Silver(I,III) oxide

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Silver(I,III) oxide
AgO-monoclinic-xtal-2x2x2-oxcol-3D-bs-17.png
Ag(I) Ag(III) O
Names
IUPAC name
silver(I,III) Oxide
Other names
tetrasilver tetroxide, silver peroxide, argentic oxide, silver suboxide, divasil
Identifiers
3D model (JSmol)
ECHA InfoCard 100.013.726 OOjs UI icon edit-ltr-progressive.svg
EC Number
  • 215-098-2
PubChem CID
UNII
  • InChI=1S/4Ag.4O
    Key: RARXNJBGGSMBMG-UHFFFAOYSA-N
  • [Ag]O[Ag].O=[Ag]O[Ag]=O
Properties
Ag4O4

Ag2O.Ag2O3

Molar mass 123.87 g/mol
Appearancegrey-black powder
diamagnetic
Density 7.48 g/cm3
Melting point >100 °C, decomposition
.0027 g/100 mL
Solubility soluble in alkalis
Hazards
GHS labelling:
GHS-pictogram-rondflam.svg GHS-pictogram-acid.svg GHS-pictogram-exclam.svg GHS-pictogram-pollu.svg
Danger
H272, H315, H319, H335
NFPA 704 (fire diamond)
NFPA 704.svgHealth 3: Short exposure could cause serious temporary or residual injury. E.g. chlorine gasFlammability 0: Will not burn. E.g. waterInstability 1: Normally stable, but can become unstable at elevated temperatures and pressures. E.g. calciumSpecial hazards (white): no code
3
0
1
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Silver(I,III) oxide or tetrasilver tetroxide is the inorganic compound with the formula Ag4O4. It is a component of silver zinc batteries. It can be prepared by the slow addition of a silver(I) salt to a persulfate solution e.g. AgNO3 to a Na2S2O8 solution. [1] It adopts an unusual structure, being a mixed-valence compound. [2] It is a dark brown solid that decomposes with evolution of O2 in water. It dissolves in concentrated nitric acid to give brown solutions containing the Ag2+ ion. [3]

Contents

Structure

Although its empirical formula, AgO, suggests that the compound tetrasilver tetraoxide has silver in the +2 oxidation state, each unit has two monovalent silver atoms bonded to an oxygen atom, and two trivalent silver atoms bonded to three oxygen atoms, and it is in fact diamagnetic. X-ray diffraction studies show that the silver atoms adopt two different coordination environments, one having two collinear oxide neighbours and the other four coplanar oxide neighbours. [1] tetrasilver tetraoxide is therefore formulated as AgIAgIIIO2 [4] or Ag2O·Ag2O3. It has previously been called silver peroxide, which is incorrect since it does not contain the peroxide ion, O22−.

Uses

Tetrasilver tetroxide has been marketed under a trade name "Tetrasil." In 2010, the FDA issued a warning letter to an American company concerning the firm's marketing of Tetrasil and Genisil ointments of tetrasilver tetroxide for herpes and similar conditions. [5]

Related Research Articles

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<span class="mw-page-title-main">Coordination complex</span> Molecule or ion containing ligands datively bonded to a central metallic atom

A coordination complex is a chemical compound consisting of a central atom or ion, which is usually metallic and is called the coordination centre, and a surrounding array of bound molecules or ions, that are in turn known as ligands or complexing agents. Many metal-containing compounds, especially those that include transition metals, are coordination complexes.

<span class="mw-page-title-main">Oxide</span> Chemical compound where oxygen atoms are combined with atoms of other elements

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<span class="mw-page-title-main">Osmium tetroxide</span> Chemical compound

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<span class="mw-page-title-main">Ferrous</span> The element iron in its +2 oxidation state

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<span class="mw-page-title-main">Oxidizing agent</span> Chemical compound used to oxidize another substance in a chemical reaction

An oxidizing agent is a substance in a redox chemical reaction that gains or "accepts"/"receives" an electron from a reducing agent. In other words, an oxidizer is any substance that oxidizes another substance. The oxidation state, which describes the degree of loss of electrons, of the oxidizer decreases while that of the reductant increases; this is expressed by saying that oxidizers "undergo reduction" and "are reduced" while reducers "undergo oxidation" and "are oxidized". Common oxidizing agents are oxygen, hydrogen peroxide, and the halogens.

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<span class="mw-page-title-main">Iron(II) hydroxide</span> Chemical compound

Iron (II) hydroxide or ferrous hydroxide is an inorganic compound with the formula Fe(OH)2. It is produced when iron (II) salts, from a compound such as iron(II) sulfate, are treated with hydroxide ions. Iron(II) hydroxide is a white solid, but even traces of oxygen impart a greenish tinge. The air-oxidised solid is sometimes known as "green rust".

<span class="mw-page-title-main">Silver(II) fluoride</span> Chemical compound

Silver(II) fluoride is a chemical compound with the formula AgF2. It is a rare example of a silver(II) compound - silver usually exists in its +1 oxidation state. It is used as a fluorinating agent.

An oxyacid, oxoacid, or ternary acid is an acid that contains oxygen. Specifically, it is a compound that contains hydrogen, oxygen, and at least one other element, with at least one hydrogen atom bonded to oxygen that can dissociate to produce the H+ cation and the anion of the acid.

<span class="mw-page-title-main">Uranate</span>

A uranate is a ternary oxide involving the element uranium in one of the oxidation states 4, 5 or 6. A typical chemical formula is MxUyOz, where M represents a cation. The uranium atom in uranates(VI) has two short collinear U–O bonds and either four or six more next nearest oxygen atoms. The structures are infinite lattice structures with the uranium atoms linked by bridging oxygen atoms.

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<span class="mw-page-title-main">Antimony tetroxide</span> Chemical compound

Antimony tetroxide is an inorganic compound with the formula Sb2O4. This material, which exists as the mineral cervantite, is white but reversibly yellows upon heating. The material, with empirical formula SbO2, is called antimony tetroxide to signify the presence of two kinds of Sb centers.

<span class="mw-page-title-main">Bromous acid</span> Chemical compound

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<span class="mw-page-title-main">Hydrogen polyoxide</span> Chemical compound

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References

  1. 1 2 Wells A.F. (1984) Structural Inorganic Chemistry 5th edition Oxford Science Publications ISBN   0-19-855370-6
  2. David Tudela "Silver(II) Oxide or Silver(I,III) Oxide?" J. Chem. Educ., 2008, volume 85, p 863. doi : 10.1021/ed085p863
  3. Peter Fischer, Martin Jansen "Electrochemical Syntheses of Binary Silver Oxides" 1995, vol. 30, pp. 50–55. doi : 10.1002/9780470132616.ch11
  4. Greenwood, Norman N.; Earnshaw, Alan (1997). Chemistry of the Elements (2nd ed.). Butterworth-Heinemann. ISBN   978-0-08-037941-8. p. 1181.
  5. "FDA Warning Letter to Aidance Skincare and Topical Solutions, LLC | Quackwatch". 19 July 2010.