| ||||||||||||||||||||||||||||||||||||
Standard atomic weight Ar°(Si) | ||||||||||||||||||||||||||||||||||||
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Silicon (14Si) has 23 known isotopes, with mass numbers ranging from 22 to 44. 28Si (the most abundant isotope, at 92.23%), 29Si (4.67%), and 30Si (3.1%) are stable. The longest-lived radioisotope is 32Si, which is produced by cosmic ray spallation of argon. Its half-life has been determined to be approximately 150 years (with decay energy 0.21 MeV), and it decays by beta emission to 32 P (which has a 14.27-day half-life) [1] and then to 32 S. After 32Si, 31Si has the second longest half-life at 157.3 minutes. All others have half-lives under 7 seconds.
Nuclide [n 1] | Z | N | Isotopic mass (Da) [4] [n 2] [n 3] | Half-life [1] [n 4] | Decay mode [1] [n 5] | Daughter isotope [n 6] | Spin and parity [1] [n 7] [n 4] | Natural abundance (mole fraction) | |||||||||||
---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
Excitation energy | Normal proportion [1] | Range of variation | |||||||||||||||||
22Si | 14 | 8 | 22.03611(54)# | 28.7(11) ms | β+, p (62%) | 21Mg | 0+ | ||||||||||||
β+ (37%) | 22Al | ||||||||||||||||||
β+, 2p (0.7%) | 20Na | ||||||||||||||||||
23Si | 14 | 9 | 23.02571(54)# | 42.3(4) ms | β+, p (88%) | 22Mg | 3/2+# | ||||||||||||
β+ (8%) | 23Al | ||||||||||||||||||
β+, 2p (3.6%) | 21Na | ||||||||||||||||||
24Si | 14 | 10 | 24.011535(21) | 143.2 (21) ms | β+ (65.5%) | 24Al | 0+ | ||||||||||||
β+, p (34.5%) | 23Mg | ||||||||||||||||||
25Si | 14 | 11 | 25.004109(11) | 220.6(10) ms | β+ (65%) | 25Al | 5/2+ | ||||||||||||
β+, p (35%) | 24Mg | ||||||||||||||||||
26Si | 14 | 12 | 25.99233382(12) | 2.2453(7) s | β+ | 26Al | 0+ | ||||||||||||
27Si | 14 | 13 | 26.98670469(12) | 4.117(14) s | β+ | 27Al | 5/2+ | ||||||||||||
28Si | 14 | 14 | 27.97692653442(55) | Stable | 0+ | 0.92223(19) | 0.92205–0.92241 | ||||||||||||
29Si | 14 | 15 | 28.97649466434(60) | Stable | 1/2+ | 0.04685(8) | 0.04678–0.04692 | ||||||||||||
30Si | 14 | 16 | 29.973770137(23) | Stable | 0+ | 0.03092(11) | 0.03082–0.03102 | ||||||||||||
31Si | 14 | 17 | 30.975363196(46) | 157.16(20) min | β− | 31P | 3/2+ | ||||||||||||
32Si | 14 | 18 | 31.97415154(32) | 157(7) y | β− | 32P | 0+ | trace | cosmogenic | ||||||||||
33Si | 14 | 19 | 32.97797696(75) | 6.18(18) s | β− | 33P | 3/2+ | ||||||||||||
34Si | 14 | 20 | 33.97853805(86) | 2.77(20) s | β− | 34P | 0+ | ||||||||||||
34mSi | 4256.1(4) keV | <210 ns | IT | 34Si | (3−) | ||||||||||||||
35Si | 14 | 21 | 34.984550(38) | 780(120) ms | β− | 35P | 7/2−# | ||||||||||||
β−, n? | 34P | ||||||||||||||||||
36Si | 14 | 22 | 35.986649(77) | 503(2) ms | β− (88%) | 36P | 0+ | ||||||||||||
β−, n (12%) | 35P | ||||||||||||||||||
37Si | 14 | 23 | 36.99295(12) | 141.0(35) ms | β− (83%) | 37P | (5/2−) | ||||||||||||
β−, n (17%) | 36P | ||||||||||||||||||
β−, 2n? | 35P | ||||||||||||||||||
38Si | 14 | 24 | 37.99552(11) | 63(8) ms | β− (75%) | 38P | 0+ | ||||||||||||
β−, n (25%) | 37P | ||||||||||||||||||
39Si | 14 | 25 | 39.00249(15) | 41.2(41) ms | β− (67%) | 39P | (5/2−) | ||||||||||||
β−, n (33%) | 38P | ||||||||||||||||||
β−, 2n? | 37P | ||||||||||||||||||
40Si | 14 | 26 | 40.00608(13) | 31.2(26) ms | β− (62%) | 40P | 0+ | ||||||||||||
β−, n (38%) | 39P | ||||||||||||||||||
β−, 2n? | 38P | ||||||||||||||||||
41Si | 14 | 27 | 41.01417(32)# | 20.0(25) ms | β−, n (>55%) | 40P | 7/2−# | ||||||||||||
β− (<45%) | 41P | ||||||||||||||||||
β−, 2n? | 39P | ||||||||||||||||||
42Si | 14 | 28 | 42.01808(32)# | 15.5(4 (stat), 16 (sys)) ms [5] | β− (51%) | 42P | 0+ | ||||||||||||
β−, n (48%) | 41P | ||||||||||||||||||
β−, 2n (1%) | 40P | ||||||||||||||||||
43Si | 14 | 29 | 43.02612(43)# | 13(4 (stat), 2 (sys)) ms [5] | β−, n (52%) | 42P | 3/2−# | ||||||||||||
β− (27%) | 43P | ||||||||||||||||||
β−, 2n (21%) | 41P | ||||||||||||||||||
44Si | 14 | 30 | 44.03147(54)# | 4# ms [>360 ns] | β−? | 44P | 0+ | ||||||||||||
β−, n? | 43P | ||||||||||||||||||
β−, 2n? | 42P | ||||||||||||||||||
This table header & footer: |
IT: | Isomeric transition |
n: | Neutron emission |
p: | Proton emission |
Silicon-28, the most abundant isotope of silicon, is of particular interest in the construction of quantum computers when highly enriched, as the presence of 29Si in a sample of silicon contributes to quantum decoherence. [6] Extremely pure (>99.9998%) samples of 28Si can be produced through selective ionization and deposition of 28Si from silane gas. [7] Due to the extremely high purity that can be obtained in this manner, the Avogadro project sought to develop a new definition of the kilogram by making a 93.75 mm (3.691 in) sphere of the isotope and determing the exact number of atoms in the sample. [8] [9]
Silicon-28 is produced in stars during the alpha process and the oxygen-burning process, and drives the silicon-burning process in massive stars shortly before they go supernova. [10] [11]
Silicon-29 is of note as the only stable silicon isotope with a nuclear spin (I = 1/2). [12] As such, it can be employed in nuclear magnetic resonance and hyperfine transition studies, for example to study the properties of the so-called A-center defect in pure silicon. [13]
Silicon-34 is a radioactive isotope wth a half-life of 2.8 seconds. [1] In addition to the usual N = 20 closed shell, the nucleus also shows a strong Z = 14 shell closure, making it behave like a doubly magic spherical nucleus, except that it is also located two protons above an island of inversion. [14] Silicon-34 has an unusual "bubble" structure where the proton distribution is less dense at the center than near the surface, as the 2s1/2 proton orbital is almost unoccupied in the ground state, unlike in 36S where it is almost full. [15] [16] Silicon-34 is one of the known cluster decay emission particles; it is produced in the decay of 242Cm with a branching ratio of approximately 1×10−16. [17]
Alpha decay or α-decay is a type of radioactive decay in which an atomic nucleus emits an alpha particle and thereby transforms or 'decays' into a different atomic nucleus, with a mass number that is reduced by four and an atomic number that is reduced by two. An alpha particle is identical to the nucleus of a helium-4 atom, which consists of two protons and two neutrons. It has a charge of +2 e and a mass of 4 Da. For example, uranium-238 decays to form thorium-234.
In nuclear physics, beta decay (β-decay) is a type of radioactive decay in which an atomic nucleus emits a beta particle, transforming into an isobar of that nuclide. For example, beta decay of a neutron transforms it into a proton by the emission of an electron accompanied by an antineutrino; or, conversely a proton is converted into a neutron by the emission of a positron with a neutrino in so-called positron emission. Neither the beta particle nor its associated (anti-)neutrino exist within the nucleus prior to beta decay, but are created in the decay process. By this process, unstable atoms obtain a more stable ratio of protons to neutrons. The probability of a nuclide decaying due to beta and other forms of decay is determined by its nuclear binding energy. The binding energies of all existing nuclides form what is called the nuclear band or valley of stability. For either electron or positron emission to be energetically possible, the energy release or Q value must be positive.
The neutron is a subatomic particle, symbol
n
or
n0
, which has a neutral charge, and a mass slightly greater than that of a proton. Protons and neutrons constitute the nuclei of atoms. Since protons and neutrons behave similarly within the nucleus, they are both referred to as nucleons. Nucleons have a mass of approximately one atomic mass unit, or dalton, symbol Da. Their properties and interactions are described by nuclear physics. Protons and neutrons are not elementary particles; each is composed of three quarks.
A proton is a stable subatomic particle, symbol
p
, H+, or 1H+ with a positive electric charge of +1 e (elementary charge). Its mass is slightly less than the mass of a neutron and 1,836 times the mass of an electron (the proton-to-electron mass ratio). Protons and neutrons, each with masses of approximately one atomic mass unit, are jointly referred to as "nucleons" (particles present in atomic nuclei).
Nihonium is a synthetic chemical element; it has symbol Nh and atomic number 113. It is extremely radioactive: its most stable known isotope, nihonium-286, has a half-life of about 10 seconds. In the periodic table, nihonium is a transactinide element in the p-block. It is a member of period 7 and group 13.
Hydrogen (1H) has three naturally occurring isotopes, sometimes denoted 1
H
, 2
H
, and 3
H
. 1
H
and 2
H
are stable, while 3
H
has a half-life of 12.32(2) years. Heavier isotopes also exist, all of which are synthetic and have a half-life of less than one zeptosecond (10−21 s). Of these, 5
H
is the least stable, while 7
H
is the most.
Cluster decay, also named heavy particle radioactivity, heavy ion radioactivity or heavy cluster decay, is a rare type of nuclear decay in which an atomic nucleus emits a small "cluster" of neutrons and protons, more than in an alpha particle, but less than a typical binary fission fragment. Ternary fission into three fragments also produces products in the cluster size. The loss of protons from the parent nucleus changes it to the nucleus of a different element, the daughter, with a mass number Ad = A − Ae and atomic number Zd = Z − Ze, where Ae = Ne + Ze. For example:
Naturally occurring lithium (3Li) is composed of two stable isotopes, lithium-6 and lithium-7, with the latter being far more abundant on Earth. Both of the natural isotopes have an unexpectedly low nuclear binding energy per nucleon when compared with the adjacent lighter and heavier elements, helium and beryllium. The longest-lived radioisotope of lithium is lithium-8, which has a half-life of just 838.7(3) milliseconds. Lithium-9 has a half-life of 178.2(4) ms, and lithium-11 has a half-life of 8.75(6) ms. All of the remaining isotopes of lithium have half-lives that are shorter than 10 nanoseconds. The shortest-lived known isotope of lithium is lithium-4, which decays by proton emission with a half-life of about 91(9) yoctoseconds, although the half-life of lithium-3 is yet to be determined, and is likely to be much shorter, like helium-2 (diproton) which undergoes proton emission within 10−9 s.
Lead (82Pb) has four observationally stable isotopes: 204Pb, 206Pb, 207Pb, 208Pb. Lead-204 is entirely a primordial nuclide and is not a radiogenic nuclide. The three isotopes lead-206, lead-207, and lead-208 represent the ends of three decay chains: the uranium series, the actinium series, and the thorium series, respectively; a fourth decay chain, the neptunium series, terminates with the thallium isotope 205Tl. The three series terminating in lead represent the decay chain products of long-lived primordial 238U, 235U, and 232Th. Each isotope also occurs, to some extent, as primordial isotopes that were made in supernovae, rather than radiogenically as daughter products. The fixed ratio of lead-204 to the primordial amounts of the other lead isotopes may be used as the baseline to estimate the extra amounts of radiogenic lead present in rocks as a result of decay from uranium and thorium.
There are seven stable isotopes of mercury (80Hg) with 202Hg being the most abundant (29.86%). The longest-lived radioisotopes are 194Hg with a half-life of 444 years, and 203Hg with a half-life of 46.612 days. Most of the remaining 40 radioisotopes have half-lives that are less than a day. 199Hg and 201Hg are the most often studied NMR-active nuclei, having spin quantum numbers of 1/2 and 3/2 respectively. All isotopes of mercury are either radioactive or observationally stable, meaning that they are predicted to be radioactive but no actual decay has been observed. These isotopes are predicted to undergo either alpha decay or double beta decay.
Antimony (51Sb) occurs in two stable isotopes, 121Sb and 123Sb. There are 35 artificial radioactive isotopes, the longest-lived of which are 125Sb, with a half-life of 2.75856 years; 124Sb, with a half-life of 60.2 days; and 126Sb, with a half-life of 12.35 days. All other isotopes have half-lives less than 4 days, most less than an hour.
Naturally occurring titanium (22Ti) is composed of five stable isotopes; 46Ti, 47Ti, 48Ti, 49Ti and 50Ti with 48Ti being the most abundant. Twenty-one radioisotopes have been characterized, with the most stable being 44Ti with a half-life of 60 years, 45Ti with a half-life of 184.8 minutes, 51Ti with a half-life of 5.76 minutes, and 52Ti with a half-life of 1.7 minutes. All of the remaining radioactive isotopes have half-lives that are less than 33 seconds, and the majority of these have half-lives that are less than half a second.
Although phosphorus (15P) has 22 isotopes from 26P to 47P, only 31P is stable; as such, phosphorus is considered a monoisotopic element. The longest-lived radioactive isotopes are 33P with a half-life of 25.34 days and 32P with a half-life of 14.268 days. All others have half-lives of under 2.5 minutes, most under a second. The least stable known isotope is 47P, with a half-life of 2 milliseconds.
Aluminium or aluminum (13Al) has 22 known isotopes from 22Al to 43Al and 4 known isomers. Only 27Al (stable isotope) and 26Al (radioactive isotope, t1/2 = 7.2×105 y) occur naturally, however 27Al comprises nearly all natural aluminium. Other than 26Al, all radioisotopes have half-lives under 7 minutes, most under a second. The standard atomic weight is 26.9815385(7). 26Al is produced from argon in the atmosphere by spallation caused by cosmic-ray protons. Aluminium isotopes have found practical application in dating marine sediments, manganese nodules, glacial ice, quartz in rock exposures, and meteorites. The ratio of 26Al to 10Be has been used to study the role of sediment transport, deposition, and storage, as well as burial times, and erosion, on 105 to 106 year time scales. 26Al has also played a significant role in the study of meteorites.
Although there are nine known isotopes of helium (2He), only helium-3 and helium-4 are stable. All radioisotopes are short-lived, the longest-lived being 6
He
with a half-life of 806.92(24) milliseconds. The least stable is 10
He
, with a half-life of 260(40) yoctoseconds, although it is possible that 2
He
may have an even shorter half-life.
Bohrium (107Bh) is an artificial element. Like all artificial elements, it has no stable isotopes, and a standard atomic weight cannot be given. The first isotope to be synthesized was 262Bh in 1981. There are 11 known isotopes ranging from 260Bh to 274Bh, and 1 isomer, 262mBh. The longest-lived isotope is 270Bh with a half-life of 2.4 minutes, although the unconfirmed 278Bh may have an even longer half-life of about 690 seconds.
Darmstadtium (110Ds) is a synthetic element, and thus a standard atomic weight cannot be given. Like all synthetic elements, it has no stable isotopes. The first isotope to be synthesized was 269Ds in 1994. There are 11 known radioisotopes from 267Ds to 281Ds and 2 or 3 known isomers. The longest-lived isotope is 281Ds with a half-life of 14 seconds.
Nihonium (113Nh) is a synthetic element. Being synthetic, a standard atomic weight cannot be given and like all artificial elements, it has no stable isotopes. The first isotope to be synthesized was 284Nh as a decay product of 288Mc in 2003. The first isotope to be directly synthesized was 278Nh in 2004. There are 6 known radioisotopes from 278Nh to 286Nh, along with the unconfirmed 287Nh and 290Nh. The longest-lived isotope is 286Nh with a half-life of 9.5 seconds.
Flerovium (114Fl) is a synthetic element, and thus a standard atomic weight cannot be given. Like all synthetic elements, it has no stable isotopes. The first isotope to be synthesized was 289Fl in 1999. Flerovium has six known isotopes, along with the unconfirmed 290Fl, and possibly two nuclear isomers. The longest-lived isotope is 289Fl with a half-life of 1.9 seconds, but 290Fl may have a longer half-life of 19 seconds.
Unbiquadium, also known as element 124 or eka-uranium, is a hypothetical chemical element; it has placeholder symbol Ubq and atomic number 124. Unbiquadium and Ubq are the temporary IUPAC name and symbol, respectively, until the element is discovered, confirmed, and a permanent name is decided upon. In the periodic table, unbiquadium is expected to be a g-block superactinide and the sixth element in the 8th period. Unbiquadium has attracted attention, as it may lie within the island of stability, leading to longer half-lives, especially for 308Ubq which is predicted to have a magic number of neutrons (184).