Isotopes of fluorine

Last updated
Isotopes of fluorine  (9F)
Main isotopes Decay
abun­dance half-life (t1/2) mode pro­duct
18F trace 109.734 min β+ 18O
19F 100% stable
[1]
Standard atomic weight Ar°(F)
  • 18.998403162±0.000000005
  • 18.998±0.001 (abridged) [2] [3]

Fluorine (9F) has 18 known isotopes ranging from 13
F
to 31
F
(with the exception of 30
F
) and two isomers (18m
F
and 26m
F
). Only fluorine-19 is stable and naturally occurring in more than trace quantities; therefore, fluorine is a monoisotopic and mononuclidic element.

Contents

The longest-lived radioisotope is 18
F
; it has a half-life of 109.734(8) min. All other fluorine isotopes have half-lives of less than a minute, and most of those less than a second. The least stable known isotope is 14
F
, whose half-life is 500(60) yoctoseconds, [4] corresponding to a resonance width of 910(100) keV.

List of isotopes

Nuclide [5]
[n 1]
Z N Isotopic mass (Da) [6]
[n 2] [n 3]
Half-life
[n 4]
Decay
mode

[n 5]
Daughter
isotope

[n 6]
Spin and
parity
[n 7] [n 4]
Natural abundance (mole fraction)
Excitation energyNormal proportionRange of variation
13
F
[7]
9413.045120(540)# p  ? [n 8] 12
O
 ?
1/2+#
14
F
9514.034320(40)500(60) ys
[910(100) keV]
p  ? [n 8] 13
O
 ?
2−
15
F
9615.017785(15)1.1(3) zs
[376 keV]
p14
O
1/2+
16
F
9716.011460(6)21(5) zs
[21.3(5.1) keV]
p15
O
0−
17
F
[n 9]
9817.00209524(27)64.370(27) s β+ 17
O
5/2+
18
F
[n 10]
9918.0009373(5)109.734(8) minβ+18
O
1+Trace
18m
F
1121.36(15) keV162(7) ns IT 18
F
5+
19
F
91018.998403162067(883)Stable1/2+1
20
F
91119.99998125(3)11.0062(80) sβ20
Ne
2+
21
F
91220.9999489(19)4.158(20) sβ21
Ne
5/2+
22
F
91322.002999(13)4.23(4) sβ (> 89%)22
Ne
(4+)
βn (< 11%)21
Ne
23
F
91423.003530(40)2.23(14) sβ (> 86%)23
Ne
5/2+
βn (< 14%)22
Ne
24
F
91524.008100(100)384(16) msβ (> 94.1%)24
Ne
3+
βn (< 5.9%)23
Ne
25
F
91625.012170(100)80(9) msβ (76.9(4.5)%)25
Ne
(5/2+)
βn (23.1(4.5)%)24
Ne
β2n ? [n 8] 23
Ne
 ?
26
F
91726.020050(110)8.2(9) msβ (86.5(4.0)%)26
Ne
1+
βn (13.5(4.0)%)25
Ne
β2n ? [n 8] 24
Ne
 ?
26m
F
643.4(1) keV2.2(1) msIT (82(11)%)26
F
(4+)
βn (12(8)%)25
Ne
β ? [n 8] 26
Ne
 ?
27
F
91827.026980(130)5.0(2) msβn (77(21)%)26
Ne
5/2+#
β (23(21)%)27
Ne
β2n ? [n 8] 25
Ne
 ?
28
F
91928.035860(130)46 zsn27
F
(4−)
29
F
92029.043100(560)2.5(3) msβn (60(40)%)28
Ne
(5/2+)
β (40(40)%)29
Ne
β2n ? [n 8] 27
Ne
 ?
31
F
92231.06020(570)#2 ms# [> 260 ns]β ? [n 8] 31
Ne
 ?
5/2+#
βn ? [n 8] 30
Ne
 ?
β2n ? [n 8] 29
Ne
 ?
This table header & footer:
  1. mF  Excited nuclear isomer.
  2. ()  Uncertainty (1σ) is given in concise form in parentheses after the corresponding last digits.
  3. #  Atomic mass marked #: value and uncertainty derived not from purely experimental data, but at least partly from trends from the Mass Surface (TMS).
  4. 1 2 #  Values marked # are not purely derived from experimental data, but at least partly from trends of neighboring nuclides (TNN).
  5. Modes of decay:
    EC: Electron capture
    IT: Isomeric transition
    n: Neutron emission
    p: Proton emission
  6. Bold symbol as daughter  Daughter product is stable.
  7. () spin value  Indicates spin with weak assignment arguments.
  8. 1 2 3 4 5 6 7 8 9 10 Decay mode shown is energetically allowed, but has not been experimentally observed to occur in this nuclide.
  9. Intermediate product of various CNO cycles in stellar nucleosynthesis as part of the process producing helium from hydrogen
  10. Has medicinal uses

Fluorine-18

Of the unstable nuclides of fluorine, 18
F
has the longest half-life, 109.734(8) min. It decays to 18
O
via β+ decay. For this reason 18
F
is a commercially important source of positrons. Its major value is in the production of the radiopharmaceutical fludeoxyglucose, used in positron emission tomography in medicine.

Fluorine-18 is the lightest unstable nuclide with equal odd numbers of protons and neutrons, having 9 of each. (See also the "magic numbers" discussion of nuclide stability.) [8]

Fluorine-19

Fluorine-19 is the only stable isotope of fluorine. Its abundance is 100%; no other isotopes of fluorine exist in significant quantities. Its binding energy is 147801.3648(38) keV. Fluorine-19 is NMR-active with a spin of 1/2+, so it is used in fluorine-19 NMR spectroscopy.

Fluorine-20

Fluorine-20 is an unstable isotope of fluorine. It has a half-life of 11.0062(80) s and decays via beta decay to the stable nuclide 20
Ne
. Its specific radioactivity is 1.8693(14)×10+21 Bq/g and has a mean lifetime of 15.879(12) s.

Fluorine-21

Fluorine-21, as with fluorine-20, is also an unstable isotope of fluorine. It has a half-life of 4.158(20) s. It undergoes beta decay as well, decaying to 21
Ne
, which is a stable nuclide. Its specific activity is 4.781(23)×10+21 Bq/g.

Isomers

Only two nuclear isomers (long-lived excited nuclear states), fluorine-18m and fluorine-26m, have been characterized. [4] The half-life of 18m
F
before it undergoes isomeric transition is 162(7)  nanoseconds . [4] This is less than the decay half-life of any of the fluorine radioisotope nuclear ground states except for mass numbers 14–16, 28, and 31. [9] The half-life of 26m
F
is 2.2(1) milliseconds; it decays mainly to its ground state of 26
F
or (rarely, via beta-minus decay) to one of high excited states of 26
Ne
with delayed neutron emission. [4]

Related Research Articles

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There are 42 isotopes of polonium (84Po). They range in size from 186 to 227 nucleons. They are all radioactive. 210Po with a half-life of 138.376 days has the longest half-life of any naturally-occurring isotope of polonium and is the most common isotope of polonium. It is also the most easily synthesized polonium isotope. 209Po, which does not occur naturally, has the longest half-life of all isotopes of polonium at 125.2 years. 209Po can be made by using a cyclotron to bombard bismuth with protons, as can 208Po.

Bismuth (83Bi) has 41 known isotopes, ranging from 184Bi to 224Bi. Bismuth has no stable isotopes, but does have one very long-lived isotope; thus, the standard atomic weight can be given as 208.98040(1). Although bismuth-209 is now known to be radioactive, it has classically been considered to be a stable isotope because it has a half-life of approximately 2.01×1019 years, which is more than a billion times the age of the universe. Besides 209Bi, the most stable bismuth radioisotopes are 210mBi with a half-life of 3.04 million years, 208Bi with a half-life of 368,000 years and 207Bi, with a half-life of 32.9 years, none of which occurs in nature. All other isotopes have half-lives under 1 year, most under a day. Of naturally occurring radioisotopes, the most stable is radiogenic 210Bi with a half-life of 5.012 days. 210mBi is unusual for being a nuclear isomer with a half-life multiple orders of magnitude longer than that of the ground state.

<span class="mw-page-title-main">Isotopes of thallium</span> Nuclides with atomic number of 81 but with different mass numbers

Thallium (81Tl) has 41 isotopes with atomic masses that range from 176 to 216. 203Tl and 205Tl are the only stable isotopes and 204Tl is the most stable radioisotope with a half-life of 3.78 years. 207Tl, with a half-life of 4.77 minutes, has the longest half-life of naturally occurring Tl radioisotopes. All isotopes of thallium are either radioactive or observationally stable, meaning that they are predicted to be radioactive but no actual decay has been observed.

There are seven stable isotopes of mercury (80Hg) with 202Hg being the most abundant (29.86%). The longest-lived radioisotopes are 194Hg with a half-life of 444 years, and 203Hg with a half-life of 46.612 days. Most of the remaining 40 radioisotopes have half-lives that are less than a day. 199Hg and 201Hg are the most often studied NMR-active nuclei, having spin quantum numbers of 1/2 and 3/2 respectively. All isotopes of mercury are either radioactive or observationally stable, meaning that they are predicted to be radioactive but no actual decay has been observed. These isotopes are predicted to undergo either alpha decay or double beta decay.

There are two natural isotopes of iridium (77Ir), and 37 radioisotopes, the most stable radioisotope being 192Ir with a half-life of 73.83 days, and many nuclear isomers, the most stable of which is 192m2Ir with a half-life of 241 years. All other isomers have half-lives under a year, most under a day. All isotopes of iridium are either radioactive or observationally stable, meaning that they are predicted to be radioactive but no actual decay has been observed.

Naturally occurring erbium (68Er) is composed of 6 stable isotopes, with 166Er being the most abundant. 39 radioisotopes have been characterized with between 74 and 112 neutrons, or 142 to 180 nucleons, with the most stable being 169Er with a half-life of 9.4 days, 172Er with a half-life of 49.3 hours, 160Er with a half-life of 28.58 hours, 165Er with a half-life of 10.36 hours, and 171Er with a half-life of 7.516 hours. All of the remaining radioactive isotopes have half-lives that are less than 3.5 hours, and the majority of these have half-lives that are less than 4 minutes. This element also has numerous meta states, with the most stable being 167mEr.

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<span class="mw-page-title-main">Isotopes of silicon</span> Nuclides with atomic number of 14 but with different mass numbers

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Na
to 39
Na
, and two isomers. 23
Na
is the only stable isotope. It is considered a monoisotopic element and it has a standard atomic weight of 22.98976928(2). Sodium has two radioactive cosmogenic isotopes. With the exception of those two isotopes, all other isotopes have half-lives under a minute, most under a second. The shortest-lived is 18
Na
, with a half-life of 1.3(4)×10−21 seconds.

<span class="mw-page-title-main">Isotopes of magnesium</span> Nuclides with atomic number of 12 but with different mass numbers

Magnesium (12Mg) naturally occurs in three stable isotopes: 24
Mg
, 25
Mg
, and 26
Mg
. There are 19 radioisotopes that have been discovered, ranging from 18
Mg
to 40
Mg
. The longest-lived radioisotope is 28
Mg
with a half-life of 20.915(9) h. The lighter isotopes mostly decay to isotopes of sodium while the heavier isotopes decay to isotopes of aluminium. The shortest-lived is proton-unbound 19
Mg
with a half-life of 5(3) picoseconds, though the half-life of similarly unbound 18
Mg
has not been measured.

<span class="mw-page-title-main">Isotopes of neon</span> Nuclides with atomic number of 10 but with different mass numbers

Neon (10Ne) possesses three stable isotopes: 20
Ne
, 21
Ne
, and 22
Ne
. In addition, 17 radioactive isotopes have been discovered, ranging from 15
Ne
to 34
Ne
, all short-lived. The longest-lived is 24
Ne
with a half-life of 3.38(2) min. All others are under a minute, most under a second. The least stable is 15
Ne
with a half-life of 770(300) ys. See isotopes of carbon for notes about the measurement. Light radioactive neon isotopes usually decay to fluorine or oxygen, while heavier ones decay to sodium.

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Am
being an order of magnitude longer lived than 241
Am
, the former is harder to obtain than the latter as more of it is present in spent nuclear fuel.

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Mendelevium (101Md) is a synthetic element, and thus a standard atomic weight cannot be given. Like all artificial elements, it has no stable isotopes. The first isotope to be synthesized was 256Md in 1955. There are 17 known radioisotopes, ranging in atomic mass from 244Md to 260Md, and 5 isomers. The longest-lived isotope is 258Md with a half-life of 51.3 days, and the longest-lived isomer is 258mMd with a half-life of 57 minutes.

References

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  5. Half-life, decay mode, nuclear spin, and isotopic composition is sourced in:
    Kondev, F. G.; Wang, M.; Huang, W. J.; Naimi, S.; Audi, G. (2021). "The NUBASE2020 evaluation of nuclear properties" (PDF). Chinese Physics C. 45 (3): 030001. doi:10.1088/1674-1137/abddae.
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  7. Charity, R. J. (2 April 2021). "Observation of the Exotic Isotope 13 F Located Four Neutrons beyond the Proton Drip Line". Physical Review Letters. 126 (13): 2501. Bibcode:2021PhRvL.126m2501C. doi:10.1103/PhysRevLett.126.132501. OSTI   1773500. PMID   33861136. S2CID   233259561 . Retrieved 5 April 2021.
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Sources