in 124Xe and double beta decay in 136Xe, which are among the longest measured half-lives of all nuclides. The isotopes 126Xe and 134Xe are also predicted to undergo double beta decay, but this process has never been observed in these isotopes, so they are considered to be stable. Beyond these stable forms, 32 artificial unstable isotopes and various isomers have been studied, the longest-lived of which is 127Xe with a half-life of 36.345 days. All other isotopes have half-lives less than 12 days, most less than 20 hours. The shortest-lived isotope, 108Xe, has a half-life of 58 μs, and is the heaviest known nuclide with equal numbers of protons and neutrons. Of known isomers, the longest-lived is 131mXe with a half-life of 11.934 days. 129Xe is produced by beta decay of 129I ; 131mXe, 133Xe, 133mXe, and 135Xe are some of the fission products of both 235U and 239Pu, so are used as indicators of nuclear explosions.
Tin (50Sn) is the element with the greatest number of stable isotopes. This is probably related to the fact that 50 is a "magic number" of protons. In addition, twenty-nine unstable tin isotopes are known, including tin-100 (100Sn) and tin-132 (132Sn), which are both "doubly magic". The longest-lived tin radioisotope is tin-126 (126Sn), with a half-life of 230,000 years. The other 28 radioisotopes have half-lives of less than a year.
Natural palladium (46Pd) is composed of six stable isotopes, 102Pd, 104Pd, 105Pd, 106Pd, 108Pd, and 110Pd, although 102Pd and 110Pd are theoretically unstable. The most stable radioisotopes are 107Pd with a half-life of 6.5 million years, 103Pd with a half-life of 17 days, and 100Pd with a half-life of 3.63 days. Twenty-three other radioisotopes have been characterized with atomic weights ranging from 90.949 u (91Pd) to 128.96 u (129Pd). Most of these have half-lives that are less than 30 minutes except 101Pd, 109Pd, and 112Pd.
Naturally occurring ruthenium (44Ru) is composed of seven stable isotopes. Additionally, 27 radioactive isotopes have been discovered. Of these radioisotopes, the most stable are 106Ru, with a half-life of 373.59 days; 103Ru, with a half-life of 39.26 days and 97Ru, with a half-life of 2.9 days.
Naturally occurring niobium (41Nb) is composed of one stable isotope (93Nb). The most stable radioisotope is 92Nb with a half-life of 34.7 million years. The next longest-lived niobium isotopes are 94Nb and 91Nb with a half-life of 680 years. There is also a meta state of 93Nb at 31 keV whose half-life is 16.13 years. Twenty-seven other radioisotopes have been characterized. Most of these have half-lives that are less than two hours, except 95Nb, 96Nb and 90Nb. The primary decay mode before stable 93Nb is electron capture and the primary mode after is beta emission with some neutron emission occurring in 104–110Nb.
Naturally occurring zirconium (40Zr) is composed of four stable isotopes (of which one may in the future be found radioactive), and one very long-lived radioisotope (96Zr), a primordial nuclide that decays via double beta decay with an observed half-life of 2.0×1019 years; it can also undergo single beta decay, which is not yet observed, but the theoretically predicted value of t1/2 is 2.4×1020 years. The second most stable radioisotope is 93Zr, which has a half-life of 1.53 million years. Thirty other radioisotopes have been observed. All have half-lives less than a day except for 95Zr (64.02 days), 88Zr (83.4 days), and 89Zr (78.41 hours). The primary decay mode is electron capture for isotopes lighter than 92Zr, and the primary mode for heavier isotopes is beta decay.
The alkaline earth metal strontium (38Sr) has four stable, naturally occurring isotopes: 84Sr (0.56%), 86Sr (9.86%), 87Sr (7.0%) and 88Sr (82.58%). Its standard atomic weight is 87.62(1).
Bromine (35Br) has two stable isotopes, 79Br and 81Br, and 35 known radioisotopes, the most stable of which is 77Br, with a half-life of 57.036 hours.
Arsenic (33As) has 32 known isotopes and at least 10 isomers. Only one of these isotopes, 75As, is stable; as such, it is considered a monoisotopic element. The longest-lived radioisotope is 73As with a half-life of 80 days.
Copper (29Cu) has two stable isotopes, 63Cu and 65Cu, along with 28 radioisotopes. The most stable radioisotope is 67Cu with a half-life of 61.83 hours. Most of the others have half-lives under a minute. Unstable copper isotopes with atomic masses below 63 tend to undergo β+ decay, while isotopes with atomic masses above 65 tend to undergo β− decay. 64Cu decays by both β+ and β−.
Naturally occurring scandium (21Sc) is composed of one stable isotope, 45Sc. Twenty-seven radioisotopes have been characterized, with the most stable being 46Sc with a half-life of 83.8 days, 47Sc with a half-life of 3.35 days, and 48Sc with a half-life of 43.7 hours and 44Sc with a half-life of 3.97 hours. All the remaining isotopes have half-lives that are less than four hours, and the majority of these have half-lives that are less than two minutes, the least stable being proton unbound 39Sc with a half-life shorter than 300 nanoseconds. This element also has 13 meta states with the most stable being 44m2Sc.