Dysprosium(III) bromide

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Dysprosium(III) bromide
Kristallstruktur Bismut(III)-iodid.png
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.034.933 OOjs UI icon edit-ltr-progressive.svg
EC Number
  • 238-443-9
PubChem CID
  • InChI=1S/3BrH.Dy/h3*1H;/q;;;+3/p-3
    Key: GBLDKMKYYYAAKD-UHFFFAOYSA-K
  • [Br-].[Br-].[Br-].[Dy+3]
Properties
Appearancecolourless solid (anhydrous) [1]
white solid (hexahydrate) [2]
Density 5.8 g·cm−3 [3]
Melting point 881 °C (1,154 K) [1]
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

Dysprosium(III) bromide is an inorganic compound of bromine and dysprosium, with the chemical formula of DyBr3.

Contents

Preparation

Dysprosium(III) bromide can be obtained by reacting dysprosium with bromine: [4]

2Dy + 3Br2 → 2DyBr3

Dysprosium bromide hexahydrate can be obtained by crystallization from its solution, [2] which can be heated with ammonium bromide in vacuum to obtain the anhydrous form. [1]

Dysprosium(III) oxide and aluminium bromide (in the form of Al2Br6 at a high temperature react a DyAl3Br12, which decomposes to dysprosium(III) bromide at a lower temperature: [5]

Dy2O3 + Al2Br6 → Al2O3 + 2 DyBr3

Properties

Dysprosium(III) bromide is a white-gray hygroscopic solid that is soluble in water. [6] It has a trigonal crystal structure of the bismuth(III) iodide type with space group R3 (No. 148). [7]

References

  1. 1 2 3 Jantsch, G.; Jawurek, H.; Skalla, N.; Gawalowski, H. Halides of the rare earths. VI. Halides of the terbium and erbium earth groups. Zeitschrift fuer Anorganische und Allgemeine Chemie, 1932. 207. 353-367. ISSN   0044-2313.
  2. 1 2 D. Brown, S. Fletcher, D. G. Holah (1968). "The preparation and crystallographic properties of certain lanthanide and actinide tribromides and tribromide hexahydrates" . Journal of the Chemical Society A: Inorganic, Physical, Theoretical: 1889–1894. doi:10.1039/j19680001889. ISSN   0022-4944 . Retrieved 2020-05-29.{{cite journal}}: CS1 maint: multiple names: authors list (link)
  3. ↑ Roger Blachnik (Hrsg.): Taschenbuch für Chemiker und Physiker. Band III: Elemente, anorganische Verbindungen und Materialien, Minerale. begründet von Jean d’Ans, Ellen Lax. 4., neubearbeitete und revidierte Auflage. Springer, Berlin 1998, ISBN 3-540-60035-3, S. 442, 1386
  4. ↑ WebElements: Chemical reactions of Dysprosium
  5. ↑ 杨冬梅, 于锦, 蒋军辉,等. 化学气相传输法制备无水溴化镝. 石油化工高等学校学报, 2003, 16(4). doi: 10.3969/j.issn.1006-396X.2003.04.004.
  6. ↑ Dysprosium(III) bromide, ultra dry, 99.99% (REO) at AlfaAesar, accessed on 2013-10-30 ( PDF ) (JavaScript required).[ dead link ]
  7. ↑ Ans, Jean d'; Lax, Ellen (December 1997). Taschenbuch für Chemiker und Physiker. Springer. pp. 442, 1386. ISBN   3540600353.
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